NO875086L - Fremgangsmaate for fremstilling av organotitanmaterialer og anvendelse av disse. - Google Patents

Fremgangsmaate for fremstilling av organotitanmaterialer og anvendelse av disse.

Info

Publication number: NO875086L
Authority: NO; Norway
Prior art keywords: acid; sorbitol; titanium; solution; mol
Prior art date: 1986-12-08

Application number

NO875086A

Other languages

English (en)

Norwegian (no)

Other versions

NO875086D0 (no

Inventor

Kenneth Cleon Smeltz

Original Assignee

Du Pont

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1986-12-08

Filing date

1987-12-07

Publication date

1988-06-09

1987-12-07 Application filed by Du Pont filed Critical Du Pont

1987-12-07 Publication of NO875086D0 publication Critical patent/NO875086D0/no

1988-06-09 Publication of NO875086L publication Critical patent/NO875086L/no

Links

239000000463 material Substances 0.000 title claims description 26
238000000034 method Methods 0.000 title claims description 25
238000004519 manufacturing process Methods 0.000 title description 6
JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 31
239000010936 titanium Substances 0.000 claims description 28
239000000243 solution Substances 0.000 claims description 27
FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 26
239000000600 sorbitol Substances 0.000 claims description 26
229910052719 titanium Inorganic materials 0.000 claims description 25
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 24
FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 21
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 19
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 18
239000007864 aqueous solution Substances 0.000 claims description 16
235000014655 lactic acid Nutrition 0.000 claims description 16
229920005862 polyol Polymers 0.000 claims description 16
150000003077 polyols Chemical class 0.000 claims description 16
BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 15
239000004310 lactic acid Substances 0.000 claims description 15
239000001630 malic acid Substances 0.000 claims description 15
BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 12
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 12
239000002253 acid Substances 0.000 claims description 12
235000011090 malic acid Nutrition 0.000 claims description 12
150000003609 titanium compounds Chemical class 0.000 claims description 12
150000004676 glycans Chemical class 0.000 claims description 11
229920001282 polysaccharide Polymers 0.000 claims description 11
239000005017 polysaccharide Substances 0.000 claims description 11
230000015572 biosynthetic process Effects 0.000 claims description 10
RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 claims description 8
HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 claims description 8
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 8
229910003074 TiCl4 Inorganic materials 0.000 claims description 7
AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 claims description 6
235000015165 citric acid Nutrition 0.000 claims description 6
FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 5
FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 5
239000011975 tartaric acid Substances 0.000 claims description 5
235000002906 tartaric acid Nutrition 0.000 claims description 5
FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 claims description 4
HEBKCHPVOIAQTA-QWWZWVQMSA-N D-arabinitol Chemical compound OC[C@@H](O)C(O)[C@H](O)CO HEBKCHPVOIAQTA-QWWZWVQMSA-N 0.000 claims description 4
RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 claims description 4
239000004386 Erythritol Substances 0.000 claims description 4
UNXHWFMMPAWVPI-UHFFFAOYSA-N Erythritol Natural products OCC(O)C(O)CO UNXHWFMMPAWVPI-UHFFFAOYSA-N 0.000 claims description 4
229930195725 Mannitol Natural products 0.000 claims description 4
TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 claims description 4
UNXHWFMMPAWVPI-ZXZARUISSA-N erythritol Chemical compound OC[C@H](O)[C@H](O)CO UNXHWFMMPAWVPI-ZXZARUISSA-N 0.000 claims description 4
235000019414 erythritol Nutrition 0.000 claims description 4
229940009714 erythritol Drugs 0.000 claims description 4
FBPFZTCFMRRESA-GUCUJZIJSA-N galactitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-GUCUJZIJSA-N 0.000 claims description 4
239000000174 gluconic acid Substances 0.000 claims description 4
235000012208 gluconic acid Nutrition 0.000 claims description 4
CDAISMWEOUEBRE-GPIVLXJGSA-N inositol Chemical compound O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@H](O)[C@@H]1O CDAISMWEOUEBRE-GPIVLXJGSA-N 0.000 claims description 4
229960000367 inositol Drugs 0.000 claims description 4
239000000594 mannitol Substances 0.000 claims description 4
235000010355 mannitol Nutrition 0.000 claims description 4
CDAISMWEOUEBRE-UHFFFAOYSA-N scyllo-inosotol Natural products OC1C(O)C(O)C(O)C(O)C1O CDAISMWEOUEBRE-UHFFFAOYSA-N 0.000 claims description 4
239000000811 xylitol Substances 0.000 claims description 4
HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 claims description 4
235000010447 xylitol Nutrition 0.000 claims description 4
229960002675 xylitol Drugs 0.000 claims description 4
QBYIENPQHBMVBV-HFEGYEGKSA-N (2R)-2-hydroxy-2-phenylacetic acid Chemical compound O[C@@H](C(O)=O)c1ccccc1.O[C@@H](C(O)=O)c1ccccc1 QBYIENPQHBMVBV-HFEGYEGKSA-N 0.000 claims description 3
RBNPOMFGQQGHHO-UHFFFAOYSA-N -2,3-Dihydroxypropanoic acid Natural products OCC(O)C(O)=O RBNPOMFGQQGHHO-UHFFFAOYSA-N 0.000 claims description 3
RBNPOMFGQQGHHO-UWTATZPHSA-N D-glyceric acid Chemical compound OC[C@@H](O)C(O)=O RBNPOMFGQQGHHO-UWTATZPHSA-N 0.000 claims description 3
SQUHHTBVTRBESD-UHFFFAOYSA-N Hexa-Ac-myo-Inositol Natural products CC(=O)OC1C(OC(C)=O)C(OC(C)=O)C(OC(C)=O)C(OC(C)=O)C1OC(C)=O SQUHHTBVTRBESD-UHFFFAOYSA-N 0.000 claims description 3
IWYDHOAUDWTVEP-UHFFFAOYSA-N R-2-phenyl-2-hydroxyacetic acid Natural products OC(=O)C(O)C1=CC=CC=C1 IWYDHOAUDWTVEP-UHFFFAOYSA-N 0.000 claims description 3
150000002016 disaccharides Chemical class 0.000 claims description 3
229960002510 mandelic acid Drugs 0.000 claims description 3
150000002772 monosaccharides Chemical class 0.000 claims description 3
230000001105 regulatory effect Effects 0.000 claims description 3
235000000346 sugar Nutrition 0.000 claims description 3
229910010062 TiCl3 Inorganic materials 0.000 claims 1
YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 claims 1
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 129
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 22
239000011541 reaction mixture Substances 0.000 description 19
239000000047 product Substances 0.000 description 15
229910052757 nitrogen Inorganic materials 0.000 description 11
238000003756 stirring Methods 0.000 description 11
238000001816 cooling Methods 0.000 description 10
238000005303 weighing Methods 0.000 description 10
238000005755 formation reaction Methods 0.000 description 9
229940099690 malic acid Drugs 0.000 description 9
239000008367 deionised water Substances 0.000 description 8
229910021641 deionized water Inorganic materials 0.000 description 8
239000012530 fluid Substances 0.000 description 8
PODWXQQNRWNDGD-UHFFFAOYSA-L sodium thiosulfate pentahydrate Chemical compound O.O.O.O.O.[Na+].[Na+].[O-]S([S-])(=O)=O PODWXQQNRWNDGD-UHFFFAOYSA-L 0.000 description 8
238000004132 cross linking Methods 0.000 description 7
239000003431 cross linking reagent Substances 0.000 description 7
150000003608 titanium Chemical class 0.000 description 7
239000007789 gas Substances 0.000 description 6
-1 titanium ester Chemical class 0.000 description 6
229940061720 alpha hydroxy acid Drugs 0.000 description 5
150000001280 alpha hydroxy acids Chemical class 0.000 description 5
238000006243 chemical reaction Methods 0.000 description 5
239000000499 gel Substances 0.000 description 4
150000007522 mineralic acids Chemical class 0.000 description 4
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
239000012736 aqueous medium Substances 0.000 description 3
150000001875 compounds Chemical class 0.000 description 3
238000010438 heat treatment Methods 0.000 description 3
125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
239000000203 mixture Substances 0.000 description 3
244000303965 Cyamopsis psoralioides Species 0.000 description 2
SRBFZHDQGSBBOR-IOVATXLUSA-N D-xylopyranose Chemical compound O[C@@H]1COC(O)[C@H](O)[C@H]1O SRBFZHDQGSBBOR-IOVATXLUSA-N 0.000 description 2
WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
125000005907 alkyl ester group Chemical group 0.000 description 2
150000002763 monocarboxylic acids Chemical class 0.000 description 2
238000004064 recycling Methods 0.000 description 2
239000008399 tap water Substances 0.000 description 2
235000020679 tap water Nutrition 0.000 description 2
OMDQUFIYNPYJFM-XKDAHURESA-N (2r,3r,4s,5r,6s)-2-(hydroxymethyl)-6-[[(2r,3s,4r,5s,6r)-4,5,6-trihydroxy-3-[(2s,3s,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]methoxy]oxane-3,4,5-triol Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@@H]1OC[C@@H]1[C@@H](O[C@H]2[C@H]([C@@H](O)[C@H](O)[C@@H](CO)O2)O)[C@H](O)[C@H](O)[C@H](O)O1 OMDQUFIYNPYJFM-XKDAHURESA-N 0.000 description 1
LUEWUZLMQUOBSB-FSKGGBMCSA-N (2s,3s,4s,5s,6r)-2-[(2r,3s,4r,5r,6s)-6-[(2r,3s,4r,5s,6s)-4,5-dihydroxy-2-(hydroxymethyl)-6-[(2r,4r,5s,6r)-4,5,6-trihydroxy-2-(hydroxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-4,5-dihydroxy-2-(hydroxymethyl)oxan-3-yl]oxy-6-(hydroxymethyl)oxane-3,4,5-triol Chemical compound O[C@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@@H](O[C@@H]2[C@H](O[C@@H](OC3[C@H](O[C@@H](O)[C@@H](O)[C@H]3O)CO)[C@@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O LUEWUZLMQUOBSB-FSKGGBMCSA-N 0.000 description 1
OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 1
GUBGYTABKSRVRQ-XLOQQCSPSA-N Alpha-Lactose Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@H](O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-XLOQQCSPSA-N 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
ILOZMGXKMDMJNC-UHFFFAOYSA-N CC(C)[Ti]C(C)C.OCCN(CCO)CCO.OCCN(CCO)CCO Chemical compound CC(C)[Ti]C(C)C.OCCN(CCO)CCO.OCCN(CCO)CCO ILOZMGXKMDMJNC-UHFFFAOYSA-N 0.000 description 1
229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
244000025596 Cassia laevigata Species 0.000 description 1
235000006693 Cassia laevigata Nutrition 0.000 description 1
GUBGYTABKSRVRQ-CUHNMECISA-N D-Cellobiose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-CUHNMECISA-N 0.000 description 1
WQZGKKKJIJFFOK-QTVWNMPRSA-N D-mannopyranose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-QTVWNMPRSA-N 0.000 description 1
241000196324 Embryophyta Species 0.000 description 1
240000003168 Filicium decipiens Species 0.000 description 1
229930091371 Fructose Natural products 0.000 description 1
RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
239000005715 Fructose Substances 0.000 description 1
229920000926 Galactomannan Polymers 0.000 description 1
229920002581 Glucomannan Polymers 0.000 description 1
WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
229920002907 Guar gum Polymers 0.000 description 1
229920000569 Gum karaya Polymers 0.000 description 1
GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 description 1
229920000161 Locust bean gum Polymers 0.000 description 1
GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 1
241000219100 Rhamnaceae Species 0.000 description 1
239000004133 Sodium thiosulphate Substances 0.000 description 1
241000934878 Sterculia Species 0.000 description 1
CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
229930006000 Sucrose Natural products 0.000 description 1
229910010068 TiCl2 Inorganic materials 0.000 description 1
GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
WDJHALXBUFZDSR-UHFFFAOYSA-M acetoacetate Chemical compound CC(=O)CC([O-])=O WDJHALXBUFZDSR-UHFFFAOYSA-M 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
238000013019 agitation Methods 0.000 description 1
230000001476 alcoholic effect Effects 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
229910052784 alkaline earth metal Inorganic materials 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
WQZGKKKJIJFFOK-PHYPRBDBSA-N alpha-D-galactose Chemical compound OC[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-PHYPRBDBSA-N 0.000 description 1
239000000908 ammonium hydroxide Substances 0.000 description 1
PYMYPHUHKUWMLA-UHFFFAOYSA-N arabinose Natural products OCC(O)C(O)C(O)C=O PYMYPHUHKUWMLA-UHFFFAOYSA-N 0.000 description 1
239000002585 base Substances 0.000 description 1
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WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 description 1
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
239000001768 carboxy methyl cellulose Substances 0.000 description 1
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239000007795 chemical reaction product Substances 0.000 description 1
239000002537 cosmetic Substances 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
150000001991 dicarboxylic acids Chemical class 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
238000000605 extraction Methods 0.000 description 1
238000007710 freezing Methods 0.000 description 1
230000008014 freezing Effects 0.000 description 1
229930182830 galactose Natural products 0.000 description 1
229940046240 glucomannan Drugs 0.000 description 1
239000008103 glucose Substances 0.000 description 1
239000000665 guar gum Substances 0.000 description 1
235000010417 guar gum Nutrition 0.000 description 1
229960002154 guar gum Drugs 0.000 description 1
150000001261 hydroxy acids Chemical class 0.000 description 1
239000000231 karaya gum Substances 0.000 description 1
235000010494 karaya gum Nutrition 0.000 description 1
229940039371 karaya gum Drugs 0.000 description 1
239000008101 lactose Substances 0.000 description 1
239000010985 leather Substances 0.000 description 1
239000007788 liquid Substances 0.000 description 1
239000000711 locust bean gum Substances 0.000 description 1
235000010420 locust bean gum Nutrition 0.000 description 1
229920001206 natural gum Polymers 0.000 description 1
230000035699 permeability Effects 0.000 description 1
239000001103 potassium chloride Substances 0.000 description 1
235000011164 potassium chloride Nutrition 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
239000000523 sample Substances 0.000 description 1
239000004576 sand Substances 0.000 description 1
229940124513 senna glycoside Drugs 0.000 description 1
AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
235000019345 sodium thiosulphate Nutrition 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
239000007858 starting material Substances 0.000 description 1
239000005720 sucrose Substances 0.000 description 1
239000004753 textile Substances 0.000 description 1
LLZRNZOLAXHGLL-UHFFFAOYSA-J titanic acid Chemical compound O[Ti](O)(O)O LLZRNZOLAXHGLL-UHFFFAOYSA-J 0.000 description 1
229910000349 titanium oxysulfate Inorganic materials 0.000 description 1
ZWYDDDAMNQQZHD-UHFFFAOYSA-L titanium(ii) chloride Chemical compound [Cl-].[Cl-].[Ti+2] ZWYDDDAMNQQZHD-UHFFFAOYSA-L 0.000 description 1
150000003628 tricarboxylic acids Chemical class 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/60—Compositions for stimulating production by acting on the underground formation
- C09K8/62—Compositions for forming crevices or fractures
- C09K8/66—Compositions based on water or polar solvents
- C09K8/68—Compositions based on water or polar solvents containing organic compounds
- C09K8/685—Compositions based on water or polar solvents containing organic compounds containing cross-linking agents
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic Table without C-Metal linkages

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Life Sciences & Earth Sciences (AREA)
General Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Inorganic Compounds Of Heavy Metals (AREA)
Glass Compositions (AREA)

NO875086A 1986-12-08 1987-12-07 Fremgangsmaate for fremstilling av organotitanmaterialer og anvendelse av disse. NO875086L (no)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US94107686A	1986-12-08	1986-12-08

Publications (2)

Publication Number	Publication Date
NO875086D0 NO875086D0 (no)	1987-12-07
NO875086L true NO875086L (no)	1988-06-09

Family

ID=25475884

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NO875086A NO875086L (no)	1986-12-08	1987-12-07	Fremgangsmaate for fremstilling av organotitanmaterialer og anvendelse av disse.

Country Status (6)

Country	Link
EP (1)	EP0271060A3 (pt)
AU (1)	AU602033B2 (pt)
BR (1)	BR8706575A (pt)
MY (1)	MY102726A (pt)
NO (1)	NO875086L (pt)
NZ (1)	NZ222812A (pt)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN108484908B (zh) *	2018-03-31	2022-01-25	青岛大学	一种新型稠油降粘剂的制备方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB1514361A (en) *	1976-03-13	1978-06-14	Tioxide Group Ltd	Titanium chelates
AU583589B2 (en) *	1984-10-09	1989-05-04	E.I. Du Pont De Nemours And Company	Organic titanium compositions and their use as cross-linkers
US4609479A (en) *	1984-10-09	1986-09-02	E. I. Du Pont De Nemours And Company	Organic titanium compositions and their use as cross-linkers
EP0195531A3 (en) *	1985-03-21	1987-12-02	E.I. Du Pont De Nemours And Company	Organic titanium compositions useful as cross-linkers

1987
- 1987-12-04 NZ NZ222812A patent/NZ222812A/xx unknown
- 1987-12-07 AU AU82139/87A patent/AU602033B2/en not_active Ceased
- 1987-12-07 BR BR8706575A patent/BR8706575A/pt unknown
- 1987-12-07 NO NO875086A patent/NO875086L/no unknown
- 1987-12-08 MY MYPI87003162A patent/MY102726A/en unknown
- 1987-12-08 EP EP87118151A patent/EP0271060A3/en not_active Withdrawn

Also Published As

Publication number	Publication date
EP0271060A3 (en)	1989-12-13
EP0271060A2 (en)	1988-06-15
MY102726A (en)	1992-09-30
BR8706575A (pt)	1988-07-12
NO875086D0 (no)	1987-12-07
AU8213987A (en)	1988-06-09
NZ222812A (en)	1989-08-29
AU602033B2 (en)	1990-09-27

Publication	Publication Date	Title
US4609479A (en)	1986-09-02	Organic titanium compositions and their use as cross-linkers
US5310489A (en)	1994-05-10	Borate cross-linking solutions
CA2073806C (en)	2003-09-23	Delayed borate crosslinking fracturing fluid
US7754660B2 (en)	2010-07-13	Process to prepare zirconium-based cross-linker compositions and their use in oil field applications
US7795188B2 (en)	2010-09-14	Zirconium-base cross-linker compositions and their use in high pH oil field applications
US4466890A (en)	1984-08-21	Liquid gel concentrates and methods of using the same
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US8252731B2 (en)	2012-08-28	Solid zirconium-based cross-linking agent and use in oil field applications
GB2070028A (en)	1981-09-03	Liquid gel concentrates
CA2704542A1 (en)	2009-05-07	High temperature aqueous-based zirconium fracturing fluid and use
US4960527A (en)	1990-10-02	Delayed crosslinking of guar gelling agents with ceric salts
CA1158428A (en)	1983-12-13	Method of inhibiting crosslinking of aqueous xanthan gums in the presence of ferric acid
US4798902A (en)	1989-01-17	Zirconium chelates and their use for cross-linking
CA2678783C (en)	2016-10-18	Zirconium-based cross-linker compositions and their use in high ph oil field applications
NO171595B (no)	1992-12-28	Organozirkoniumforbindelser
US4749041A (en)	1988-06-07	Hydraulic fracturing method using delayed crosslinker composition
US5182408A (en)	1993-01-26	Process for preparation of stable aqueous solutions of zirconium chelates
US5252234A (en)	1993-10-12	Borate cross-linking solutions
US5798320A (en)	1998-08-25	Gelation additive for hydraulic fracturing fluids
US5950729A (en)	1999-09-14	Using gelation additive for hydraulic fracturing fluids
US5252235A (en)	1993-10-12	Borate cross-linking solutions
US7732384B2 (en)	2010-06-08	Solid borozirconate and borotitanate cross-linkers
US4958038A (en)	1990-09-18	Organotitanium compositions useful for cross-linking
US4953621A (en)	1990-09-04	Organic titanium compositions useful as cross-linkers
NO875086L (no)	1988-06-09	Fremgangsmaate for fremstilling av organotitanmaterialer og anvendelse av disse.