AR005532A1 - DIHALOPROPEN COMPOUNDS, THE INSECTICIDE / ACARICIDE COMPOSITIONS CONTAINING THEM AND THE SYNTHESIS INTERMEDIARIES OF SUCH COMPOUNDS - Google Patents
DIHALOPROPEN COMPOUNDS, THE INSECTICIDE / ACARICIDE COMPOSITIONS CONTAINING THEM AND THE SYNTHESIS INTERMEDIARIES OF SUCH COMPOUNDSInfo
- Publication number
- AR005532A1 AR005532A1 ARP970100278A ARP970100278A AR005532A1 AR 005532 A1 AR005532 A1 AR 005532A1 AR P970100278 A ARP970100278 A AR P970100278A AR P970100278 A ARP970100278 A AR P970100278A AR 005532 A1 AR005532 A1 AR 005532A1
- Authority
- AR
- Argentina
- Prior art keywords
- compounds
- alkyl
- hydrogen
- dihalopropen
- insecticide
- Prior art date
Links
- 150000001875 compounds Chemical class 0.000 title abstract 5
- 239000000203 mixture Substances 0.000 title abstract 3
- 230000015572 biosynthetic process Effects 0.000 title abstract 2
- 238000003786 synthesis reaction Methods 0.000 title abstract 2
- 230000000895 acaricidal effect Effects 0.000 title 1
- 239000000642 acaricide Substances 0.000 title 1
- 239000002917 insecticide Substances 0.000 title 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 5
- 239000001257 hydrogen Substances 0.000 abstract 5
- 125000006273 (C1-C3) alkyl group Chemical group 0.000 abstract 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 3
- 229910052760 oxygen Inorganic materials 0.000 abstract 3
- 239000001301 oxygen Substances 0.000 abstract 3
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- 150000002367 halogens Chemical class 0.000 abstract 2
- 230000000749 insecticidal effect Effects 0.000 abstract 2
- 230000003129 miticidal effect Effects 0.000 abstract 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 abstract 1
- 125000004450 alkenylene group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000002947 alkylene group Chemical group 0.000 abstract 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052794 bromium Inorganic materials 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 239000000543 intermediate Substances 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
- 239000011593 sulfur Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
- C07D295/16—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms
- C07D295/18—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms by radicals derived from carboxylic acids, or sulfur or nitrogen analogues thereof
- C07D295/182—Radicals derived from carboxylic acids
- C07D295/192—Radicals derived from carboxylic acids from aromatic carboxylic acids
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N39/00—Biocides, pest repellants or attractants, or plant growth regulators containing aryloxy- or arylthio-aliphatic or cycloaliphatic compounds, containing the group or, e.g. phenoxyethylamine, phenylthio-acetonitrile, phenoxyacetone
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/30—Derivatives containing the group >N—CO—N aryl or >N—CS—N—aryl
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C217/00—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton
- C07C217/78—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton
- C07C217/80—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of non-condensed six-membered aromatic rings
- C07C217/82—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of non-condensed six-membered aromatic rings of the same non-condensed six-membered aromatic ring
- C07C217/84—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of non-condensed six-membered aromatic rings of the same non-condensed six-membered aromatic ring the oxygen atom of at least one of the etherified hydroxy groups being further bound to an acyclic carbon atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C235/00—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms
- C07C235/42—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms having carbon atoms of carboxamide groups bound to carbon atoms of six-membered aromatic rings and singly-bound oxygen atoms bound to the same carbon skeleton
- C07C235/44—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms having carbon atoms of carboxamide groups bound to carbon atoms of six-membered aromatic rings and singly-bound oxygen atoms bound to the same carbon skeleton with carbon atoms of carboxamide groups and singly-bound oxygen atoms bound to carbon atoms of the same non-condensed six-membered aromatic ring
- C07C235/46—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms having carbon atoms of carboxamide groups bound to carbon atoms of six-membered aromatic rings and singly-bound oxygen atoms bound to the same carbon skeleton with carbon atoms of carboxamide groups and singly-bound oxygen atoms bound to carbon atoms of the same non-condensed six-membered aromatic ring having the nitrogen atoms of the carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C271/00—Derivatives of carbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
- C07C271/06—Esters of carbamic acids
- C07C271/40—Esters of carbamic acids having oxygen atoms of carbamate groups bound to carbon atoms of six-membered aromatic rings
- C07C271/42—Esters of carbamic acids having oxygen atoms of carbamate groups bound to carbon atoms of six-membered aromatic rings with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms
- C07C271/44—Esters of carbamic acids having oxygen atoms of carbamate groups bound to carbon atoms of six-membered aromatic rings with the nitrogen atoms of the carbamate groups bound to hydrogen atoms or to acyclic carbon atoms to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C275/00—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
- C07C275/28—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups having nitrogen atoms of urea groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
- C07C275/32—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups having nitrogen atoms of urea groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton being further substituted by singly-bound oxygen atoms
- C07C275/34—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups having nitrogen atoms of urea groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton being further substituted by singly-bound oxygen atoms having nitrogen atoms of urea groups and singly-bound oxygen atoms bound to carbon atoms of the same non-condensed six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C65/00—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
- C07C65/21—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups containing ether groups, groups, groups, or groups
- C07C65/24—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups containing ether groups, groups, groups, or groups polycyclic
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C65/00—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
- C07C65/21—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups containing ether groups, groups, groups, or groups
- C07C65/28—Compounds having carboxyl groups bound to carbon atoms of six—membered aromatic rings and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups containing ether groups, groups, groups, or groups having unsaturation outside the aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/76—Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring
- C07C69/84—Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring of monocyclic hydroxy carboxylic acids, the hydroxy groups and the carboxyl groups of which are bound to carbon atoms of a six-membered aromatic ring
- C07C69/92—Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring of monocyclic hydroxy carboxylic acids, the hydroxy groups and the carboxyl groups of which are bound to carbon atoms of a six-membered aromatic ring with etherified hydroxyl groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Agronomy & Crop Science (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Se describen compuestos de dihalopropeno de la fórmula general (I), en donde R, R2 y R3 son cada uno independientemente halógeno C1-C3, alquilo osemejante; R4 es hidrógeno o C1-C3 alquilo; R5 y R6 son cada uno independientemente hidrógeno C1-C3 alquilo o semejante; R7 es halógeno,C1-C3 alquilo o semejante o R8 y R9 son cada uno independientemente, hidrógeno C1-C6 alquilo o semejante; R8 y R9 se combinan juntos para formaropcionalmente C2-C6 alquileno sustituido o C4-C6 alquenileno; Q1 es un enlace simple o un grupo de enlace; Q2 es un enlace simple, oxígeno o NR14 en elcual R14 es hidrógeno o C1-C3 alquilo; las X son cada una independientemente cloro o bromo; Y es oxígeno, NH o sulfuro; Z es oxígeno, azufre o NR15 en elcual R15 es hidrógeno o C1-C3 alquilo; l es un entero de 0 a 4; p es un entero de 0 a 6; y r es un entero de 0 a 2. Dichos compuestos tienen excelenteactividad insecticida/acaricida y son, por lo tanto, útiles como ingredientes de agentes o composiciones insecticidas/acaricidas. Se describen dichascomposiciones y los intermediarios de síntesis de los compuestos de la fórmula (I).Dihalopropene compounds of the general formula (I) are described, wherein R, R2 and R3 are each independently C1-C3 halogen, alkyl or the like; R4 is hydrogen or C1-C3 alkyl; R5 and R6 are each independently hydrogen C1-C3 alkyl or the like; R7 is halogen, C1-C3 alkyl or the like or R8 and R9 are each independently hydrogen C1-C6 alkyl or the like; R8 and R9 are combined together to optionally form C2-C6 substituted alkylene or C4-C6 alkenylene; Q1 is a single bond or a bond group; Q2 is a single bond, oxygen or NR14 in which R14 is hydrogen or C1-C3 alkyl; the Xs are each independently chlorine or bromine; Y is oxygen, NH, or sulfide; Z is oxygen, sulfur or NR15 in which R15 is hydrogen or C1-C3 alkyl; l is an integer from 0 to 4; p is an integer from 0 to 6; and r is an integer from 0 to 2. Such compounds have excellent insecticidal / miticidal activity and are therefore useful as ingredients of insecticidal / miticidal agents or compositions. Said compositions and the synthesis intermediates of the compounds of formula (I) are described.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1042496 | 1996-01-24 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR005532A1 true AR005532A1 (en) | 1999-06-23 |
Family
ID=11749780
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP970100278A AR005532A1 (en) | 1996-01-24 | 1997-01-23 | DIHALOPROPEN COMPOUNDS, THE INSECTICIDE / ACARICIDE COMPOSITIONS CONTAINING THEM AND THE SYNTHESIS INTERMEDIARIES OF SUCH COMPOUNDS |
Country Status (5)
| Country | Link |
|---|---|
| AR (1) | AR005532A1 (en) |
| AU (1) | AU1399297A (en) |
| CO (1) | CO4770917A1 (en) |
| WO (1) | WO1997027173A2 (en) |
| ZA (1) | ZA97559B (en) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10155385A1 (en) | 2001-11-10 | 2003-05-28 | Bayer Cropscience Gmbh | Dihalopropene compounds, processes for their preparation, compositions containing them and their use as pesticides |
| TW200406370A (en) * | 2002-06-28 | 2004-05-01 | Syngenta Participations Ag | 4-(3,3-Dihalo-allyloxy)phenoxy alkyl derivatives |
| TW200406152A (en) * | 2002-08-30 | 2004-05-01 | Syngenta Participations Ag | 4-(3,3-Dihalo-allyloxy) phenol derivatives having pesticidal properties |
| TW200507752A (en) | 2003-06-23 | 2005-03-01 | Syngenta Participations Ag | Pesticidally active ketone and oxime derivatives |
| US7723362B2 (en) | 2004-01-08 | 2010-05-25 | Syngenta Crop Protection, Inc. | Pesticidal heterocyclic dihaloallyl compounds |
| WO2009050707A1 (en) | 2007-10-15 | 2009-04-23 | Can-Fite Biopharma Ltd. | Method for inducing hepatocyte proliferation and uses thereof |
| KR20120022919A (en) | 2009-05-17 | 2012-03-12 | 캔-파이트 바이오파마 리미티드 | A3 adenosine receptor agonists for the reduction of intraocular pressure |
| EP2456419B1 (en) | 2009-07-21 | 2016-11-23 | Oradin Pharmaceutical Ltd. | A3 adenosine receptor ligands for modulation of pigmentation |
| EP2542242A1 (en) | 2010-03-03 | 2013-01-09 | The Govt. Of U.S.A. As Represented By The Secretary Of The Department Of Health And Human Services | A3ar agonists for the treatment of uveitis |
| CN102718701B (en) | 2011-03-30 | 2014-05-07 | 中国中化股份有限公司 | Aryloxy dihalide propylene ether compound and application thereof |
| WO2014024195A1 (en) | 2012-08-09 | 2014-02-13 | Can-Fite Biopharma Ltd. | A3 adenosine receptor ligands for use in treatment of a sexual dysfunction |
| IL242723B (en) | 2015-11-23 | 2019-12-31 | Can Fite Biopharma Ltd | An a3 adenosine receptor ligand for use in treating ectopic fat accumulation |
| IL254535A0 (en) | 2017-09-17 | 2017-11-30 | Can Fite Biopharma Ltd | A3 adenosine receptor ligand for managing cytokine release syndrome |
| IL264112A (en) | 2019-01-06 | 2020-07-30 | Fishman Pnina | An a3 adenosine receptor ligand for use for reducing level of adipocytes |
| IT202300014340A1 (en) | 2023-07-10 | 2025-01-10 | Consiglio Nazionale Ricerche | TREATMENT OF DISEASES ASSOCIATED WITH OCRL GENE DYSFUNCTION. |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IL111252A0 (en) * | 1993-10-19 | 1994-12-29 | Sumitomo Chemical Co | Dihalopropene compound, insecticide/acaricide containing said dihalopropene compound as active ingredient,and intermediate compound for use in production of said dihalopropene compound |
| JPH07330651A (en) * | 1994-06-14 | 1995-12-19 | Sumitomo Chem Co Ltd | Dihalopropene compound and insecticide containing the same as active ingredient |
| CZ129696A3 (en) * | 1994-08-04 | 1996-09-11 | Sumitomo Chemical Co | Dihalogenpropene compounds, insecticidal-acaricidal agents in which said compounds are comprised and intermediates for their preparation |
| TW307746B (en) * | 1994-10-14 | 1997-06-11 | Sumitomo Chemical Co | |
| DE69610204T2 (en) * | 1995-04-18 | 2001-05-03 | Sumitomo Chemical Co., Ltd. | DIHALOPROPEN COMPOUNDS, THESE INSECTICIDES AND INTERMEDIATES FOR THEIR PRODUCTION |
-
1997
- 1997-01-17 WO PCT/JP1997/000076 patent/WO1997027173A2/en not_active Ceased
- 1997-01-17 AU AU13992/97A patent/AU1399297A/en not_active Abandoned
- 1997-01-23 CO CO97003007A patent/CO4770917A1/en unknown
- 1997-01-23 ZA ZA9700559A patent/ZA97559B/en unknown
- 1997-01-23 AR ARP970100278A patent/AR005532A1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| WO1997027173A3 (en) | 1998-04-02 |
| WO1997027173A2 (en) | 1997-07-31 |
| CO4770917A1 (en) | 1999-04-30 |
| AU1399297A (en) | 1997-08-20 |
| ZA97559B (en) | 1997-07-30 |
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