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AR037115A1 - Proceso y catalizador para la deshidrogenacion de alcoholes primarios en la elaboracion de sales de acido carboxilico - Google Patents

Proceso y catalizador para la deshidrogenacion de alcoholes primarios en la elaboracion de sales de acido carboxilico

Info

Publication number
AR037115A1
AR037115A1 ARP020103935A ARP020103935A AR037115A1 AR 037115 A1 AR037115 A1 AR 037115A1 AR P020103935 A ARP020103935 A AR P020103935A AR P020103935 A ARP020103935 A AR P020103935A AR 037115 A1 AR037115 A1 AR 037115A1
Authority
AR
Argentina
Prior art keywords
catalyst
dehydrogenation
elaboration
acid salts
primary alcohols
Prior art date
Application number
ARP020103935A
Other languages
English (en)
Inventor
David A Morgenstern
Juan Arhancet
Howard Berk
William Moench
James P Coleman
James Peterson
Original Assignee
Monsanto Technology Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Technology Llc filed Critical Monsanto Technology Llc
Publication of AR037115A1 publication Critical patent/AR037115A1/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C227/00—Preparation of compounds containing amino and carboxyl groups bound to the same carbon skeleton
    • C07C227/02—Formation of carboxyl groups in compounds containing amino groups, e.g. by oxidation of amino alcohols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/745—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J25/00—Catalysts of the Raney type
    • B01J25/02—Raney nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/34—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation
    • B01J37/348—Electrochemical processes, e.g. electrochemical deposition or anodisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
    • C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
    • C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/755—Nickel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Plasma & Fusion (AREA)
  • Electrochemistry (AREA)
  • Physics & Mathematics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Proceso para elaborar una sal de un ácido carboxílico. El proceso comprende poner un catalizador en contacto con una mezcla alcalina que comprende alcohol primario. En una realización, el catalizador comprende un soporte de metal (preferentemente un soporte de metal esponjoso que comprende por ejemplo un 10% en peso aproximadamente) que posee una fase activa que contiene cobre sobre la superficie de la misma y hierro como modificador del catalizador. El soporte es resistente a la deformación bajo las condiciones de una reacción de deshidrogenación. También se refiere a catalizadores que contienen níquel que poseen una fase activa que contiene cobre y hierro como modificador del catalizador que se puede utilizar, por ejemplo, en el proceso anterior. La presente se refiere además a procesos para elaborar dichos catalizadores.
ARP020103935A 2001-10-18 2002-10-18 Proceso y catalizador para la deshidrogenacion de alcoholes primarios en la elaboracion de sales de acido carboxilico AR037115A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US33022601P 2001-10-18 2001-10-18

Publications (1)

Publication Number Publication Date
AR037115A1 true AR037115A1 (es) 2004-10-20

Family

ID=23288828

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP020103935A AR037115A1 (es) 2001-10-18 2002-10-18 Proceso y catalizador para la deshidrogenacion de alcoholes primarios en la elaboracion de sales de acido carboxilico

Country Status (10)

Country Link
US (1) US7126024B2 (es)
EP (1) EP1436080A2 (es)
CN (1) CN1729052A (es)
AR (1) AR037115A1 (es)
AU (1) AU2002362929B2 (es)
BR (1) BR0213428A (es)
CA (1) CA2463776A1 (es)
IN (1) IN2004CH00786A (es)
MX (1) MX244781B (es)
WO (1) WO2003033140A2 (es)

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BRPI0721719A2 (pt) * 2007-05-29 2013-02-13 Evonik Degussa Gmbh catalisadores baseados em metais ativados
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DE102008013474B4 (de) * 2008-03-10 2013-08-08 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Katalytisches Verfahren zur Gewinnung von chemischen Grundstoffen aus nachwachsenden Rohstoffen
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US9062278B2 (en) 2010-02-19 2015-06-23 Basf Se Preparing ether carboxylates
AU2011217307B2 (en) 2010-02-19 2016-07-28 Basf Se Method for the production of ether carboxylates
JP5149364B2 (ja) * 2010-11-08 2013-02-20 国立大学法人群馬大学 炭素触媒及びその製造方法並びにこれを用いた電極及び電池
CN108347916B (zh) 2015-10-14 2022-02-08 先时迈纳米生物科技股份有限公司 一种减少冰晶形成的组合物及其方法
CA3212507A1 (en) * 2021-03-04 2022-09-09 Monsanto Technology Llc Two-compartment bipolar membrane electrodialysis of salts of amino acids
CN117797803A (zh) * 2022-09-26 2024-04-02 中国石油化工股份有限公司 一种具有强Lewis酸性的催化剂及其制备方法和应用

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Also Published As

Publication number Publication date
US20050043566A1 (en) 2005-02-24
MXPA04003658A (es) 2004-07-22
WO2003033140A2 (en) 2003-04-24
AU2002362929B2 (en) 2007-08-09
IN2004CH00786A (es) 2006-01-13
AU2002362929A1 (en) 2003-04-28
US7126024B2 (en) 2006-10-24
MX244781B (es) 2007-04-03
CA2463776A1 (en) 2003-04-24
WO2003033140A3 (en) 2003-07-17
BR0213428A (pt) 2005-12-20
EP1436080A2 (en) 2004-07-14
CN1729052A (zh) 2006-02-01

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