AR006266A1 - Catalizador de polimerizacion de coordinacion, complejo de metal comprendido en el mismo y proceso de polimerizacion que lo aplica - Google Patents
Catalizador de polimerizacion de coordinacion, complejo de metal comprendido en el mismo y proceso de polimerizacion que lo aplicaInfo
- Publication number
- AR006266A1 AR006266A1 ARP970101064A ARP970101064A AR006266A1 AR 006266 A1 AR006266 A1 AR 006266A1 AR P970101064 A ARP970101064 A AR P970101064A AR P970101064 A ARP970101064 A AR P970101064A AR 006266 A1 AR006266 A1 AR 006266A1
- Authority
- AR
- Argentina
- Prior art keywords
- applies
- same
- metal complex
- group
- complex included
- Prior art date
Links
- 238000006116 polymerization reaction Methods 0.000 title abstract 2
- 150000004696 coordination complex Chemical class 0.000 title 1
- 238000012718 coordination polymerization Methods 0.000 title 1
- 239000002685 polymerization catalyst Substances 0.000 title 1
- 239000003054 catalyst Substances 0.000 abstract 2
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 2
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 125000003800 germyl group Chemical class [H][Ge]([H])([H])[*] 0.000 abstract 1
- 125000005647 linker group Chemical group 0.000 abstract 1
- 239000000203 mixture Chemical class 0.000 abstract 1
- 125000001181 organosilyl group Chemical class [SiH3]* 0.000 abstract 1
- 239000004711 α-olefin Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Se trata de complejos de metal del Grupo 4 que comprenden un grupo indenilo sustituido en la posición 2 ó 3 con por lo menos un grupo seleccionado entrehidrocarbilo, hidrocarbilo perfluoro-sustituido, sililo, germilo y mezclas de los mismos, endon de dicho grupo indenilo se encuentra en enlace covalente conel metal por medio de un grupo ligante divalente. Se proponen también catalizadores que incluyen dichos complejos y la polimerización de alfa-olefinas aplicando dichoscatalizadore s.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US591395P | 1995-10-27 | 1995-10-27 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR006266A1 true AR006266A1 (es) | 1999-08-11 |
Family
ID=21718328
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP970101064A AR006266A1 (es) | 1995-10-27 | 1997-03-18 | Catalizador de polimerizacion de coordinacion, complejo de metal comprendido en el mismo y proceso de polimerizacion que lo aplica |
Country Status (22)
| Country | Link |
|---|---|
| EP (1) | EP0874860B1 (es) |
| JP (1) | JP4454698B2 (es) |
| KR (1) | KR100419698B1 (es) |
| CN (1) | CN1098857C (es) |
| AR (1) | AR006266A1 (es) |
| AT (1) | ATE227729T1 (es) |
| AU (1) | AU717869B2 (es) |
| BR (1) | BR9611128A (es) |
| CA (1) | CA2229608C (es) |
| CZ (1) | CZ129998A3 (es) |
| DE (1) | DE69624839T2 (es) |
| ES (1) | ES2183978T3 (es) |
| HU (1) | HUP9802868A3 (es) |
| MY (1) | MY127666A (es) |
| NO (1) | NO322510B1 (es) |
| PL (1) | PL186283B1 (es) |
| PT (1) | PT874860E (es) |
| RO (1) | RO118295B1 (es) |
| RU (1) | RU2175325C2 (es) |
| TW (1) | TW430674B (es) |
| WO (1) | WO1997015583A1 (es) |
| ZA (1) | ZA969000B (es) |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE69710491T2 (de) * | 1996-12-19 | 2002-10-02 | The Dow Chemical Co., Midland | Metallkomplexe enthaltend in position 3 arylsubstituierte indenylderivate, und polymerisationsverfahren |
| US5965756A (en) * | 1996-12-19 | 1999-10-12 | The Dow Chemical Company | Fused ring substituted indenyl metal complexes and polymerization process |
| US6420507B1 (en) | 1997-05-01 | 2002-07-16 | The Dow Chemical Company | Olefin polymers prepared with substituted indenyl containing metal complexes |
| AR012645A1 (es) * | 1997-05-01 | 2000-11-08 | Dow Global Technologies Inc | Polimeros de alfa-olefinas preparados por polimerizacion en presencia de complejos de metales que contienen grupos indenilo |
| US6150297A (en) | 1997-09-15 | 2000-11-21 | The Dow Chemical Company | Cyclopentaphenanthrenyl metal complexes and polymerization process |
| US6630545B2 (en) | 1997-09-15 | 2003-10-07 | The Dow Chemical Company | Polymerization process |
| EP0980375B1 (en) * | 1998-01-30 | 2005-11-09 | Boulder Scientific Company | N-silylated compound synthesis |
| KR100623106B1 (ko) | 1998-11-02 | 2006-09-13 | 다우 글로벌 테크놀로지스 인크. | 전단시닝 에틸렌/α―올레핀 인터폴리머 및 그의 제조 방법 |
| US6806327B2 (en) | 2000-06-30 | 2004-10-19 | Dow Global Technologies Inc. | Substituted polycyclic, fused ring compounds, metal complexes and polymerization process |
| WO2002002577A1 (en) * | 2000-06-30 | 2002-01-10 | Dow Global Technology Inc. | Polycyclic, fused ring compounds, metal complexes and polymerization process |
| DE60204686T2 (de) * | 2001-05-14 | 2006-05-18 | Dow Global Technologies, Inc., Midland | 3-arylsubstituierte zyklopentadienyl-metal-komplexe und polymerisationsverfahren |
| US6946531B2 (en) | 2001-05-14 | 2005-09-20 | Dow Global Technologies Inc. | Low molecular weight ethylene interpolymers and polymerization process |
| JP4624679B2 (ja) * | 2002-03-14 | 2011-02-02 | ダウ グローバル テクノロジーズ インコーポレイティド | 置換インデニル金属錯体及び重合方法 |
| US6927264B2 (en) | 2003-05-28 | 2005-08-09 | Dow Global Technologies Inc. | Metal complexes and polymerization process using same |
| RU2373592C1 (ru) * | 2006-09-11 | 2009-11-20 | Асахи Касеи Кабусики Кайся | Полимерный электролит, способ его получения и электрохимический элемент |
| MY158186A (en) | 2009-07-28 | 2016-09-15 | Univation Tech Llc | Polymerization process using a supported constrained geometry catalyst |
| CA2724943A1 (en) * | 2010-12-10 | 2012-06-10 | Nova Chemicals Corporation | Catalyst activation in a dual reactor process |
| US9708418B2 (en) | 2011-03-08 | 2017-07-18 | Dow Global Technologies Llc | Process for recycling solvent used in an ethylene-based polymerization reaction and system therefor |
| US8664461B2 (en) * | 2012-03-19 | 2014-03-04 | Exxonmobil Chemical Patents Inc. | Catalysts for producing polyalpha-olefins and processes related thereto |
| ES2746913T3 (es) | 2015-01-06 | 2020-03-09 | Scg Chemicals Co Ltd | Microesferas de hidróxido doble con capa de SiO2 y métodos para fabricarlas |
| KR102010630B1 (ko) * | 2016-01-20 | 2019-08-13 | 한화토탈 주식회사 | 올레핀 중합촉매 및 이를 이용한 올레핀 중합방법 |
| GB201608384D0 (en) | 2016-05-12 | 2016-06-29 | Scg Chemicals Co Ltd | Unsymmetrical metallocene catalysts and uses thereof |
| GB201610457D0 (en) * | 2016-06-15 | 2016-07-27 | Scg Chemicals Co Ltd | Catalysts |
| KR101870513B1 (ko) | 2016-06-29 | 2018-06-22 | 강정영 | 소형 탈취장치 |
| CN112939844B (zh) * | 2019-12-10 | 2023-02-03 | 华东师范大学 | 一种多取代四氢咔唑及其衍生物及其合成方法和应用 |
| WO2022155026A1 (en) | 2021-01-12 | 2022-07-21 | Exxonmobil Chemical Patents Inc. | Asymmetric constrained geometry catalysts |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL8600045A (nl) * | 1986-01-11 | 1987-08-03 | Stamicarbon | Katalysatorsysteem voor hoge temperatuur (co)polymerisatie van etheen. |
| US5096867A (en) * | 1990-06-04 | 1992-03-17 | Exxon Chemical Patents Inc. | Monocyclopentadienyl transition metal olefin polymerization catalysts |
| NZ235032A (en) * | 1989-08-31 | 1993-04-28 | Dow Chemical Co | Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component |
| US5026798A (en) * | 1989-09-13 | 1991-06-25 | Exxon Chemical Patents Inc. | Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system |
| EP0705269B1 (en) * | 1993-06-24 | 1997-01-15 | The Dow Chemical Company | Titanium(ii) or zirconium(ii) complexes and addition polymerization catalysts therefrom |
| WO1995014024A1 (en) * | 1993-11-18 | 1995-05-26 | Idemitsu Kosan Co., Ltd. | Transition metal compound, olefin polymerization catalyst, and process for producing olefin polymer by using said catalyst |
| ATE185822T1 (de) * | 1994-09-02 | 1999-11-15 | Dow Chemical Co | Wärmehärtbare elastomere |
-
1996
- 1996-10-03 DE DE69624839T patent/DE69624839T2/de not_active Expired - Lifetime
- 1996-10-03 HU HU9802868A patent/HUP9802868A3/hu unknown
- 1996-10-03 AU AU73929/96A patent/AU717869B2/en not_active Ceased
- 1996-10-03 WO PCT/US1996/016012 patent/WO1997015583A1/en not_active Ceased
- 1996-10-03 AT AT96936227T patent/ATE227729T1/de not_active IP Right Cessation
- 1996-10-03 CA CA002229608A patent/CA2229608C/en not_active Expired - Fee Related
- 1996-10-03 RO RO98-00892A patent/RO118295B1/ro unknown
- 1996-10-03 JP JP51662097A patent/JP4454698B2/ja not_active Expired - Lifetime
- 1996-10-03 KR KR10-1998-0702982A patent/KR100419698B1/ko not_active Expired - Lifetime
- 1996-10-03 RU RU98109935/04A patent/RU2175325C2/ru not_active IP Right Cessation
- 1996-10-03 ES ES96936227T patent/ES2183978T3/es not_active Expired - Lifetime
- 1996-10-03 PL PL96326426A patent/PL186283B1/pl not_active IP Right Cessation
- 1996-10-03 CZ CZ981299A patent/CZ129998A3/cs unknown
- 1996-10-03 CN CN96197902A patent/CN1098857C/zh not_active Expired - Lifetime
- 1996-10-03 BR BR9611128A patent/BR9611128A/pt not_active IP Right Cessation
- 1996-10-03 EP EP96936227A patent/EP0874860B1/en not_active Expired - Lifetime
- 1996-10-03 PT PT96936227T patent/PT874860E/pt unknown
- 1996-10-24 TW TW085113065A patent/TW430674B/zh not_active IP Right Cessation
- 1996-10-25 ZA ZA9609000A patent/ZA969000B/xx unknown
- 1996-10-25 MY MYPI96004449A patent/MY127666A/en unknown
-
1997
- 1997-03-18 AR ARP970101064A patent/AR006266A1/es active IP Right Grant
-
1998
- 1998-04-24 NO NO19981854A patent/NO322510B1/no not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| KR100419698B1 (ko) | 2004-05-17 |
| KR19990067045A (ko) | 1999-08-16 |
| ZA969000B (en) | 1998-04-28 |
| AU717869B2 (en) | 2000-04-06 |
| NO322510B1 (no) | 2006-10-16 |
| NO981854D0 (no) | 1998-04-24 |
| CA2229608A1 (en) | 1997-05-01 |
| WO1997015583A1 (en) | 1997-05-01 |
| DE69624839D1 (de) | 2002-12-19 |
| CA2229608C (en) | 2005-06-21 |
| JPH11514376A (ja) | 1999-12-07 |
| RO118295B1 (ro) | 2003-04-30 |
| NO981854L (no) | 1998-06-23 |
| CN1200735A (zh) | 1998-12-02 |
| DE69624839T2 (de) | 2003-08-28 |
| EP0874860B1 (en) | 2002-11-13 |
| CZ129998A3 (cs) | 1998-08-12 |
| PL186283B1 (pl) | 2003-12-31 |
| HUP9802868A3 (en) | 1999-04-28 |
| TW430674B (en) | 2001-04-21 |
| RU2175325C2 (ru) | 2001-10-27 |
| MY127666A (en) | 2006-12-29 |
| ATE227729T1 (de) | 2002-11-15 |
| BR9611128A (pt) | 1999-03-30 |
| ES2183978T3 (es) | 2003-04-01 |
| PL326426A1 (en) | 1998-09-14 |
| HUP9802868A2 (hu) | 1999-03-29 |
| CN1098857C (zh) | 2003-01-15 |
| EP0874860A1 (en) | 1998-11-04 |
| PT874860E (pt) | 2003-02-28 |
| JP4454698B2 (ja) | 2010-04-21 |
| AU7392996A (en) | 1997-05-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG | Grant, registration |