NL8001063A - Koperchromietkatalysator, alsmede de toepassing ervan bij de bereiding van furfurylalcohol uit furfural volgens een ladingsgewijze of vloeistoffasewerkwijze. - Google Patents
Koperchromietkatalysator, alsmede de toepassing ervan bij de bereiding van furfurylalcohol uit furfural volgens een ladingsgewijze of vloeistoffasewerkwijze. Download PDFInfo
- Publication number
- NL8001063A NL8001063A NL8001063A NL8001063A NL8001063A NL 8001063 A NL8001063 A NL 8001063A NL 8001063 A NL8001063 A NL 8001063A NL 8001063 A NL8001063 A NL 8001063A NL 8001063 A NL8001063 A NL 8001063A
- Authority
- NL
- Netherlands
- Prior art keywords
- copper
- catalyst
- copper chromite
- furfural
- complex
- Prior art date
Links
- XPFVYQJUAUNWIW-UHFFFAOYSA-N furfuryl alcohol Chemical compound OCC1=CC=CO1 XPFVYQJUAUNWIW-UHFFFAOYSA-N 0.000 title claims description 117
- HYBBIBNJHNGZAN-UHFFFAOYSA-N furfural Chemical compound O=CC1=CC=CO1 HYBBIBNJHNGZAN-UHFFFAOYSA-N 0.000 title claims description 82
- 239000003054 catalyst Substances 0.000 title claims description 38
- 238000000034 method Methods 0.000 title claims description 16
- 239000010949 copper Substances 0.000 title claims description 8
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims description 5
- 229910052802 copper Inorganic materials 0.000 title claims description 5
- 238000002360 preparation method Methods 0.000 title description 15
- 239000007791 liquid phase Substances 0.000 title description 9
- JGDFBJMWFLXCLJ-UHFFFAOYSA-N copper chromite Chemical compound [Cu]=O.[Cu]=O.O=[Cr]O[Cr]=O JGDFBJMWFLXCLJ-UHFFFAOYSA-N 0.000 claims description 56
- 238000000354 decomposition reaction Methods 0.000 claims description 17
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 16
- 239000001257 hydrogen Substances 0.000 claims description 16
- 229910052739 hydrogen Inorganic materials 0.000 claims description 16
- 239000002244 precipitate Substances 0.000 claims description 12
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 9
- 239000000908 ammonium hydroxide Substances 0.000 claims description 9
- 150000001299 aldehydes Chemical class 0.000 claims description 8
- 229910000365 copper sulfate Inorganic materials 0.000 claims description 8
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000000047 product Substances 0.000 claims description 6
- JHWIEAWILPSRMU-UHFFFAOYSA-N 2-methyl-3-pyrimidin-4-ylpropanoic acid Chemical compound OC(=O)C(C)CC1=CC=NC=N1 JHWIEAWILPSRMU-UHFFFAOYSA-N 0.000 claims description 4
- 239000011651 chromium Substances 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052804 chromium Inorganic materials 0.000 claims description 2
- -1 copper copper ammonium chromate Chemical compound 0.000 claims description 2
- 238000001556 precipitation Methods 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims 2
- 150000003839 salts Chemical class 0.000 claims 2
- 150000001844 chromium Chemical class 0.000 claims 1
- 150000001879 copper Chemical class 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 description 32
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 13
- 239000000292 calcium oxide Substances 0.000 description 12
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 11
- 230000000694 effects Effects 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 229910001220 stainless steel Inorganic materials 0.000 description 4
- 239000010935 stainless steel Substances 0.000 description 4
- ASMZBOYDOWEBKG-UHFFFAOYSA-L Cl(=O)(=O)[O-].[Na+].[Na+].Cl(=O)(=O)[O-] Chemical compound Cl(=O)(=O)[O-].[Na+].[Na+].Cl(=O)(=O)[O-] ASMZBOYDOWEBKG-UHFFFAOYSA-L 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 239000003153 chemical reaction reagent Substances 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- 238000005984 hydrogenation reaction Methods 0.000 description 3
- 229910044991 metal oxide Inorganic materials 0.000 description 3
- 150000004706 metal oxides Chemical class 0.000 description 3
- 238000005245 sintering Methods 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- GXDVEXJTVGRLNW-UHFFFAOYSA-N [Cr].[Cu] Chemical compound [Cr].[Cu] GXDVEXJTVGRLNW-UHFFFAOYSA-N 0.000 description 2
- LRFQSNDOLFTQCR-UHFFFAOYSA-M [O-][Cr](O)(=O)=O.N.[Cu+] Chemical compound [O-][Cr](O)(=O)=O.N.[Cu+] LRFQSNDOLFTQCR-UHFFFAOYSA-M 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000005749 Copper compound Substances 0.000 description 1
- 206010037660 Pyrexia Diseases 0.000 description 1
- LTCZNWAAKWEYLG-UHFFFAOYSA-M [O-][Cr](O)=O.N.[Cu+] Chemical compound [O-][Cr](O)=O.N.[Cu+] LTCZNWAAKWEYLG-UHFFFAOYSA-M 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 150000001845 chromium compounds Chemical class 0.000 description 1
- 229910001430 chromium ion Inorganic materials 0.000 description 1
- 150000001880 copper compounds Chemical class 0.000 description 1
- JZCCFEFSEZPSOG-UHFFFAOYSA-L copper(II) sulfate pentahydrate Chemical compound O.O.O.O.O.[Cu+2].[O-]S([O-])(=O)=O JZCCFEFSEZPSOG-UHFFFAOYSA-L 0.000 description 1
- HFTNNOZFRQLFQB-UHFFFAOYSA-N ethenoxy(trimethyl)silane Chemical compound C[Si](C)(C)OC=C HFTNNOZFRQLFQB-UHFFFAOYSA-N 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 125000002485 formyl group Chemical group [H]C(*)=O 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- PXLIDIMHPNPGMH-UHFFFAOYSA-N sodium chromate Chemical compound [Na+].[Na+].[O-][Cr]([O-])(=O)=O PXLIDIMHPNPGMH-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000012916 structural analysis Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D307/40—Radicals substituted by oxygen atoms
- C07D307/42—Singly bound oxygen atoms
- C07D307/44—Furfuryl alcohol
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/86—Chromium
- B01J23/868—Chromium copper and chromium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/015,574 US4251396A (en) | 1979-02-26 | 1979-02-26 | Copper chromite catalyst for preparation of furfuryl alcohol from furfural |
| US1557479 | 1979-02-26 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NL8001063A true NL8001063A (nl) | 1980-08-28 |
Family
ID=21772219
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NL8001063A NL8001063A (nl) | 1979-02-26 | 1980-02-21 | Koperchromietkatalysator, alsmede de toepassing ervan bij de bereiding van furfurylalcohol uit furfural volgens een ladingsgewijze of vloeistoffasewerkwijze. |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US4251396A (es) |
| BE (1) | BE881903A (es) |
| BR (1) | BR8001132A (es) |
| DE (1) | DE3007139C2 (es) |
| ES (2) | ES488911A0 (es) |
| FR (1) | FR2449478A1 (es) |
| GB (1) | GB2047219B (es) |
| IN (1) | IN153681B (es) |
| IT (1) | IT1141216B (es) |
| MX (1) | MX153509A (es) |
| NL (1) | NL8001063A (es) |
| ZA (1) | ZA801034B (es) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6376718B1 (en) | 2000-11-17 | 2002-04-23 | Arco Chemical Technology, L.P. | Dehydrogenation of alkylene glycol ethers to ether ketones and aldehydes |
| US7015359B1 (en) * | 2004-12-23 | 2006-03-21 | Council Of Scientific And Industrial Research | Vapor phase catalytic process for simultaneous furfural hydrogenation and cyclohexanol dehydrogenation |
| US7994347B2 (en) | 2006-06-09 | 2011-08-09 | Battelle Memorial Institute | Hydroxymethylfurfural reduction methods and methods of producing furandimethanol |
| DE102009053992B4 (de) | 2009-11-20 | 2013-08-08 | Süd-Chemie Ip Gmbh & Co. Kg | Verfahren zur Herstellung kupfer- und chromhaltiger Mischoxide mit großer spezifischer Oberfläche |
| RU2504517C1 (ru) * | 2012-05-29 | 2014-01-20 | Открытое акционерное общество "Калужский научно-исследовательский институт телемеханических устройств" | Способ получения гидроксохроматов меди(+2) |
| CN102698760A (zh) * | 2012-06-21 | 2012-10-03 | 中北大学 | 一种磁性加氢催化剂及其制备方法和应用 |
| DE102013014267A1 (de) | 2013-08-27 | 2015-03-05 | Clariant Produkte (Deutschland) Gmbh | Verfahren zur Herstellung kupfer- und chromhaltiger Mischoxide |
| CN103524437B (zh) * | 2013-10-25 | 2015-07-08 | 江苏七洲绿色化工股份有限公司 | 一种三唑醇的制备方法 |
| CN110467588A (zh) * | 2019-09-05 | 2019-11-19 | 吉林大学 | 一种氢氧化锆磁性材料催化糠醛到糠醇的方法 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2077422A (en) * | 1931-08-26 | 1937-04-20 | Du Pont | Process for hydrogenating furfural |
| US2094975A (en) * | 1932-05-18 | 1937-10-05 | Quaker Oats Co | Method of hydrogenation of furfural to furfuryl alcohol |
| CH279628A (de) * | 1949-02-21 | 1951-12-15 | Ici Ltd | Verfahren zur Herstellung von Furfurylalkohol. |
| DE1057582B (de) * | 1956-06-01 | 1959-05-21 | Rolf K Ladisch Dr Ing | Verfahren zur Herstellung von Kupferchromit-Katalysatoren |
| GB1006839A (en) * | 1962-03-17 | 1965-10-06 | Nikki Kagaku Kabushiki Kaisha | Improvements in or relating to the catalytic production of edible oils |
| US3374184A (en) * | 1964-03-11 | 1968-03-19 | Air Prod & Chem | Copper chromite-alkali metal oxide high surface area hydrogenation catalyst |
| FR1506874A (fr) * | 1966-12-28 | 1967-12-22 | Kanegafuchi Spinning Co Ltd | Procédé de fabrication d'epsilon-caprolactame |
| US3547972A (en) * | 1968-04-01 | 1970-12-15 | Du Pont | Addition of hydrogen cyanide to butadiene |
| US3855388A (en) * | 1971-01-11 | 1974-12-17 | Mobil Oil | Method of preparing an oxidation catalyst for partially combusted gases |
| US3767595A (en) * | 1971-10-28 | 1973-10-23 | Grace W R & Co | Process for producing copper chromite catalysts |
| CA988495A (en) * | 1972-03-02 | 1976-05-04 | W.R. Grace And Co. | Process for preparing copper oxide-chromium oxide catalysts |
| US3935128A (en) * | 1974-12-30 | 1976-01-27 | Dart Industries Inc. | Copper chromite catalyst and the process for producing it |
-
1979
- 1979-02-26 US US06/015,574 patent/US4251396A/en not_active Expired - Lifetime
-
1980
- 1980-02-05 IN IN80/DEL/80A patent/IN153681B/en unknown
- 1980-02-15 IT IT19951/80A patent/IT1141216B/it active
- 1980-02-19 GB GB8005618A patent/GB2047219B/en not_active Expired
- 1980-02-21 NL NL8001063A patent/NL8001063A/nl not_active Application Discontinuation
- 1980-02-21 FR FR8003847A patent/FR2449478A1/fr not_active Withdrawn
- 1980-02-22 ZA ZA00801034A patent/ZA801034B/xx unknown
- 1980-02-25 BE BE0/199537A patent/BE881903A/fr not_active IP Right Cessation
- 1980-02-25 ES ES488911A patent/ES488911A0/es active Granted
- 1980-02-26 BR BR8001132A patent/BR8001132A/pt unknown
- 1980-02-26 DE DE3007139A patent/DE3007139C2/de not_active Expired
- 1980-02-26 MX MX181334A patent/MX153509A/es unknown
- 1980-10-24 ES ES496265A patent/ES8107047A1/es not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| ZA801034B (en) | 1981-03-25 |
| ES496265A0 (es) | 1981-10-01 |
| DE3007139A1 (de) | 1980-08-28 |
| ES8103074A1 (es) | 1981-02-16 |
| BE881903A (fr) | 1980-06-16 |
| GB2047219A (en) | 1980-11-26 |
| US4251396A (en) | 1981-02-17 |
| ES488911A0 (es) | 1981-02-16 |
| IN153681B (es) | 1984-08-04 |
| IT1141216B (it) | 1986-10-01 |
| GB2047219B (en) | 1983-03-09 |
| BR8001132A (pt) | 1980-11-04 |
| FR2449478A1 (fr) | 1980-09-19 |
| MX153509A (es) | 1986-11-10 |
| DE3007139C2 (de) | 1982-11-11 |
| IT8019951A0 (it) | 1980-02-15 |
| ES8107047A1 (es) | 1981-10-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A1A | A request for search or an international-type search has been filed | ||
| BB | A search report has been drawn up | ||
| BC | A request for examination has been filed | ||
| A85 | Still pending on 85-01-01 | ||
| BV | The patent application has lapsed |