NZ735104B2 - A process for manufacturing plasterboard liner (PBL) for plaster board - Google Patents
A process for manufacturing plasterboard liner (PBL) for plaster board Download PDFInfo
- Publication number
- NZ735104B2 NZ735104B2 NZ735104A NZ73510416A NZ735104B2 NZ 735104 B2 NZ735104 B2 NZ 735104B2 NZ 735104 A NZ735104 A NZ 735104A NZ 73510416 A NZ73510416 A NZ 73510416A NZ 735104 B2 NZ735104 B2 NZ 735104B2
- Authority
- NZ
- New Zealand
- Prior art keywords
- pbl
- paper
- fibre
- rcf
- vkf
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 91
- 230000008569 process Effects 0.000 title claims abstract description 91
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 46
- 239000011505 plaster Substances 0.000 title claims abstract description 13
- 239000000123 paper Substances 0.000 claims abstract description 170
- 239000000835 fiber Substances 0.000 claims abstract description 118
- 238000004513 sizing Methods 0.000 claims abstract description 60
- 239000000203 mixture Substances 0.000 claims abstract description 49
- 239000002655 kraft paper Substances 0.000 claims abstract description 32
- 238000001035 drying Methods 0.000 claims abstract description 31
- 238000002156 mixing Methods 0.000 claims abstract description 29
- 239000011436 cob Substances 0.000 claims description 17
- 239000011087 paperboard Substances 0.000 abstract description 4
- 238000000576 coating method Methods 0.000 description 55
- 239000011248 coating agent Substances 0.000 description 54
- 239000000126 substance Substances 0.000 description 44
- 239000000049 pigment Substances 0.000 description 42
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 33
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 17
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 17
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 17
- 238000002360 preparation method Methods 0.000 description 16
- 238000005516 engineering process Methods 0.000 description 14
- 229910052602 gypsum Inorganic materials 0.000 description 13
- 239000010440 gypsum Substances 0.000 description 13
- 239000002002 slurry Substances 0.000 description 13
- 230000008901 benefit Effects 0.000 description 12
- 150000002500 ions Chemical class 0.000 description 11
- 238000010586 diagram Methods 0.000 description 9
- 229920003043 Cellulose fiber Polymers 0.000 description 8
- 239000000654 additive Substances 0.000 description 8
- 125000002091 cationic group Chemical group 0.000 description 8
- 229920002472 Starch Polymers 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 7
- 235000019698 starch Nutrition 0.000 description 7
- -1 Alkyl Ketene Dimer Chemical compound 0.000 description 6
- 230000000996 additive effect Effects 0.000 description 6
- 239000011111 cardboard Substances 0.000 description 6
- 239000008107 starch Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 5
- 125000000129 anionic group Chemical group 0.000 description 5
- BUACSMWVFUNQET-UHFFFAOYSA-H dialuminum;trisulfate;hydrate Chemical compound O.[Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O BUACSMWVFUNQET-UHFFFAOYSA-H 0.000 description 5
- 239000010813 municipal solid waste Substances 0.000 description 5
- 102200150779 rs200154873 Human genes 0.000 description 5
- 238000006467 substitution reaction Methods 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- 229940037003 alum Drugs 0.000 description 4
- 239000000356 contaminant Substances 0.000 description 4
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 238000011068 loading method Methods 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 238000007670 refining Methods 0.000 description 4
- 229920000881 Modified starch Polymers 0.000 description 3
- 235000019426 modified starch Nutrition 0.000 description 3
- 238000005728 strengthening Methods 0.000 description 3
- 208000012641 Pigmentation disease Diseases 0.000 description 2
- 229920001131 Pulp (paper) Polymers 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000019612 pigmentation Effects 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 238000002203 pretreatment Methods 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- GLLRIXZGBQOFLM-UHFFFAOYSA-N Xanthorin Natural products C1=C(C)C=C2C(=O)C3=C(O)C(OC)=CC(O)=C3C(=O)C2=C1O GLLRIXZGBQOFLM-UHFFFAOYSA-N 0.000 description 1
- 230000003466 anti-cipated effect Effects 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000001066 destructive effect Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 238000007380 fibre production Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- RECVMTHOQWMYFX-UHFFFAOYSA-N oxygen(1+) dihydride Chemical compound [OH2+] RECVMTHOQWMYFX-UHFFFAOYSA-N 0.000 description 1
- 239000010893 paper waste Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000004537 pulping Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000011122 softwood Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229940014800 succinic anhydride Drugs 0.000 description 1
- OORLZFUTLGXMEF-UHFFFAOYSA-N sulfentrazone Chemical compound O=C1N(C(F)F)C(C)=NN1C1=CC(NS(C)(=O)=O)=C(Cl)C=C1Cl OORLZFUTLGXMEF-UHFFFAOYSA-N 0.000 description 1
- 239000002352 surface water Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B13/00—Layered products comprising a a layer of water-setting substance, e.g. concrete, plaster, asbestos cement, or like builders' material
- B32B13/04—Layered products comprising a a layer of water-setting substance, e.g. concrete, plaster, asbestos cement, or like builders' material comprising such water setting substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B13/08—Layered products comprising a a layer of water-setting substance, e.g. concrete, plaster, asbestos cement, or like builders' material comprising such water setting substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
- B32B37/24—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer not being coherent before laminating, e.g. made up from granular material sprinkled onto a substrate
- B32B2037/243—Coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/26—All layers being made of paper or paperboard
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/12—Coating on the layer surface on paper layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2272/00—Resin or rubber layer comprising scrap, waste or recycling material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/718—Weight, e.g. weight per square meter
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/73—Hydrophobic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2310/00—Treatment by energy or chemical effects
- B32B2310/04—Treatment by energy or chemical effects using liquids, gas or steam
- B32B2310/0409—Treatment by energy or chemical effects using liquids, gas or steam using liquids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2554/00—Paper of special types, e.g. banknotes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2607/00—Walls, panels
- B32B2607/02—Wall papers, wall coverings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B29/00—Layered products comprising a layer of paper or cardboard
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/14—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
- B32B37/15—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer being manufactured and immediately laminated before reaching its stable state, e.g. in which a layer is extruded and laminated while in semi-molten state
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B38/16—Drying; Softening; Cleaning
- B32B38/164—Drying
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
- D21H11/02—Chemical or chemomechanical or chemothermomechanical pulp
- D21H11/04—Kraft or sulfate pulp
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
- D21H11/14—Secondary fibres
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/17—Ketenes, e.g. ketene dimers
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/62—Rosin; Derivatives thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/16—Sizing or water-repelling agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/10—Packing paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/30—Multi-ply
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/30—Multi-ply
- D21H27/40—Multi-ply at least one of the sheets being non-planar, e.g. crêped
Abstract
process for manufacturing paperboard liner (PBL) for plaster board, including the steps of receiving virgin Kraft fibre ( VKF); receiving recycled paper fibre (RCF); blending the VKF and the RCF to produce multiple fibre blend streams; forming said streams into paper plys; forming the plys into a multi ply paper sheet; chemically sizing the paper sheet to increase hydrophobicity; and drying the multi ply paper sheet over drying drums to produce the PBL, wherein the density of the PBL is no more than 140 grams per square meter (gsm). The liner has reduced weight whilst maintaining the necessary paper tensile strength, and has a light coloured surface. multi ply paper sheet; chemically sizing the paper sheet to increase hydrophobicity; and drying the multi ply paper sheet over drying drums to produce the PBL, wherein the density of the PBL is no more than 140 grams per square meter (gsm). The liner has reduced weight whilst maintaining the necessary paper tensile strength, and has a light coloured surface.
Description
(12) Granted patent specificaon (19) NZ (11) 735104 (13) B2
(47) Publicaon date: 2021.12.24
(54) A process for manufacturing plasterboard liner (PBL) for r board
(51) Internaonal Patent Classificaon(s):
B32B 13/08 B32B 29/00 B32B 33/00 B32B 37/14 D21H 21/14 D21H 11/14 D21H 19/00
D21H 27/30 D21H 11/04
(22) Filing date: (73) Owner(s):
2016.02.24 VISY R & D PTY LTD
(23) Complete specificaon filing date: (74) Contact:
2016.02.24 DAVIES COLLISON CAVE PTY LTD
(30) Internaonal Priority Data: (72) Inventor(s):
AU 0738 2015.03.03 CLARK, Robert Kenneth
MILUNOVIC, Vesna
(86) Internaonal Applicaon No.: LE ROUX, Gary Mark
2016/050122
(87) Internaonal Publicaon number:
WO/2016/138554
(57) Abstract:
A process for cturing oard liner (PBL) for plaster board, including the steps of
receiving virgin Kra fibre ( VKF); receiving recycled paper fibre (RCF); blending the VKF and the
RCF to produce mulple fibre blend streams; forming said streams into paper plys; forming the
plys into a mul ply paper sheet; chemically sizing the paper sheet to increase hydrophobicity; and
drying the mul ply paper sheet over drying drums to produce the PBL, wherein the density of
the PBL is no more than 140 grams per square meter (gsm). The liner has reduced weight whilst
maintaining the necessary paper tensile strength, and has a light ed surface.
NZ 735104 B2
C:\Users\tld\AppData\Roaming\iManage\Work\Recent\35272257NZ A system and process\Spec. inc. 2SPA clean pgs - 35272257(21827042.1).doc-4/08/2021
A PROCESS FOR MANUFACTURING PLASTERBOARD LINER (PBL) FOR
PLASTER BOARD.
Technical Field of the Invention
The present invention relates to a system and process for manufacturing plasterboard
liner. The plasterboard liner is preferably light weight Kraft based liner paper for the
production of plasterboard.
Background of the Invention
As shown in Figure 1, the manufacture of r board has traditionally involved the
steps of:
1. rolling out a layer of face plasterboard liner (face PBL );
2. pouring a slurry of Gypsum over the face PBL;
3. rolling out a layer of back plasterboard liner (back PBL) (also referred to as a
base) over slurry of gypsum;
4. cutting the plasterboard into sheets; and
5. drying the plasterboard sheets.
To be suitable for use in plasterboard, plasterboard liner (PBL ) has previously had the
following characteristics:
1. a high degree of ional stability with cross-direction wet expansion not
exceeding 0.7%; and
2. high degree of tensile th machine direction (MD ) to cross-direction (CD )
tensile ratio in the range of 2.4 to 2.8.
It is also desirable for face PBL to have a light coloured outer surface in anticipation of
the rboard being later painted.
A known system for manufacturing PBL is shown schematically in Figures 2a to 2d. As
shown, the system uses recycled paper fibre (RCF ) as the main source of paper fibre.
PBL manufactured using a majority of RCF can achieve the necessary end product
C:\Users\tld\AppData\Roaming\iManage\Work\Recent\35272257NZ A system and process\Spec. inc. 2SPA clean pgs - 35272257(21827042.1).doc-4/08/2021
(plasterboard) market characteristics of:
1. smooth, flat, ripple free surfaces evident by visual inspection;
2. high bending / flexural strength with breaking forc e MD:CD tensile ration not
less than 2.4; and
3. face having a light colour with diffuse blue reflectance factor (also known as
ISO brightness) not less than 40.
Over the past 15 years, PBL weight has been reduced from greater than 200 gsm to
150 gsm. This has been achieved through various incremental improvements that
have allowed for reduced RCF volume and hence weight. These improvements include:
a. General increase in RCF strength (due to increased Kraft fibre production from
virgin wood and subsequent OCC fibre increase);
b. General improvements to equipment, such as lower ply paper machines (i.e.
from 7 ply to 3 ply);
c. Better process knowledge and y control measures which, for example,
has allowed for improved fibre formation; and
d. Additives, such as starch, which are used to increase paper tensile strength.
PBL of weight r than 150 gsm ctured using 100% RCF has the
advantages of high dimensional stability and tensile strength which is necessary for
the subsequent manufacture of plasterboard sheet. However, it is generally desirable
to e a plasterboard liner that is lighter in weight and contains an appreciable
content of virgin fibre. To this end, the lighter PBL would:
1. Reduce fibre input per PBL unit ;
2. Increase volume of virgin Kraft fibre product per unit ted fibre;
3. Reduce transport cost per PBL unit ;
4. Increase plasterboard unit length per PBL unit weight; and
. Reduce plasterboard drying l energy per unit length.
PBL of weight less than 130 gsm manufactured using 100% RCF is not able as
it does not meet tensile strength requirements for subsequent plasterboard
manufacture. PBL with an appreciable content of virgin Kraft fibre is not marketable
C:\Users\tld\AppData\Roaming\iManage\Work\Recent\35272257NZ A system and process\Spec. inc. 2SPA clean pgs - 35272257(21827042.1).doc-4/08/2021
as it does not meet the dimensional stability requirements for subsequent
rboard manufacture.
Tensile strength for paper is expressed as MD:CD ratio. This is the ratio of the
maximum pulling stress before ng of the paper sheet in both the machine
direction (MD) and the cross ion (CD). In a paper sheet, fibres oriented in the
MD lay in the longitudinal direction of travel of the paper sheet through the paper
machine. Fibres oriented in the CD lay dicular to the MD. Traditional PBL of
greater than 150 gsm has a high MD:CD ratio for both back and face PBL. This is
because there is sufficient fibre available to allow non-specialised fibre orientation in
the PBL compared with l paper making in which the predominant fibre
orientation is in the MD.
Dimensional stability for paper means its resistance to change in size as the result of a
change in moisture content. Paper fibres have a natural tendency to absorb moisture
and hydro expand. A measure of dimensional ity is wet expansion, which is the
percentage difference between a paper sheet's dry and wet size. Traditional PBL of
greater than 150 gsm has a high dimensional stability in part because it does not
contain an appreciable content of virgin Kraft fibre.
Cellulose fibre used for paper making is recyclable. However, each time a fibre is
ed, it loses th until it is no longer able to be used. Typically, a cellulose
fibre can be recycled for paper making up to about 8 times. The term Kraft fibre is
derived from the Kraft process technology for converting wood into wood pulp and
extracting virgin cellulose fibres for paper manufacture. This process produces virgin
Kraft fibre that has not previously been used for paper manufacture. ‘Kraft’ is a
German word for ‘strength’. However, the term Kraft fibre also is used to more
broadly refer to cellulose fibres that retain strength similar to that of virgin cellulose
fibre and so it can encompass fibres that have been recycled up to about twice.
Kraft fibre is stronger than RCF and its inclusion in PBL can allow for reduced weight
whilst maintaining the ary paper tensile strength. However, the inclusion of
virgin Kraft fibre in PBL reduces the dimensional stability as virgin Kraft fibre is more
reactive in contact with moisture than recycled fibre. This is because the fibre is
damaged through each e, which s its strength and also makes it less
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reactive to t with moisture. The vity of cellulose fibre to contact with
water is a known phenomenon to which the paper industry worldwide invests
substantial research. This is important in the manufacture of plasterboard sheet as
the process involves contact with moisture via the gypsum slurry.
As mentioned, it is also ble for face PBL to have a light coloured outer
surface in anticipation of the rboard being later painted. A light coloured surface
for PBL face has usly been achieved through the addition of a ‘light colour fibre’
layer during the manufacture process. The process to produce RCF light colour fibre
imposes an ongoing operational expense and its feedstock of recovered white paper is
becoming less available. Figures 2a to 2d show schematically how this ‘light colour
fibre’ layer is produced from recovered white paper feedstock via a ing process
during the stock preparation stage.
It is generally desirable to overcome or rate one or more of the above
mentioned difficulties, or at least provide a useful alternative.
Summary of the Invention
In accordance with the invention, there is ed a process for manufacturing
plasterboard liner (PBL ) for plaster board, including the steps of:
(a) receiving virgin Kraft fibre (VKF );
(b) receiving recycled paper fibre (RCF );
(c) blending the VKF and the RCF to produce multiple fibre blend streams;
(d) forming said streams into paper plys;
(e) forming the plys into a multi ply paper sheet;
(f) chemically sizing the paper sheet to increase its hydrophobicity; and
(g) drying the multi ply paper sheet over drying drums to produce the PBL,
wherein a density of the PBL is no more than 140 grams per square meter
(gsm).
Preferably, the PBL is no more than 130 grams per square meter (gsm).
Preferably, a Cobb (60 second) value of the PBL is less than 30 gsm.
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Preferably, a cross direction wet expansion of the PBL is no greater than 0.8%.
Preferably, the step of blending results in multiple fibre blend streams each having a
substantially even mixture of RCF and VKF. For example, the substantially even
mixture includes greater than 35% VKF.
Preferably, the PBL is for a base of the plasterboard and the process includes the step
of manipulating fibres of the fibre blend streams so that a machine ion to cross
ion tensile ratio (MD:CD) of the PBL is not more than 1.4.
Preferably, the PBL is for a face of the plasterboard and the process includes the step
of lating fibres of the fibre blend streams so that a machine direction to cross
direction tensile ratio (MD:CD) of the PBL is not less than 2.2. Further, the process
advantageously es the step of applying a pigment coating to the face PBL. The
pigment coating preferably provides a light colour surface with diffuse blue reflectance
factor not less than 30. Alternatively, the pigment coating preferably provides a light
colour e with diffuse blue reflectance factor not less than 40.
The present invention also provides plasterboard liner for use in manufacturing
rboard formed from the described process.
The present invention also provides base plasterboard liner for use in manufacturing
plasterboard formed from the above-described process.
The present invention also provides face plasterboard liner for use in manufacturing
plasterboard formed from the above described process.
The present invention also provides plaster board, including gypsum interposed
between the above described face plasterboard liner and the above described base
plasterboard liner.
The present ion also es a system for manufacturing plasterboard liner
(PBL ) for plaster board, including:
(a) fibre preparation and blending apparatus, said apparatus for performing
the steps of:
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(i) receiving virgin Kraft fibre (VKF );
(ii) receiving ed paper fibre (RCF ); and
(iii) blending the VKF and the RCF to produce multiple fibre blend
s; and
(b) paper making apparatus, said paper making apparatus for performing
the steps of:
(i) receiving the multiple fibre blend streams from the fibre
preparation and blending apparatus;
(ii) forming said streams into paper plys;
(iii) forming the plys into a multi ply paper sheet;
(iv) chemically sizing the paper sheet to increase its hydrophobicity;
(v) drying the multi ply paper sheet over drying drums to produce
the PBL,
n a density of the PBL is no more than 140 grams per square meter
(gsm).
Preferably, the PBL is no more than 130 grams per square meter (gsm).
Preferably, a Cobb (60 second) value of the PBL is less than 30 gsm.
Preferably, a cross direction wet expansion of the PBL is no greater than 0.8%.
Preferably, the step of blending results in multiple fibre blend streams each having a
substantially even mixture of RCF and VKF. For example, the substantially even
mixture includes greater than 35% VKF.
Preferably, the PBL is for a base of the plasterboard and the system includes the step
of manipulating fibres of the fibre blend streams so that a machine ion to cross
direction e ratio (MD:CD) of the PBL is not more than 1.4.
Preferably, the PBL is for a face of the plasterboard and the system includes the step
of manipulating fibres of the fibre blend streams so that a machine direction to cross
direction tensile ratio (MD:CD) of the PBL is not less than 2.2. Further, the system
advantageously includes the step of ng a pigment coating to the face PBL. The
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pigment g preferably provides a light colour surface with diffuse blue reflectance
factor not less than 30. Alternatively, the pigment coating preferably provides a light
colour surface with diffuse blue reflectance factor not less than 40.
Brief Description of the Drawings
Preferred embodiments of the t invention are hereafter described, by way of
non-limiting example only, with reference to the accompanying drawing in which:
Figure 1 is a schematic diagram g steps performed by a known system for
manufacturing plaster board from plasterboard liner and gypsum slurry;
Figure 2a is a schematic diagram showing steps performed by a known system for
manufacturing plasterboard liner from mainly recycled paper fibre;
Figure 2b is a schematic diagram g steps med for stock preparation by
the known system shown in Figure 2a;
Figure 2c is a tic diagram showing steps performed for paper making by the
known system shown in Figure 2a;
Figure 2d is a schematic diagram showing steps performed for paper strengthening by
the system shown in Figure 2a;
Figure 3a is a schematic diagram showing steps performed by a system for
manufacturing plasterboard liner;
Figure 3b is a schematic diagram showing steps performed for fibre preparation and
ng by the system shown in Figure 3a;
Figure 3c is a tic diagram showing steps performed for paper making by the
system shown in Figure 3a;
Figure 3d is a schematic diagram showing steps performed for pigment coating by the
system shown in Figure 3a; and
Figures 4 to 9 show test data for plasterboard liner ed by the system shown in
Figure 3a.
Detailed Description of Preferred Embodiments of the Invention
The system 10 shown in s 3a includes apparatus 12 for manufacturing
plasterboard liner (PBL ) 14 of less than 140 grams per square meter ( gsm ). For
example, the system 10 can advantageously produce PBL ranging between 110gsm
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and 130gsm. Advantageously, the system 10 achieves PBL of less than 140 gsm with
one or more of the following:
Back PBL MD:CD tensile ratio not greater than 1.4;
Face PBL MD:CD tensile ratio not less than 2.2;
CD wet expansion less than 0.8%;
Cobb value (60 seconds) less than 40 gsm; and
Face PBL light colour e not less than ISO brightness 30.
The PBL thus achieves the necessary characteristics of dimensional stability, and
tensile strength for the combined back and face to make it suitable for uent
rboard sheet manufacture. The system 10 achieves these results using a
substantially even ratio of recycled paper fibre (RCF ) 16 and virgin Kraft fibre (VKF )
18, for example. Alternatively, the system uses any other suitable ratio of RCF and
VKF to achieve a PBL 14 of less than 140 gsm.
The system 10 is also suitable for manufacturing plasterboard liner (PBL ) 14 of less
than 130 grams per square meter (gsm ). For example, the system 10 can
advantageously produce PBL ranging between 110gsm and 125gsm. Advantageously,
the system 10 achieves PBL of less than 130 gsm with one or more of the following:
Back PBL MD:CD tensile ratio not greater than 1.4;
Face PBL MD:CD tensile ratio not less than 2.2;
CD wet expansion less than 0.8%;
Cobb value (60 seconds) less than 30 gsm; and
Face PBL light colour surface not less than ISO ness 40.
The PBL thus achieves the ary characteristics of dimensional stability, and
tensile th for the combined back and face to make it suitable for subsequent
plasterboard sheet manufacture. The system 10 achieves these results using a
substantially even ratio of ed paper fibre (RCF ) 16 and virgin Kraft fibre (VKF )
18, for example. Alternatively, the system uses any other suitable ratio of RCF and
VKF to achieve a PBL 14 of less than 130 gsm.
In either case, the lighter PBL 14 is advantageous across a number of manufacturing
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and commercial aspects including:
The market units of lighter PBL are increased for the same weight of paper
ed and this has a commercial advantage for transporting the PBL 14;
The paper product volume is increased for the same weight virgin Kraft fibre by
mixing with RCF and this has a manufacturing advantage for a pulp mill in
reducing the bottle neck imposed by the rate and cost of pulp production to output
of paper products; and
The plasterboard sheet manufacture drying energy is reduced for the same unit
length of rboard sheet due to the reduced weight of the PBL 14.
The system 10 also advantageously solves the problem of a light ed PBL face
without additional fibre layer. The system 10 includes an option to apply a pigment
coating 24 to PBL to achieve an ivory coloured e with ISO brightness not less
than 30, for example. Alternatively, the system 10 includes an option to apply a
pigment coating 24 to PBL to achieve an ivory coloured surface with ISO brightness
not less than 40, for example. This is achieved using an application process to the PBL
surface. The advantage of the solution is that PBL face with a light coloured e is
ctured without the need to use light coloured RCF and this avoids the need for
RCF recovered white paper feedstock and the stock preparation de-inking process or
the purchase of white fibre feedstock.
The apparatus 12 includes:
1. fibre preparation and blending apparatus 20;
2. paper making apparatus 22; and
3. pigment g tus 24.
By way of non limiting example, a detailed description on the operation of each
apparatus 20 to 24 is set out below.
1. Fibre Preparation & Blending Apparatus 20
The fibre preparation and blending apparatus 20 receives RCF 16 and VKF 18 from
preceding ated manufacturing processes. The VKF 18 is manufactured using the
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Kraft process technology and refined to e paper properties using known process
technology. For example, Visy's Tumut Kraft Mill in Australia produces high quality
kraft paper for domestic and international markets using ips from softwood
plantations in southern NSW supplemented by recyclable wastepaper. The RCF 16 is
manufactured using recovered paper/cardboard from which recyclable cellulose fibres
are extracted using known process technology.
RCF 16 and water 32 are added to the RCF pulper tank 26. The contents of the pulper
tank 26 is then passed through contaminant screens 30 to remove contaminant
materials such as plastic and metal in a known step common to paper making using
RCF. The RCF is then sent to the blend tank 34.
VKF 18 and water 32 are added to the Kraft fibre pulper & pre-treatment tank 28.
Charge control chemicals are added to maximise reactivity of the VKF 18 with sizing
chemicals later added by the al additive apparatus 38 (described below in
further detail with reference to the paper making tus 22).. For example,
adding anionic trash tor (ATC) at 1 to 2 KG per tonne to achieve 500 to 1000
uEq/l. The pre-treated VKF is then sent to the blend tank 34.
The blend tank 34 takes the pre-treated VKF 18 and the screened RCF 16 and
tes multiple fibre blend streams of ntially even mixtures. As above
mentioned, it is anticipated that other mixtures of RCF 16 and VKF 18 can be used
with a view to obtaining PBL of less than 140 gsm or 130 gsm. For example, the
mixture may be 40% VKF. However, for ease of description, the system 10 is
described below with reference to the mixture being substantially even.
Each stream forms a ply of the multi ply paper machine 36 of the paper making
tus 22 with a substantially even fibre g on the total PBL of RCF 16 and
VKF 18.
All paper products have a natural tendency to absorb moisture and hydro expand
(called wet expansion). Even with internal and surface applied chemical sizing
technology, wet expansion results in dimensional changes on the paper relative to the
original paper in the dry state.
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n fibres have a greater potential to reabsorb moisture than others. In the
example of PBL, RCF has a lower level of wet expansion than VKF. However, RCF has
a lower tensile strength than VKF.
The blend tank 34 maintains a balance between RCF 16 and VKF 18 content of the
fibre streams for each ply of the multi ply paper machine 36. It uses fibre slurry
consistency and flow rate to achieve a specified RCF 16 and VKF 18 composition of the
multiple outflow fibre streams. Each outflow fibre stream forms a ply and the multiple
plys are combined through the paper making apparatus 22 to form a multi ply paper
sheet. The bution of RCF and VKF is very important within the respective paper
plys as well as the ply split within the composite PBL. The blending of RCF 16 and VKF
18 to achieve the necessary fibre blend of the fibre streams is fied schematically
in Figure 3b.
An advantage of RCF is than it has a lower level of wet ion and icantly
cheaper raw material to manufacture PBL. A disadvantage with RCF is that
manufactured PBL has a lower tensile strength than, for example, an equivalent
weight PBL using virgin Kraft fibre. The advantage of virgin Kraft fibre is that
manufactured PBL has a vastly or tensile strength. The disadvantage of virgin
Kraft fibre is that manufactured PBL has a high level of wet expansion.
To obtain an optimal balance n the benefits of using VKF 18 to obtain higher
tensile strength and minimising wet ion, the blend tank 34 provides a
substantially even mixture of RCF 16 and VKF 18 in multiple streams for the paper
making apparatus 22. This results in an even fibre ratio across the total multi ply PBL
sheet, for example.
2. Paper Making Apparatus 22
The paper making apparatus 22 includes:
a. a multi ply paper machine 36, including:
i. paper fibre formation apparatus 37 (also known as paper machine wet
end);
ii. chemical additive apparatus 38; and
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iii. speed control tus 40; and
b. drying drums 42.
The operation of each one of the above is below described in further detail.
a. Multi Ply Paper Machine 36
The multi ply paper machine 36 manufactures paper sheet by first forming multiple
fibre plys that are then ed into a multi ply paper sheet prior to drying. The
formation of paper sheet using a 2 ply paper machine is shown schematically in Figure
3c, for example.
i. Paper Fibre Formation tus 37
The paper machine wet end 37 receives fibre from the blend tank 34 in multiple
s and this is carefully manipulated to achieve the required basis weight of the
combined ply paper sheet, for example 130gsm, and composition of RCF 16 and VKF
18, for example, greater than 35% virgin Kraft fibre.
Importantly, the paper machine wet end 37 -wire ratio is carefully manipulated
to control the physical fibre orientation of the paper sheet. This ratio, which is the
difference between the speed of the fibre forming n jet and that of the forming
section wire, is used to fine-tune a PBL's fibre structure. It also ively determines
the dominant directional tensile strength of the paper sheet in either the machine
direction (MD) or cross direction (CD).
Traditionally the jet-to-wire ratio is less than unity, and the fibre content is high, and
this 'draws' or 'drags' the fibres out in the MD and achieves a high MD:CD tensile
ratio. For PBL the jet-to-wire ratio is carefully controlled to either 'drag' or 'rush'
(when jet-to-wire ratio is greater than unity) the paper sheet to manipulate the
proportion of fibre alignment in the CD. Combined with the low fibre content, this
achieves MD:CD tensile ratios that differ substantially between back and face PBL. For
example:
PBL Jet-to-wire Fibre content MD:CD tensile ratio
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ratio
Back 1.000 120 gsm 1.1
Face 1.015 125 gsm 2.6
Importantly the jet-to-wire ratio and resultant fibre orientation also affects the
dimensional stability through the degree of wet expansion. The advantages of very
low MD:CD tensile ratio for back PBL is that it attains a lower CD wet expansion, for
example 0.8%.
ii. The Chemical Additive Apparatus 38
The chemical additive apparatus 38 chemically sizes the multiple paper substrate plys
to increase hydrophobicity of both RCF 16 and VKF 18 y reducing the multi ply
paper s tendency to absorb liquid. The following steps are performed in that
regard:
a. the VKF 18 is pre-treated at the fibre preparation and blending apparatus 20
with charge control chemical technology to maximize the virgin Kraft fibre’s
ability to react with sizing chemicals;
internal sizing chemical technology is d to the multi ply paper sheet by the
chemical additive apparatus 38 using for example the following cationic rosin >12
kg/t, aluminum sulphate (Alum) >24 kg/t, and Alkyl Ketene Dimer >3 kg/t
In addition, surface sizing chemical technology is applied at the coating machine 44 by
the surface sizing apparatus 46, as shown in Figure 3d.
The steps med by the multi ply paper e 36, as described above, are
shown schematically in Figure 3c, using a 2 ply paper machine for example. They
result in improved dimensional ity and tensile strength and of PBL containing
substantial content of VKF 18.
The PBL manufactured by the system 10 includes the use and sizing of VKF 18 to
achieve the necessary dimensional stability and tensile th suitable for the
subsequent manufacture of plasterboard sheet. This, in turn, s the plasterboard
sheet to achieve its required market characteristics of flat, ripple free surfaces and
high blending strength.
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The system 10 solves the problem of d VKF 18 which is reactive to contact with
moisture and this makes it unsuitable for use in PBL as the required dimensional
stability is not ed. The manufacture of plasterboard sheet requires the PBL to be
in contact with gypsum slurry as it is sandwiched between the face and back PBL. Too
much wet expansion through water absorption from the slurry during pressing to
adjust thickness can result in subsequent rippling of the end product surfaces
following drying of the slurry to produce the plasterboard sheet.
The system 10 can use various functional sizing al technology for PBL . A
combination of sizing chemicals is used, for example:
a. cationic rosin >12 kg/t;
b. aluminum sulphate (Alum) >24 kg/t;
c. Alkyl Ketene Dimer >3 kg/t; and
d. e sizing agent 3-12 kg/t.
Both VKF 18 and RCF 16 are d with internal sizing chemical technology to
manufacture PBL grades.
Functional sizing chemical technology reduces the natural tendency of fibres to reabsorb
moisture after paper has been dried. Internal sizing chemical technology
reduces the paper tendency to absorb water by attaching hydrophobic les to
the fibres. These molecules effectively repel water before water is able to penetrate
into the fibre structure.
To further enhance hydrophobicity, surface sizing al technology is also applied
at the surface sizing chemical apparatus 46 of the coating machine 44. Here a limited
amount of sizing chemical is applied as a layer to create surface r to reduce
water ation into the PBL.
2(a)(iii) & 2(b). Speed Control Apparatus 40 & Drying Drums 42
The speed control apparatus 40 acts to reduce the draw between successive processes
on the formed paper sheet through its pressing and drying. This reduces the tendency
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for formed paper sheet to react when contacted with water thereby reducing the hydro
expansion. This feature is identified schematically in Figure 3c.
Successive paper machine sections (press, dryer and reel) relative speed controls are
carefully lled by the speed control apparatus 40 to minimize fibre draw in the
MD before application to the drying drums 42 to minimise sheet shrinkage to less than
2% for example.
3. Pigment g apparatus 24
The pigment coating apparatus 24 includes:
a. a coating machine 44;
b. surface sizing chemical apparatus 46;
c. pigment ation tus 48; and
d. drying drums 50.
Traditional Ivory PBL utilizes de-inked RCF from recovered white paper feedstock to
manufacture the face (Ivory) grades. With the incorporation of the coating machine
44, for example a film press, there is the option of pigment coating the PBL 14 to
resemble the ivory sheet appearance for face PBL, or any other desired colour. The
coating refers to a layer of material from a single stage application, for e
including pigment formulation, starch and sizing agent.
This offers the t of improved strength gains associated with starch to offset the
negative effect of the pigment coating and an overall benefit of lower cost of pigment.
Figure 3d shows schematically how the coating machine 44 is used for this feature.
The advantage of pigment coating is that g can be formulated to achieve the
d surface appearance, for example light coloured face PBL of ISO brightness not
less than 30. atively, the coating can be formulated to achieve the desired
surface appearance, for example light coloured face PBL of ISO brightness not less
than 40. Pigment coating is significantly r than light coloured RCF used in
traditional Ivory grades. A disadvantage is that pigment coating chemicals do not have
any tensile strength enhancement of the PBL. As such, the tensile strength must be
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derived from the VKF 18 and the RCF 16.
The coating machine 44 works by enabling a finite amount of pigment coating film to
be metered onto one (or two) rolls through which paper runs. The pigment coating
film effectively transfers onto the sheet once the paper passes through the rolls. The
amount of pigment coating is carefully controlled by the coating recipe, its solid
content, the applicator rod ion and contact time on the rolls.
The pigment g recipe includes a mixture of different clay and/or calcium
carbonate pigments and binders.
Coating machines for single stage applications have previously been installed on paper
machines to enhance dry strength with the application of modified starches. In the
example shown in Figure 3d, the coating machine 44, for example a film press,
includes the pigment ation apparatus 48 and the surface sizing chemical
apparatus 46. The incorporation of the pigment application apparatus 48 allows the
coating machine 44 to add a coating pigment in addition to the applied starch. The
reason for the addition of pigment is to affect the surface appearance of the face PBL.
The addition of the surface sizing chemical apparatus 46 to the coating e 44
allows for blending surface sizing chemical technology with starch, water or coating
pigment to enhance hydrophobicity of the paper and e a coating thickness of 7-
8 ml/m2 for example. In this application the surface sizing chemical is 100% retained
on the face PBL sheet. Figure 3d shows schematically how the coating machine 44, for
e a film press, is used for this feature.
The advantages of the coating e 44 is that cheaper alternative pigments eg.
clay and calcium carbonate can be precisely metered onto the PBL sheet to ate
an Ivory ply for face PBL. Other ages are that the appearance can be modified
with recipe of coating and ation loading.
atives to a coating machine 44 are:
a. For light colour: to use a de-inked RCF from red white paper feedstock
on the face PBL (Ivory ply);
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b. For dry strength enhancement: to use lized dry strength chemicals in the
fibre ; and
c. For surface sizing: there is no effective alternative as only internal sizing
chemicals can be applied using the paper e.
Many modifications will be apparent to those skilled in the art without departing from
the scope of the present invention. To this end, the apparatus for manufacturing
plasterboard liner 12 has been above described, by way of non-limiting example, with
reference to the following being separate apparatus:
1. fibre preparation and blending apparatus 20;
2. paper making apparatus 22; and
3. pigment coating apparatus 24.
However, in ce, the above is alternatively formed as one unit, or many separate
units.
Sizing for paper means the use of chemicals to reduce its tendency to absorb liquid.
Internal sizing chemicals are applied during paper formation to be incorporated
throughout the paper sheet h bonding to ose fibres to increase their
hydrophobicity. Surface sizing chemicals are d as a thin coating on the paper
sheet and have a hydrophillic end that joins to the cellulose fibre and a hydrophobic
end that faces away to make the paper surface more ant to the penetration of
liquid. A measure of resistance to liquid absorption is the Cobb value, which is the
surface water absorption in grams per square meter over 60 seconds. As the
manufacture of plasterboard sheet requires PBL to be in t with moisture via the
gypsum slurry, PBL is 'hard sized' paper. This means it is in the category of papers
with the highest water resistance.
The reference to any prior art in this specification is not, and should not be taken as,
an acknowledgment or any form of suggestion that the prior art forms part of the
common general knowledge in Australia
In this specification and the claims that follow, unless stated otherwise, the word
"comprise" and its variations, such as "comprises" and "comprising", imply the
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inclusion of a stated integer, step, or group of integers or steps, but not the exclusion
of any other integer or step or group of integers or steps.
References in this specification to any prior publication, information derived from any
said prior publication, or any known matter are not and should not be taken as an
acknowledgement, admission or suggestion that said prior publication, or any
information derived from this prior publication or known matter forms part of the
common general knowledge in the field of endeavour to which the ication
relates.
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Summary of Paper Trials:
Trial 1
Initial base line study to ine quality at normal ply loading at 30% RCF
substitution to the top wire (TW ) (also referred to as the "bottom ply").
Trial 2
Second ne study based on 50:50 ply loading. RCF loading increased to 40% and
ng study to understand impact on ty. Secondary objective to establish the
impact of the BW FormMaster.
Moderate water absorption test performed on paper (COBB ) 1’ 25-30 at maximum
CRS size dosage for normal wet end chemistry. The test resulted in significant
rippling associated with Wet Expansion.
Trial 3
Trial to test the baseline to understand %RCF and Tensile ratio on Wet Expansion.
Also TOPKraft jumbo. The trial also included manufacture K110PB at low Tensile ratio
and TOPKraft jumbo.
The trial resulted in significant ement in back rippling. That is, it was less
defined and finer. The TopKraft paper did not show any benefit. That is, it appeared
easier to delaminate.
Lower tensile ratio 260-280 N MD breaking strength MD (AS/NZ minimum 360N).
Trial 4
Implement trial 3 machine set up at lowest Tensile ratio. Focus on improving wet end
chemistry for maximum or HIGH SIZE cationic rosin size efficiency. That is, the
lowest COBB capability.
• Incorporating anionic trash collection application
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• Establish effect on Wet ion at extreme e ratio set-up
• Rewetting paper at VPC to reduce internal strain with water uptake on gypsum
application
• Third Plasterboard trial 14/06/2013 at Boral Port Melbourne
• Rippling for low Tensile ratio was as good as second trial
• High Tensile ratio paper was not tested
Trial 5
• ASA (Alkyl Succinic Anhydride) size conversion trial achieve as low COBB as
possible
• Substitute 60% RCF for 110 gsm and 115 gsm
• Rewetting paper at VPC to reduce internal strain with water uptake on gypsum
application
• Fourth rboard trial 11/07/2013 at Boral Pinkenba
• General consensus hard sized ASA compared with hard sized Rosin sized
paper for rippling
• 60% RCF substitution reel gave the best OVERALL result on rippling
• med by the lowest Wet Expansion < 0.8%
Trial 6
Objective to establish the max. and min. Tensile MD at 110 gsm and 125 gsm.
Standardize 50% RCF for 115 gsm and 125 gsm. Rewetting paper at VPC to reduce
internal strain with water uptake on gypsum application.
ation max. and min. Tensile ratio was ran for FACE and BASE
Max. Tensile MD paper acceptable for FACE break strength
MD Break Strength K110PB 280 N ; K125PB 380 N (Spec 360N)
BASE rippling is almost acceptable but more work required to achieve PN150
flatness
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Process Capability and Expected Quality:
1. Minimum Wet Expansion (BASE) K110PB K125PB
a. Tensile MD 50-52 N.m/g 7 kN/m 6.25-6.5 kN/m
b. Tensile CD 40-42 N.m/g 4.4 – 4.6 5.0-5.25 kN/m
c. Tensile ratio 1.0 – 1.1
d. Porosity 250 – 300 ml/min
e. ASA Sizing. COBB does not correlate with wet expansion. EMCO s on
Trial 4 and Trial 5 indicates a significant ence in initial water hold out
(40-80%) with ASA hard sized paper.
f. Higher RCF substitution up to 60%
g. Minimum refining levels
h. Lowest risk of rippling at Wet Expansion 0.7- 1.0%
2. Balanced Tensile Strength (BASE) K110PB K125PB
a. Tensile MD 55-60 N.m/g 6.0–6.6 kN/m 6.9-7.5 kN/m
b. e CD 45 N.m/g 5.0 kN/m 5.6 kN/m
c. Tensile ratio 1.2– 1.5
d. Porosity 230 – 250 ml/min
e. ASA Sizing.
f. Higher RCF substitution up to 50%
g. Moderate refining levels CSF 500-550 CSF
h. Higher risk of ng with Wet Expansion 1.0-1.5%
3. Highest e Strength (FACE) K110PB K125PB
a. Tensile MD 70-73 N.m/g 7.7–8.0 kN/m 8.8-9.12 kN/m
b. Tensile CD 23 - 30 N.m/g 2.5-3.3 kN/m 2.9-3.75 kN/m
c. Tensile ratio >2.7
d. Porosity 200 – 220 ml/min
e. High Size Cationic Rosin High Size.
f. RCF substitution up to 50%
g. Max refining levels < CSF 500 CSF
h. Highest risk of rippling with Wet Expansion > 1.5%
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4. Chemical additives
a. Fibre preparation sizing:
Anionic trash collector 3kg/t 500-1000uEq/l
b. Paper making internal sizing:
Cationic rosin > 12 kg/t
Aluminum sulphate > 24 kg/t
AKD (Alkyl Ketene Dimer) > 3 kg/t
c. Film press surface sizing
Surface sizing agent 3-12 kg/t
General:
1. BASE ation best option is Capability 1 (lowest tensile ratio) K125PB:
a. Expect plasterboard MD ng strength 300 N ( in combination with PV170)
b. ASA hard sized 4.5-5 kg/Adt
c. Lowest risk of rippling
2. FACE ation best option is Capability 3 (highest tensile ratio) K125PB and
high sized ROSIN:
a. Rosin hard sized 10-11 kg/Adt
b. Expect plasterboard MD breaking strength >360 N ( in combination
with PV170)
c. Lowest risk of board break on the gypsum line
3. Although COBB does not correlate well with Wet ion, EMCO testing
indicates a difference between hard sized ASA vs ROSIN:
a. ASA appears to have superior initial water hold-out
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Glossary
TW Top Wire (Bottom ply)
GSM Grams per square meter
BW Bottom Wire (Top ply)
FormMaster Name of papermaking Equipment
COBB Water absorptiveness (cobb value) is the mass of water absorbed in a
specific time by one square meter of paper, board, or ated
fibreboard under one centimetre of water.
CRS cationic Rosin Size (rosin is a chemical added to achieve water
holdout).
jumbo jumbo / master reels of paper
K110PB Paper grade
MD Machine Direction - paper direction along the le ngth of the paper
machine.
VPC Visy Paper Coatings
K125PB Paper grade
CD Cross Direction - paper direction across the width of the paper machine.
EMCO Water absorption test equipment name.
CSF Canadian Standard Freeness. A measure of the ge of paper pulp
linked to refining and pulp quality.
PV170 170gsm Ivory Face paperboard liner
TSI e Stiffness Index. Ultrasonic, non-destructive test method for
determining the strength of paper, and plaster board liner.
ABB AWP Moisturising bar from ABB used at VP9
furnish paper going to pulping stage of papermaking.
WIS Web Inspection System - hole detector
WW White Water - aking water removed from wet sheet and
recycled back into the process water.
PSD Paper machine shutdown
WRV Water ion Value - laboratory test for delivering how much water
a pulp will hold under controlled conditions.
Mutec Laboratory equipment for measuring charge in water.
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INDEX
Figure 1
A Plasterboard liner - face
B Gypsum slurry
C Plasterboard liner - back
D Cutter
E Plasterboard sheets
F Drying
Figure 2a
G Recovered paper - newsprint
H red paper – Office white
I Recovered paper - mixed
J Recovered cardboard - mixed
K Recovered cardboard – high content Kraft fibre
L Water
M Stock preparation
N RCF Slurry
O Paper making
P Paper strengthening
Q Paper board liner
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Figure 2b
R Recovered paper - newsprint
S Recovered paper – Office white
T red paper - mixed
U Recovered cardboard - mixed
V Recovered cardboard – high content Kraft fibre
W Water
X RCF pulper
Y Contaminant screens
Z Detergent
AB Floatation tank
AC Disperser
AD RCF blending (as required)
AE RCF De-Inking (Face PBL only)
AF RCF Slurry
Figure 2c
AG RCF Slurry
AH 3 ply machine Paper sheet formation
AI Paper making
AJ Drying drums
Figure 2d
AK Starch bath
AL Paper strengthening
AM Drying drums
AN Plasterboard liner
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Figure 3a
AO Virgin Kraft fibre
AP Recovered cardboard
AQ RCF
AR Water
AS Fibre ation and blending
AT Paper making
AU Pigment coating
AV Kraft Plasterboard liner
Figure 3b
AW Water
AX Virgin Kraft fibre
AY RCF
AZ Kraft fibre pulper & pre-treatment
BA RCF pulper
BB Contaminant screens
Figure 3c
BC Fibre preparation & blending
BD Paper fibre formation
BE Chemical additive apparatus
BF Speed control apparatus
BG Multi Ply Paper Machine
BH Drying drums
Figure 3d
BI Surface sizing chemical apparatus
BJ Pigment application apparatus
BK Coating machine
BL Drying
BM Kraft Plasterboard liner
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Claims Defining the Invention
1. A process for manufacturing plasterboard liner (PBL ) for plaster board,
including the steps of:
(a) ing virgin Kraft fibre (VKF );
(b) receiving recycled paper fibre (RCF );
(c) blending the VKF and the RCF to produce multiple fibre blend streams;
(d) forming said s into paper plys;
(e) forming the plys into a multi ply paper sheet;
(f) chemically sizing the paper sheet to increase hydrophobicity; and
(g) drying the multi ply paper sheet over drying drums to produce the PBL,
wherein a density of the PBL is no more than 140 grams per square meter
(gsm).
2. The process claimed in claim 1, wherein the density of the PBL is no more than
130 grams per square meter (gsm).
3. The process claimed in claim 1 or claim 2, wherein a Cobb (60 second) value of
the PBL is less than 30 gsm.
4. The process claimed in any one of claims 1 to 3, wherein cross ion wet
expansion of the PBL is no greater than 0.8%.
. The process claimed in any one of claims 1 to 4, wherein the step of blending
s in multiple fibre blend streams each having a substantially even mixture of RCF
and VKF.
6. The process claimed in claim 5, wherein the ntially even mixture includes
greater than 35% VKF.
7. The process claimed in any one of claims 1 to 6, n the density of the
plasterboard liner ranges between 110gsm and .
8. The process claimed in any one of claims 1 to 6, wherein the density of the
plasterboard liner ranges between 110gsm and 130gsm.
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9. The process claimed in any one of claims 1 to 8, wherein the step of chemically
sizing the VKF and RCF includes the step of applying internal sizing chemicals to the
paper sheet.
. The process claimed in claim 9, wherein the internal sizing als include:
Cationic rosin > 12 kg/t
Aluminum sulphate > 24 kg/t
AKD (Alkyl Ketene Dimer) > 3 kg/t
11. The process d in claim 9 or claim 10, wherein the step of chemically
sizing the VKF includes the step of applying surface sizing chemicals to the multi ply
paper substrate.
12. The s claimed in claim 11, wherein the surface sizing chemicals include
surface sizing agent 3 to 12 kg/t.
13. The process claimed in any one of claims 9 to 12, wherein the step of
chemically treating the VKF includes the step of pre-treating the VKF to improve the
VKF's ability to react with the sizing chemicals.
14. The process d in claim 13, wherein the sizing chemicals include anionic
trash collector 3kg/t to achieve 500 to1000uEq/l.
15. The process d in any one of claims 1 to 14, wherein the PBL is for a base
of the plasterboard and the process es the step of manipulating fibres of the
fibre blend streams so that a machine direction to cross direction e ratio
(MD:CD) of the PBL is not more than 1.4.
16. The process claimed in any one of claims 1 to 14, wherein the PBL is for a face
of the plasterboard and the process includes the step of manipulating fibres of the
fibre blend streams so that a machine direction to cross direction tensile ratio
(MD:CD) of the PBL is not less than 2.2.
17. The process d in claim 16, including the step of applying a pigment
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coating to the face PBL.
18. The process claimed in claim 17, wherein the step of applying the pigment
coating to the face PBL includes the step of ing dry strength with application of
modified starches.
19. The process claimed in claim 17 or claim 18, wherein the pigment g
provides a light colour surface with diffuse blue reflectance factor not less than 40.
20. The process claimed in claim 17 or claim 18, wherein the t coating
provides a light colour surface with diffuse blue reflectance factor not less than 30.
21. Plasterboard liner for use in manufacturing plasterboard formed from the
process claimed in any one of claims 1 to 20.
22. Base plasterboard liner for use in manufacturing plasterboard formed from the
process claimed in claim 15.
23. Face plasterboard liner for use in manufacturing plasterboard formed from the
process claimed in any one of claims 16 to 19.
24. Plaster board, including gypsum interposed between the face plasterboard liner
claimed in claim 23 and the base plasterboard liner claimed in claim 22.
25. A system for manufacturing plasterboard liner (PBL ) for plaster board,
ing:
(a) fibre preparation and blending apparatus, said apparatus for performing
the steps of:
(i) receiving virgin Kraft fibre (VKF );
(ii) receiving recycled paper fibre (RCF); and
(iii) blending the VKF and the RCF to produce multiple fibre blend
s; and
(b) paper making apparatus, said paper making apparatus for performing
the steps of:
(i) receiving the multiple fibre blend streams from the fibre
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preparation and blending apparatus;
(ii) g said streams into paper plys;
(iii) forming the plys into a multi ply paper sheet;
(iv) chemically sizing the paper sheet to increase hydrophobicity; and
(v) drying the multi ply paper sheet over drying drums to produce
the PBL,
wherein a density of the PBL is no more than 140 grams per square meter
(gsm).
26. The system claimed in claim 25, wherein the density of the PBL is no more
than 130 grams per square meter (gsm)
27. The system claimed in claim 25 or claim 26, wherein a Cobb (60 second) value
of the PBL is less than 30 gsm.
28. The system d in any one of claims 25 to 27, wherein cross direction wet
expansion of the PBL is no greater than 0.8%.
29. The system claimed in any one of claims 25 to 28, wherein the step of blending
results in multiple fibre blend streams each having a substantially even mixture of RCF
and VKF.
. The system claimed in claim 29, wherein the substantially even mixture
includes r than 35% VKF.
31. The system claimed in any one of claims 25 to 30, wherein the density of the
plasterboard liner ranges between 110gsm and .
32. The system claimed in any one of claims 25 to 30, n the density of the
plasterboard liner ranges between 110gsm and 130gsm.
33. The system claimed in any one of claims 25 to 32, wherein the step of
chemically sizing the VKF and the RCF includes the step of applying internal sizing
chemicals to the paper sheet.
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34. The system claimed in claim 33, wherein the internal sizing chemicals include:
Cationic rosin > 12 kg/t
Aluminum sulphate > 24 kg/t
AKD (Alkyl Ketene Dimer) > 3 kg/t
. The system claimed in claim 33 or claim 34, wherein the step of ally
sizing the PBL includes the step of ng surface sizing chemicals to the multi ply
paper sheet.
36. The system claimed in claim 35, wherein the surface sizing chemicals include
surface sizing agent 3 to 12 kg/t.
37. The system claimed in any one of claims 33 to 36, including the step of presizing
the VKF to improve the VKF's y to react with the sizing chemicals.
38. The system d in claim 37, wherein the sizing chemicals include anionic
trash tor 3 kg/t to achieve 500 to 1000uEq/l.
39. The system claimed in any one of claims 25 to 38, wherein the PBL is for a
base of the plasterboard and the s includes the step of manipulating fibres of
the fibre blend streams so that a machine direction to cross direction tensile ratio
(MD:CD) of the PBL is not more than 1.4.
40. The system claimed in any one of claims 25 to 39, wherein the PBL is for a face
of the plasterboard and the process includes the step of manipulating fibres of the
fibre blend streams so that a machine direction to cross direction tensile ratio
(MD:CD) of the PBL is not less than 2.2.
40. The system d in claim 40, further including pigment coating tus,
said coating apparatus for performing the step of applying a pigment coating to the
PBL.
41. The system claimed in claim 40, wherein the pigment coating apparatus
includes a film press for performing the step of enhancing dry strength with
application of modified starches.
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42. The system claimed in claim 41, wherein the pigment coating apparatus
includes a pigment coater for adding said coating t to the applied starches.
43. The system claimed in claim 42, wherein the pigment coating apparatus
includes surface sizing chemical apparatus for blending surface sizing als in
with starch, water or coating pigment to enhance hydrophobicity of the PBL.
44. The system claimed in any one of claims 41 to 43, wherein the t coating
provides a light colour surface with diffuse blue reflectance factor not less than 40.
45. The system claimed in any one of claims 41 to 43, wherein the pigment coating
provides a light colour surface with diffuse blue tance factor not less than 30.
46. The system claimed in any one of claims 25 to 44, wherein the paper making
apparatus performs the steps of reducing a draw between successive processes so as
to reduce the tendency for dried paper to react when contacted with water thereby
reducing the hydro expansion.
47. The system claimed in claim 46, wherein reducing the draw results in paper
with very low tensile ratio (ratio of machine direction to cross direction) so that it has
a low wet expansion.
1/12
Figure 1
2/12
I M N
Figure 2a
X Y Z AB AC
X Y AF 3/12 U
X Y
Figure 2b
AG 4/12
– AH AI
Figure 2c
Figure 4 5/12
Figure 2d
6/12
18 AR
AP AQ
Figure 3a
AW 28
AZ 7/12
AY BB
16 30
26 34
Figure 3b
37 38 40
BD BF 8/12
36 42
Figure 3c
46 48
50 14
BI BJ
9/12
BK BL
Figure 3d
/12
Fig 1 VP9 K110PB Tensile MD Index vs. Tensile Ratio
Tensile MD Index [N.m/g]
80.0
70.0
60.0
50.0
Trial 3.2
40.0
Trial 4
.0
Trial 5
.0
Trial 6
.0
0.0 0.5 1.0 1.5 2.0 2.5 3.0
Tensile Ratio
Figure 4
Fig 2 VP9 K110PB Tensile MD Index vs. ty
Tensile MD Index [N.m/g]
80.0
70.0
60.0
50.0
Trial 3.2
40.0
Trial 4
.0
Trial 5
.0
Trial 6
.0
0 50 100 150 200 250 300 350 400
Bendsten porosity [ml/min]
Figure 5
11/12
Fig 3 VP9 K110PB %Wet Expansion vs. Tensile Ratio
Wet Expansion [%]
Trial 3.2
Trial 4
Trial 5
Trial 6
0.0 0.5 1.0 1.5 2.0 2.5 3.0
e Ratio
Figure 6
Fig 4 VP9 K110PB COBB vs. % Wet Expansion
1'COBB [gsm]
BOTTOM
0.4 0.6 0.8 Wet Expansion [%]1 1.2 1.4 1.6
Figure 7
12/12
Fig 5: Top Sheet EMCO Comparison
High Sized Rosin vs ASA K110PB
3.5 tB = inital wetting time
tS = time to max. adsorp.rate
3 S = max. rate
2 High Size Rosin:Alum
1.5 High Size ASA
tB [sec] tS [sec] S [% r/s]
Figure 8
Fig 6: Bottom Sheet EMCO Comparison
High Sized Rosin vs ASA K110PB
tB = inital wetting time
tS = time to max. adsorp.rate
S = max. absop.rate
3 High Size Rosin:Alum
2 High Size ASA
tB [sec] tS [sec] S [% r/s]
Figure 9
Claims (8)
1. A process for manufacturing plasterboard liner (PBL ) for plaster board, including the steps of: 5 (a) ing virgin Kraft fibre (VKF ); (b) receiving recycled paper fibre (RCF ); (c) blending the VKF and the RCF to produce multiple fibre blend streams; (d) forming said s into paper plys; (e) forming the plys into a multi ply paper sheet; 10 (f) chemically sizing the paper sheet to increase hydrophobicity; and (g) drying the multi ply paper sheet over drying drums to produce the PBL, wherein a density of the PBL is no more than 140 grams per square meter (gsm). 15
2. The process claimed in claim 1, wherein the density of the PBL is no more than 130 grams per square meter (gsm).
3. The process claimed in claim 1 or claim 2, wherein a Cobb (60 second) value of the PBL is less than 30 gsm.
4. The process claimed in any one of claims 1 to 3, wherein cross ion wet expansion of the PBL is no greater than 0.8%.
5. The process claimed in any one of claims 1 to 4, wherein the step of blending 25 s in multiple fibre blend streams each having a substantially even mixture of RCF and VKF.
6. The process claimed in claim 5, wherein the ntially even mixture includes greater than 35% VKF.
7. The process claimed in any one of claims 1 to 6, n the density of the plasterboard liner ranges between 110gsm and .
8. The process claimed in any one of claims 1 to 6, wherein the density of the 35 plasterboard liner ranges between 110gsm and 130gsm. C:\Users\tld\AppData\Roaming\iManage\Work\Recent\35272257NZ A system and process\Spec. inc. 2SPA clean pgs - 35272257(21827042.1).doc-
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AU2015900738 | 2015-03-03 | ||
| AU2015900738A AU2015900738A0 (en) | 2015-03-03 | A system and process | |
| PCT/AU2016/050122 WO2016138554A1 (en) | 2015-03-03 | 2016-02-24 | A system and process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| NZ735104A NZ735104A (en) | 2021-08-27 |
| NZ735104B2 true NZ735104B2 (en) | 2021-11-30 |
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