MY171403A - A continuous process for the carbonylation of ethylene - Google Patents
A continuous process for the carbonylation of ethyleneInfo
- Publication number
- MY171403A MY171403A MYPI2014701673A MYPI2014701673A MY171403A MY 171403 A MY171403 A MY 171403A MY PI2014701673 A MYPI2014701673 A MY PI2014701673A MY PI2014701673 A MYPI2014701673 A MY PI2014701673A MY 171403 A MY171403 A MY 171403A
- Authority
- MY
- Malaysia
- Prior art keywords
- alkyl ester
- ester product
- product
- alkanol
- distillation column
- Prior art date
Links
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title abstract 2
- 239000005977 Ethylene Substances 0.000 title abstract 2
- 230000006315 carbonylation Effects 0.000 title abstract 2
- 238000005810 carbonylation reaction Methods 0.000 title abstract 2
- 238000010924 continuous production Methods 0.000 title abstract 2
- 125000005907 alkyl ester group Chemical group 0.000 abstract 6
- 239000000047 product Substances 0.000 abstract 6
- 229910052751 metal Inorganic materials 0.000 abstract 3
- 239000002184 metal Substances 0.000 abstract 3
- 230000003197 catalytic effect Effects 0.000 abstract 2
- 239000003446 ligand Substances 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- 238000000926 separation method Methods 0.000 abstract 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000012043 crude product Substances 0.000 abstract 1
- 238000004821 distillation Methods 0.000 abstract 1
- 238000007701 flash-distillation Methods 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
- C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/48—Separation; Purification; Stabilisation; Use of additives
- C07C67/52—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
- C07C67/54—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
A continuous process for the production of an alkyl ester product is described. The process comprises the steps of carbonylating ethylene with carbon monoxide in the presence of C1-6 alkanol co-reactant to form the alkyl ester product. The carbonylation takes place in the presence of a catalyst system comprising; a. a bidentate ligand, b. a catalytic metal selected from a group 8, 9 or 10 metal or a compound thereof, and c. a sulphonic acid capable of forming an acid alkyl ester with the C1-6 alkanol. The process includes the step of separating the alkyl ester product from a carbonylated crude product stream by treatment effective to vaporise the alkyl ester product in a single stage flash distillation column and provide a purified alkyl ester product stream separated from the bidentate ligand and catalytic metal. The distillation column includes further separation means effective to provide further separation of the product. Fig 1.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB201122054A GB201122054D0 (en) | 2011-12-21 | 2011-12-21 | A continuous process for the carbonylation of ethylene |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MY171403A true MY171403A (en) | 2019-10-11 |
Family
ID=45572827
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MYPI2014701673A MY171403A (en) | 2011-12-21 | 2012-12-20 | A continuous process for the carbonylation of ethylene |
Country Status (18)
| Country | Link |
|---|---|
| US (1) | US9382190B2 (en) |
| EP (1) | EP2794548B1 (en) |
| JP (3) | JP2015502393A (en) |
| KR (1) | KR102105599B1 (en) |
| CN (2) | CN104011007B (en) |
| AU (1) | AU2012356457B2 (en) |
| BR (1) | BR112014015157B1 (en) |
| CA (1) | CA2857572C (en) |
| EA (1) | EA032583B1 (en) |
| ES (1) | ES2742329T3 (en) |
| GB (1) | GB201122054D0 (en) |
| IN (1) | IN2014DN05822A (en) |
| MX (1) | MX348494B (en) |
| MY (1) | MY171403A (en) |
| SG (2) | SG10201700374VA (en) |
| TW (1) | TWI631103B (en) |
| WO (1) | WO2013093472A1 (en) |
| ZA (1) | ZA201404484B (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB201122054D0 (en) * | 2011-12-21 | 2012-02-01 | Lucite Int Uk Ltd | A continuous process for the carbonylation of ethylene |
| CN112898123B (en) * | 2019-11-19 | 2022-02-11 | 中国科学院大连化学物理研究所 | A kind of method for preparing propanol |
| US20240083926A1 (en) * | 2020-12-15 | 2024-03-14 | Agency For Science, Technology And Research | Phosphorus compounds and methods thereof |
| CN115957823B (en) * | 2021-10-13 | 2025-04-08 | 上海浦景化工技术股份有限公司 | Ethylene carbonylation catalyst and its application |
| CN115959994B (en) * | 2021-10-13 | 2025-11-04 | 上海浦景化工技术股份有限公司 | A system and method for preparing high-purity MMA |
| CN116139939B (en) * | 2022-12-28 | 2025-08-26 | 浙江新和成股份有限公司 | Catalyst system and carbonylation reaction method |
| CN116082157B (en) * | 2023-01-18 | 2025-09-16 | 上海梓龄化工技术有限公司 | Method for preparing organic carboxylic ester by olefine unsaturated compound alkoxycarbonyl reaction |
Family Cites Families (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5440901A (en) * | 1977-09-07 | 1979-03-31 | Masabumi Isobe | Flash tank which houses filler |
| US4262138A (en) * | 1979-04-09 | 1981-04-14 | Chem Systems Inc. | Preparation of carboxylic acid esters with BF3 complex catalyst |
| EP0055875B1 (en) | 1981-01-06 | 1986-08-20 | Shell Internationale Researchmaatschappij B.V. | Process for the carbonylation of olefins |
| CA1231346A (en) | 1982-09-30 | 1988-01-12 | Eit Drent | Process for the carbonylation of olefinically unsaturated compounds with a palladium catalyst |
| JPS62102883A (en) * | 1985-10-30 | 1987-05-13 | Hitachi Ltd | waste liquid concentrator |
| GB8531624D0 (en) | 1985-12-23 | 1986-02-05 | Shell Int Research | Carbonylation of ethylenically unsaturated compounds |
| GB8605034D0 (en) | 1986-02-28 | 1986-04-09 | Shell Int Research | Carbonylation of compounds |
| KR880007426A (en) | 1986-12-24 | 1988-08-27 | 오노 알버어스 | Carbonylation Method of Olefinic Unsaturated Compound Using Palladium Catalyst |
| GB8705699D0 (en) | 1987-03-11 | 1987-04-15 | Shell Int Research | Carbonylation of olefinically unsaturated compounds |
| KR0144567B1 (en) | 1989-03-03 | 1998-07-15 | 오노 알버어스 | Catalyst system for carbonylation |
| CA2034971A1 (en) | 1990-02-05 | 1991-08-06 | Eit Drent | Carbonylation catalyst system |
| FI91135C (en) | 1990-03-19 | 1994-05-25 | Valmet Paper Machinery Inc | A method of drilling holes in the cylinder liner of a paper machine and the equipment used in the method |
| CA2055628A1 (en) | 1990-12-03 | 1992-06-04 | Eit Drent | Carbonylation process and catalyst composition |
| DE69204691T2 (en) | 1991-01-15 | 1996-04-11 | Shell Int Research | Process for carbonylation of olefin. |
| EP0495547B1 (en) | 1991-01-15 | 1996-04-24 | Shell Internationale Researchmaatschappij B.V. | Carbonylation of olefins |
| EP0499329B1 (en) | 1991-02-15 | 1994-05-04 | Shell Internationale Researchmaatschappij B.V. | Carbonylation catalyst system |
| JP3489592B2 (en) * | 1994-02-28 | 2004-01-19 | 三菱瓦斯化学株式会社 | Method for producing esters |
| GB9425911D0 (en) | 1994-12-22 | 1995-02-22 | Ici Plc | Process for the carbonylation of olefins and catalyst system for use therein |
| JP2922848B2 (en) * | 1996-06-14 | 1999-07-26 | 株式会社日本触媒 | Method for producing aromatic carbonate |
| GB9705699D0 (en) | 1997-03-19 | 1997-05-07 | Ici Plc | Process for the carbonylation of ethylene |
| US6156934A (en) | 1997-03-26 | 2000-12-05 | Shell Oil Company | Diphosphines |
| US6706912B2 (en) | 2000-03-14 | 2004-03-16 | Shell Oil Company | Process for the carbonylation of ethylenically unsaturated compounds |
| DE10048874A1 (en) | 2000-09-29 | 2002-04-11 | Basf Ag | Catalyst system and process for carbonylation |
| DE10228293A1 (en) | 2001-07-28 | 2003-02-13 | Basf Ag | Preparation of dialkyl ketones, e.g. 3-pentanone, used as solvent or intermediate e.g. in synthesis of trimethylphenol and vitamin E, uses amide in palladium phosphine catalyst system in reductive carbonylation of olefin |
| JP2003267917A (en) * | 2002-03-15 | 2003-09-25 | Mitsubishi Chemicals Corp | How to shut down the distillation column |
| JP2003113138A (en) * | 2001-10-09 | 2003-04-18 | Mitsubishi Chemicals Corp | (Meth) acrylic acid distillation method |
| CN100516017C (en) | 2002-02-19 | 2009-07-22 | 国际壳牌研究有限公司 | Process for the carbonylation of an ethylenically unsaturated compound and catalyst therefore |
| ES2429871T3 (en) | 2002-09-12 | 2013-11-18 | Lucite International Uk Limited | A catalyst system comprising a 1,2-bis- (phosphin) metallocene ligand |
| EP1625109A1 (en) | 2003-05-22 | 2006-02-15 | Shell Internationale Researchmaatschappij B.V. | Process for the carbonylation of a conjugated diene |
| GB0403592D0 (en) * | 2004-02-18 | 2004-03-24 | Lucite Int Uk Ltd | A catalyst system |
| WO2005082830A1 (en) | 2004-02-26 | 2005-09-09 | Shell Internationale Research Maatschappij B.V. | Process for the carbonylation of ethylenically or acetylenically unsaturated compounds |
| DK1907319T3 (en) * | 2005-07-18 | 2010-05-17 | Union Engineering As | Process for using high purity carbon dioxide from a gas source comprising nitrogen compounds |
| GB0516556D0 (en) * | 2005-08-12 | 2005-09-21 | Lucite Int Uk Ltd | Improved catalyst system |
| US20120309613A1 (en) * | 2009-12-15 | 2012-12-06 | Lucite International Uk Limited | Carbonylation process |
| GB0921875D0 (en) * | 2009-12-15 | 2010-01-27 | Lucite Int Uk Ltd | A continuous process for the carbonylation of ethylene |
| GB201122054D0 (en) * | 2011-12-21 | 2012-02-01 | Lucite Int Uk Ltd | A continuous process for the carbonylation of ethylene |
-
2011
- 2011-12-21 GB GB201122054A patent/GB201122054D0/en not_active Ceased
-
2012
- 2012-12-20 SG SG10201700374VA patent/SG10201700374VA/en unknown
- 2012-12-20 CA CA2857572A patent/CA2857572C/en active Active
- 2012-12-20 JP JP2014548192A patent/JP2015502393A/en active Pending
- 2012-12-20 AU AU2012356457A patent/AU2012356457B2/en not_active Ceased
- 2012-12-20 KR KR1020147020382A patent/KR102105599B1/en active Active
- 2012-12-20 EA EA201491208A patent/EA032583B1/en not_active IP Right Cessation
- 2012-12-20 SG SG11201402921RA patent/SG11201402921RA/en unknown
- 2012-12-20 US US14/364,718 patent/US9382190B2/en active Active
- 2012-12-20 CN CN201280063887.8A patent/CN104011007B/en active Active
- 2012-12-20 BR BR112014015157-1A patent/BR112014015157B1/en not_active IP Right Cessation
- 2012-12-20 CN CN201710180912.5A patent/CN106928061B/en active Active
- 2012-12-20 IN IN5822DEN2014 patent/IN2014DN05822A/en unknown
- 2012-12-20 EP EP12809846.4A patent/EP2794548B1/en active Active
- 2012-12-20 MY MYPI2014701673A patent/MY171403A/en unknown
- 2012-12-20 WO PCT/GB2012/053204 patent/WO2013093472A1/en not_active Ceased
- 2012-12-20 MX MX2014007326A patent/MX348494B/en active IP Right Grant
- 2012-12-20 ES ES12809846T patent/ES2742329T3/en active Active
- 2012-12-21 TW TW101149102A patent/TWI631103B/en active
-
2014
- 2014-06-18 ZA ZA2014/04484A patent/ZA201404484B/en unknown
-
2017
- 2017-07-12 JP JP2017135935A patent/JP6716503B2/en active Active
-
2019
- 2019-02-28 JP JP2019035068A patent/JP2019089844A/en not_active Withdrawn
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