AR038976A1 - Complejos de metal de indenilo sustituido y procedimiento de polimerizacion - Google Patents
Complejos de metal de indenilo sustituido y procedimiento de polimerizacionInfo
- Publication number
- AR038976A1 AR038976A1 ARP030100906A ARP030100906A AR038976A1 AR 038976 A1 AR038976 A1 AR 038976A1 AR P030100906 A ARP030100906 A AR P030100906A AR P030100906 A ARP030100906 A AR P030100906A AR 038976 A1 AR038976 A1 AR 038976A1
- Authority
- AR
- Argentina
- Prior art keywords
- group
- hydrogen
- substituted
- atoms
- independently
- Prior art date
Links
- 239000002184 metal Substances 0.000 title abstract 3
- 238000006116 polymerization reaction Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 7
- 229910052739 hydrogen Inorganic materials 0.000 abstract 5
- 239000001257 hydrogen Substances 0.000 abstract 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 125000000129 anionic group Chemical group 0.000 abstract 2
- 125000004429 atom Chemical group 0.000 abstract 2
- 125000004122 cyclic group Chemical group 0.000 abstract 2
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 2
- 125000003114 inden-1-yl group Chemical group [H]C1=C([H])C([H])(*)C2=C([H])C([H])=C([H])C([H])=C12 0.000 abstract 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000005842 heteroatom Chemical group 0.000 abstract 1
- -1 hydrocarbyloxy Chemical group 0.000 abstract 1
- 150000002736 metal compounds Chemical class 0.000 abstract 1
- 230000007935 neutral effect Effects 0.000 abstract 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 abstract 1
- 230000000737 periodic effect Effects 0.000 abstract 1
- 239000002685 polymerization catalyst Substances 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/02—Cp or analog bridged to a non-Cp X anionic donor
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
Se relevan complejos de metal que comprenden un grupo inden-1-ilo sustituido o derivado del mismo hidrógeno o parcialmente hidrogenado, en donde dicho grupo es sustituido por lo menos en la posición 2 del mismo con un grupo ligante C4-30 que contiene un patrón de sustitución secundaria o terciaria en el carbono b del mismo; catalizadores de polimerización, y procedimientos de polimerización de olefina que utilizan los mismos. Reivindicación 1: Un compuesto de metal que corresponde a la fórmula: CpM(Z)z(X)x(T)t(X')x', Cp es un grupo inden-1-ilo sustituido o un derivado parcialmente hidrogenado del mismo, en donde dicho grupo es sustituido por lo menos en la posición 2 del mismo con un alquilo C4-30, aralquilo, o grupo trihidrocarbilsililhidrocarbilo o un derivado del mismo que contiene heteroátomo Grupo 15 o 16, en donde dicho grupo contiene 2 ó 3 sustituyentes que no son hidrógeno en una posición-? del mismo; M es un metal seleccionado entre los Grupos 3-10 o la serie Lantanida de la Tabla Periódica de Elementos; Z es una parte divalente de la fórmula -Z'Y- que une Cp y M, en donde Z' ese SIR62, CR62, SIR62CR62, CR6=CR6, CR62SIR62, BR6, o GeR62, unido en la posición 1 Cp; Y' es -O-, -S-, -NR5-, -PR5-; NR5-, o -PR52; R5, independientemente en cada caso, es hidrocarbilo, trihidrocarbilsililo o trihidrocarbilsililhidrocarbilo, en donde dicho R5 posee hasta 20 átomos que no sean hidrógeno, y opcionalmente dos grupos R5 o R5 junto con Y forman un sistema de anillo; R6, independientemente en cada caso, es hidrógeno, o un miembro seleccionado entre hidrocarbilo, hidrocarbiloxi, sililo, alquilo halogenado, arilo halogenado, -NR52, y combinaciones de los mismos, en donde dicho R6 posee hasta 30 átomos que no son hidrógenos, y opcionalmente dos grupos R6 forman un sistema de anillo; X es hidrógeno o un grupo ligante aniónico monovalente que posee hasta 60 átomos que no cuentan con hidrógeno; T independientemente en cada caso, es un compuesto ligante neutral que posee hasta 20 átomos, que no son hidrógeno, y opcionalmente T y X se unen; X' es un grupo ligante aniónico divalente que posee hasta 60 átomos que no son hidrógeno; z es 0, 1 ó 2; x 0, 1, 2 ó 3; t es un número de 0 a 2, y x' es 0 ó 1.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US36470602P | 2002-03-14 | 2002-03-14 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR038976A1 true AR038976A1 (es) | 2005-02-02 |
Family
ID=28041952
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP030100906A AR038976A1 (es) | 2002-03-14 | 2003-03-14 | Complejos de metal de indenilo sustituido y procedimiento de polimerizacion |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US7098356B2 (es) |
| EP (1) | EP1487886B1 (es) |
| JP (2) | JP4624679B2 (es) |
| KR (2) | KR101002620B1 (es) |
| CN (1) | CN100484973C (es) |
| AR (1) | AR038976A1 (es) |
| AT (1) | ATE403684T1 (es) |
| AU (1) | AU2003216476A1 (es) |
| CA (1) | CA2477776C (es) |
| DE (1) | DE60322684D1 (es) |
| ES (1) | ES2307956T3 (es) |
| SA (1) | SA03240063B1 (es) |
| WO (1) | WO2003078483A1 (es) |
Families Citing this family (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4624679B2 (ja) * | 2002-03-14 | 2011-02-02 | ダウ グローバル テクノロジーズ インコーポレイティド | 置換インデニル金属錯体及び重合方法 |
| CN1934150A (zh) | 2004-03-17 | 2007-03-21 | 陶氏环球技术公司 | 用于形成乙烯共聚物的包括穿梭剂的催化剂组合物 |
| SG151302A1 (en) | 2004-03-17 | 2009-04-30 | Dow Global Technologies Inc | Catalyst composition comprising shuttling agent for higher olefin multi- block copolymer formation |
| EP2221329B1 (en) | 2004-03-17 | 2014-11-26 | Dow Global Technologies LLC | Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation |
| CN1968973B (zh) | 2004-06-16 | 2011-08-17 | 陶氏环球技术有限责任公司 | 选择聚合改性剂的方法 |
| MX2007011337A (es) | 2005-03-17 | 2007-10-02 | Dow Global Technologies Inc | Composicion de catalizador que comprende un agente de transporte para la formacion de copolimero de bloques multiples tactico/atactico. |
| CN101142245B (zh) | 2005-03-17 | 2012-08-08 | 陶氏环球技术有限责任公司 | 用于形成立体无规多嵌段共聚物的包含梭移剂的催化剂组合物 |
| US9410009B2 (en) | 2005-03-17 | 2016-08-09 | Dow Global Technologies Llc | Catalyst composition comprising shuttling agent for tactic/ atactic multi-block copolymer formation |
| CN101331164B (zh) | 2005-09-15 | 2011-03-23 | 陶氏环球技术公司 | 经由多中心穿梭剂控制聚合物结构和分子量分布 |
| ITMI20070878A1 (it) | 2007-05-02 | 2008-11-03 | Dow Global Technologies Inc | Processo per la polimerizzazine di polimeri tattici con l'uso di catalizzatori chirali |
| ITMI20070877A1 (it) | 2007-05-02 | 2008-11-03 | Dow Global Technologies Inc | Processo per la produzione di copolimeri a blocchi multipli con l'utilizzo di solventi polari |
| KR101621703B1 (ko) | 2009-07-29 | 2016-05-17 | 다우 글로벌 테크놀로지스 엘엘씨 | 다작용성 쇄 셔틀링제 |
| CN102822180B (zh) | 2010-02-19 | 2016-06-15 | 陶氏环球技术有限责任公司 | 金属配体配合物和催化剂 |
| ES2738498T3 (es) | 2010-02-19 | 2020-01-23 | Dow Global Technologies Llc | Proceso para polimerizar un monómero de olefina y catalizador para el mismo |
| WO2012103080A1 (en) | 2011-01-26 | 2012-08-02 | Dow Global Technologies Llc | Process for making a polyolefin-polysiloxane block copolymer |
| WO2012155022A1 (en) | 2011-05-12 | 2012-11-15 | Dow Global Technologies Llc | Non-cyclopentadienyl-based chromium catalysts for olefin polymerization |
| KR101212637B1 (ko) | 2011-06-09 | 2012-12-14 | 에스케이종합화학 주식회사 | 신규한 사이클로펜타［ｂ］플루오레닐 전이금속 화합물, 이를 포함하는 전이금속 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법 |
| CN103890023B (zh) | 2011-10-24 | 2016-11-16 | 三菱化学株式会社 | 热塑性弹性体组合物及其制造方法 |
| KR101774615B1 (ko) * | 2013-12-02 | 2017-09-04 | 주식회사 엘지화학 | 인덴기를 갖는 메탈로센형 촉매 및 이를 이용한 올레핀 중합체의 제조방법 |
| US10723816B2 (en) | 2015-09-30 | 2020-07-28 | Dow Global Technologies Llc | Multi- or dual-headed compositions useful for chain shuttling and process to prepare the same |
| WO2018064540A1 (en) | 2016-09-30 | 2018-04-05 | Dow Global Technologies Llc | Process for preparing multi- or dual-headed compositions useful for chain shuttling |
| CN109937217B (zh) | 2016-09-30 | 2021-09-14 | 陶氏环球技术有限责任公司 | 适用于链梭移的多头或双头组合物和其制备方法 |
| EP3519456B1 (en) | 2016-09-30 | 2024-07-03 | Dow Global Technologies Llc | Capped multi- or dual-headed compositions useful for chain shuttling and process to prepare the same |
| EP3596143B1 (en) | 2017-03-15 | 2023-04-26 | Dow Global Technologies LLC | Catalyst system for multi-block copolymer formation |
| EP3596142B1 (en) | 2017-03-15 | 2023-05-24 | Dow Global Technologies LLC | Catalyst system for multi-block copolymer formation |
| CN110582518B (zh) | 2017-03-15 | 2022-08-09 | 陶氏环球技术有限责任公司 | 用于形成多嵌段共聚物的催化剂体系 |
| EP3596146B1 (en) | 2017-03-15 | 2023-07-19 | Dow Global Technologies LLC | Catalyst system for multi-block copolymer formation |
| EP3596138B1 (en) | 2017-03-15 | 2024-04-03 | Dow Global Technologies LLC | Catalyst system for multi-block copolymer formation |
| KR102643986B1 (ko) * | 2017-09-29 | 2024-03-07 | 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 | 신규한 인덴계 전이금속 화합물, 이를 포함하는 전이금속 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법 |
| WO2019064247A1 (ko) * | 2017-09-29 | 2019-04-04 | 사빅 에스케이 넥슬렌 컴퍼니 피티이 엘티디 | 신규한 인덴계 전이금속 화합물, 이를 포함하는 전이금속 촉매 조성물, 및 이를 이용한 에틸렌 단독중합체 또는 에틸렌과 α-올레핀의 공중합체의 제조방법 |
| BR112020019180A2 (pt) | 2018-03-19 | 2021-01-05 | Dow Global Technologies Llc | Compostos organometálicos terminados em silício e processos para preparar os mesmos |
| EP3865517A4 (en) * | 2019-09-27 | 2022-05-18 | LG Chem, Ltd. | SUPPORTED HYBRID CATALYST AND METHOD OF MAKING POLYOLEFIN THEREWITH |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NZ235032A (en) * | 1989-08-31 | 1993-04-28 | Dow Chemical Co | Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component |
| JP2545006B2 (ja) * | 1990-07-03 | 1996-10-16 | ザ ダウ ケミカル カンパニー | 付加重合触媒 |
| US5721185A (en) * | 1991-06-24 | 1998-02-24 | The Dow Chemical Company | Homogeneous olefin polymerization catalyst by abstraction with lewis acids |
| US5374696A (en) * | 1992-03-26 | 1994-12-20 | The Dow Chemical Company | Addition polymerization process using stabilized reduced metal catalysts |
| US5470993A (en) * | 1993-06-24 | 1995-11-28 | The Dow Chemical Company | Titanium(II) or zirconium(II) complexes and addition polymerization catalysts therefrom |
| US5486632A (en) * | 1994-06-28 | 1996-01-23 | The Dow Chemical Company | Group 4 metal diene complexes and addition polymerization catalysts therefrom |
| US5541349A (en) * | 1994-09-12 | 1996-07-30 | The Dow Chemical Company | Metal complexes containing partially delocalized II-bound groups and addition polymerization catalysts therefrom |
| DE69624839T2 (de) * | 1995-10-27 | 2003-08-28 | The Dow Chemical Co., Midland | Substituierte indenyl enthaltende metallkomplexe und olefinpolymerisierungsverfahren. |
| DE19543427C2 (de) | 1995-11-21 | 2003-01-30 | Infineon Technologies Ag | Chipmodul, insbesondere zum Einbau in eine Chipkarte |
| NZ333877A (en) * | 1996-08-08 | 2000-08-25 | Dow Chemical Co | metal complex of a substituted indene derivative and use of the complex in an olefin polymerization process |
| US6015868A (en) * | 1996-10-03 | 2000-01-18 | The Dow Chemical Company | Substituted indenyl containing metal complexes and olefin polymerization process |
| DE69710491T2 (de) * | 1996-12-19 | 2002-10-02 | The Dow Chemical Co., Midland | Metallkomplexe enthaltend in position 3 arylsubstituierte indenylderivate, und polymerisationsverfahren |
| US5965756A (en) * | 1996-12-19 | 1999-10-12 | The Dow Chemical Company | Fused ring substituted indenyl metal complexes and polymerization process |
| CA2287963A1 (en) * | 1997-04-30 | 1998-11-05 | Debra J. Mangold | Ethylene/alpha-olefin/diene interpolymers and their preparation |
| US6150297A (en) * | 1997-09-15 | 2000-11-21 | The Dow Chemical Company | Cyclopentaphenanthrenyl metal complexes and polymerization process |
| JP4624679B2 (ja) * | 2002-03-14 | 2011-02-02 | ダウ グローバル テクノロジーズ インコーポレイティド | 置換インデニル金属錯体及び重合方法 |
-
2003
- 2003-03-03 JP JP2003576482A patent/JP4624679B2/ja not_active Expired - Fee Related
- 2003-03-03 EP EP03744610A patent/EP1487886B1/en not_active Expired - Lifetime
- 2003-03-03 AU AU2003216476A patent/AU2003216476A1/en not_active Abandoned
- 2003-03-03 US US10/503,828 patent/US7098356B2/en not_active Expired - Lifetime
- 2003-03-03 CN CNB038060108A patent/CN100484973C/zh not_active Expired - Fee Related
- 2003-03-03 AT AT03744610T patent/ATE403684T1/de not_active IP Right Cessation
- 2003-03-03 WO PCT/US2003/006315 patent/WO2003078483A1/en not_active Ceased
- 2003-03-03 KR KR1020047014479A patent/KR101002620B1/ko not_active Expired - Fee Related
- 2003-03-03 CA CA2477776A patent/CA2477776C/en not_active Expired - Fee Related
- 2003-03-03 KR KR1020107019516A patent/KR20100101024A/ko not_active Withdrawn
- 2003-03-03 ES ES03744610T patent/ES2307956T3/es not_active Expired - Lifetime
- 2003-03-03 DE DE60322684T patent/DE60322684D1/de not_active Expired - Lifetime
- 2003-03-14 AR ARP030100906A patent/AR038976A1/es unknown
- 2003-04-02 SA SA03240063A patent/SA03240063B1/ar unknown
-
2010
- 2010-03-17 JP JP2010061305A patent/JP2010189396A/ja not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| CN100484973C (zh) | 2009-05-06 |
| CA2477776A1 (en) | 2003-09-25 |
| EP1487886B1 (en) | 2008-08-06 |
| DE60322684D1 (de) | 2008-09-18 |
| SA03240063B1 (ar) | 2007-12-29 |
| ATE403684T1 (de) | 2008-08-15 |
| JP2005519969A (ja) | 2005-07-07 |
| KR20040091742A (ko) | 2004-10-28 |
| US20050143536A1 (en) | 2005-06-30 |
| CA2477776C (en) | 2011-11-15 |
| KR20100101024A (ko) | 2010-09-15 |
| CN1643004A (zh) | 2005-07-20 |
| KR101002620B1 (ko) | 2010-12-21 |
| ES2307956T3 (es) | 2008-12-01 |
| JP4624679B2 (ja) | 2011-02-02 |
| JP2010189396A (ja) | 2010-09-02 |
| US7098356B2 (en) | 2006-08-29 |
| EP1487886A1 (en) | 2004-12-22 |
| AU2003216476A1 (en) | 2003-09-29 |
| WO2003078483A1 (en) | 2003-09-25 |
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