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NO984469L - Allyl inneholdende metallkomplekser og fremgangsmÕte for polymerisasjon av olefin - Google Patents

Allyl inneholdende metallkomplekser og fremgangsmÕte for polymerisasjon av olefin

Info

Publication number
NO984469L
NO984469L NO984469A NO984469A NO984469L NO 984469 L NO984469 L NO 984469L NO 984469 A NO984469 A NO 984469A NO 984469 A NO984469 A NO 984469A NO 984469 L NO984469 L NO 984469L
Authority
NO
Norway
Prior art keywords
group
hydrocarbyl
bonded
hydrogen atoms
germyl
Prior art date
Application number
NO984469A
Other languages
English (en)
Other versions
NO984469D0 (no
Inventor
Peter N Nickias
David D Devore
Francis J Timmers
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Publication of NO984469L publication Critical patent/NO984469L/no
Publication of NO984469D0 publication Critical patent/NO984469D0/no

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61916—Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)

Abstract

Metallkomplekser nyttige som olefin -polymerisasjonskatalysatorer og som tilsvarer formelen: Z-Y / l L ¿MX'nX"p eller en dimer, et oppløst addukt, et chelatert derivat eller en blanding derav, hvor. L er en cyklisk gruppe eller Y, som er bundet til M ved en delokalisert n- binding, idet nevnte gruppe inneholder opptil 50 ikke-hydrogen atomer; M er et metall fra gruppe 3, 4 eller Lanthanidrekken i den periodiske tabell; Z er en kovalent bundet, divalent substituent med opptil 50 ikke-hydrogen atomer og som har formelen, -(ER2)m-, hvor E uavhengig hver forekomst er karbon, silisium eller germanium, R er uavhengig hver forekomst valgt fra gruppen bestående av hydrokarbyl, hydrokarbyloksy, silyl og germyl med opptil 20 atomer forskjellig fra hydrogen og m er et helt tall fra 1 til 3; Y er en allyl eller en hydrokarbyl-, silyl- eller germyl-substituert allylgruppe inneholdende opptil 20 ikke-hydrogen atomer bundet til Z og bundet til M ved en rf-n binding; X' er en nøytral ligand som har opptil 20 ikke-hydrogen atomer; X" er uavhengig hver forekomst en monovalent, anionisk gruppe valgt blant hydrid, halogen, hydrokarbyl, silyl, germyl, hydrokarbyloksy, amid, siloksy, halogenhydrokarbyl, halogensilyl, silylhydrokarbyl og aminohydrokarbyl som har opptil 20 ikke-hydrogen atomer eller to X" grupper danner sammen en divalent hydrokarbadiylgruppe; n er et tall fra O til 3; og p er et helt tall fra O til 2.
NO984469A 1996-03-27 1998-09-25 Allyl inneholdende metallkomplekser og fremgangsmÕte for polymerisasjon av olefin NO984469D0 (no)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US1428596P 1996-03-27 1996-03-27
PCT/US1997/012821 WO1997035894A2 (en) 1996-03-27 1997-03-11 Allyl containing metal complexes and olefin polymerization process

Publications (2)

Publication Number Publication Date
NO984469L true NO984469L (no) 1998-09-25
NO984469D0 NO984469D0 (no) 1998-09-25

Family

ID=21764556

Family Applications (1)

Application Number Title Priority Date Filing Date
NO984469A NO984469D0 (no) 1996-03-27 1998-09-25 Allyl inneholdende metallkomplekser og fremgangsmÕte for polymerisasjon av olefin

Country Status (16)

Country Link
US (2) US5892076A (no)
EP (1) EP0889913B1 (no)
JP (1) JP2000507560A (no)
KR (1) KR20000005029A (no)
CN (1) CN1214700A (no)
AR (1) AR006422A1 (no)
AT (1) ATE244265T1 (no)
AU (1) AU3603797A (no)
BR (1) BR9708243A (no)
CA (1) CA2247506A1 (no)
DE (1) DE69723244T2 (no)
ID (1) ID19625A (no)
NO (1) NO984469D0 (no)
TW (1) TW494109B (no)
WO (1) WO1997035894A2 (no)
ZA (1) ZA972613B (no)

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Also Published As

Publication number Publication date
DE69723244D1 (de) 2003-08-07
DE69723244T2 (de) 2004-04-22
JP2000507560A (ja) 2000-06-20
NO984469D0 (no) 1998-09-25
AU3603797A (en) 1997-10-17
US5994255A (en) 1999-11-30
WO1997035894A2 (en) 1997-10-02
AR006422A1 (es) 1999-08-25
WO1997035894A3 (en) 1997-11-27
US5892076A (en) 1999-04-06
ZA972613B (en) 1998-09-28
EP0889913A2 (en) 1999-01-13
ID19625A (id) 1998-07-23
EP0889913B1 (en) 2003-07-02
BR9708243A (pt) 1999-07-27
CN1214700A (zh) 1999-04-21
ATE244265T1 (de) 2003-07-15
CA2247506A1 (en) 1997-10-02
TW494109B (en) 2002-07-11
KR20000005029A (ko) 2000-01-25

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