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NO176176B - Analogifremgangsmåte for fremstilling av terapeutisk aktive arylsulfonamider - Google Patents

Analogifremgangsmåte for fremstilling av terapeutisk aktive arylsulfonamider Download PDF

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Publication number
NO176176B
NO176176B NO902099A NO902099A NO176176B NO 176176 B NO176176 B NO 176176B NO 902099 A NO902099 A NO 902099A NO 902099 A NO902099 A NO 902099A NO 176176 B NO176176 B NO 176176B
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group
formula
compound
constitutes
carbon
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NO902099A
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NO902099L (no
NO902099D0 (no
NO176176C (no
Inventor
Armin Heckel
Josef Nickl
Rainer Soyka
Wolfgang Eisert
Thomas Muller
Hans Weisenberger
Christopher Meade
Gojko Muacevic
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Thomae Gmbh Dr K
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Priority claimed from DE3915506A external-priority patent/DE3915506A1/de
Application filed by Thomae Gmbh Dr K filed Critical Thomae Gmbh Dr K
Publication of NO902099D0 publication Critical patent/NO902099D0/no
Publication of NO902099L publication Critical patent/NO902099L/no
Publication of NO176176B publication Critical patent/NO176176B/no
Publication of NO176176C publication Critical patent/NO176176C/no

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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D213/00Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/24Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D213/54Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D401/00Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/06Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a carbon chain containing only aliphatic carbon atoms
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61PSPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P11/00Drugs for disorders of the respiratory system
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61PSPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P37/00Drugs for immunological or allergic disorders
    • A61P37/08Antiallergic agents
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61PSPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P43/00Drugs for specific purposes, not provided for in groups A61P1/00-A61P41/00
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61PSPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P7/00Drugs for disorders of the blood or the extracellular fluid
    • A61P7/02Antithrombotic agents; Anticoagulants; Platelet aggregation inhibitors
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61PSPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P9/00Drugs for disorders of the cardiovascular system
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61PSPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P9/00Drugs for disorders of the cardiovascular system
    • A61P9/10Drugs for disorders of the cardiovascular system for treating ischaemic or atherosclerotic diseases, e.g. antianginal drugs, coronary vasodilators, drugs for myocardial infarction, retinopathy, cerebrovascula insufficiency, renal arteriosclerosis
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D213/00Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/24Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D213/54Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C07D213/55Acids; Esters
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D213/00Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/24Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D213/54Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C07D213/56Amides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D409/00Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
    • C07D409/02Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings
    • C07D409/06Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings linked by a carbon chain containing only aliphatic carbon atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D409/00Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
    • C07D409/02Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings
    • C07D409/12Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links

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  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Engineering & Computer Science (AREA)
  • Veterinary Medicine (AREA)
  • Medicinal Chemistry (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • General Chemical & Material Sciences (AREA)
  • Pharmacology & Pharmacy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Heart & Thoracic Surgery (AREA)
  • Pulmonology (AREA)
  • Cardiology (AREA)
  • Immunology (AREA)
  • Urology & Nephrology (AREA)
  • Vascular Medicine (AREA)
  • Diabetes (AREA)
  • Hematology (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Pyridine Compounds (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Pyrrole Compounds (AREA)
  • Other In-Based Heterocyclic Compounds (AREA)

Claims (3)

1. Analogifremgangsmåte for fremstilling av terapeutisk aktive arylsulfonamider med formel hvor Rx betyr en fenylalkyl-, trialkylfenyl-, tetrametylfenyl- eller pentametylfenylgruppe, en tienylgruppe som eventuelt er substituert med et halogenatom eller en alkylgruppe, eller en fenylgruppe som er monosubstituert med en nitrogruppe eller mono- eller disubstituert med et halogenatom,.en alkyl-, trifluormetyl- eller alkoksygruppe hvor substituentene kan være like eller forskjellige, R2, R4 og R5 som kan være like eller forskjellige, hver utgjør et hydrogenatom eller en alkylgruppe eller R2 er et hydrogenatom eller en alkylgruppe og R4 og R5 sammen utgjør en karbon-karbon-binding, R3 er en pyridylgruppe, R6 er en hydroksy-, alkoksy-, benzylamino- eller dialkylaminogruppe, A er en gruppe med formel hvor R7 er et hydrogenatom eller en alkylgruppe, R8 er et hydrogenatom eller R7 og R8 sammen utgjør en metylen- eller etylengruppe og X utgjør en iminogruppe som er substituert med en alkylgruppe, eller et svovel atom, hvor -CHR7-gruppen er forbundet med -NR2-gruppen, og B er en karbon-karbon-binding eller en rettkjedet alkylengruppe med 1 til 4 karbonatomer som eventuelt er substituert med én eller to alkylgrupper, hvor samtlige tidligere nevnte alkyl- og alkoksydeler kan inneholde 1 til 3 karbonatomer, deres enantiomerer, deres cis- og trans-isomerer, dersom RA og R5 sammen utgjør en karbon-karbon-binding, og deres addisjonssalter, karakterisert ved at a.) en forbindelse med formel hvor R2 til R5, A og B er som ovenfor definert, acyleres med et sulfonsyre-derivat med formel hvor R-l er som ovenfor definert, og X utgjør en nukleofil utgående gruppe så som et halogenatom eller en alkoksygruppe, f.eks. et klor- eller bromatom, en metoksy- eller etoksygruppe, eller b.) for fremstilling av forbindelser med formel I hvor R6 utgjør en hydroksygruppe: ■ det fra en forbindelse med den generelle formel hvor Rx til R5, A og B er som ovenfor definert og Z utgjør en hydrolytisk, termolytisk eller hydrogenolytisk avspaltbar beskyttelsesgruppe for en karboksygruppe, eller et funksjonelt derivat av karboksygruppen, avspaltes en beskyttelsesrest, eller c.) for fremstilling av forbindelser med formel I, hvor R4 og R5 hver utgjør et hydrogenatom: en forbindelse med formel hvor Rx til R3, R6, A og B er som ovenfor definert, hydreres, eller d.) for fremstilling av forbindelser med formel I, hvor R4 og R5 sammen utgjør en karbon-karbon-binding: en forbindelse med formel hvor Rx til R3 og A er som ovenfor definert, omsettes med en forbindelse med formel hvor B og R6 er som ovenfor definert, R5'betyr et hydrogenatom eller en alkylgruppe med 1 til 3 karbonatomer og W utgjør en trifenylfosfoniumhalogenid-, dialkylfosfonsyre-eller magnesiumhalogenidrest, og eventuelt deretter dehydratiseres, og en således oppnådd forbindelse med formel I, hvor R2 utgjør et hydrogenatom, ved alkylering overføres i en tilsvarende forbindelse med formel I, hvori R2 utgjør en alkylgruppe, eller en således oppnådd forbindelse med formel I, hvori R6 utgjør en hydroksygruppe, ved forestring eller amidering, overføres i en tilsvarende forbindelse med formel I, hvori R6 utgjør en alkoksy-, benzylamino- eller dialkylaminogruppe, eller en således oppnådd forbindelse med formel I, hvori RA og R5 sammen utgjør en karbon-karbon-binding, spaltes i dens cis- og trans-isomerer, eller en således oppnådd forbindelse med formel I spaltes i dens enantiomerer, eller en således oppnådd forbindelse med formel I overføres i dens addisjonssalter, spesielt i dens fysiologisk akseptable addisjonssalter med dens uorganiske eller organiske baser.
2. Fremgangsmåte ifølge krav 1 for fremstilling av forbindelsene 6-(2-(4-toluensulfonylamino)indan-5-yl)-6-(3-pyridyl)heks-5-en-syre, 6-(4-(2-(4-klorbenzensulfonylamino)etyl)fenyl)-6-(3-pyridyl)-heks-5-en-syre, eller 6-(4-(2-(4-trifluormetylbenzensulfonylamino)etyl)fenyl)-6-(3-pyridyl)heks-5-en-syre og deres syreaddisjonssalter, karakterisert ved at tilsvarende utgangsforbindelser benyttes.
3. Fremgangsmåte ifølge krav 1 for fremstilling av 6-(4-(2-(4-klorbenzensulfonylamino)etyl)fenyl)-6-(3-pyridyl)-heks-5-en-syre og dens syreaddisjonssalter, karakterisert ved at tilsvarende utgangsforbindelser benyttes.
NO902099A 1989-05-12 1990-05-11 Analogifremgangsmåte for fremstilling av terapeutisk aktive arylsulfonamider NO176176C (no)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3915506A DE3915506A1 (de) 1989-05-12 1989-05-12 Neue arylsulfonamide, diese verbindungen enthaltende arzneimittel und verfahren zu ihrer herstellung
DE3932403A DE3932403A1 (de) 1989-05-12 1989-09-28 Neue arylsulfonamide, diese verbindungen enthaltende arzneimittel und verfahren zu ihrer herstellung

Publications (4)

Publication Number Publication Date
NO902099D0 NO902099D0 (no) 1990-05-11
NO902099L NO902099L (no) 1990-11-13
NO176176B true NO176176B (no) 1994-11-07
NO176176C NO176176C (no) 1995-02-15

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NO902099A NO176176C (no) 1989-05-12 1990-05-11 Analogifremgangsmåte for fremstilling av terapeutisk aktive arylsulfonamider

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US (3) US5294626A (no)
EP (1) EP0397044B1 (no)
JP (1) JP2868283B2 (no)
KR (1) KR0153527B1 (no)
AT (1) ATE132138T1 (no)
AU (1) AU627024B2 (no)
CA (1) CA2016646C (no)
DE (2) DE3932403A1 (no)
DK (1) DK0397044T3 (no)
ES (1) ES2083394T3 (no)
FI (1) FI95372C (no)
GR (1) GR3019044T3 (no)
HU (1) HU214586B (no)
IE (1) IE74207B1 (no)
IL (1) IL94347A0 (no)
MX (1) MX9202816A (no)
NO (1) NO176176C (no)
NZ (1) NZ233638A (no)
PT (1) PT93994B (no)
RU (1) RU2096405C1 (no)
UA (1) UA26136C2 (no)

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US5153214A (en) * 1989-06-28 1992-10-06 Ciba-Geigy Corporation Certain (arylsulfonamido- and imidazolyl-)-substituted carboxylic acids and derivatives thereof and use for suppressing thromboxane activity
DE4025818A1 (de) * 1990-08-16 1992-02-20 Bayer Ag Phenylsulfonamid substituierte pyridinalken- und -aminooxyalkancarbonsaeure-derivate
US5286736A (en) * 1990-11-22 1994-02-15 Dr. Karl Thomae Gmbh Pyridyl compounds and pharmaceutical compositions containing these compounds
DE4037112A1 (de) * 1990-11-22 1992-05-27 Thomae Gmbh Dr K Neue pyridylderivate, diese verbindungen enthaltende arzneimittel und verfahren zu ihrer herstellung
US5374641A (en) * 1991-02-25 1994-12-20 Terumo Kabushiki Kaisha N-(3-pyridylalkyl)sulfonamide compounds which have useful pharmaceutical activity
GB9107043D0 (en) * 1991-04-04 1991-05-22 Pfizer Ltd Therapeutic agents
DE4216364A1 (de) * 1991-12-14 1993-11-25 Thomae Gmbh Dr K Neue Pyridylderivate, diese Verbindungen enthaltende Arzneimittel und Verfahren zu ihrer Herstellung
FR2686339B1 (fr) * 1992-01-22 1994-03-11 Adir Cie Nouveaux amides et sulfonamides naphtaleniques, leurs procedes de preparation et les compositions pharmaceutiques qui les contiennent.
DE4213919A1 (de) * 1992-04-28 1993-11-04 Thomae Gmbh Dr K Cyclische iminoderivate, verfahren zu ihrer herstellung und diese verbindungen enthaltende arzneimittel
CN1148190C (zh) 1998-10-23 2004-05-05 东丽株式会社 用于免疫调节的药物组合物
YU78601A (sh) * 1999-05-05 2005-07-19 Aventis Pharma Deutschland Gmbh. 1-(p-tienilbenzil)-imidazoli kao agonisti angiotenzin-(1-7)- receptora, postupak za njihovu proizvodnju, njihova primena i farmaceutski preparati koji ih sadrže
WO2010115952A1 (en) * 2009-04-09 2010-10-14 N.V. Organon Indane derivatives
KR101701943B1 (ko) 2009-11-13 2017-02-02 도레이 카부시키가이샤 당뇨병의 치료 또는 예방약
US9955802B2 (en) 2015-04-08 2018-05-01 Fasteners For Retail, Inc. Divider with selectively securable track assembly

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CA1134828A (en) * 1978-12-28 1982-11-02 Tadao Tanouchi Pyridine derivatives
EP0098690B1 (en) * 1982-06-14 1987-09-09 Takeda Chemical Industries, Ltd. Vinyl carboxylic acid derivatives, their production and use
US4518602A (en) * 1982-10-07 1985-05-21 Takeda Chemical Industries, Ltd. Vinyl carboxylic acid derivatives, their production and use as inhibitors of thromboxane synthetase
US4563446A (en) * 1983-07-27 1986-01-07 Takeda Chemical Industries, Ltd. Thromboxane synthetase inhibiting 3-(1-alkenyl) pyridines
EP0219756B1 (de) * 1985-10-09 1994-01-05 Shell Internationale Researchmaatschappij B.V. Neue Acrylsäureamide
DE3623944A1 (de) * 1986-07-16 1988-02-11 Thomae Gmbh Dr K Neue benzolsulfonamido-indanylverbindungen, diese verbindungen enthaltende arzneimittel und verfahren zu ihrer herstellung
GB8708233D0 (en) * 1987-04-07 1987-05-13 Smith Kline French Lab Pharmaceutically active compounds
WO1989001330A2 (en) * 1987-08-20 1989-02-23 Smith Kline & French Laboratories Limited W-arylsulphonamidoalkanoic acids for treatment of thromboxane mediated diseases

Also Published As

Publication number Publication date
US5426119A (en) 1995-06-20
EP0397044A3 (de) 1991-10-16
US5294626A (en) 1994-03-15
KR0153527B1 (ko) 1998-11-16
FI95372C (fi) 1996-01-25
AU5492490A (en) 1990-11-15
IL94347A0 (en) 1991-03-10
PT93994A (pt) 1991-01-08
NO902099L (no) 1990-11-13
UA26136C2 (uk) 1999-06-07
JPH035457A (ja) 1991-01-11
IE901708L (en) 1990-11-12
EP0397044A2 (de) 1990-11-14
GR3019044T3 (en) 1996-05-31
US5681961A (en) 1997-10-28
ATE132138T1 (de) 1996-01-15
MX9202816A (es) 1992-06-30
CA2016646A1 (en) 1990-11-12
CA2016646C (en) 1999-09-07
DE59009994D1 (de) 1996-02-08
KR900018031A (ko) 1990-12-20
NZ233638A (en) 1992-03-26
PT93994B (pt) 1997-04-30
DE3932403A1 (de) 1991-04-11
HU903013D0 (en) 1990-09-28
IE901708A1 (en) 1991-06-19
IE74207B1 (en) 1997-07-16
HUT54649A (en) 1991-03-28
EP0397044B1 (de) 1995-12-27
DK0397044T3 (da) 1996-05-13
HU214586B (hu) 1998-04-28
NO902099D0 (no) 1990-05-11
AU627024B2 (en) 1992-08-13
NO176176C (no) 1995-02-15
FI902358A0 (fi) 1990-05-11
FI95372B (fi) 1995-10-13
ES2083394T3 (es) 1996-04-16
JP2868283B2 (ja) 1999-03-10
RU2096405C1 (ru) 1997-11-20

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