NL216658A - - Google Patents
Info
- Publication number
- NL216658A NL216658A NL216658DA NL216658A NL 216658 A NL216658 A NL 216658A NL 216658D A NL216658D A NL 216658DA NL 216658 A NL216658 A NL 216658A
- Authority
- NL
- Netherlands
- Prior art keywords
- component
- compounds
- organic
- alloys
- olefines
- Prior art date
Links
- 229910052751 metal Inorganic materials 0.000 abstract 16
- 239000002184 metal Substances 0.000 abstract 16
- 150000001875 compounds Chemical class 0.000 abstract 10
- 239000003054 catalyst Substances 0.000 abstract 6
- 150000002739 metals Chemical class 0.000 abstract 6
- 239000000178 monomer Substances 0.000 abstract 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract 4
- 125000004429 atom Chemical group 0.000 abstract 4
- 239000003085 diluting agent Substances 0.000 abstract 4
- 150000004820 halides Chemical class 0.000 abstract 4
- 229910052736 halogen Inorganic materials 0.000 abstract 4
- 150000002367 halogens Chemical class 0.000 abstract 4
- 150000002894 organic compounds Chemical class 0.000 abstract 4
- 229910052760 oxygen Inorganic materials 0.000 abstract 4
- 238000006116 polymerization reaction Methods 0.000 abstract 4
- 229910017060 Fe Cr Inorganic materials 0.000 abstract 3
- 229910002544 Fe-Cr Inorganic materials 0.000 abstract 3
- 229910002551 Fe-Mn Inorganic materials 0.000 abstract 3
- 229910001021 Ferroalloy Inorganic materials 0.000 abstract 3
- 125000002877 alkyl aryl group Chemical group 0.000 abstract 3
- -1 chloro- Chemical class 0.000 abstract 3
- UPHIPHFJVNKLMR-UHFFFAOYSA-N chromium iron Chemical compound [Cr].[Fe] UPHIPHFJVNKLMR-UHFFFAOYSA-N 0.000 abstract 3
- MDLUTESQPRTTJB-UHFFFAOYSA-N C(CCCC)[Ba] Chemical compound C(CCCC)[Ba] MDLUTESQPRTTJB-UHFFFAOYSA-N 0.000 abstract 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 2
- 239000005977 Ethylene Substances 0.000 abstract 2
- 229910000640 Fe alloy Inorganic materials 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 abstract 2
- 229910052776 Thorium Inorganic materials 0.000 abstract 2
- 229910052769 Ytterbium Inorganic materials 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- 150000001298 alcohols Chemical class 0.000 abstract 2
- 229910045601 alloy Inorganic materials 0.000 abstract 2
- 239000000956 alloy Substances 0.000 abstract 2
- 229910052782 aluminium Inorganic materials 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 2
- 229910052788 barium Inorganic materials 0.000 abstract 2
- 229910052790 beryllium Inorganic materials 0.000 abstract 2
- 230000015572 biosynthetic process Effects 0.000 abstract 2
- 229910052793 cadmium Inorganic materials 0.000 abstract 2
- 229910052792 caesium Inorganic materials 0.000 abstract 2
- 229910052791 calcium Inorganic materials 0.000 abstract 2
- 229910052799 carbon Inorganic materials 0.000 abstract 2
- 150000003841 chloride salts Chemical class 0.000 abstract 2
- 125000001309 chloro group Chemical group Cl* 0.000 abstract 2
- 239000000470 constituent Substances 0.000 abstract 2
- 229910052802 copper Inorganic materials 0.000 abstract 2
- 230000001627 detrimental effect Effects 0.000 abstract 2
- 150000001993 dienes Chemical class 0.000 abstract 2
- 239000007789 gas Substances 0.000 abstract 2
- 229910052732 germanium Inorganic materials 0.000 abstract 2
- 229930195733 hydrocarbon Natural products 0.000 abstract 2
- 150000002430 hydrocarbons Chemical class 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 2
- 229910052738 indium Inorganic materials 0.000 abstract 2
- 229910003480 inorganic solid Inorganic materials 0.000 abstract 2
- 229910052745 lead Inorganic materials 0.000 abstract 2
- 229910052744 lithium Inorganic materials 0.000 abstract 2
- 229910052749 magnesium Inorganic materials 0.000 abstract 2
- 239000000463 material Substances 0.000 abstract 2
- 150000001247 metal acetylides Chemical class 0.000 abstract 2
- 229910052987 metal hydride Inorganic materials 0.000 abstract 2
- 150000004681 metal hydrides Chemical class 0.000 abstract 2
- 229910052750 molybdenum Inorganic materials 0.000 abstract 2
- 229910052757 nitrogen Inorganic materials 0.000 abstract 2
- 239000001301 oxygen Substances 0.000 abstract 2
- 230000000737 periodic effect Effects 0.000 abstract 2
- 150000002978 peroxides Chemical class 0.000 abstract 2
- 239000002685 polymerization catalyst Substances 0.000 abstract 2
- 229910052700 potassium Inorganic materials 0.000 abstract 2
- 239000000843 powder Substances 0.000 abstract 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 2
- 229910052761 rare earth metal Inorganic materials 0.000 abstract 2
- 150000002910 rare earth metals Chemical class 0.000 abstract 2
- 230000002829 reductive effect Effects 0.000 abstract 2
- 229910052701 rubidium Inorganic materials 0.000 abstract 2
- 229910052706 scandium Inorganic materials 0.000 abstract 2
- 229910052711 selenium Inorganic materials 0.000 abstract 2
- 229910052709 silver Inorganic materials 0.000 abstract 2
- 229910052708 sodium Inorganic materials 0.000 abstract 2
- 239000011734 sodium Substances 0.000 abstract 2
- 239000011780 sodium chloride Substances 0.000 abstract 2
- CCBAWKDSULZOID-UHFFFAOYSA-N sodium;1,4-xylene Chemical compound [Na].CC1=CC=C(C)C=C1 CCBAWKDSULZOID-UHFFFAOYSA-N 0.000 abstract 2
- ONQCKWIDZTZEJA-UHFFFAOYSA-N sodium;pentane Chemical compound [Na+].CCCC[CH2-] ONQCKWIDZTZEJA-UHFFFAOYSA-N 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- 229910052712 strontium Inorganic materials 0.000 abstract 2
- 229910052717 sulfur Inorganic materials 0.000 abstract 2
- 229910052714 tellurium Inorganic materials 0.000 abstract 2
- 229910052716 thallium Inorganic materials 0.000 abstract 2
- 229910052718 tin Inorganic materials 0.000 abstract 2
- 229910052719 titanium Inorganic materials 0.000 abstract 2
- 150000005671 trienes Chemical class 0.000 abstract 2
- 239000013638 trimer Substances 0.000 abstract 2
- 229910052721 tungsten Inorganic materials 0.000 abstract 2
- 229910052720 vanadium Inorganic materials 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- 229910052725 zinc Inorganic materials 0.000 abstract 2
- 229910052726 zirconium Inorganic materials 0.000 abstract 2
- 229910017116 Fe—Mo Inorganic materials 0.000 abstract 1
- 238000004458 analytical method Methods 0.000 abstract 1
- 125000001246 bromo group Chemical group Br* 0.000 abstract 1
- 125000001153 fluoro group Chemical group F* 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
- C07F1/02—Lithium compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
- C07F1/08—Copper compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
- C07F5/061—Aluminium compounds with C-aluminium linkage
- C07F5/062—Al linked exclusively to C
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F114/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F114/02—Monomers containing chlorine
- C08F114/04—Monomers containing two carbon atoms
- C08F114/06—Vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F114/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F114/18—Monomers containing fluorine
- C08F114/26—Tetrafluoroethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F12/02—Monomers containing only one unsaturated aliphatic radical
- C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F12/06—Hydrocarbons
- C08F12/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F12/02—Monomers containing only one unsaturated aliphatic radical
- C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F12/14—Monomers containing only one unsaturated aliphatic radical containing one ring substituted by hetero atoms or groups containing heteroatoms
- C08F12/16—Halogens
- C08F12/18—Chlorine
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
- C08F4/12—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of boron, aluminium, gallium, indium, thallium or rare earths
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/42—Introducing metal atoms or metal-containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/04—Dual catalyst, i.e. use of two different catalysts, where none of the catalysts is a metallocene
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
A polymerization catalyst comprises a monometatalled organic compound "1" and Friedel Crafts compounds "2b" with or without a modifying polar compound "2a" and/or a carrier component "3". Component "1" is defined as containing a single metal atom bonded to the organic moiety by a carbon-metal bond; said moiety may be polymeric or nonpolymeric, while the metal atoms are selected from Li, Na, K, Rb, Cs, Cu, Ag, Be, Mg, Ca, Sr, Ba, Zn, Cd, Hg, B, Al, Sc, Yb, La, Ga, In, Tl, Ti, Zr, Th, Ge, Sn, Pb and the rare-earth metals. Component "2b" comprises mixed halides obtained by burning in halogen gases or vapours the ferro-alloys of metals of Periodic Group IV, V, VI, iron group VIII, and Mn, with or without reductive after treatment with metal powders, metal hydrides, metal carbides and/or hydrogen and the said halides may be partially reacted with oxygen water and/or reactive organic compounds such as alcohols. Component "2a" consists of organic donor compounds containing one or more of O, N, S, Se, Te, halogens; various classes of such compounds being mentioned and a number of peroxides and azo compounds being also specified; such donor compounds include those in which active hydrogen atoms have been replaced by metals. Component "3" is an organic or inorganic solid not detrimental to the polymerization and including shaped materials and carbon. Many metals and acid radicals suitable as constituents of this component are listed as are many specified oxides. The usual hydrocarbons and their halogenated derivatives are mentioned as solvents for catalyst formation and polymerization. In examples, ethylene and propylene are homopolymerized in presence of catalysts containing components selected from the following: "1": amyl barium, amyl sodium, p-xylene monosodium and a -methylstyrene trimer monosodium; "2a": ethyl ether; "2b" chlorides derived from Fe alloys with V, Mo, W or Cb; "3": NaCl. Also specified as alloys from which "2b" can be derived are Fe-Mn and Fe-Cr. The monomers which in general may be polymerized with the above catalyst contain at least one polymerizable ethylenic and/or acetylenic linkage; the monomer may itself form the diluent as an alternative to using a separate diluent. Numerous monomers are listed in the Specification; these include the following types: a -olefines; chloro-, fluoro-, chlorofluoro- and bromo-olefines including chloro- and bromo-aryl and alkaryl olefines; aryl and alkaryl olefines; conjugated dienes and trienes. Specifications 873,616 and 873,658 are referred to.ALSO:A polymerization catalyst comprises a mono-metallated organic compound "1" and Friedel Crafts compounds "2b" with or without a modifying polar compound "2a" and/or a carrier component "3". Component "1" is defined as containing a single metal atom bonded to the organic moiety by a carbon-metal bond; said moiety may be polymeric or non-polymeric, while the metal atom is selected from Li, Na, K, Rb, Cs, Cu, Ag, Be, Mg, Ca, Sr, Ba, Zn, Cd, Hg, B, Al, Sc, Yb, La, Ga, In, Tl, Ti, Zr, Th, Ge, Sn, Pb and the rare-earth metals. Component "2b" comprises mixed halides obtained by burning in halogen gases or vapours the ferro-alloys of metals of Periodic Group IV, V, VI, iron Group VIII, and Mn, with or without reductive after treatment with metal powders, metal hydrides, metal carbides and/or hydrogen and the said halides may be partially reacted with oxygen water and/or reactive organic compounds such as alcohols. Component "2a" consists of organic donor compounds containing one or more of O, N, S, Se, Te, halogens; various classes of such compounds being mentioned and a number of peroxides and azo-compounds being also specified; such donor compounds include those in which active hydrogen atoms have been replaced by metals. Component "3" is an organic or inorganic solid not detrimental to the polymerization and including shaped materials and carbon. Many metals and acid radicals suitable as constituents of this component are listed as are many specified oxides. The usual hydrocarbons and their halogenated derivatives are mentioned as solvents for catalyst formation and polymerization. In examples, ethylene and propylene are homopolymerized in presence of catalysts containing components selected from the following:-"1": amyl barium, amyl sodium, p-xylene monosodium and a -methylstyrene trimer monosodium; "2a": ethyl ether; "2b": chlorides derived from Fe alloys with V, Mo, W or Cb; "3": NaCl. Also specified as alloys from which "2b" can be derived are Fe-Mn and Fe-Cr. The monomers which in general may be polymerized with the above catalyst contain at least one polymerizable ethylenic and/or acetylonic linkage; the monomer may itself form the diluent as an alternative to using a separate diluent. Numerous monomers are listed in the Specification; these include the following types:-a -olefines; chloro, fluoro, chlorofluoro and bromo olefines including chloro and bromo aryl and alkaryl olefines; aryl and alkaryl olefins; conjugated dienes and trienes. Specifications 873,616 and 873,658 also are referred to.ALSO:The Specification describes analyses of certain ferro-alloys thus:- (1) Fe-W: W 81.02, Mn 0.13, Mo 0.70, C 0.51, Si 0.17; (2) Fe-V: V 62.0; (3) Fe-Mn: Mn 78.6, C 6.38, Si 1.38; (4) Fe-Mo: Mo 62.6, Si 0.56; (5) Fe-Cr: Cr 71.23, C 0.4, Si 0.57; (6) Fe-Cb: Cb 57.36, C 0.35, Si 6.47%. In all cases, iron constitutes the approximate balance. Specifications 873,658 and 873,616 also are referred to.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US58064256A | 1956-04-25 | 1956-04-25 | |
| US641047A US3196116A (en) | 1956-04-25 | 1957-02-19 | Multiply metallated polymerization catalysts |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NL216658A true NL216658A (en) | 1900-01-01 |
Family
ID=27078095
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NL216658D NL216658A (en) | 1956-04-25 |
Country Status (5)
| Country | Link |
|---|---|
| BE (1) | BE556975A (en) |
| DE (3) | DE1158067B (en) |
| FR (1) | FR1187677A (en) |
| GB (4) | GB873657A (en) |
| NL (1) | NL216658A (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL265477A (en) * | 1961-03-10 | |||
| CN114656628B (en) * | 2022-03-28 | 2023-11-17 | 浙江皇马科技股份有限公司 | High molecular weight allyl alcohol polyoxyethylene polyoxypropylene ether and preparation method thereof |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE538782C (en) * | 1931-11-16 | Patra Patent Treuhand | Electric arc lamp with a series resistor serving as a light body | |
| US1938180A (en) * | 1931-06-23 | 1933-12-05 | Shell Dev | Process for the manufacture of organic metallo compounds |
| DE1003731B (en) | 1955-02-25 | 1957-03-07 | Basf Ag | Process for the stabilization of organosodium compounds |
-
0
- NL NL216658D patent/NL216658A/xx unknown
-
1957
- 1957-04-18 DE DEB61984A patent/DE1158067B/en active Pending
- 1957-04-18 DE DEB44363A patent/DE1172429B/en active Pending
- 1957-04-18 DE DEB61982A patent/DE1168428B/en active Pending
- 1957-04-25 FR FR1187677D patent/FR1187677A/en not_active Expired
- 1957-04-25 GB GB12921/57A patent/GB873657A/en not_active Expired
- 1957-04-25 GB GB39985/60A patent/GB873661A/en not_active Expired
- 1957-04-25 GB GB1233/61A patent/GB873662A/en not_active Expired
- 1957-04-25 BE BE556975A patent/BE556975A/en unknown
- 1957-04-25 GB GB39984/60A patent/GB873660A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| GB873661A (en) | 1961-07-26 |
| DE1172429B (en) | 1964-06-18 |
| DE1158067B (en) | 1963-11-28 |
| FR1187677A (en) | 1959-09-15 |
| DE1168428B (en) | 1964-04-23 |
| GB873662A (en) | 1961-07-26 |
| BE556975A (en) | 1957-10-25 |
| GB873657A (en) | 1961-07-26 |
| GB873660A (en) | 1961-07-26 |
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