NL8601701A - TRANSPARENT SOAP. - Google Patents
TRANSPARENT SOAP. Download PDFInfo
- Publication number
- NL8601701A NL8601701A NL8601701A NL8601701A NL8601701A NL 8601701 A NL8601701 A NL 8601701A NL 8601701 A NL8601701 A NL 8601701A NL 8601701 A NL8601701 A NL 8601701A NL 8601701 A NL8601701 A NL 8601701A
- Authority
- NL
- Netherlands
- Prior art keywords
- soap
- composition according
- fatty acids
- polyol
- transparent
- Prior art date
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- 239000000344 soap Substances 0.000 title claims description 44
- 239000000203 mixture Substances 0.000 claims description 28
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 24
- 239000000194 fatty acid Substances 0.000 claims description 24
- 229930195729 fatty acid Natural products 0.000 claims description 24
- 150000004665 fatty acids Chemical class 0.000 claims description 23
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 20
- 239000011780 sodium chloride Substances 0.000 claims description 10
- 229920005862 polyol Polymers 0.000 claims description 9
- 150000003077 polyols Chemical class 0.000 claims description 9
- 239000004615 ingredient Substances 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 5
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 claims description 4
- 239000000470 constituent Substances 0.000 claims description 4
- 239000002304 perfume Substances 0.000 claims description 4
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 3
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 3
- 239000003086 colorant Substances 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000000600 sorbitol Substances 0.000 claims description 3
- 239000003381 stabilizer Substances 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 150000005846 sugar alcohols Chemical class 0.000 claims description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 2
- -1 C 3 fatty acids Chemical class 0.000 claims 1
- 239000004721 Polyphenylene oxide Substances 0.000 claims 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims 1
- 229920000570 polyether Polymers 0.000 claims 1
- 238000007127 saponification reaction Methods 0.000 description 8
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 8
- 239000004166 Lanolin Substances 0.000 description 7
- 229940039717 lanolin Drugs 0.000 description 7
- 235000019388 lanolin Nutrition 0.000 description 7
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 235000021588 free fatty acids Nutrition 0.000 description 3
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- 239000005639 Lauric acid Substances 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- 229920000151 polyglycol Polymers 0.000 description 2
- 239000010695 polyglycol Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000003760 tallow Substances 0.000 description 2
- DUXYWXYOBMKGIN-UHFFFAOYSA-N trimyristin Chemical compound CCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCC DUXYWXYOBMKGIN-UHFFFAOYSA-N 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N 1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylic acid Chemical compound C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229930195725 Mannitol Natural products 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- IPCSVZSSVZVIGE-UHFFFAOYSA-N palmitic acid group Chemical group C(CCCCCCCCCCCCCCC)(=O)O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- RPACBEVZENYWOL-XFULWGLBSA-M sodium;(2r)-2-[6-(4-chlorophenoxy)hexyl]oxirane-2-carboxylate Chemical compound [Na+].C=1C=C(Cl)C=CC=1OCCCCCC[C@]1(C(=O)[O-])CO1 RPACBEVZENYWOL-XFULWGLBSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/02—Compositions of detergents based essentially on soap on alkali or ammonium soaps
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0095—Solid transparent soaps or detergents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/007—Soaps or soap mixtures with well defined chain length
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/26—Organic compounds, e.g. vitamins containing oxygen
- C11D9/262—Organic compounds, e.g. vitamins containing oxygen containing carbohydrates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/26—Organic compounds, e.g. vitamins containing oxygen
- C11D9/267—Organic compounds, e.g. vitamins containing oxygen containing free fatty acids
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Molecular Biology (AREA)
- Detergent Compositions (AREA)
Description
#· - * -1- R7019# · - * -1- R7019
Transparante zeepTransparent soap
De aanvrage heeft betrekking op een transparante zeep compositie. Transparante zeep, in het bijzonder transparante toiletzeep is reeds geruime tijd een bekend product. Echter om zulke zeep te vervaardigen heeft men lang zijn toevlucht 5 moeten nemen tot ingewikkelde en dure technieken als op bijzondere wijze mengen met speciaal "high shear" mengers of bijvoorbeeld de toepassing van alcohol als oplosmiddel voor de zeep. Ook moesten veelal aanmerkelijke hoeveelheden aan bijzondere bestanddelen als harsve t zuurz e ep, lanoline of 10 dergelijke opgenomen worden.The application relates to a transparent soap composition. Transparent soap, in particular transparent toilet soap, has been a well-known product for quite some time. However, in order to manufacture such soap, one has long had to resort to complex and expensive techniques such as special mixing with special "high shear" mixers or, for example, the use of alcohol as a solvent for the soap. Also, substantial amounts of special constituents such as resin acid, lanolin or the like had to be included.
Een recente ontwikkeling op dit gebied staat beschreven in GB-A-2 126 603 (Colgate Palmolive Co) waarbij in het zeepmengsel lanoline (vetzuren) worden opgenomen en waarbij blijkens de voorbeelden op klassieke wijze door zieden een 15 mengsel van talkvet- en cocosoliezeep bereid werd waaraan de overige ingrediënten als lanoline (vetzuur) eventueel polyol * enz. toegevoegd worden. Aan deze zeepsamenstelling, die ca. 0,5% natriumchloride alsmede glycerol bevat, wordt dus vervolgens o.a. lanoline (vetzuur), enz. toegevoegd. Het 20 natriumchloride dient om de zeep uit te zouten en verleent ook de vereiste hardheid aan het te vervaardigen zeeptablet.A recent development in this field is described in GB-A-2 126 603 (Colgate Palmolive Co), in which lanolin (fatty acids) are included in the soap mixture and, according to the examples, a mixture of tallow fat and coconut oil soap prepared in a classic manner by seizing. to which the other ingredients such as lanolin (fatty acid), optionally polyol * etc. are added. Thus, inter alia, lanolin (fatty acid) etc. is added to this soap composition, which contains approximately 0.5% sodium chloride and glycerol. The sodium chloride serves to salt out the soap and also imparts the required hardness to the soap tablet to be manufactured.
In de beschrijving van het Engels octrooischrift staat op blz. 6 regel 29 nog terloops vermeld dat de zeep ook door continue verzeping van vetzuur bereid kan worden waarna 25 klaarblijkelijk de verdere bestanddelen als bijvoorbeeld lanoline zouden worden toegevoegd.In the description of the English patent on page 6 line 29 it is mentioned in passing that the soap can also be prepared by continuous saponification of fatty acid, after which apparently the further constituents such as for instance lanolin would be added.
Uit het oogpunt van eenvoudige procesvoering zou het gewenst zijn alle bestanddelen direct in te voeren in een inrichting die directe verzeping van vetzuren bewerkstelligt maar 30 daarbij treedt de complicatie op dat de lanoline tendele verzeept en dat bederft de werking ervan. Het toevoegen van natriumchloride in verband met de gewenste hardheid, en/of 8601701 'sr -2- van triethanolamine in verband met de doorschijnendheid kan ook al tot complicaties bij de aansluitend plaatsvindende continue verzeping van vetzuren aanleiding geven zodat eerst verzepen en daarna compounderen noodzakelijk is. Inmengen na 5 de verzeping is weer een extra processtap.From a simple process viewpoint, it would be desirable to introduce all ingredients directly into a device that accomplishes direct saponification of fatty acids, but the complication occurs that the lanolin partially saponifies and spoils its performance. The addition of sodium chloride in connection with the desired hardness, and / or 8601701 'sr -2- of triethanolamine in connection with the transparency may also lead to complications in the subsequent continuous saponification of fatty acids, so that first saponification and then compounding is necessary. . Mixing in after the saponification is an extra process step.
De aanvrage nu verschaft een transparante zeepsamenstelling welke zich op eenvoudige wijze middels directe verzeping van vetzuur laat bereiden en deze samenstelling verschilt van die volgens het Britse octrooischrift (GB-A) 2 126 603 10 daarin dat er geen lanoline (vetzuur) in aanwezig is en de hoeveelheid natriumchloride minder dan 0,2% bedraagt terwijl het daarvan vervaardigde zeeptablet uitstekend transparant en ook bijvoorbeeld voldoende hard is.The application now provides a transparent soap composition which can be prepared in a simple manner by direct saponification of fatty acid and this composition differs from that according to British patent specification (GB-A) 2 126 603 10 in that it does not contain lanolin (fatty acid) and the amount of sodium chloride is less than 0.2%, while the soap tablet made therefrom is extremely transparent and, for example, also sufficiently hard.
De aanvrage verschaft derhalve een transparante zeep van de 15 volgende samenstelling: A: 55 - 79,5 % (ww) zeep van een vetzuurmengsel bestaande uit 85 - 70 % ^16"^18 vetzuren en 20 15 - 30 % vetzuren B: 7 - 20 % (ww) van een thermostabiel polyol dwz een bij 150°C niet aanmerkelijk verkleurend polyol 25 C: 0,5 - 7,5 % (ww) vrije C^Q-C^g vetzuren D: 12 - 20 % (ww) water E: minder dan 0,2 % (ww) NaCl 30 F: Tot 2% gebruikelijke bestanddelen als parfum, kleurstof, stabilisator etc.The application therefore provides a transparent soap of the following composition: A: 55 - 79.5% (ww) soap of a fatty acid mixture consisting of 85 - 70% ^ 16 "^ 18 fatty acids and 20 15 - 30% fatty acids B: 7 - 20% (ww) of a thermostable polyol ie a polyol not discolouring at 150 ° C 25 C: 0.5 - 7.5% (ww) free C ^ QC ^ g fatty acids D: 12 - 20% (ww) water E: less than 0.2% (ww) NaCl 30 F: Up to 2% common ingredients such as perfume, colorant, stabilizer etc.
$ 0 v e * v 4 -3- ? - s$ 0 v e * v 4 -3-? - s
Bij voorkeur is de zeepsamenstelling als volgt: A: 64 - 76 % B: 8 - 15 % 5 C: 2 - 5 % B: 14 - 18 % E: minder dan 0,1% (ww) NaClPreferably the soap composition is as follows: A: 64 - 76% B: 8 - 15% 5 C: 2 - 5% B: 14 - 18% E: less than 0.1% (ww) NaCl
Hoewel transparante zeep als regel kalium en/of 10 triethanolamine zeep bevat is het volgens de onderhavige uitvinding zo dat al reeds uitstekende resultaten verkregen worden met overwegend of zelfs uitsluitend natriumzeep.Although transparent soap usually contains potassium and / or triethanolamine soap, according to the present invention it is already the case that already excellent results are obtained with predominantly or even exclusively sodium soap.
Als thermostabiel polyol wordt in de eerste plaats gedacht aan suikeralcoholen als b.v. sorbitol, mannitol en aan z.g.As a thermostable polyol, sugar alcohols such as e.g. sorbitol, mannitol and so-called
15 polyglycolen afgeleid van C2-C3 glycolen. Ook polyolen als trimethylolpropaan, pentaerythritol enz. zijn bruikbaar.15 polyglycols derived from C2-C3 glycols. Polyols such as trimethylol propane, pentaerythritol etc. are also useful.
Als vrije vetzuren zijn C^Q-C^g vetzuren ift het bijzonder C10"C14 vetzuren bijzonder geschikt. Zij kunnen als zodanig worden toegevoegd, maar ook kan men met ondermaat loog 20 verzepen. Be verzeping vindt plaats bij temperaturen van 20-160°C en bij normale of verhoogde druk· Be verzeping kan plaats vinden in een autoclaaf, die atmosferisch of onder druk bedreven wordt, of in speciaal hiervoor ontworpen apparatuur. Wat de loog betreft past men bij voorkeur 25 overwegend, of zelfs uitsluitend natriumhydroxide toe,As free fatty acids, C ^ QC ^ g fatty acids are particularly suitable if C10 "C14 fatty acids are concerned. They can be added as such, but can also be saponified with a lower amount of caustic 20. Saponification takes place at temperatures of 20-160 ° C and at normal or elevated pressure · Saponification can take place in an autoclave, which is operated atmospheric or under pressure, or in equipment specially designed for this purpose. As far as the lye is concerned, it is preferred to use predominantly, or even exclusively sodium hydroxide,
Kaliumhydroxide toevoegen brengt geen duidelijke verbetering en verhoogt in ieder geval de prijs van het product. Als gebruikelijk bestanddeel moet gedacht worden aan parfum, stabilisatoren en kleurstoffen. Beze ingrediënten dienen 30 met enig overleg gekozen te worden omdat zij ondoorzichtigheid kunnen veroorzaken. Er zijn echter uit de stand der techniek voor transparante zeep geschikte bestanddelen bekend.Adding potassium hydroxide does not clearly improve and in any case increases the price of the product. Perfume, stabilizers and dyes are a common ingredient. These ingredients should be chosen with some consultation because they can cause opacity. However, suitable ingredients for transparent soap are known in the art.
Be onderhavige aanvrage verschaft ook een eenvoudige 35 werkwijze voor de bereiding van transparante zeep waarbij een vetzuurmengsel van C^-C^g en Gjq-C^ vetzuren en eventuele overige bestanddelen in een geschikte onderlinge 3601701 -4- verhouding al dan niet volledig geneutraliseerd wordt en na toevoeging van de overige bestanddelen B en C als hierboven gedefinieerd wordt gedroogd tot een watergehalte van 12-20% en het aldus verkregen materiaal bij voorkeur met standaard 5 zeepverwerkings apparatuur tot doorschijnende stukken zeep wordt verwerkt. Deze apparatuur is bijvoorbeeld een opstelling bestaande uit een menger waarin de parfum en kleurstof met de zeepkorrels worden gemengd, een refinerplodder en een vacuumplodder waarbij aan de uitlaat 10 een zeepstaaf wordt gevormd, die in een matrijs tot zeeptablet wordt geperst.The present application also provides a simple process for the preparation of transparent soap in which a fatty acid mixture of C 1 -C 2 g and Gjq-C 2 fatty acids and any other constituents is or is not completely neutralized in a suitable mutual 3601 701 -4 ratio. and after adding the other components B and C as defined above, it is dried to a water content of 12-20% and the material thus obtained is preferably processed into transparent bars of soap using standard soap processing equipment. This equipment is, for example, an arrangement consisting of a mixer in which the perfume and colorant are mixed with the soap granules, a refiner splatter and a vacuum splatter in which a soap bar is formed at the outlet 10, which is pressed into a soap tablet in a mold.
8601731 T -¾.8601731 T -¾.
-5--5-
Voorbeeld IExample I
2000 gram van een mengsel bestaande uit 80% talkvetzuren (in hoofdzaak bestaande uit ca 30% palmitine- 17% stearine-5 en 52% oliezuur en homologen daarvan) en 20% cocosvetzuren (in hoofdzaak bestaande uit ca 50% laurine-, 20% myristine-, 11% palmitine- en 10% oliezuur)werden gemengd en verwarmd tot 60°C. Hierna werd dit mengsel verzeept bij 100°C door dit mengsel toe te voegen aan 1105 g waterige natronloog 10 (27,6% oplossing in water) in een reaktievat. Na 10 minuten werd aan deze zgn. "neat soap" 464 g sorbitol oplossing (70% in water), 75 g technisch laurinezuur (93% zuiver), 42 g polyethyleenglycol met een gemiddeld moleculair gewicht(M) van 400 en 12,5 ml waterige oplossing van het Na-zout van 15 ethaan-l-hydroxy-l,l-difosfonzuur (EHDP) (30% in water) toegevoegd. Na grondig mengen van deze componenten werd het gehele mengsel gedroogd tot een watergebalte van 16%. Het NaCl gehalte was kleiner dan 0,01%, het vrije vetzuurgehalte 5,3%. Na verwerking tot korrels bleken deze goed transparant 20 te zijn 20 evenals de hieruit gefabriceerde tabletten zeep die van uitstekende kwaliteit bleken.2000 grams of a mixture consisting of 80% tallow fatty acids (mainly consisting of approximately 30% palmitine-17% stearic-5 and 52% oleic acid and homologues thereof) and 20% coconut fatty acids (mainly consisting of approximately 50% lauric, 20% myristin, 11% palmitic and 10% oleic acid) were mixed and heated to 60 ° C. This mixture was then saponified at 100 ° C by adding this mixture to 1105 g of aqueous sodium hydroxide solution (27.6% aqueous solution) in a reaction vessel. After 10 minutes, 464 g of sorbitol solution (70% in water), 75 g of technical lauric acid (93% pure), 42 g of polyethylene glycol with an average molecular weight (M) of 400 and 12.5 were added to this so-called "neat soap". ml of aqueous solution of the Na salt of ethane-1-hydroxy-1,1-diphosphonic acid (EHDP) (30% in water) was added. After thorough mixing of these components, the entire mixture was dried to a water content of 16%. The NaCl content was less than 0.01%, the free fatty acid content 5.3%. After granulation, these were found to be highly transparent, 20 as were the soap tablets manufactured therefrom, which were of excellent quality.
Voorbeeld IIExample II
25 Op analoge wijze als in Voorbeeld 1 beschreven werd een transparante zeep bereid waarin de 42 g polyglycol vervangen werd door 40 g polypropyleenglycol Ms1000 en er werd gedroogd tot een watergehalte van 18%. Ook deze zeep was goed doorzichtig.Analogously as described in Example 1, a transparent soap was prepared in which the 42 g of polyglycol was replaced with 40 g of polypropylene glycol Ms1000 and dried to a water content of 18%. This soap was also very transparent.
3030
Voorbeeld IIIExample III
Op analoge wijze als beschreven in Voorbeeld 1 werd een zeepsamenstelling bereid. Nu werd echter geen 75 g technisch 35 laurinezuur toegevoegd doch 42 g en dit resulteerde in een transparante zeepsamenstelling met 0,01% NaCl en 3% vrij vetzuur.A soap composition was prepared in an analogous manner as described in Example 1. Now, however, not 75 g of technical lauric acid was added, but 42 g, and this resulted in a transparent soap composition with 0.01% NaCl and 3% free fatty acid.
86017018601701
Claims (10)
Priority Applications (11)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL8601701A NL8601701A (en) | 1986-06-30 | 1986-06-30 | TRANSPARENT SOAP. |
| MT1005A MTP1005B (en) | 1986-06-30 | 1987-06-26 | Transparent soap |
| EP87201229A EP0251410A1 (en) | 1986-06-30 | 1987-06-26 | Transparent soap |
| DK332587A DK332587A (en) | 1986-06-30 | 1987-06-29 | TRANSPARENT SAEBE AND MANUFACTURING THEREOF |
| PT85202A PT85202A (en) | 1986-06-30 | 1987-06-29 | Transparent soap |
| BR8703299A BR8703299A (en) | 1986-06-30 | 1987-06-29 | TRANSPARENT SOAP COMPOSITION AND PROCESS TO PREPARE A TRANSPARENT SOAP COMPOSITION |
| NO872717A NO872717L (en) | 1986-06-30 | 1987-06-29 | TRANSPARENT SOAP. |
| AU74926/87A AU7492687A (en) | 1986-06-30 | 1987-06-29 | Transparent soap |
| FI872876A FI872876A7 (en) | 1986-06-30 | 1987-06-30 | TRANSPARENT TVAOL. |
| KR1019870006681A KR880000570A (en) | 1986-06-30 | 1987-06-30 | Transparent soap composition and its manufacturing method |
| JP62163881A JPS6339998A (en) | 1986-06-30 | 1987-06-30 | Transparent soap composition |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL8601701A NL8601701A (en) | 1986-06-30 | 1986-06-30 | TRANSPARENT SOAP. |
| NL8601701 | 1986-06-30 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NL8601701A true NL8601701A (en) | 1988-01-18 |
Family
ID=19848242
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NL8601701A NL8601701A (en) | 1986-06-30 | 1986-06-30 | TRANSPARENT SOAP. |
Country Status (11)
| Country | Link |
|---|---|
| EP (1) | EP0251410A1 (en) |
| JP (1) | JPS6339998A (en) |
| KR (1) | KR880000570A (en) |
| AU (1) | AU7492687A (en) |
| BR (1) | BR8703299A (en) |
| DK (1) | DK332587A (en) |
| FI (1) | FI872876A7 (en) |
| MT (1) | MTP1005B (en) |
| NL (1) | NL8601701A (en) |
| NO (1) | NO872717L (en) |
| PT (1) | PT85202A (en) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4758370A (en) * | 1987-04-30 | 1988-07-19 | Neutrogena Corp. | Compositions and processes for the continuous production of transparent soap |
| JPH064876B2 (en) * | 1987-12-16 | 1994-01-19 | 乾 恵美子 | Transparent soap |
| JP2562937B2 (en) * | 1988-05-20 | 1996-12-11 | 株式会社資生堂 | Detergent composition |
| GB8814295D0 (en) * | 1988-06-16 | 1988-07-20 | Unilever Plc | Cosmetic composition |
| US5194172A (en) * | 1990-09-13 | 1993-03-16 | The Procter & Gamble Company | Aerated and freezer bar soap compositions containing sucrose as a mildness aid and a processing aid |
| WO1995030737A2 (en) * | 1994-05-10 | 1995-11-16 | The Procter & Gamble Company | Personal cleansing soap-synthetic bar compositions with low levels of nonionic, polyethylene/polypropylene glycol polymers for improved mildness |
| BRPI0507214A (en) * | 2004-02-20 | 2007-06-19 | Unilever Nv | non-granular solid cleaning composition |
| US8080503B2 (en) | 2005-06-18 | 2011-12-20 | The Procter & Gamble Company | Cleansing bar compositions comprising a high level of water |
| US8129327B2 (en) | 2006-12-01 | 2012-03-06 | The Procter & Gamble Company | Packaging for high moisture bar soap |
| US8093200B2 (en) * | 2007-02-15 | 2012-01-10 | Ecolab Usa Inc. | Fast dissolving solid detergent |
| ES2529708T3 (en) * | 2009-08-12 | 2015-02-24 | Unilever N.V. | Concentrated liquid soap formulations that have an easily pumpable viscosity |
| CN106544191A (en) * | 2016-11-02 | 2017-03-29 | 北京玫瑰谷香露有限公司 | A kind of natural essential oil soap and its preparation technology |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL264272A (en) * | 1960-01-26 | 1900-01-01 | ||
| GB1247009A (en) * | 1968-04-23 | 1971-09-22 | Unilever Ltd | Preservatives for detergent bar |
| US3864272A (en) * | 1973-01-12 | 1975-02-04 | Armour Dial Inc | Process for making translucent soap bars |
| US4165293A (en) * | 1977-05-16 | 1979-08-21 | Amway Corporation | Solid transparent cleanser |
| US4290904A (en) * | 1980-12-01 | 1981-09-22 | Neutrogena Corporation | Transparent soap |
| US4493786A (en) * | 1982-09-02 | 1985-01-15 | Colgate-Palmolive Company | Translucent soaps and processes for manufacture thereof |
-
1986
- 1986-06-30 NL NL8601701A patent/NL8601701A/en not_active Application Discontinuation
-
1987
- 1987-06-26 MT MT1005A patent/MTP1005B/en unknown
- 1987-06-26 EP EP87201229A patent/EP0251410A1/en not_active Withdrawn
- 1987-06-29 PT PT85202A patent/PT85202A/en unknown
- 1987-06-29 DK DK332587A patent/DK332587A/en unknown
- 1987-06-29 NO NO872717A patent/NO872717L/en unknown
- 1987-06-29 BR BR8703299A patent/BR8703299A/en unknown
- 1987-06-29 AU AU74926/87A patent/AU7492687A/en not_active Abandoned
- 1987-06-30 JP JP62163881A patent/JPS6339998A/en active Pending
- 1987-06-30 FI FI872876A patent/FI872876A7/en not_active Application Discontinuation
- 1987-06-30 KR KR1019870006681A patent/KR880000570A/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| EP0251410A1 (en) | 1988-01-07 |
| NO872717D0 (en) | 1987-06-29 |
| FI872876A0 (en) | 1987-06-30 |
| FI872876A7 (en) | 1987-12-31 |
| DK332587A (en) | 1987-12-31 |
| NO872717L (en) | 1988-01-04 |
| KR880000570A (en) | 1988-03-26 |
| DK332587D0 (en) | 1987-06-29 |
| BR8703299A (en) | 1988-03-15 |
| MTP1005B (en) | 1988-10-18 |
| JPS6339998A (en) | 1988-02-20 |
| PT85202A (en) | 1987-07-01 |
| AU7492687A (en) | 1988-01-07 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A1B | A search report has been drawn up | ||
| BV | The patent application has lapsed |