NZ208130A - Anfo emulsion explosive composition with minimal transportation of water to an particles - Google Patents
Anfo emulsion explosive composition with minimal transportation of water to an particlesInfo
- Publication number
- NZ208130A NZ208130A NZ208130A NZ20813084A NZ208130A NZ 208130 A NZ208130 A NZ 208130A NZ 208130 A NZ208130 A NZ 208130A NZ 20813084 A NZ20813084 A NZ 20813084A NZ 208130 A NZ208130 A NZ 208130A
- Authority
- NZ
- New Zealand
- Prior art keywords
- emulsion
- fatty acid
- oil
- water
- blend
- Prior art date
Links
- 239000000839 emulsion Substances 0.000 title claims description 269
- 239000000203 mixture Substances 0.000 title claims description 162
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims description 80
- 239000002245 particle Substances 0.000 title claims description 35
- 239000002360 explosive Substances 0.000 title claims description 22
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims description 141
- 239000003921 oil Substances 0.000 claims description 105
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 76
- 239000000194 fatty acid Substances 0.000 claims description 76
- 229930195729 fatty acid Natural products 0.000 claims description 76
- 238000000034 method Methods 0.000 claims description 50
- 150000004665 fatty acids Chemical class 0.000 claims description 46
- 239000003995 emulsifying agent Substances 0.000 claims description 43
- -1 fatty acid salt Chemical class 0.000 claims description 33
- 150000003839 salts Chemical class 0.000 claims description 29
- 239000007788 liquid Substances 0.000 claims description 27
- 230000001804 emulsifying effect Effects 0.000 claims description 23
- 239000000243 solution Substances 0.000 claims description 23
- 239000000446 fuel Substances 0.000 claims description 22
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 22
- 238000011065 in-situ storage Methods 0.000 claims description 19
- 238000002156 mixing Methods 0.000 claims description 18
- 239000002585 base Substances 0.000 claims description 17
- 239000007864 aqueous solution Substances 0.000 claims description 16
- 230000001590 oxidative effect Effects 0.000 claims description 15
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 14
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 13
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 13
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 13
- 239000005642 Oleic acid Substances 0.000 claims description 13
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 13
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 8
- 229910052783 alkali metal Inorganic materials 0.000 claims description 8
- 150000002763 monocarboxylic acids Chemical class 0.000 claims description 8
- 150000001340 alkali metals Chemical group 0.000 claims description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims description 7
- 239000007762 w/o emulsion Substances 0.000 claims description 7
- 238000009792 diffusion process Methods 0.000 claims description 6
- 235000021588 free fatty acids Nutrition 0.000 claims description 6
- 229920006395 saturated elastomer Polymers 0.000 claims description 6
- 230000001235 sensitizing effect Effects 0.000 claims description 6
- 125000005210 alkyl ammonium group Chemical group 0.000 claims description 5
- 239000011248 coating agent Substances 0.000 claims description 4
- 238000000576 coating method Methods 0.000 claims description 4
- FVFJGQJXAWCHIE-UHFFFAOYSA-N [4-(bromomethyl)phenyl]methanamine Chemical group NCC1=CC=C(CBr)C=C1 FVFJGQJXAWCHIE-UHFFFAOYSA-N 0.000 claims description 3
- 238000013019 agitation Methods 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims 2
- 241001125671 Eretmochelys imbricata Species 0.000 claims 1
- 239000012071 phase Substances 0.000 description 37
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 24
- 239000008346 aqueous phase Substances 0.000 description 22
- 238000005086 pumping Methods 0.000 description 17
- 239000007787 solid Substances 0.000 description 16
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 15
- 239000004927 clay Substances 0.000 description 12
- 235000021313 oleic acid Nutrition 0.000 description 12
- 239000004317 sodium nitrate Substances 0.000 description 12
- 235000010344 sodium nitrate Nutrition 0.000 description 12
- 239000000126 substance Substances 0.000 description 12
- 239000002253 acid Substances 0.000 description 9
- 230000008901 benefit Effects 0.000 description 9
- 238000002425 crystallisation Methods 0.000 description 9
- 230000008025 crystallization Effects 0.000 description 9
- 230000001050 lubricating effect Effects 0.000 description 9
- 230000002950 deficient Effects 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- 239000000295 fuel oil Substances 0.000 description 7
- 239000007789 gas Substances 0.000 description 7
- 238000010521 absorption reaction Methods 0.000 description 6
- 238000005474 detonation Methods 0.000 description 6
- 229940049964 oleate Drugs 0.000 description 6
- 239000012266 salt solution Substances 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 230000002209 hydrophobic effect Effects 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000004530 micro-emulsion Substances 0.000 description 5
- 239000007800 oxidant agent Substances 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 238000003860 storage Methods 0.000 description 5
- 238000012546 transfer Methods 0.000 description 5
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 description 4
- 230000003247 decreasing effect Effects 0.000 description 4
- 239000010881 fly ash Substances 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 238000010899 nucleation Methods 0.000 description 4
- 239000008188 pellet Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000001593 sorbitan monooleate Substances 0.000 description 4
- 235000011069 sorbitan monooleate Nutrition 0.000 description 4
- 229940035049 sorbitan monooleate Drugs 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- 239000000314 lubricant Substances 0.000 description 3
- 239000012188 paraffin wax Substances 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 238000010008 shearing Methods 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- 229910002651 NO3 Inorganic materials 0.000 description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
- BCKXLBQYZLBQEK-KVVVOXFISA-M Sodium oleate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCC([O-])=O BCKXLBQYZLBQEK-KVVVOXFISA-M 0.000 description 2
- NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000000908 ammonium hydroxide Substances 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 239000004568 cement Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000004005 microsphere Substances 0.000 description 2
- 239000012875 nonionic emulsifier Substances 0.000 description 2
- 239000010743 number 2 fuel oil Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 239000011343 solid material Substances 0.000 description 2
- 229950004959 sorbitan oleate Drugs 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 239000011800 void material Substances 0.000 description 2
- 238000003109 Karl Fischer titration Methods 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- SNIOPGDIGTZGOP-UHFFFAOYSA-N Nitroglycerin Chemical compound [O-][N+](=O)OCC(O[N+]([O-])=O)CO[N+]([O-])=O SNIOPGDIGTZGOP-UHFFFAOYSA-N 0.000 description 1
- 239000000006 Nitroglycerin Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- 206010070834 Sensitisation Diseases 0.000 description 1
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000005422 blasting Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000002301 combined effect Effects 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 230000000368 destabilizing effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical compound O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 229960003711 glyceryl trinitrate Drugs 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 238000010952 in-situ formation Methods 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 239000008258 liquid foam Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical class CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- IPCSVZSSVZVIGE-UHFFFAOYSA-N palmitic acid group Chemical group C(CCCCCCCCCCCCCCC)(=O)O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 230000037452 priming Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000034563 regulation of cell size Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 230000008313 sensitization Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000001587 sorbitan monostearate Substances 0.000 description 1
- 235000011076 sorbitan monostearate Nutrition 0.000 description 1
- 229940035048 sorbitan monostearate Drugs 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 230000000153 supplemental effect Effects 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B47/00—Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase
- C06B47/14—Compositions in which the components are separately stored until the moment of burning or explosion, e.g. "Sprengel"-type explosives; Suspensions of solid component in a normally non-explosive liquid phase, including a thickened aqueous phase comprising a solid component and an aqueous phase
- C06B47/145—Water in oil emulsion type explosives in which a carbonaceous fuel forms the continuous phase
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B31/00—Compositions containing an inorganic nitrogen-oxygen salt
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Liquid Carbonaceous Fuels (AREA)
- Colloid Chemistry (AREA)
- Silicon Compounds (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NZ22334184A NZ223341A (en) | 1983-05-12 | 1984-05-11 | Water-in-oil emulsion containing liquid carbonaceous fuel for blending with ammonium nitrate prills to form an explosive |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US49391683A | 1983-05-12 | 1983-05-12 | |
| US57660284A | 1984-02-03 | 1984-02-03 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NZ208130A true NZ208130A (en) | 1990-04-26 |
Family
ID=27051230
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NZ208130A NZ208130A (en) | 1983-05-12 | 1984-05-11 | Anfo emulsion explosive composition with minimal transportation of water to an particles |
Country Status (21)
| Country | Link |
|---|---|
| EP (1) | EP0131355B1 (de) |
| KR (1) | KR910003094B1 (de) |
| AU (1) | AU573217B2 (de) |
| BR (1) | BR8402200A (de) |
| CA (1) | CA1217342A (de) |
| CS (1) | CS345884A3 (de) |
| DE (1) | DE3481767D1 (de) |
| ES (1) | ES8703394A1 (de) |
| GB (1) | GB2140404B (de) |
| HK (1) | HK17988A (de) |
| IE (1) | IE57411B1 (de) |
| IN (1) | IN162344B (de) |
| MA (1) | MA20117A1 (de) |
| MX (1) | MX162156A (de) |
| MY (1) | MY100182A (de) |
| NO (1) | NO841906L (de) |
| NZ (1) | NZ208130A (de) |
| OA (1) | OA07771A (de) |
| PT (1) | PT78579B (de) |
| TR (1) | TR22230A (de) |
| ZW (1) | ZW7684A1 (de) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MW2884A1 (en) * | 1984-02-08 | 1986-08-13 | Aeci Ltd | An explosive which includes an explosive emulsion |
| IE862703L (en) * | 1985-10-15 | 1987-04-15 | Ct Europ De Rech S Mauvernay C | Emulsion-containing explosive compositions |
| ZA888819B (en) * | 1987-12-02 | 1990-07-25 | Ici Australia Operations | Process for preparing explosive |
| ZA891501B (en) * | 1988-03-02 | 1989-11-29 | Ici Australia Operations | Explosive composition |
| GB9003613D0 (en) * | 1990-02-16 | 1990-04-11 | Explosives Tech Eti | Method of reducing the overloading of a borehole and explosive composition used therefor |
| DE19649763A1 (de) * | 1996-11-30 | 1998-06-04 | Appenzeller Albert | Sprengstoff für zivile, insbesondere bergmännische Zwecke |
| ES2123468B1 (es) * | 1997-06-26 | 2000-02-01 | Espanola Explosivos | Procedimiento e instalacion para la sensibilizacion in situ de explosivos de base acuosa. |
| AUPQ105299A0 (en) * | 1999-06-18 | 1999-07-08 | Orica Australia Pty Ltd | Emulsion explosive |
| AUPR024400A0 (en) * | 2000-09-20 | 2000-10-12 | Orica Explosives Technology Pty Ltd | Sensitisation of emulsion explosives |
| RU2252926C2 (ru) * | 2003-08-25 | 2005-05-27 | ОАО "Знамя" | Состав эмульсионного взрывчатого вещества |
| RU2446134C1 (ru) * | 2010-07-23 | 2012-03-27 | Федеральное Казенное Предприятие "Бийский Олеумный Завод" | Состав эмульсионного взрывчатого вещества |
| CN105272783A (zh) * | 2015-11-10 | 2016-01-27 | 天津宏泰华凯科技有限公司 | 一种乳化炸药的乳化制药系统 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3161551A (en) * | 1961-04-07 | 1964-12-15 | Commercial Solvents Corp | Ammonium nitrate-containing emulsion sensitizers for blasting agents |
| US3447978A (en) * | 1967-08-03 | 1969-06-03 | Atlas Chem Ind | Ammonium nitrate emulsion blasting agent and method of preparing same |
| GB1306546A (en) * | 1970-06-09 | 1973-02-14 | Explosives & Chem Prod | Blasting explosive composition |
| US4111727A (en) * | 1977-09-19 | 1978-09-05 | Clay Robert B | Water-in-oil blasting composition |
| US4181546A (en) * | 1977-09-19 | 1980-01-01 | Clay Robert B | Water resistant blasting agent and method of use |
| NZ192888A (en) * | 1979-04-02 | 1982-03-30 | Canadian Ind | Water-in-oil microemulsion explosive compositions |
| US4259977A (en) * | 1979-04-16 | 1981-04-07 | Atlas Powder Company | Transportation and placement of water-in-oil emulsion explosives and blasting agents |
| US4287010A (en) * | 1979-08-06 | 1981-09-01 | E. I. Du Pont De Nemours & Company | Emulsion-type explosive composition and method for the preparation thereof |
| EP0099695B1 (de) * | 1982-07-21 | 1988-01-27 | Imperial Chemical Industries Plc | Emulsionsexplosive Zusammensetzung |
| US4404050A (en) * | 1982-09-29 | 1983-09-13 | C-I-L Inc. | Water-in-oil emulsion blasting agents containing unrefined or partly refined petroleum product as fuel component |
-
1984
- 1984-05-09 ES ES532316A patent/ES8703394A1/es not_active Expired
- 1984-05-09 BR BR8402200A patent/BR8402200A/pt not_active IP Right Cessation
- 1984-05-10 AU AU27894/84A patent/AU573217B2/en not_active Ceased
- 1984-05-10 IN IN323/CAL/84A patent/IN162344B/en unknown
- 1984-05-10 CS CS843458A patent/CS345884A3/cs unknown
- 1984-05-10 CA CA000454071A patent/CA1217342A/en not_active Expired
- 1984-05-11 GB GB08412026A patent/GB2140404B/en not_active Expired
- 1984-05-11 MA MA20339A patent/MA20117A1/fr unknown
- 1984-05-11 DE DE8484303208T patent/DE3481767D1/de not_active Expired - Lifetime
- 1984-05-11 TR TR22230A patent/TR22230A/xx unknown
- 1984-05-11 OA OA58297A patent/OA07771A/xx unknown
- 1984-05-11 MX MX201324A patent/MX162156A/es unknown
- 1984-05-11 NO NO841906A patent/NO841906L/no unknown
- 1984-05-11 PT PT78579A patent/PT78579B/pt unknown
- 1984-05-11 IE IE1170/84A patent/IE57411B1/en unknown
- 1984-05-11 NZ NZ208130A patent/NZ208130A/en unknown
- 1984-05-11 ZW ZW76/84A patent/ZW7684A1/xx unknown
- 1984-05-11 EP EP84303208A patent/EP0131355B1/de not_active Expired - Lifetime
- 1984-05-12 KR KR1019840002561A patent/KR910003094B1/ko not_active Expired
-
1986
- 1986-10-23 MY MYPI86000028A patent/MY100182A/en unknown
-
1988
- 1988-03-03 HK HK179/88A patent/HK17988A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DE3481767D1 (de) | 1990-05-03 |
| MX162156A (es) | 1991-04-03 |
| IE841170L (en) | 1984-11-12 |
| EP0131355B1 (de) | 1990-03-28 |
| NO841906L (no) | 1984-11-13 |
| ES8703394A1 (es) | 1987-02-16 |
| TR22230A (tr) | 1986-10-09 |
| PT78579B (en) | 1986-06-26 |
| KR850002250A (ko) | 1985-05-10 |
| HK17988A (en) | 1988-03-11 |
| ZW7684A1 (en) | 1984-07-25 |
| IN162344B (de) | 1988-05-07 |
| CA1217342A (en) | 1987-02-03 |
| ES532316A0 (es) | 1987-02-16 |
| CS345884A3 (en) | 1992-11-18 |
| IE57411B1 (en) | 1992-08-26 |
| GB2140404A (en) | 1984-11-28 |
| MY100182A (en) | 1990-03-29 |
| MA20117A1 (fr) | 1984-12-31 |
| KR910003094B1 (ko) | 1991-05-18 |
| PT78579A (en) | 1984-06-01 |
| AU2789484A (en) | 1984-11-15 |
| GB8412026D0 (en) | 1984-06-20 |
| EP0131355A2 (de) | 1985-01-16 |
| GB2140404B (en) | 1987-09-03 |
| BR8402200A (pt) | 1984-12-18 |
| AU573217B2 (en) | 1988-06-02 |
| EP0131355A3 (en) | 1985-05-29 |
| OA07771A (fr) | 1985-08-30 |
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