NL7702200A - Pesticides contg. phosphorus acid derivs. of (thio)urea - including (N)-(thio)carbamoyl phosphoramido-(di)thioates - Google Patents
Pesticides contg. phosphorus acid derivs. of (thio)urea - including (N)-(thio)carbamoyl phosphoramido-(di)thioatesInfo
- Publication number
- NL7702200A NL7702200A NL7702200A NL7702200A NL7702200A NL 7702200 A NL7702200 A NL 7702200A NL 7702200 A NL7702200 A NL 7702200A NL 7702200 A NL7702200 A NL 7702200A NL 7702200 A NL7702200 A NL 7702200A
- Authority
- NL
- Netherlands
- Prior art keywords
- thio
- alkyl
- opt
- substd
- aryl
- Prior art date
Links
- SSGGNFYQMRDXFH-UHFFFAOYSA-N sulfanylurea Chemical compound NC(=O)NS SSGGNFYQMRDXFH-UHFFFAOYSA-N 0.000 title abstract 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title 1
- 239000002253 acid Substances 0.000 title 1
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 title 1
- 239000000575 pesticide Substances 0.000 title 1
- 229910052698 phosphorus Inorganic materials 0.000 title 1
- 239000011574 phosphorus Substances 0.000 title 1
- 125000000217 alkyl group Chemical group 0.000 abstract 5
- 125000003118 aryl group Chemical group 0.000 abstract 4
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 3
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 3
- 125000003545 alkoxy group Chemical group 0.000 abstract 2
- PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 abstract 2
- 230000001069 nematicidal effect Effects 0.000 abstract 2
- ZCEQFHMBKQAETE-UHFFFAOYSA-O CCC(C)[S+]=P(N)(OCC)OC(NC1CCCCC1)=O Chemical compound CCC(C)[S+]=P(N)(OCC)OC(NC1CCCCC1)=O ZCEQFHMBKQAETE-UHFFFAOYSA-O 0.000 abstract 1
- 230000000895 acaricidal effect Effects 0.000 abstract 1
- 239000000642 acaricide Substances 0.000 abstract 1
- 125000003342 alkenyl group Chemical group 0.000 abstract 1
- 125000004183 alkoxy alkyl group Chemical group 0.000 abstract 1
- 125000003282 alkyl amino group Chemical group 0.000 abstract 1
- 125000006350 alkyl thio alkyl group Chemical group 0.000 abstract 1
- 125000004414 alkyl thio group Chemical group 0.000 abstract 1
- 125000004966 cyanoalkyl group Chemical group 0.000 abstract 1
- 239000002917 insecticide Substances 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 125000004573 morpholin-4-yl group Chemical group N1(CCOCC1)* 0.000 abstract 1
- 239000005645 nematicide Substances 0.000 abstract 1
- 125000000587 piperidin-1-yl group Chemical group [H]C1([H])N(*)C([H])([H])C([H])([H])C([H])([H])C1([H])[H] 0.000 abstract 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract 1
- 125000003373 pyrazinyl group Chemical group 0.000 abstract 1
- 125000004076 pyridyl group Chemical group 0.000 abstract 1
- 125000005344 pyridylmethyl group Chemical group [H]C1=C([H])C([H])=C([H])C(=N1)C([H])([H])* 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/06—Phosphorus compounds without P—C bonds
- C07F9/22—Amides of acids of phosphorus
- C07F9/24—Esteramides
- C07F9/2454—Esteramides the amide moiety containing a substituent or a structure which is considered as characteristic
- C07F9/2479—Compounds containing the structure P(=X)n-N-acyl, P(=X)n-N-heteroatom, P(=X)n-N-CN (X = O, S, Se; n = 0, 1)
- C07F9/2487—Compounds containing the structure P(=X)n-N-acyl, P(=X)n-N-heteroatom, P(=X)n-N-CN (X = O, S, Se; n = 0, 1) containing the structure P(=X)n-N-C(=X) (X = O, S, Se; n = 0, 1)
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/44—Amides thereof
- C07F9/4461—Amides thereof the amide moiety containing a substituent or a structure which is considered as characteristic
- C07F9/4484—Compounds containing the structure C-P(=X)(N-acyl)-X, C-P(=X)(N-heteroatom)-X or C-P(=X)(N-CN)-X (X = O, S, Se)
- C07F9/4492—Compounds containing the structure P(=X)(N-C(=X)-) (X = O, S, Se)
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
- C07F9/576—Six-membered rings
- C07F9/58—Pyridine rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
- C07F9/576—Six-membered rings
- C07F9/59—Hydrogenated pyridine rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/645—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having two nitrogen atoms as the only ring hetero atoms
- C07F9/6509—Six-membered rings
- C07F9/650952—Six-membered rings having the nitrogen atoms in the positions 1 and 4
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Crystallography & Structural Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Arthropodicidal and nematocidal compsns. contain P-contg (thio)urea derivs. of formula R1R2N-CX-NR3POR4R5 (I) or their metal salts or complexes. In the formula, R1 is H, 1-12C alkyl, 3-8C cycloalkyl, or opt. substd. =11 C aralkyl, 6-14C aryl, pyridyl, pyridylmethyl, pyridylethyl or pyrazinyl, and R2 is H, 1-10C alkyl, 3-8C cycloalkyl, 2-10C alkoxyalkyl, 2-10C alkylthioalkyl, 1-6C cyanoalkyl, 3-6C alkenyl or opt. substd. =11C aralkyl or 6-10C aryl, or NR1R2 can be morpholino or piperidino opt. mono- or disubstd. by 1-4C alkyl. R3 is H, 3-8C cycloalkyl or opt. substd. =11C aralkyl or 6-10C aryl. R4 is 1-6C alkoxy, 1-6C alkylthio or di(-1-6C alkyl)amino, and R5 is 1-6C alkyl, 1-6C alkylthio-or 1-6C alkylamino, provided that R4 is not alkoxy and R5 is not alkyl when R1 is H and R2 is opt. substd. aryl. X is O or S. The compsns. are esp. useful as agricultural insecticides, acaricides and nematocides. A typical cpd. (I) is N-cyclohexylaminocarbonyl O-ethyl S-(1-methylpropyl)phosphoramidothioate. In an example, this was prepd. from cyclohexylamine and O-ethyl S-(1-methylpropyl)phosphorisocyanatothioate.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US66274576A | 1976-03-01 | 1976-03-01 | |
| US05/662,751 US4259330A (en) | 1976-03-01 | 1976-03-01 | Nematocidal phosphoramidates |
| US05/662,743 US4087521A (en) | 1976-03-01 | 1976-03-01 | Arthropodicidal and nematocidal phosphoramidates |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NL7702200A true NL7702200A (en) | 1977-09-05 |
Family
ID=27418071
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NL7702200A NL7702200A (en) | 1976-03-01 | 1977-03-01 | Pesticides contg. phosphorus acid derivs. of (thio)urea - including (N)-(thio)carbamoyl phosphoramido-(di)thioates |
Country Status (2)
| Country | Link |
|---|---|
| NL (1) | NL7702200A (en) |
| SE (1) | SE7702200L (en) |
-
1977
- 1977-02-28 SE SE7702200A patent/SE7702200L/en not_active Application Discontinuation
- 1977-03-01 NL NL7702200A patent/NL7702200A/en not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| SE7702200L (en) | 1977-09-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| BV | The patent application has lapsed |