NO983786L - FremgangsmÕte for fremstilling av alkenpolymerer ved gassfasepolymerisasjon - Google Patents
FremgangsmÕte for fremstilling av alkenpolymerer ved gassfasepolymerisasjonInfo
- Publication number
- NO983786L NO983786L NO983786A NO983786A NO983786L NO 983786 L NO983786 L NO 983786L NO 983786 A NO983786 A NO 983786A NO 983786 A NO983786 A NO 983786A NO 983786 L NO983786 L NO 983786L
- Authority
- NO
- Norway
- Prior art keywords
- phase polymerization
- preparation
- gas phase
- olefin polymers
- catalyst systems
- Prior art date
Links
- 238000012685 gas phase polymerization Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 229920000098 polyolefin Polymers 0.000 title 1
- 239000003054 catalyst Substances 0.000 abstract 2
- 150000001335 aliphatic alkanes Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61908—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/61916—Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
- C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/61922—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Abstract
Fremgangsmåte for fremstilling av polymerisater av alkener ved gassfasepolymerisering i nærvær av katalysatorsystemer, idet det som katalysatorsystemer anvendes understøttede katalysatorsystemer som fås ved A) omsetting av et u- organisk bærermateriale med en metallforbindelse med den generelle formel (I) M^R1),^2).^3),^4),, hvor M1 angir et alkalimetall, et jordalkalimetall eller et metall i III. eller IV. hovedgruppe i det periodiske system, R1 angir hydrogen, C^-Cm-alkyl, C6-C15-aryl, alkylaryl eller arylalkyl med i hvert tilfelle 1-10 C-atomer i alkylresten og 6-20 C-atomer i arylresten, R2-R4 angir hydrogen, halogen, C,-C10-alkyl, C6- C15-aryl, alkylaryl, arylalkyl, alkoksy eller dialkylamino med i hvert tilfelle 1-10 C- atomer i alkylresten og 6-20 C-atomer i arylresten, r angir et helt tall fra 1 til 4, og s, t og u angir hele tall fra O til 3, idet summen r+s+t+u tilsvarer verdien av M1, B) omsetting av materialet oppnådd ifølge A), med et metallocenkompleks i sin me- talldihalogenid-form og en metalloceniumion-dannende forbindelse, og C) deretter omsetting med en metallforbindelse med den generelle formel II M2(R5)0(Re)p(R7)q hvor M2 angir et metall i III. hovedgruppe i det periodiske system, R5 angir hydro- gen, C^-Cm-alkyl, C6-C,5-aryl, alkylaryl eller arylalkyl med i hvert tilfelle 1-10 C-- atomer i alkylresten og 6-20 C-atomer i arylresten, R8 og R7 angir hydrogen, halo- gen, C,-C10-alkyl, CB-C,5-aryl, alkylaryl, arylalkyl eller alkoksy med i hvert tilfelle 1-10 C-atomer i alkylresten og 6-20 C-atomer i arylresten, o angir et helt tall fra 1 til 3 og p og q angir hele tall fra O til 2, idet summen o+p+q tilsvarer verdien av M2.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19606165A DE19606165A1 (de) | 1996-02-20 | 1996-02-20 | Verfahren zur Herstellung von Polymerisaten von Alkenen durch Gasphasenpolymerisation |
| PCT/EP1997/000772 WO1997031039A1 (de) | 1996-02-20 | 1997-02-19 | Verfahren zur herstellung von polymerisaten von alkenen durch gasphasenpolymerisation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| NO983786D0 NO983786D0 (no) | 1998-08-19 |
| NO983786L true NO983786L (no) | 1998-10-19 |
Family
ID=7785834
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO983786A NO983786L (no) | 1996-02-20 | 1998-08-19 | FremgangsmÕte for fremstilling av alkenpolymerer ved gassfasepolymerisasjon |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US6433110B1 (no) |
| EP (1) | EP0882077B1 (no) |
| JP (1) | JP2000504777A (no) |
| KR (1) | KR100470578B1 (no) |
| CN (1) | CN1128815C (no) |
| AT (1) | ATE200904T1 (no) |
| AU (1) | AU732527B2 (no) |
| BR (1) | BR9707572A (no) |
| CA (1) | CA2246307A1 (no) |
| DE (2) | DE19606165A1 (no) |
| ES (1) | ES2156362T3 (no) |
| NO (1) | NO983786L (no) |
| TW (1) | TW467920B (no) |
| WO (1) | WO1997031039A1 (no) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19806435A1 (de) * | 1998-02-17 | 1999-08-19 | Basf Ag | Verfahren zur Herstellung eines geträgerten Katalysatorsystems |
| DE19927766A1 (de) * | 1999-06-17 | 2000-12-21 | Basf Ag | Trägerkatalysator zur Olefinpolymerisation |
| EP1146058A1 (de) * | 2000-04-13 | 2001-10-17 | Basf Aktiengesellschaft | Katalysatorlösung, enthaltend ionisch aktivierte Metallocen-Verbindungen |
| KR101113341B1 (ko) | 2002-10-15 | 2012-09-27 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 올레핀 중합용 다중 촉매 시스템 및 이로부터 제조된중합체 |
| US7223822B2 (en) | 2002-10-15 | 2007-05-29 | Exxonmobil Chemical Patents Inc. | Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom |
| US7541402B2 (en) | 2002-10-15 | 2009-06-02 | Exxonmobil Chemical Patents Inc. | Blend functionalized polyolefin adhesive |
| US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
| US7550528B2 (en) | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
| JP5222544B2 (ja) * | 2007-12-13 | 2013-06-26 | 日本ポリプロ株式会社 | プロピレン（共）重合体の製造方法 |
| RU2509782C2 (ru) | 2008-09-25 | 2014-03-20 | Базелль Полиолефине Гмбх | Ударопрочная композиция лпэнп и полученные из нее пленки |
| US8957158B2 (en) | 2008-09-25 | 2015-02-17 | Basell Polyolefine Gmbh | Impact resistant LLDPE composition and films made thereof |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2141797T5 (es) * | 1990-01-02 | 2008-06-01 | Exxonmobil Chemical Patents Inc. | Catalizadores ionicos de metalocenos soportados para la polimerizacion de olefinas. |
| KR940009020B1 (ko) * | 1990-07-24 | 1994-09-29 | 미쓰이 도오아쓰 가가쿠 가부시키가이샤 | α-올레핀의 중합촉매 및 그것을 이용한 폴리 α-올레핀의 제조방법 |
| EP0522581B1 (en) * | 1991-07-11 | 1997-10-15 | Idemitsu Kosan Company Limited | Process for producing olefin based polymers and olefin polymerization catalyst |
| JPH07509752A (ja) | 1992-08-05 | 1995-10-26 | エクソン・ケミカル・パテンツ・インク | オレフィン重合用の担持されたイオン遷移金属触媒 |
| JP3202349B2 (ja) | 1992-09-22 | 2001-08-27 | 三菱化学株式会社 | 触媒組成物およびそれを用いるオレフィンの重合法 |
| BE1006880A3 (fr) | 1993-03-01 | 1995-01-17 | Solvay | Precurseur solide d'un systeme catalytique pour la polymerisation d'olefines, procede pour sa preparation, systeme catalytique comprenant ce precurseur solide et procede de polymerisation d'olefines en presence de ce systeme catalytique. |
| EP0619326B1 (en) * | 1993-04-09 | 1997-06-25 | Tosoh Corporation | Olefin polymerization catalyst and olefin polymerisation process |
| EP0629631B1 (en) * | 1993-06-07 | 2002-08-28 | Mitsui Chemicals, Inc. | Novel transition metal compound, and polymerization catalyst containing it |
| JP2882241B2 (ja) * | 1993-06-07 | 1999-04-12 | 東ソー株式会社 | オレフィン重合用触媒およびオレフィンの重合方法 |
| US5422325A (en) * | 1993-09-17 | 1995-06-06 | Exxon Chemical Patents Inc. | Supported polymerization catalysts, their production and use |
| EP0729477B1 (en) * | 1993-11-19 | 1999-10-27 | Exxon Chemical Patents Inc. | Polymerization catalyst systems, their production and use |
| US5498582A (en) * | 1993-12-06 | 1996-03-12 | Mobil Oil Corporation | Supported metallocene catalysts for the production of polyolefins |
| DE4431837A1 (de) * | 1994-09-07 | 1996-03-14 | Basf Ag | Geträgerte Metallocen-Katalysatorsysteme |
| DE4431838A1 (de) * | 1994-09-07 | 1996-03-14 | Basf Ag | Geträgerte Metallocen-Katalysatorsysteme |
| WO1996034020A1 (en) | 1995-04-28 | 1996-10-31 | Exxon Chemical Patents Inc. | Polymerization catalyst systems, their production and use |
-
1996
- 1996-02-20 DE DE19606165A patent/DE19606165A1/de not_active Ceased
-
1997
- 1997-02-19 EP EP97905048A patent/EP0882077B1/de not_active Expired - Lifetime
- 1997-02-19 ES ES97905048T patent/ES2156362T3/es not_active Expired - Lifetime
- 1997-02-19 JP JP9529786A patent/JP2000504777A/ja active Pending
- 1997-02-19 CN CN97192408A patent/CN1128815C/zh not_active Expired - Fee Related
- 1997-02-19 BR BR9707572A patent/BR9707572A/pt not_active IP Right Cessation
- 1997-02-19 WO PCT/EP1997/000772 patent/WO1997031039A1/de not_active Ceased
- 1997-02-19 KR KR10-1998-0706413A patent/KR100470578B1/ko not_active Expired - Fee Related
- 1997-02-19 US US09/125,317 patent/US6433110B1/en not_active Expired - Fee Related
- 1997-02-19 AT AT97905048T patent/ATE200904T1/de active
- 1997-02-19 AU AU18746/97A patent/AU732527B2/en not_active Ceased
- 1997-02-19 CA CA002246307A patent/CA2246307A1/en not_active Abandoned
- 1997-02-19 DE DE59703469T patent/DE59703469D1/de not_active Expired - Lifetime
- 1997-02-20 TW TW086102038A patent/TW467920B/zh active
-
1998
- 1998-08-19 NO NO983786A patent/NO983786L/no not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| ATE200904T1 (de) | 2001-05-15 |
| US6433110B1 (en) | 2002-08-13 |
| CN1128815C (zh) | 2003-11-26 |
| AU1874697A (en) | 1997-09-10 |
| JP2000504777A (ja) | 2000-04-18 |
| EP0882077A1 (de) | 1998-12-09 |
| DE59703469D1 (de) | 2001-06-07 |
| AU732527B2 (en) | 2001-04-26 |
| KR100470578B1 (ko) | 2005-05-16 |
| WO1997031039A1 (de) | 1997-08-28 |
| NO983786D0 (no) | 1998-08-19 |
| CA2246307A1 (en) | 1997-08-27 |
| BR9707572A (pt) | 1999-07-27 |
| TW467920B (en) | 2001-12-11 |
| DE19606165A1 (de) | 1997-08-21 |
| CN1211997A (zh) | 1999-03-24 |
| KR19990082667A (ko) | 1999-11-25 |
| ES2156362T3 (es) | 2001-06-16 |
| EP0882077B1 (de) | 2001-05-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FC2A | Withdrawal, rejection or dismissal of laid open patent application |