NO20003936L - Katalysator med bimodal poreradiusfordeling - Google Patents
Katalysator med bimodal poreradiusfordelingInfo
- Publication number
- NO20003936L NO20003936L NO20003936A NO20003936A NO20003936L NO 20003936 L NO20003936 L NO 20003936L NO 20003936 A NO20003936 A NO 20003936A NO 20003936 A NO20003936 A NO 20003936A NO 20003936 L NO20003936 L NO 20003936L
- Authority
- NO
- Norway
- Prior art keywords
- catalyst
- pore radius
- radius distribution
- bimodal pore
- bimodal
- Prior art date
Links
- 230000002902 bimodal effect Effects 0.000 title 1
- 239000003054 catalyst Substances 0.000 title 1
- 239000011148 porous material Substances 0.000 title 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/08—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of gallium, indium or thallium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/321—Catalytic processes
- C07C5/324—Catalytic processes with metals
- C07C5/325—Catalytic processes with metals of the platinum group
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/66—Pore distribution
- B01J35/69—Pore distribution bimodal
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
- C07C2521/04—Alumina
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- C07C2521/08—Silica
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/14—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of germanium, tin or lead
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
- C07C2523/42—Platinum
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19937107A DE19937107A1 (de) | 1999-08-06 | 1999-08-06 | Katalysator mit bimodaler Porenradienverteilung |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NO20003936D0 NO20003936D0 (no) | 2000-08-03 |
| NO20003936L true NO20003936L (no) | 2001-02-07 |
| NO320582B1 NO320582B1 (no) | 2005-12-27 |
Family
ID=7917412
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO20003936A NO320582B1 (no) | 1999-08-06 | 2000-08-03 | Katalysator med bimodal poreradiusfordeling, fremgangsmate for fremstilling derav, anvendelse av katalysatoren og fremgangsmate for dehydrogenering. |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US6670303B1 (no) |
| EP (1) | EP1074301B1 (no) |
| CN (1) | CN1121268C (no) |
| DE (2) | DE19937107A1 (no) |
| ES (1) | ES2212945T3 (no) |
| MY (1) | MY126767A (no) |
| NO (1) | NO320582B1 (no) |
Families Citing this family (42)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2276808T3 (es) | 2000-06-14 | 2007-07-01 | Basf Aktiengesellschaft | Metodo para la produccion de acroleina y/o acido acrilico. |
| CA2432200C (en) * | 2000-12-22 | 2007-06-26 | Basf Aktiengesellschaft | Catalyst with bimodal pore radius distribution |
| WO2002051540A1 (de) * | 2000-12-22 | 2002-07-04 | Basf Aktiengesellschaft | Oxidkatalysatoren enthaltend zuminest silika und gruppe ivp oxid |
| DE10211275A1 (de) | 2002-03-13 | 2003-09-25 | Basf Ag | Verfahren der kontinuierlichen heterogen katalysierten partiellen Dehydrierung |
| US7067453B1 (en) * | 2001-07-13 | 2006-06-27 | Innovatek, Inc. | Hydrocarbon fuel reforming catalyst and use thereof |
| DE10219879A1 (de) * | 2002-05-03 | 2003-11-20 | Basf Ag | Katalysatorträger und Verfahren zu seiner Herstellung |
| DE10240129B4 (de) | 2002-08-30 | 2004-11-11 | Basf Ag | Integriertes Verfahren zur Synthese von Propylenoxid |
| DE10350045A1 (de) | 2003-10-27 | 2005-05-25 | Basf Ag | Verfahren zur Herstellung von 1-Buten |
| DE10350044A1 (de) | 2003-10-27 | 2005-05-25 | Basf Ag | Verfahren zur Herstellung von 1-Buten |
| DE10361822A1 (de) | 2003-12-30 | 2005-08-11 | Basf Ag | Verfahren zur Herstellung von Butadien |
| DE10361823A1 (de) | 2003-12-30 | 2005-08-11 | Basf Ag | Verfahren zur Herstellung von Butadien und 1-Buten |
| DE10361824A1 (de) | 2003-12-30 | 2005-07-28 | Basf Ag | Verfahren zur Herstellung von Butadien |
| US7309480B2 (en) * | 2004-04-16 | 2007-12-18 | H2Gen Innovations, Inc. | Catalyst for hydrogen generation through steam reforming of hydrocarbons |
| DE102004059355A1 (de) * | 2004-12-09 | 2006-06-14 | Basf Ag | Verfahren zur Herstellung von Propan zu Propen |
| DE102004061772A1 (de) * | 2004-12-22 | 2006-07-06 | Basf Ag | Verfahren zur Herstellung von Propen aus Propan |
| WO2007038370A1 (en) * | 2005-09-23 | 2007-04-05 | Eastman Chemical Company | Catalyst for the production of methyl isopropyl ketone |
| WO2007038371A1 (en) * | 2005-09-23 | 2007-04-05 | Eastman Chemical Company | Catalysts selective for the preparation of mixed ketones from a mixture of carboxylic acids |
| CN100425337C (zh) * | 2006-01-27 | 2008-10-15 | 中国石油化工股份有限公司 | 一种ZrO2-SiO2复合氧化物及其制备方法与应用 |
| EA200802034A1 (ru) * | 2006-03-29 | 2009-02-27 | Басф Се | Способ получения пропена из пропана |
| US7842846B2 (en) | 2006-03-30 | 2010-11-30 | Basf Aktiengesellschaft | Process for heterogeneously catalyzed partial dehydrogenation of at least one hydrocarbon to be dehydrogenated |
| KR20090031633A (ko) | 2006-07-20 | 2009-03-26 | 바스프 에스이 | 상응 알칸으로부터의 이소프로판올 및 2-부탄올의 제조 방법 |
| DE102006035718A1 (de) | 2006-07-28 | 2008-01-31 | Basf Ag | Verfahren zum Langzeitbetrieb einer kontinuierlich betriebenen heterogen katalysierten partiellen Dehydrierung eines zu dehydrierenden Kohlenwasserstoffs |
| US7932408B2 (en) | 2006-09-29 | 2011-04-26 | Scientific Design Company, Inc. | Catalyst with bimodal pore size distribution and the use thereof |
| US7977274B2 (en) | 2006-09-29 | 2011-07-12 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Catalyst with bimodal pore size distribution and the use thereof |
| DE102006060509A1 (de) | 2006-12-19 | 2008-06-26 | Basf Se | Reaktor zur Durchführung einer kontinuierlichen Oxidehydrierung sowie Verfahren |
| DE102007006647A1 (de) | 2007-02-06 | 2008-08-07 | Basf Se | Verfahren zur Regenerierung eines im Rahmen einer heterogen katalysierten partiellen Dehydrierung eines Kohlenwasserstoffs deaktivierten Katalysatorbetts |
| CN101240189B (zh) * | 2007-02-09 | 2011-06-22 | 中国石油化工股份有限公司 | 一种含酸原油的固定床加氢处理方法 |
| DE102007036750A1 (de) | 2007-08-03 | 2009-02-05 | Uhde Gmbh | Regeneration von Katalysatoren zur Dehydrierung von Alkanen |
| US8530717B2 (en) | 2008-07-21 | 2013-09-10 | Basf Se | Process for the industrial isolation of propene |
| DE102008044946B4 (de) | 2008-08-29 | 2022-06-15 | Evonik Superabsorber Gmbh | Einsatz von Schaumkörpern in Oxidations-Reaktoren zur Herstellung ungesättigter Carbonsäuren |
| JP5770718B2 (ja) * | 2009-05-20 | 2015-08-26 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | モノリス触媒とその使用方法 |
| EP2667968A2 (de) * | 2011-01-25 | 2013-12-04 | Basf Se | Katalysatorträger aus der flammen-spraypyrolyse und katalysator für die autotherme propandehydrierung |
| EP2667969A1 (de) * | 2011-01-25 | 2013-12-04 | Basf Se | Katalysator aus der flammen-spraypyrolyse für die autotherme propandehydrierung |
| US8680005B2 (en) | 2011-01-25 | 2014-03-25 | Basf Se | Catalyst from flame-spray pyrolysis and catalyst for autothermal propane dehydrogenation |
| CN102989453B (zh) * | 2011-09-09 | 2015-05-13 | 中国石油天然气股份有限公司 | 碳二前加氢催化剂及制备方法 |
| JP6217442B2 (ja) * | 2013-03-29 | 2017-10-25 | 日本ゼオン株式会社 | イソプレンの製造方法 |
| EP3002058A1 (de) * | 2014-10-02 | 2016-04-06 | Evonik Degussa GmbH | Katalysatorsystem zur Herstellung von Ketonen aus Epoxiden |
| CN108722403B (zh) * | 2017-04-20 | 2019-09-27 | 中国石油化工股份有限公司 | 一种丙烷脱氢催化剂及其制备方法和丙烷脱氢制丙烯的方法 |
| CN108722402B (zh) * | 2017-04-20 | 2019-08-20 | 中国石油化工股份有限公司 | 一种丙烷脱氢催化剂及其制备方法和丙烷脱氢制丙烯的方法 |
| JP7064896B2 (ja) * | 2018-02-15 | 2022-05-11 | Eneos株式会社 | 不飽和炭化水素の製造方法 |
| WO2020012870A1 (ja) * | 2018-07-13 | 2020-01-16 | 富士電機株式会社 | 二酸化炭素ガスセンサ |
| CN112892612B (zh) * | 2019-12-03 | 2023-01-17 | 中国石化集团金陵石油化工有限责任公司 | 一种用于烃类转化反应的催化剂 |
Family Cites Families (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3670044A (en) * | 1969-07-18 | 1972-06-13 | Phillips Petroleum Co | Catalytic dehydrogenation process |
| US3880776A (en) * | 1971-06-10 | 1975-04-29 | Phillips Petroleum Co | Highly calcined support for catalytic dehydrogenation |
| GB1405405A (en) * | 1971-06-25 | 1975-09-10 | Johnson Matthey Co Ltd | Platinum group metal catalysts |
| US3878131A (en) * | 1971-09-29 | 1975-04-15 | Universal Oil Prod Co | Multicomponent dehydrogenation catalyst |
| US4169815A (en) * | 1973-11-15 | 1979-10-02 | Phillips Petroleum Company | Catalyst for dehydrogenation process |
| US3898155A (en) * | 1973-12-19 | 1975-08-05 | Gulf Research Development Co | Heavy oil demetallization and desulfurization process |
| US4003852A (en) * | 1974-04-08 | 1977-01-18 | Uop Inc. | Nonacidic multimetallic dehydrogenation catalyst |
| US4008180A (en) * | 1974-06-19 | 1977-02-15 | Universal Oil Products Company | Dehydrogenation method and multimetallic catalytic composite for use therein |
| US4046715A (en) * | 1974-08-27 | 1977-09-06 | Universal Oil Products Company | Nonacidic multimetallic dehydrogenation catalyst |
| US3960710A (en) | 1974-11-08 | 1976-06-01 | Universal Oil Products Company | Hydrocarbon conversion with an acidic multimetallic catalytic composite |
| US4162235A (en) * | 1976-06-17 | 1979-07-24 | Johnson, Matthey & Co., Limited | Catalysts |
| US4102822A (en) * | 1976-07-26 | 1978-07-25 | Chevron Research Company | Hydrocarbon hydroconversion catalyst and the method for its preparation |
| US4167496A (en) * | 1978-01-06 | 1979-09-11 | Uop Inc. | Nonacidic multimetallic catalytic composite for use in hydrocarbon dehydrogenation |
| US4366091A (en) * | 1979-08-20 | 1982-12-28 | Uop Inc. | Hydrocarbon dehydrogenation with an attenuated superactive multimetallic catalytic composite for use therein |
| US4549957A (en) * | 1981-06-17 | 1985-10-29 | Amoco Corporation | Hydrotreating catalyst and process |
| US4454026A (en) * | 1981-06-17 | 1984-06-12 | Standard Oil Company (Indiana) | Hydrotreating catalyst and process |
| US4486547A (en) * | 1981-11-05 | 1984-12-04 | Uop Inc. | Indium-containing dehydrogenation catalyst |
| US4568655A (en) * | 1984-10-29 | 1986-02-04 | Mobil Oil Corporation | Catalyst composition comprising Zeolite Beta |
| US4716143A (en) * | 1986-06-06 | 1987-12-29 | Uop Inc. | Dehydrogenation catalyst composition |
| US4786625A (en) * | 1987-02-25 | 1988-11-22 | Uop Inc. | Dehydrogenation catalyst compositon |
| US4788371A (en) | 1987-12-30 | 1988-11-29 | Uop Inc. | Catalytic oxidative steam dehydrogenation process |
| US4959338A (en) * | 1988-08-17 | 1990-09-25 | Toa Nenryo Kogyo Kabushiki Kaisha | Heat-resistant catalyst carrier moldings and catalysts for combustion |
| DE3918013A1 (de) | 1989-06-02 | 1990-12-06 | Huels Chemische Werke Ag | Zirkondioxidpulver, verfahren zu seiner herstellung sowie dessen verwendung zur herstellung von sinterkoerpern |
| DE3932780A1 (de) * | 1989-09-30 | 1991-04-11 | Huels Chemische Werke Ag | Zirkondioxidpulver, verfahren zu seiner herstellung, dessen verwendung sowie daraus hergestellte sinterkoerper |
| GB9010709D0 (en) * | 1990-05-12 | 1990-07-04 | Johnson Matthey Plc | Catalytic reduction |
| US5220091A (en) | 1992-02-26 | 1993-06-15 | Phillips Petroleum Company | Alkane dehydrogenation |
| US5221656A (en) * | 1992-03-25 | 1993-06-22 | Amoco Corporation | Hydroprocessing catalyst |
| NO179131C (no) | 1993-06-14 | 1996-08-14 | Statoil As | Katalysator, fremgangsmåte for dens fremstilling og fremgangsmåte for dehydrogenering av lette paraffiner |
| GB9316955D0 (en) * | 1993-08-14 | 1993-09-29 | Johnson Matthey Plc | Improvements in catalysts |
| US5322821A (en) * | 1993-08-23 | 1994-06-21 | W. R. Grace & Co.-Conn. | Porous ceramic beads |
| DE19533486A1 (de) | 1995-09-12 | 1997-03-13 | Basf Ag | Monomodale und polymodale Katalysatorträger und Katalysatoren mit engen Porengrößenverteilungen und deren Herstellverfahren |
| CN1087278C (zh) * | 1996-04-26 | 2002-07-10 | 巴斯福股份公司 | 在原处生成的钌催化剂存在下进行有机化合物反应的方法 |
| DE19645047A1 (de) * | 1996-10-31 | 1998-05-07 | Basf Ag | Katalysatoren für die Aminierung von Alkylenoxiden, Alkoholen, Aldehyden und Ketonen |
| US6162530A (en) * | 1996-11-18 | 2000-12-19 | University Of Connecticut | Nanostructured oxides and hydroxides and methods of synthesis therefor |
| DE19648270A1 (de) * | 1996-11-21 | 1998-05-28 | Basf Ag | Offenzellige poröse Sinterprodukte und Verfahren zu ihrer Herstellung |
| DE19653629A1 (de) | 1996-12-20 | 1998-06-25 | Basf Ag | Monoklines Zirconiumoxid mit hoher Oberfläche |
| US5916836A (en) * | 1996-12-27 | 1999-06-29 | Tricat Management Gmbh | Method of manufacture of molecular sieves |
-
1999
- 1999-08-06 DE DE19937107A patent/DE19937107A1/de not_active Withdrawn
-
2000
- 2000-07-21 EP EP00115727A patent/EP1074301B1/de not_active Expired - Lifetime
- 2000-07-21 ES ES00115727T patent/ES2212945T3/es not_active Expired - Lifetime
- 2000-07-21 DE DE50004770T patent/DE50004770D1/de not_active Expired - Lifetime
- 2000-07-25 US US09/625,485 patent/US6670303B1/en not_active Expired - Lifetime
- 2000-07-31 MY MYPI20003494 patent/MY126767A/en unknown
- 2000-08-03 NO NO20003936A patent/NO320582B1/no not_active IP Right Cessation
- 2000-08-05 CN CN00124057A patent/CN1121268C/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1121268C (zh) | 2003-09-17 |
| DE50004770D1 (de) | 2004-01-29 |
| ES2212945T3 (es) | 2004-08-16 |
| CN1283519A (zh) | 2001-02-14 |
| EP1074301B1 (de) | 2003-12-17 |
| NO20003936D0 (no) | 2000-08-03 |
| EP1074301A1 (de) | 2001-02-07 |
| MY126767A (en) | 2006-10-31 |
| NO320582B1 (no) | 2005-12-27 |
| US6670303B1 (en) | 2003-12-30 |
| DE19937107A1 (de) | 2001-02-08 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM1K | Lapsed by not paying the annual fees |