AR017400A1 - Catalizadores para la polimerizacion de olefinas y procedimiento para su preparacion - Google Patents
Catalizadores para la polimerizacion de olefinas y procedimiento para su preparacionInfo
- Publication number
- AR017400A1 AR017400A1 ARP980105417A ARP980105417A AR017400A1 AR 017400 A1 AR017400 A1 AR 017400A1 AR P980105417 A ARP980105417 A AR P980105417A AR P980105417 A ARP980105417 A AR P980105417A AR 017400 A1 AR017400 A1 AR 017400A1
- Authority
- AR
- Argentina
- Prior art keywords
- component
- catalysts
- procedure
- preparation
- substituents
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 3
- 150000001336 alkenes Chemical class 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 238000006116 polymerization reaction Methods 0.000 title abstract 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title 1
- -1 organometallic aluminum compounds Chemical class 0.000 abstract 2
- 125000001424 substituent group Chemical group 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- 125000002877 alkyl aryl group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 abstract 1
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 abstract 1
- 229920006395 saturated elastomer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Catalizadores para la polimerizacion de olefinas de acuerdo con la revelacion, que comprenden el producto que se obtiene poniendo en contacto: a) uncompuesto de ciclopentadienilo en puente y/o sustituido, de Ti, Zr o Hf; b) uno o más compuestos de aluminio organometálicos de formula AlR43-zHz donde lossustituyentes R4, iguales o diferentes entre sí, son radicales de alquilarilo o alquilo C1-20, lineales o ramificados, saturados o insaturados, que contienenopcionalmente átomos de Si o Ge, siendoal menos uno de los sustituyentes R4 diferentes de un grupo alquilo recto; z es 0 o 1; y c) agua; donde la relacionmolar entre el compuesto de aluminio organometálico y el agua está comprendida entre 1:1 y 100:1 y dicho catalizador se puede obtener através de unprocedimiento que comprende los siguientes pasos: i) poner en contacto el componente (a) con parte del componente (b) en ausencia del componente (c); ii) poneren contacto parte del componente (b) con el componente (c) en ausencia del componente (a) y seguidamente iii) poner en contacto los productos obtenidos en lospasos (i) y (ii).
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP97203331 | 1997-10-29 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR017400A1 true AR017400A1 (es) | 2001-09-05 |
Family
ID=8228868
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP980105417A AR017400A1 (es) | 1997-10-29 | 1998-10-29 | Catalizadores para la polimerizacion de olefinas y procedimiento para su preparacion |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US6476163B2 (es) |
| EP (1) | EP0948547B1 (es) |
| JP (1) | JP2001507402A (es) |
| KR (1) | KR20000069714A (es) |
| CN (1) | CN1242778A (es) |
| AR (1) | AR017400A1 (es) |
| AU (1) | AU1335899A (es) |
| CA (1) | CA2274903A1 (es) |
| DE (1) | DE69826633T2 (es) |
| MY (1) | MY133202A (es) |
| WO (1) | WO1999021896A1 (es) |
| ZA (1) | ZA989699B (es) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6559252B1 (en) * | 1997-10-29 | 2003-05-06 | Basell Technology Company Bv | Catalysts and processes for the polymerization of olefins |
| CA2302287A1 (en) | 1998-07-02 | 2000-01-13 | Montell Technology Company B.V. | Process for the preparation of substantially amorphous alpha-olefin polymers and compositions containing them and process for the preparation of bridged ligand |
| JP2003510381A (ja) | 1999-09-22 | 2003-03-18 | バセル テクノロジー カンパニー ビー.ブイ. | オレフィンの重合用触媒系および方法 |
| JP2005538244A (ja) * | 2002-07-15 | 2005-12-15 | バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング | 触媒組成物の製造方法 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4925821A (en) * | 1987-12-17 | 1990-05-15 | Exxon Chemical Patents Inc. | Method for utilizing triethyaluminum to prepare an alumoxane support for an active metallocene catalyst |
| IT1237398B (it) | 1989-01-31 | 1993-06-01 | Ausimont Srl | Catalizzatori per la polimerizzazione di olefine. |
| DE3922546A1 (de) | 1989-07-08 | 1991-01-17 | Hoechst Ag | Verfahren zur herstellung von cycloolefinpolymeren |
| ATE173746T1 (de) | 1991-02-27 | 1998-12-15 | Ticona Gmbh | Verfahren zur herstellung von cycloolefin(co)polymeren mit enger molekulargewichtsverteilung |
| US5210338A (en) * | 1991-10-25 | 1993-05-11 | Ethyl Corporation | Catalyzed chain growth process |
| EP0563834B1 (en) * | 1992-04-01 | 1995-10-11 | MITSUI TOATSU CHEMICALS, Inc. | Syndiotactic polypropylene wax, production process thereof, and heating roll fixing-type toner composition making use of the wax |
| AU660808B2 (en) | 1992-06-18 | 1995-07-06 | Montell Technology Company B.V. | Catalysts for the polymerization of olefins |
| IT1273661B (it) * | 1994-07-20 | 1997-07-09 | Spherilene Srl | Catalizzatori per la polimerizzazione delle olefine |
-
1998
- 1998-10-23 JP JP52322999A patent/JP2001507402A/ja not_active Withdrawn
- 1998-10-23 US US09/331,928 patent/US6476163B2/en not_active Expired - Fee Related
- 1998-10-23 DE DE69826633T patent/DE69826633T2/de not_active Expired - Fee Related
- 1998-10-23 AU AU13358/99A patent/AU1335899A/en not_active Abandoned
- 1998-10-23 KR KR1019997005793A patent/KR20000069714A/ko not_active Withdrawn
- 1998-10-23 CN CN98801614A patent/CN1242778A/zh active Pending
- 1998-10-23 EP EP98956867A patent/EP0948547B1/en not_active Expired - Lifetime
- 1998-10-23 WO PCT/EP1998/006733 patent/WO1999021896A1/en not_active Ceased
- 1998-10-23 CA CA002274903A patent/CA2274903A1/en not_active Abandoned
- 1998-10-23 ZA ZA989699A patent/ZA989699B/xx unknown
- 1998-10-28 MY MYPI98004910A patent/MY133202A/en unknown
- 1998-10-29 AR ARP980105417A patent/AR017400A1/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DE69826633D1 (de) | 2004-11-04 |
| DE69826633T2 (de) | 2005-02-03 |
| EP0948547B1 (en) | 2004-09-29 |
| AU1335899A (en) | 1999-05-17 |
| CA2274903A1 (en) | 1999-05-06 |
| US6476163B2 (en) | 2002-11-05 |
| KR20000069714A (ko) | 2000-11-25 |
| WO1999021896A1 (en) | 1999-05-06 |
| JP2001507402A (ja) | 2001-06-05 |
| MY133202A (en) | 2007-10-31 |
| ZA989699B (en) | 1999-04-25 |
| US20020091062A1 (en) | 2002-07-11 |
| EP0948547A1 (en) | 1999-10-13 |
| CN1242778A (zh) | 2000-01-26 |
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