[go: up one dir, main page]

AR028816A1 - "N-ALCOXIAMINS IMPEDED REPLACED WITH HYDROXY, COMPOSITION, PROCESS TO STABILIZE AN ORGANIC POLYMER OR RECORDING MATERIAL AGAINST DAMAGES PRODUCED BY LIGHT, OXYGEN AND / OR HEAT, AND PROCESS TO PREPARE NES. - Google Patents

"N-ALCOXIAMINS IMPEDED REPLACED WITH HYDROXY, COMPOSITION, PROCESS TO STABILIZE AN ORGANIC POLYMER OR RECORDING MATERIAL AGAINST DAMAGES PRODUCED BY LIGHT, OXYGEN AND / OR HEAT, AND PROCESS TO PREPARE NES.

Info

Publication number
AR028816A1
AR028816A1 ARP000100764A ARP000100764A AR028816A1 AR 028816 A1 AR028816 A1 AR 028816A1 AR P000100764 A ARP000100764 A AR P000100764A AR P000100764 A ARP000100764 A AR P000100764A AR 028816 A1 AR028816 A1 AR 028816A1
Authority
AR
Argentina
Prior art keywords
stabilize
oxygen
recording material
heat
light
Prior art date
Application number
ARP000100764A
Other languages
Spanish (es)
Original Assignee
Ciba Sc Holding Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US09/257,711 external-priority patent/US6271377B1/en
Priority claimed from US09/315,704 external-priority patent/US6166212A/en
Application filed by Ciba Sc Holding Ag filed Critical Ciba Sc Holding Ag
Publication of AR028816A1 publication Critical patent/AR028816A1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/92—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with a hetero atom directly attached to the ring nitrogen atom
    • C07D211/94—Oxygen atom, e.g. piperidine N-oxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/92—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with a hetero atom directly attached to the ring nitrogen atom
    • C07D211/98—Nitrogen atom

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Hydrogenated Pyridines (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paints Or Removers (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Silver Salt Photography Or Processing Solution Therefor (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Anti-Oxidant Or Stabilizer Compositions (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Saccharide Compounds (AREA)
  • Heat Sensitive Colour Forming Recording (AREA)

Abstract

Las aminas impedidas sustituidas en el átomo N con una porcion ûO-E-OH son especialmente efectivas para estabilizar composiciones de poliolefinas y revestimientos para automotores contra los efectos deletéreos de la radiacion actínica, oxidativa y térmica en las que la presencia del grupo OH en los compuestos agrega propiedades importantes que no se pueden obtener mediante el uso de porciones ûO û E - normales. Se preparan convenientemente mediante la reaccion del correspondiente compuesto N - oxilo con un alcohol en presencia de un peroxido o de un hidroperoxido orgánico y una cantidad catalítica de una sal de metal o complejo metal û ligando. Las formulas de las aminas son 1 a 30 donde los sustituyentes tienen los significados dados en la memoria descriptiva. Proceso para estabilizar un polímero orgánico o material de registro contra los danos producidos por la luz, el oxígeno y/o el calor y composiciones que contienen las aminas. Las aminas impedidas sustituidas en el átomo N con una porcion ûO û E û OH son especialmente efectivas para estabilizar composiciones de poliolefinas y revestimientos para automotores contra los efectos deletéreos de la radiacion actínica, oxidativa y térmica en las que la presencia del grupo OH en los compuestos agrega propiedades importantes que no se pueden obtener mediante el uso de porciones ûO û E- normales. Se preparan convenientemente mediante la reaccion del correspondiente compuesto N û oxilo con un alcohol en presencia de un peroxido o de un hidroperoxido orgánico y una cantidad catalítica de una sal de metal o complejo metal û ligando.The hindered amines substituted on the N atom with an ûO-E-OH portion are especially effective in stabilizing automotive polyolefin compositions and coatings against the deleterious effects of actinic, oxidative and thermal radiation in which the presence of the OH group in the Compounds add important properties that cannot be obtained by using ûO û E - normal portions. They are conveniently prepared by reacting the corresponding N-oxyl compound with an alcohol in the presence of an peroxide or an organic hydroperoxide and a catalytic amount of a metal salt or metal û ligand complex. The amines formulas are 1 to 30 where the substituents have the meanings given in the specification. Process to stabilize an organic polymer or recording material against damage caused by light, oxygen and / or heat and compositions containing amines. The hindered amines substituted on the N atom with a ûO û E û OH portion are especially effective in stabilizing automotive polyolefin compositions and coatings against the deleterious effects of actinic, oxidative and thermal radiation in which the presence of the OH group in the Compounds add important properties that cannot be obtained through the use of ûO û E-normal portions. They are conveniently prepared by reacting the corresponding N û oxyl compound with an alcohol in the presence of an peroxide or an organic hydroperoxide and a catalytic amount of a metal salt or metal û ligand complex.

ARP000100764A 1999-02-25 2000-02-23 "N-ALCOXIAMINS IMPEDED REPLACED WITH HYDROXY, COMPOSITION, PROCESS TO STABILIZE AN ORGANIC POLYMER OR RECORDING MATERIAL AGAINST DAMAGES PRODUCED BY LIGHT, OXYGEN AND / OR HEAT, AND PROCESS TO PREPARE NES. AR028816A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/257,711 US6271377B1 (en) 1999-02-25 1999-02-25 Hydroxy-substituted N-alkoxy hindered amines and compositions stabilized therewith
US09/315,704 US6166212A (en) 1999-05-20 1999-05-20 Process for the synthesis of N-(hydroxyalkoxy) substituted hindered amine stabilizers

Publications (1)

Publication Number Publication Date
AR028816A1 true AR028816A1 (en) 2003-05-28

Family

ID=26946156

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP000100764A AR028816A1 (en) 1999-02-25 2000-02-23 "N-ALCOXIAMINS IMPEDED REPLACED WITH HYDROXY, COMPOSITION, PROCESS TO STABILIZE AN ORGANIC POLYMER OR RECORDING MATERIAL AGAINST DAMAGES PRODUCED BY LIGHT, OXYGEN AND / OR HEAT, AND PROCESS TO PREPARE NES.

Country Status (18)

Country Link
JP (1) JP4757977B2 (en)
KR (1) KR100676473B1 (en)
CN (1) CN1230424C (en)
AR (1) AR028816A1 (en)
AU (1) AU773104B2 (en)
BE (1) BE1013530A5 (en)
BR (1) BR0000666B1 (en)
CA (1) CA2299754C (en)
DE (1) DE10008367B4 (en)
ES (1) ES2195674B1 (en)
FR (1) FR2790259B1 (en)
GB (2) GB0003326D0 (en)
IN (1) IN2000CH00150A (en)
IT (1) IT1319167B1 (en)
MX (1) MXPA00001961A (en)
NL (1) NL1014414C2 (en)
RU (1) RU2243216C2 (en)
TW (1) TW491876B (en)

Families Citing this family (39)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2377709B (en) * 1998-12-14 2003-06-18 Ciba Sc Holding Ag Sterically hindered amine compounds
US6376584B1 (en) * 1999-02-25 2002-04-23 Ciba Specialty Chemicals Corporation Hydroxy-substituted N-alkoxy hindered amines and compositions stabilized therewith
TWI273115B (en) * 2000-12-12 2007-02-11 Ciba Sc Holding Ag Improved weatherability of flame retardant polyolefin
DE10106543A1 (en) * 2001-02-13 2002-08-22 Basf Ag Coating compositions
US20030040593A1 (en) * 2001-04-26 2003-02-27 Nobuya Saegusa Vinyl-polymerizable monomer having tertiary hydroxyl group and polymer
JP4562324B2 (en) * 2001-07-06 2010-10-13 株式会社Adeka Stabilized polyurethane resin
ITMI20012081A1 (en) 2001-10-09 2003-04-09 3V Sigma Spa LIQUID COMPOSITIONS OF STABILIZED PEROXIDES
CN1753871A (en) * 2003-02-26 2006-03-29 西巴特殊化学品控股有限公司 Water compatible sterically hindered alkoxyamines and hydroxy substituted alkoxyamines
KR101129505B1 (en) * 2003-07-14 2012-03-29 시바 홀딩 인크 Hydrogen peroxide catalyzed process for the preparation of sterically hindered N-hydrocarbyloxyamines
US7595011B2 (en) 2004-07-12 2009-09-29 Ciba Specialty Chemicals Corporation Stabilized electrochromic media
US7410936B2 (en) 2004-08-23 2008-08-12 Ciba Specialty Chemicals Corporation Stabilized body care products, household products, textiles and fabrics
CN101218103B (en) * 2005-07-08 2011-07-13 佳能株式会社 Thermal inkjet ink and ink cartridge using the same
WO2007007855A1 (en) * 2005-07-08 2007-01-18 Canon Kabushiki Kaisha Ink for thermal ink jet ink and ink cartridge using the same
US20070072965A1 (en) * 2005-09-23 2007-03-29 Mouhcine Kanouni Color fast polyurethanes
CN101484423B (en) * 2006-07-05 2011-09-07 西巴控股有限公司 Process for the preparation of sterically hindered nitroxyl ethers
ATE449072T1 (en) * 2006-07-05 2009-12-15 Basf Se METHOD FOR PRODUCING STERICALLY HINDERED NITROXYL ETHER
MX2008016304A (en) 2006-07-05 2009-01-16 Ciba Holding Inc Process for the preparation of sterically hindered nitroxyl ethers.
US20120145241A1 (en) * 2009-08-18 2012-06-14 Basf Se Photovoltaic module with stabilized polymeric encapsulant
EP2708574A1 (en) * 2012-09-18 2014-03-19 Clariant International Ltd. Oxygen scavenging plastic material
KR101901123B1 (en) * 2013-09-30 2018-09-27 써튼티드 코포레이션 Stain repellent and voc eliminating coatings and use thereof
SG11201606231TA (en) * 2014-02-28 2016-08-30 Exxonmobil Chem Patents Inc Mooney viscosity stable brominated elastomers
SA116370295B1 (en) * 2015-02-20 2016-12-06 باسف اس اى Light stabilized polyolefin films, tapes and monofilaments
JP2018520255A (en) * 2015-07-20 2018-07-26 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ Flame retardant polyolefin
CN105085376B (en) * 2015-09-07 2018-01-05 江苏裕兴薄膜科技股份有限公司 A kind of glycol monomer and its polyester copolymer containing hindered amine group
US10767073B2 (en) 2016-10-18 2020-09-08 Ppg Industries Ohio, Inc. Curable film-forming compositions containing hydroxyl functional, branched acrylic polymers and multilayer composite coatings
KR102201293B1 (en) * 2019-05-15 2021-01-11 한국신발피혁연구원 Urethane acrylate hybrid coating composition for weather strips
CN112126060B (en) * 2019-06-25 2022-05-31 北京天罡助剂有限责任公司 A kind of polymeric polymer sterically hindered amine and preparation method thereof
CN110606986B (en) * 2019-09-20 2020-05-22 杭州聚丰新材料有限公司 Silicone rubber cross-linking agent, and preparation method and application thereof
CN110903237A (en) * 2019-12-16 2020-03-24 兰州精细化工有限责任公司 Preparation method of bis (1-octyloxy-2, 2,6, 6-tetramethyl-4-piperidyl) sebacate
US20230095019A1 (en) 2019-12-27 2023-03-30 Diahachi Chemical Industry Co., Ltd. Flame retardant composition and flame-retardant thermoplastic resin composition containing said flame retardant composit
EP4259711A1 (en) * 2020-12-09 2023-10-18 Basf Se Additive mixtures
CN116583559A (en) * 2020-12-09 2023-08-11 巴斯夫欧洲公司 Organic material-based molded article
CN112778990B (en) * 2021-02-05 2022-06-03 西南石油大学 Sewage mixing temporary plugging agent for oilfield water injection well and preparation method thereof
CN113582914B (en) * 2021-08-02 2023-11-03 天津利安隆新材料股份有限公司 Preparation method of hydroxyl-containing hindered amine light stabilizer
KR102497017B1 (en) * 2021-08-26 2023-02-07 강남제비스코 주식회사 AcrylPolyol type Surfacer composition for LiDAR reflectance
CN113956776B (en) * 2021-12-06 2022-12-13 烟台大学 Preparation method of powderable self-repairing flame-retardant low-VOC (volatile organic compound) polyurethane coating and application of powderable self-repairing flame-retardant low-VOC polyurethane coating in automobile leather
CN114940684B (en) * 2022-05-24 2023-07-21 浙江大学温州研究院 White light-emitting copper halide complex and preparation method and application thereof
CN116082705B (en) * 2022-12-05 2023-09-12 苏州易昇光学材料股份有限公司 Anti-yellowing self-repairing gel
EP4464752A1 (en) * 2023-05-17 2024-11-20 Lignocolor GmbH Process for coating hard surfaces with pigment films

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU571240B2 (en) * 1983-07-11 1988-04-14 Commonwealth Scientific And Industrial Research Organisation Alkoxy-amines, useful as initiators
SU1215332A3 (en) * 1983-12-27 1999-02-10 Научно - исследовательский институт химикатов для полимерных материалов. Epoxy resin and spatially hindered amine derivative-based oligomers light stabilizing additive to phenol antioxidant-based polypropylene thermostabilizer
EP0155912A3 (en) * 1984-03-20 1986-06-04 Ciba-Geigy Ag Radiation-stabilized polymer compositions
US5004770A (en) * 1988-10-19 1991-04-02 Ciba-Geigy Corporation Polymeric substrates stabilized with N-substituted hindered amines
US5096950A (en) * 1988-10-19 1992-03-17 Ciba-Geigy Corporation Polyolefin compositions stabilized with NOR-substituted hindered amines
EP0365481A1 (en) * 1988-10-19 1990-04-25 Ciba-Geigy Ag Polymeric substrates stabilized with N-substituted hindered amines
EP0389420B1 (en) * 1989-03-21 1994-09-21 Ciba-Geigy Ag Ethylenically unsaturated compounds containing 1-hydrocarbyloxy-2,2,6,6-tetramethylpiperidine moieties, and polymers, copolymers and stabilized compositions
IT1237126B (en) * 1989-11-07 1993-05-18 Ciba Geigy Spa POLYMERIC STABILIZERS CONTAINING PREVENTED AMINE GROUPS AND HYDROXYLAMIN GROUPS
TW270131B (en) * 1993-07-13 1996-02-11 Ciba Geigy
JPH0952975A (en) * 1995-08-18 1997-02-25 Clariant Internatl Ltd Stabilizing method for pigment and composition used therefor
US5627248A (en) * 1995-09-26 1997-05-06 The Dow Chemical Company Difunctional living free radical polymerization initiators
US5844025A (en) * 1996-12-02 1998-12-01 Ciba Specialty Chemicals Corporation 1,2-Bis-adducts of stable nitroxides with substituted ethylenes and stabilized compositions
TW509683B (en) * 1997-05-27 2002-11-11 Ciba Sc Holding Ag Triazine derivatives containing 2,2,6,6-tetramethyl-4-piperidyl groups
WO2000078709A1 (en) * 1999-06-23 2000-12-28 Nof Corporation Vinylated alkoxyamine, use thereof, and process for producing the same
EP1083169B1 (en) * 1999-09-07 2003-10-29 Bayer Ag Functionalized alkoxyamine initiators

Also Published As

Publication number Publication date
CN1273241A (en) 2000-11-15
DE10008367A1 (en) 2000-08-31
NL1014414C2 (en) 2001-07-17
BR0000666B1 (en) 2011-03-09
AU1945400A (en) 2000-09-14
FR2790259B1 (en) 2004-10-01
GB2347928A (en) 2000-09-20
JP2000302758A (en) 2000-10-31
CA2299754A1 (en) 2000-08-25
ITMI20000327A0 (en) 2000-02-23
KR100676473B1 (en) 2007-02-05
CN1230424C (en) 2005-12-07
ES2195674B1 (en) 2005-03-16
GB2347928B (en) 2001-11-28
GB0004127D0 (en) 2000-04-12
BR0000666A (en) 2001-01-16
ES2195674A1 (en) 2003-12-01
GB0003326D0 (en) 2000-04-05
DE10008367B4 (en) 2014-08-28
IN2000CH00150A (en) 2007-04-27
BE1013530A5 (en) 2002-03-05
TW491876B (en) 2002-06-21
AU773104B2 (en) 2004-05-13
JP4757977B2 (en) 2011-08-24
FR2790259A1 (en) 2000-09-01
MXPA00001961A (en) 2002-05-23
NL1014414A1 (en) 2000-08-28
RU2243216C2 (en) 2004-12-27
CA2299754C (en) 2010-02-09
KR20010014505A (en) 2001-02-26
IT1319167B1 (en) 2003-09-26
ITMI20000327A1 (en) 2001-08-23

Similar Documents

Publication Publication Date Title
AR028816A1 (en) "N-ALCOXIAMINS IMPEDED REPLACED WITH HYDROXY, COMPOSITION, PROCESS TO STABILIZE AN ORGANIC POLYMER OR RECORDING MATERIAL AGAINST DAMAGES PRODUCED BY LIGHT, OXYGEN AND / OR HEAT, AND PROCESS TO PREPARE NES.
ES2130985B1 (en) HYDROXYPHENYLTRIAZINS.
DE60141347D1 (en) COMPOSITIONS FOR ELIMINATING DISPERSES
AR050527A2 (en) IISOTIAZOLCARBOXIAMIDAS, PROCEDURE FOR THEIR OBTAINING, COMPOSITIONS THAT CONTAIN THEM, ITS USE TO PROTECT PLANTS FROM THE ATTACK OF INDEPENDABLE MICROORGANISMS AND ANIMAL PESTS, PROCEDURE TO PROTECT PLANTS FROM THE ATTACK OF MICROORGANISMS, NOT WANTED, PROCEDURES FOR THE DESIREED ANIMALS
AR030893A1 (en) COMBINED USE OF GABAA ACETILCOLINESTERASE INHIBITORS AND INVESTED AGONISTS FOR THE TREATMENT OF COGNITIVE DISORDERS
RU94033487A (en) 3-arylbenzofuranones as stabilizing agents
RU95120591A (en) METHOD FOR STABILIZING DIBENZOYLMETHANE DERIVATIVES, LIGHT-RESISTANT FILTERING COSMETIC COMPOSITION, COSMETIC PROCESSING METHOD AND APPLICATION OF AMIDATED COMPOUNDS AS A LIGHT POSITION
CO5231190A1 (en) COMBINATIONS OF ACTIVE COMPOUNDS OF THE TYPE OF CYCLE CETOENOLES WITH PIRETROIDS
IT1264452B1 (en) 3- (ACYLOXYPHENYL) BENZOFURAN-2-ONI AS STABILIZING AGENTS
ES2121603T3 (en) DERIVATIVES OF 10,11-METHANODIBENZOSUBERANO USED AS CHEMOSENSITIZING AGENTS.
CO5700823A2 (en) CYCLIC CETOENOLS, SUBSTITUTED BY N-HETEROCICLILFENILO
CO5150224A1 (en) TRIAZOL COMPOUNDS AND ITS USE
ES2090400T3 (en) AGENTS TO PRESERVE TECHNICAL MATERIALS FROM THE ATTACK BY INSECTS.
AR034282A1 (en) DERIVATIVES OF DIFENYLAZETIDINONE, MEDICATIONS CONTAINING THESE COMPOUNDS, PROCEDURE FOR PREPARATION, AND ITS USE FOR THE PREPARATION OF MEDICINES
ECSP045004A (en) INHIBITORS OF THE 17BETA-HYDROXIESTEROID DEHYDROGENASE TYPE 3 FOR THE TREATMENT OF DEPENDING ANDROGEN DISEASES
AR058569A1 (en) HISTONE DEACETILASE INHIBITORS TO IMPROVE THE ACTIVITY OF ANTIFUNGIC AGENTS
RU94033474A (en) Benzofuran-2-ones as stabilizers
ES2126484B1 (en) COMBINATION OF STABILIZER FOR SYNTHETIC ORGANIC POLYMERS.
ATE522496T1 (en) 2-AMINO-5-(SUBSTITUTED OXYMETHYL)PHENOL COMPOUNDS, DYE COMPOSITIONS CONTAINING SAME AND USES THEREOF
CO5660289A2 (en) DERIVATIVES OF 4-PYRIDINYLMETILSULFONAMIDE AS FUNGICIDE AGENTS FOR PLANTS PROTECTION
ES2036852T3 (en) PROCEDURE FOR THE OBTAINING OF TRIFLUORMETILFENIL-AZOLILMETILOXIRANOS AND ITS USE AS PROTECTING AGENTS OF PLANTS.
ES2140654T3 (en) 1,2,3,4-TETRAHIDRO-5-NITRO-PIRIMIDINAS SUBSTITUIDAS.
AR035531A1 (en) COMPOSITION FOR THE CONTROL OF ENDOPARASITIC PESTS IN LIVESTOCK AND DOMESTIC ANIMALS, A METHOD FOR THEIR CONTROL AND THE USE OF SUCH COMPOSITION FOR THE PREPARATION OF MEDICINES
AR007005A1 (en) REPELLENT ARTROPOD COMPOSITIONS AND PROCEDURE FOR REPELLERING ARTHROPODS
SE7708329L (en) HALOGENATED 1-AZOLYL-BUTANE DERIVATIVES USED AS FUNGICIDES AND METHODS OF PREPARING THE ASSOCIATIONS

Legal Events

Date Code Title Description
FG Grant, registration