[go: up one dir, main page]

AR017104A1 - Complejos de dos metales y catalizadores de polimerizacion, procedimiento de polimerizacion mejorado de monomeros utilizando catalizadores que incluyandichos complejos - Google Patents

Complejos de dos metales y catalizadores de polimerizacion, procedimiento de polimerizacion mejorado de monomeros utilizando catalizadores que incluyandichos complejos

Info

Publication number
AR017104A1
AR017104A1 ARP980104563A ARP980104563A AR017104A1 AR 017104 A1 AR017104 A1 AR 017104A1 AR P980104563 A ARP980104563 A AR P980104563A AR P980104563 A ARP980104563 A AR P980104563A AR 017104 A1 AR017104 A1 AR 017104A1
Authority
AR
Argentina
Prior art keywords
group
complexes
catalysts
attached
metals
Prior art date
Application number
ARP980104563A
Other languages
English (en)
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Publication of AR017104A1 publication Critical patent/AR017104A1/es

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/03Multinuclear procatalyst, i.e. containing two or more metals, being different or not
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Complejos de dos metales y catalizadores de polimerizacion, procedimiento de polimerizacion mejorado de monomeros utilizando catalizadores que incluyendichos complejos. Se trata de complejos de dos metales de formula (I) en donde M y M independientemente son metales de los grupos 3, 4, 5, 6 o lantanidos;L es un grupo divalente (o grupo trivalente si está unido a Q) con hasta 50 átomos diferentes de hidrogeno y que tienen un sistema pi aromático de enlace conM, estando dicho grupo L también unido a Z; L es un grupo monovalente o un grupo divalente (si está unido a L o Q) o un grupo trivalente (si está unidotanto a L como a Q) que tienen hasta 50 átomos diferentes de hidrogeno y conteniendo un sistema pi-aromático de enlace a M; L esuna fraccion que comprende boro o un miembrodel grupo 14 de la Tabla Periodica, y opcionalmente también comprende nitrogeno, fosforo, azufre u oxígeno, dicha L teniendo hasta 20 átomos no hidrogeno; Zes una porcion que comprende boro o un miembro del 14 de la Tabla Periodica de los Elementos, y opcionalmente también nitrogeno, fosforo, azufre u oxígeno; Ztiene hasta 20 átomos diferentes de hidrogeno; X y X independientemente con grupos anionicos de enlace de hasta 40 átomos exclusivos de la clase de unionesconteniendo un sistema pi-aromático a través de cuyo grupo se encuentra unido a M o M, opcionalmente dos grupos X o dos grupos X juntos forman un dieno C4-40conjugado o no conjugado opcionalmente sustituido con uno o más grupo hidrocarbilo, sililo, halocarbilo o halohidrocarbilo; X independientemente en cadaocurrencia es un compuesto de enlace neutro teniendo hasta 20 átomos; Q es un grupo de union anionico divalente ligado tanto Z como L y unido en la terminal
ARP980104563A 1997-09-15 1998-09-14 Complejos de dos metales y catalizadores de polimerizacion, procedimiento de polimerizacion mejorado de monomeros utilizando catalizadores que incluyandichos complejos AR017104A1 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US6071297P 1997-09-15 1997-09-15
US9229498P 1998-07-10 1998-07-10

Publications (1)

Publication Number Publication Date
AR017104A1 true AR017104A1 (es) 2001-08-22

Family

ID=26740275

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP980104563A AR017104A1 (es) 1997-09-15 1998-09-14 Complejos de dos metales y catalizadores de polimerizacion, procedimiento de polimerizacion mejorado de monomeros utilizando catalizadores que incluyandichos complejos

Country Status (14)

Country Link
US (1) US6153776A (es)
EP (1) EP1015462B1 (es)
JP (1) JP2001516762A (es)
KR (1) KR20010024020A (es)
CN (1) CN1270596A (es)
AR (1) AR017104A1 (es)
AT (1) ATE222917T1 (es)
AU (1) AU9037598A (es)
BR (1) BR9812308A (es)
CA (1) CA2303519A1 (es)
DE (1) DE69807506T2 (es)
NO (1) NO20001306L (es)
TR (1) TR200000665T2 (es)
WO (1) WO1999014222A1 (es)

Families Citing this family (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6284698B1 (en) * 1997-09-15 2001-09-04 The Dow Chemical Company Highly activated bimetallic complexes and polymerization process
US6228790B1 (en) * 1998-06-29 2001-05-08 Industrial Technology Research Institute Dinuclear metallocene catalyst for preparing high molecular weight olefin polymer
WO2000002891A1 (en) * 1998-07-10 2000-01-20 Exxon Chemical Patents Inc. Tethered monocyclopentadienyl polymerization catalysts
AU2001229571A1 (en) * 2000-02-11 2001-08-20 The Dow Chemical Company Dinuclear group 4 metal boron or aluminum bridge containing ansa-complexes
KR100455713B1 (ko) * 2001-01-29 2004-11-06 호남석유화학 주식회사 올레핀 중합용 다중핵 메탈로센 촉매 및 이를 이용한중합방법
DE10114345A1 (de) 2001-03-23 2002-09-26 Bayer Ag Katalysator mit einer Donor-Akzeptor-Wechselwirkung
US6642400B2 (en) * 2001-09-26 2003-11-04 Univation Technologies, Llc Linked metallocene complexes, catalyst systems, and olefin polymerization processes using same
CA2466612A1 (en) * 2001-11-30 2003-06-12 Exxonmobil Chemical Patents Inc. Bimetallic catalysts with higher activity
KR100576971B1 (ko) * 2002-09-13 2006-05-10 금호석유화학 주식회사 올레핀 중합용 이핵 전이금속 화합물의 제조 방법
US8008412B2 (en) 2002-09-20 2011-08-30 Exxonmobil Chemical Patents Inc. Polymer production at supersolution conditions
US7172987B2 (en) 2002-12-31 2007-02-06 Univation Technologies, Llc Bimetallic catalyst, method of polymerization and bimodal polyolefins therefrom
US8127224B2 (en) * 2003-06-11 2012-02-28 Wtvii, Inc. System for creating and editing mark up language forms and documents
US7087687B2 (en) * 2003-08-21 2006-08-08 Rohm And Haas Company Catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers
EP1735354A1 (en) * 2004-04-16 2006-12-27 Exxonmobil Chemical Company Inc. Heterocyclic substituted metallocene compounds for olefin polymerization
DE102004025938A1 (de) * 2004-05-27 2005-12-22 Bayer Ag Dinukleare Übergangsmetallkomplexe
CN1968973B (zh) 2004-06-16 2011-08-17 陶氏环球技术有限责任公司 选择聚合改性剂的方法
US7868197B2 (en) 2005-12-14 2011-01-11 Exxonmobil Chemical Patents Inc. Halogen substituted heteroatom-containing metallocene compounds for olefin polymerization
EP1966223B1 (en) 2005-12-30 2013-08-14 LG Chem. Ltd. Catalyst composition comprising group 4 transition metal complexes and method for preparing polyolefins using the same
KR100874032B1 (ko) * 2006-02-01 2008-12-17 주식회사 엘지화학 전이 금속 화합물을 포함하는 촉매 조성물 및 이를 이용한올레핀 중합
US8242237B2 (en) 2006-12-20 2012-08-14 Exxonmobil Chemical Patents Inc. Phase separator and monomer recycle for supercritical polymerization process
ES2446294T3 (es) 2007-06-04 2014-03-07 Exxonmobil Chemical Patents Inc. Polimerización de propileno en un sistema homogéneo en condiciones de superdisolución
US8080681B2 (en) 2007-12-28 2011-12-20 Chevron Phillips Chemical Company Lp Nano-linked metallocene catalyst compositions and their polymer products
US7863210B2 (en) 2007-12-28 2011-01-04 Chevron Phillips Chemical Company Lp Nano-linked metallocene catalyst compositions and their polymer products
US8012900B2 (en) * 2007-12-28 2011-09-06 Chevron Phillips Chemical Company, L.P. Nano-linked metallocene catalyst compositions and their polymer products
US8318875B2 (en) 2008-01-18 2012-11-27 Exxonmobil Chemical Patents Inc. Super-solution homogeneous propylene polymerization and polypropylenes made therefrom
US7812104B2 (en) * 2008-01-18 2010-10-12 Exxonmobil Chemical Patents Inc. Production of propylene-based polymers
US7919639B2 (en) * 2009-06-23 2011-04-05 Chevron Phillips Chemical Company Lp Nano-linked heteronuclear metallocene catalyst compositions and their polymer products
US9233996B2 (en) 2011-09-13 2016-01-12 California Institute Of Technology Multi-metallic organometallic complexes, and related polymers, compositions, methods and systems
EP3000817B1 (en) 2013-06-25 2017-11-15 LG Chem, Ltd. Catalyst composition, method for preparing same, and method for preparing polyolefins using same
EP2998308B1 (en) 2013-06-25 2017-11-29 LG Chem, Ltd. Binucleate metallocene compound and method for preparing same
EP3169749B1 (en) * 2014-07-17 2018-12-26 Merck Patent GmbH Bimesogenic compounds and mesogenic media
CN105273010B (zh) * 2015-10-29 2018-07-13 中国石油天然气股份有限公司 一种限制构型双核茂金属化合物及其制备方法与应用
CN105273000B (zh) * 2015-10-29 2018-07-10 中国石油天然气股份有限公司 不对称限制构型双核茂金属化合物及其制备方法与应用
KR101918484B1 (ko) * 2017-11-15 2019-01-31 금호폴리켐 주식회사 탄성 공중합체 제조용 촉매 조성물 및 이를 이용한 에틸렌 및 알파-올레핀 또는 에틸렌, 알파-올레핀 및 비공액 디엔을 포함하는 탄성 공중합체의 제조 방법
CN111741961B (zh) 2018-02-19 2024-01-12 埃克森美孚化学专利公司 催化剂、催化剂体系和使用它们的方法
SG11202008654WA (en) 2018-03-30 2020-10-29 Dow Global Technologies Llc Highly soluble bis-borate as binuclear co-catalysts for olefin polymerizations
EP3774937A1 (en) 2018-03-30 2021-02-17 Dow Global Technologies LLC Highly soluble alkyl substituted carbenium borate as co-catalysts for olefin polymerizations
SG11202008667SA (en) 2018-03-30 2020-10-29 Dow Global Technologies Llc Binuclear olefin polymerization activators
BR112021003730A2 (pt) * 2018-09-18 2021-05-25 Arlanxeo Netherlands B.V. mistura de catalisador
US11802170B2 (en) 2021-04-29 2023-10-31 Exxonmobil Chemical Patents Inc. Polyolefins prepared with binuclear metallocene catalysts
CN117903208A (zh) * 2022-10-11 2024-04-19 中国石油化工股份有限公司 膦-酚后过渡金属配合物及其制备方法和应用
CN116284514A (zh) * 2023-02-28 2023-06-23 天津科技大学 限制几何构型的阳离子茂金属催化剂、及其合成方法和应用

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3242099A (en) * 1964-03-27 1966-03-22 Union Carbide Corp Olefin polymerization catalysts
US5096867A (en) * 1990-06-04 1992-03-17 Exxon Chemical Patents Inc. Monocyclopentadienyl transition metal olefin polymerization catalysts
US5198401A (en) * 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5055438A (en) * 1989-09-13 1991-10-08 Exxon Chemical Patents, Inc. Olefin polymerization catalysts
NZ235032A (en) * 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5057475A (en) * 1989-09-13 1991-10-15 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization
US5064802A (en) * 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
US5374696A (en) * 1992-03-26 1994-12-20 The Dow Chemical Company Addition polymerization process using stabilized reduced metal catalysts
US5372980A (en) * 1993-06-03 1994-12-13 Polysar Bimetallic metallocene alumoxane catalyst system and its use in the preparation of ethylene-alpha olefin and ethylene-alpha olefin-non-conjugated diolefin elastomers
US5470993A (en) * 1993-06-24 1995-11-28 The Dow Chemical Company Titanium(II) or zirconium(II) complexes and addition polymerization catalysts therefrom
EP0739897A1 (de) * 1995-04-27 1996-10-30 Hoechst Aktiengesellschaft Mehrkernige Metallocenverbindung, Verfahren zu ihrer Herstellung und ihre Anwendung als Katalysator
DE19546501A1 (de) * 1995-12-13 1997-06-19 Hoechst Ag Metallocenverbindung

Also Published As

Publication number Publication date
NO20001306D0 (no) 2000-03-14
NO20001306L (no) 2000-03-14
EP1015462B1 (en) 2002-08-28
AU9037598A (en) 1999-04-05
CN1270596A (zh) 2000-10-18
CA2303519A1 (en) 1999-03-25
DE69807506T2 (de) 2003-05-28
US6153776A (en) 2000-11-28
JP2001516762A (ja) 2001-10-02
TR200000665T2 (tr) 2000-09-21
KR20010024020A (ko) 2001-03-26
ATE222917T1 (de) 2002-09-15
DE69807506D1 (de) 2002-10-02
WO1999014222A1 (en) 1999-03-25
BR9812308A (pt) 2000-09-05
EP1015462A1 (en) 2000-07-05

Similar Documents

Publication Publication Date Title
AR017104A1 (es) Complejos de dos metales y catalizadores de polimerizacion, procedimiento de polimerizacion mejorado de monomeros utilizando catalizadores que incluyandichos complejos
AR017262A1 (es) Complejos de ciclopentafenantrenil-metales; catalizadores para la polimerizacion de olefina que incluye dichos complejos; procedimientos de polimerizacionde olefinas utilizando dichos catalizadores y uniformes copolimeros al azar de etileno y monomeros sinilaromaticos obtenidos con dicho procedimien
AR030040A1 (es) Complejos de metales del grupo 4 sustituidos; composiciones catalizadoras formuladas con dichos complejos; procedimientos de polimerizacion de monomeros polimerizables por adicion utilizando dichos monomeros y compuestos precursores de la fraccion ciclica de dichos complejos
AR023334A1 (es) Complejos de metales de transicion del grupo 4 y procesos de polimerizacion de olefinas utilizando catalizadores que incluyen dichos complejos
NZ333878A (en) 3-heteroatom substituted cyclopentadienyl-containing metal complexes and olefin polymerization process
ES2188235T3 (es) Complejos metalicos puenteados para polimerizaciones en fase gaseosa.
BR0016770B1 (pt) complexo de organoborano/amina e composição polimerizável.
PT934322E (pt) Composicoes de alquilaluminoxano soluveis em hidrocarboneto formadas pela utilizacao de meios nao hidroliticos
ES2096475T3 (es) Complejos de titanio (ii) o circonio (ii) y catalizadores de polimerizacion por adicion obtenidos a partir de los mismos.
NZ511274A (en) 2-alkyl-4-(2,6-dialkylphenyl) indenes
WO1997035894A3 (en) Allyl containing metal complexes and olefin polymerization process
KR930701493A (ko) 올레핀의 중합을 위한 알루미늄-비함유 모노사이클로 펜타디에닐 메탈로센 촉매
NO972865D0 (no) Polymeriserbar sammensetning og en polymeriseringsfremgangsmåte
ES2091293T3 (es) Catalizador de polimerizacion por adicion con activacion oxidante.
ZA9610680B (en) Water-dispersible polymer and coating composition containing the same
KR920014832A (ko) 금속 중심 산화반응에 의한 부가 중합반응 촉매의 제조방법
MX9708208A (es) Metodo para inhibir el taponamiento de conductos por hidratos de carbono.
BR0010534A (pt) Processo de polimerização
ATE217318T1 (de) Ansa bis(.mu.-aluminium)-substituierte gruppe-4- metallkomplexe
TW376390B (en) Multinuclear metallocene compound, a process for its preparation and its use as catalyst
EP0717639A4 (en) POLYAMINO PARAMAGNETIC CHELATES CONTAINING PHOSPHONATE AND NON PHOSPHONATE FRACTIONS FOR MAGNETIC RESONANCE IMAGING (MRI)
DE69530512D1 (de) Phosphatase-aktivierte quervernetzende konjugierende und reduzierende agenzien, verfahren unter verwendung solcher agenzien und reagenzien die phosphatase-aktivierte quervernetzende und konjugierende agenzien enthalten
TW343974B (en) Synthesis of group 4 metal diene complexes
AR027486A1 (es) Complejos de metales que contienen hetearatomos como puente; proceso de polimerizacion de olefinas utilizando composiciones catalizadoras que incluyendichos metales; y dichas composiciones catalizadoras y procesos de polimerizacion de olefinas utilizando dichas composiciones catalizadoras.
ES2046510T3 (es) Procedimiento de preparacion de polimeros yodados.