AR006280A1 - A PROCESS TO ELABORATE POLYETHESTER RESINS MADE FROM DIOL DIESTERS; SAID POLYETERESTER RESINS; A THERMOFRAGUED DEPOLIETERESTER PRODUCT AND A DIOL DIESTER TO BE USED IN SUCH PROCESS - Google Patents
A PROCESS TO ELABORATE POLYETHESTER RESINS MADE FROM DIOL DIESTERS; SAID POLYETERESTER RESINS; A THERMOFRAGUED DEPOLIETERESTER PRODUCT AND A DIOL DIESTER TO BE USED IN SUCH PROCESSInfo
- Publication number
- AR006280A1 AR006280A1 ARP970101084A ARP970101084A AR006280A1 AR 006280 A1 AR006280 A1 AR 006280A1 AR P970101084 A ARP970101084 A AR P970101084A AR P970101084 A ARP970101084 A AR P970101084A AR 006280 A1 AR006280 A1 AR 006280A1
- Authority
- AR
- Argentina
- Prior art keywords
- resins
- diol
- product
- diester
- polyether
- Prior art date
Links
- 229920005989 resin Polymers 0.000 title abstract 8
- 239000011347 resin Substances 0.000 title abstract 8
- 238000000034 method Methods 0.000 title abstract 6
- -1 DIOL DIESTERS Chemical class 0.000 title abstract 4
- 150000002009 diols Chemical class 0.000 title 1
- 239000004721 Polyphenylene oxide Substances 0.000 abstract 5
- 229920000570 polyether Polymers 0.000 abstract 5
- 150000002148 esters Chemical class 0.000 abstract 3
- 239000000047 product Substances 0.000 abstract 3
- 229920001187 thermosetting polymer Polymers 0.000 abstract 3
- QWGRWMMWNDWRQN-UHFFFAOYSA-N 2-methylpropane-1,3-diol Chemical compound OCC(C)CO QWGRWMMWNDWRQN-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 239000006227 byproduct Substances 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 230000003247 decreasing effect Effects 0.000 abstract 1
- 150000005690 diesters Chemical class 0.000 abstract 1
- 239000003999 initiator Substances 0.000 abstract 1
- 238000003780 insertion Methods 0.000 abstract 1
- 230000037431 insertion Effects 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 229920000728 polyester Polymers 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/32—Polymers modified by chemical after-treatment
- C08G65/329—Polymers modified by chemical after-treatment with organic compounds
- C08G65/331—Polymers modified by chemical after-treatment with organic compounds containing oxygen
- C08G65/332—Polymers modified by chemical after-treatment with organic compounds containing oxygen containing carboxyl groups, or halides, or esters thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
- C07C69/593—Dicarboxylic acid esters having only one carbon-to-carbon double bond
- C07C69/60—Maleic acid esters; Fumaric acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/66—Polyesters containing oxygen in the form of ether groups
- C08G63/668—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/66—Polyesters containing oxygen in the form of ether groups
- C08G63/668—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/676—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
- C08G63/688—Polyesters containing atoms other than carbon, hydrogen and oxygen containing sulfur
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Polyesters Or Polycarbonates (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Polyethers (AREA)
Abstract
El proceso consiste en hacer reaccionar un poliéter con un dioldiéster en presencia de un catalizador que favorezca la inseción al azar del diéster enlas ligaduras carbono - oxígeno del poliéter para producir la resina de polieteréster. Elproceso ofrece varias ventajas, entre ellas el mayorrendimiento de las resinas, la disminución de la producción de subproductos y la posibilidad de obtener resinas de bajo color y bajo número ácido. Lasresinas son útiles para elaborar productos de polieteréster termofraguados. Se refiere también a un proceso para elaborar un producto termofraguado depolieteréster que comprende hacer reaccionar la resina de polieteréster con un monómero de vinilo en presencia de un radical iniciador yse endurece paraobtener el producto termofraguado. Otro objeto se refiere a un diol diéster que comprende el producto de reacción de 2 moles de un anhídrido cíclico yun mol de 2-metil-1,3-propanodiol para utilizar en el proceso de elaboraciónde las resinas de polieteréster.The process consists of reacting a polyether with a diol diester in the presence of a catalyst that favors the random insertion of the diester in the carbon-oxygen bonds of the polyether to produce the polyether ester resin. The process offers several advantages, including higher resin yields, decreased by-product production, and the ability to obtain low-color, low-acid resins. The resins are useful for making thermosetting polyester products. It also relates to a process for making a polyether ester thermoset product which comprises reacting the polyether ester resin with a vinyl monomer in the presence of a radical initiator and hardening to obtain the thermosetting product. Another object relates to a diester diol comprising the reaction product of 2 moles of a cyclic anhydride and one mole of 2-methyl-1,3-propanediol to be used in the process of making polyetherster resins.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/619,059 US5677396A (en) | 1996-03-20 | 1996-03-20 | Polyetherester resins from diol diesters |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR006280A1 true AR006280A1 (en) | 1999-08-11 |
Family
ID=24480294
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP970101084A AR006280A1 (en) | 1996-03-20 | 1997-03-19 | A PROCESS TO ELABORATE POLYETHESTER RESINS MADE FROM DIOL DIESTERS; SAID POLYETERESTER RESINS; A THERMOFRAGUED DEPOLIETERESTER PRODUCT AND A DIOL DIESTER TO BE USED IN SUCH PROCESS |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US5677396A (en) |
| EP (1) | EP0888396B1 (en) |
| JP (1) | JP2001500536A (en) |
| KR (1) | KR20000064763A (en) |
| CN (1) | CN1214060A (en) |
| AR (1) | AR006280A1 (en) |
| AU (1) | AU732091B2 (en) |
| BR (1) | BR9708129A (en) |
| CA (1) | CA2250072C (en) |
| DE (1) | DE69718449T2 (en) |
| ES (1) | ES2188923T3 (en) |
| NO (1) | NO984367L (en) |
| WO (1) | WO1997034942A1 (en) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5780558A (en) * | 1997-09-25 | 1998-07-14 | Arco Chemical Technology, L.P. | Process for making dicyclopentadiene polyetherester resins |
| US5770659A (en) * | 1997-11-10 | 1998-06-23 | Arco Chemical Technology, L.P. | Process for making storage-stable epoxy-capped polyetherester resins |
| US5952436A (en) * | 1998-01-13 | 1999-09-14 | Arco Chemical Technology, L.P. | Process for making water-resistant polyetherester resins and thermosets |
| US5880225A (en) * | 1998-02-18 | 1999-03-09 | Arco Chemical Technology, L.P. | Process for making polyetherester resins having high aromatic diester |
| US6348270B1 (en) | 1999-09-01 | 2002-02-19 | Reichhold Inc. | High performance polyetherester containing laminating resin compositions |
| US6492487B1 (en) * | 2001-09-05 | 2002-12-10 | Arco Chemical Technology, L.P. | Process for making reactive unsaturated polyester resins from 2-methyl-1, 3-propanediol |
| US6555623B1 (en) | 2002-03-18 | 2003-04-29 | Arco Chemical Technology, L.P. | Preparation of unsaturated polyesters |
| US6696521B2 (en) * | 2002-07-29 | 2004-02-24 | Arco Chemical Technology, Lp | High performance ortho UPR |
| US6977282B1 (en) | 2004-08-11 | 2005-12-20 | Lyondell Chemical Technology, L.P. | Preparation of dicyclopentadiene-containing unsaturated polyesters |
| EP2837647A1 (en) * | 2013-08-16 | 2015-02-18 | BASF Coatings GmbH | Carboxyfunctional poly and diester derivatives |
| CN113185679B (en) * | 2021-05-27 | 2022-02-08 | 天津大学 | Preparation method of polyether ester |
| CN114369236B (en) * | 2021-11-30 | 2024-04-12 | 山东一诺威新材料有限公司 | High-performance polyester ether polyol, and preparation method and application thereof |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3280067A (en) * | 1961-04-03 | 1966-10-18 | Monsanto Co | Plasticized halogen-containing resins |
| DE3202300C1 (en) * | 1982-01-26 | 1983-07-28 | Th. Goldschmidt Ag, 4300 Essen | Process for making epoxy resins flexible |
| EP0103893A3 (en) * | 1982-09-22 | 1986-03-19 | Daicel Chemical Industries, Ltd. | Macrocyclic diesters |
| JPS6119649A (en) * | 1984-07-06 | 1986-01-28 | Adeka Argus Chem Co Ltd | Polyvinyl chloride resin composition |
| US5319006A (en) * | 1992-11-23 | 1994-06-07 | Arco Chemical Technology, L.P. | Preparation of polyesters from polyethers by an ester-insertion process |
| DE69522251T2 (en) * | 1994-03-30 | 2002-06-13 | Arco Chemical Technology, L.P. | Process for the preparation of a polyetherester |
| US5436313A (en) * | 1994-03-30 | 1995-07-25 | Arco Chemical Technology, L.P. | Process for making a polyetherester |
| US5436314A (en) * | 1994-04-18 | 1995-07-25 | Arco Chemical Technology, L.P. | Process for making a polyetherester by insertion of a carboxylic acid into a polyether |
| US5612444A (en) * | 1995-03-28 | 1997-03-18 | Arco Chemical Technology, L.P. | Process for making polyetheresters with high aromatic ester content |
-
1996
- 1996-03-20 US US08/619,059 patent/US5677396A/en not_active Expired - Fee Related
-
1997
- 1997-03-13 KR KR1019980707526A patent/KR20000064763A/en not_active Withdrawn
- 1997-03-13 CA CA002250072A patent/CA2250072C/en not_active Expired - Fee Related
- 1997-03-13 WO PCT/EP1997/001272 patent/WO1997034942A1/en not_active Ceased
- 1997-03-13 EP EP97914236A patent/EP0888396B1/en not_active Expired - Lifetime
- 1997-03-13 JP JP09533124A patent/JP2001500536A/en active Pending
- 1997-03-13 ES ES97914236T patent/ES2188923T3/en not_active Expired - Lifetime
- 1997-03-13 AU AU21561/97A patent/AU732091B2/en not_active Ceased
- 1997-03-13 CN CN97193161A patent/CN1214060A/en active Pending
- 1997-03-13 DE DE69718449T patent/DE69718449T2/en not_active Expired - Fee Related
- 1997-03-13 BR BR9708129A patent/BR9708129A/en not_active Application Discontinuation
- 1997-03-19 AR ARP970101084A patent/AR006280A1/en unknown
-
1998
- 1998-09-18 NO NO984367A patent/NO984367L/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| AU2156197A (en) | 1997-10-10 |
| EP0888396A1 (en) | 1999-01-07 |
| CN1214060A (en) | 1999-04-14 |
| EP0888396B1 (en) | 2003-01-15 |
| WO1997034942A1 (en) | 1997-09-25 |
| NO984367D0 (en) | 1998-09-18 |
| AU732091B2 (en) | 2001-04-12 |
| CA2250072A1 (en) | 1997-09-25 |
| JP2001500536A (en) | 2001-01-16 |
| BR9708129A (en) | 1999-07-27 |
| ES2188923T3 (en) | 2003-07-01 |
| NO984367L (en) | 1998-11-19 |
| DE69718449D1 (en) | 2003-02-20 |
| KR20000064763A (en) | 2000-11-06 |
| DE69718449T2 (en) | 2003-10-02 |
| CA2250072C (en) | 2005-10-25 |
| US5677396A (en) | 1997-10-14 |
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