MXPA06011995A - Synergistic insecticide mixtures - Google Patents

Abstract

The invention relates to insecticide mixtures which comprise methiocarb and at least one additional known active substance from the group of neonicotinoids. The invention also relates to the use of said mixtures for animal pest control and for treating seeds.

Description

INSECTICIDE SYNERGIC MIXTURES FIELD OF THE INVENTION The present invention relates to new combinations of active products, which contain, as active products Methiocarb and another active product of the neonicotinoid series and which have very good insecticidal properties. BACKGROUND OF THE INVENTION It is already known that Methiocarb (3,5-dimethyl-4-methylthio) phenylmethylcarbamate) of the formula It can be used as an insecticide and acaricide for the fight against animal pests, especially against insects. Methiocarb is also known by the name "Mesurol". In addition, it is known that neonicotinoids, such as for example Thiacloprid, Clothianidin, Thiamethoxam, Aceta iprid, Nitenpyram and Dinotefuran are suitable for the fight against animal pests, especially against the insects . It has already been known to have a mixture containing Imidacloprid, another chloronicotinyl compound, and Methiocarb REF: 176459 (WO 96/37105), of course only its suitability for the treatment of leaves and soil is described. In WO 03/063592 A1, agents comprising Clothianidin and Methiocarb are cited. Also, in this case, the treatment of the leaves and the ground is especially contemplated and the general suitability for the treatment of the seeds is mentioned. The document does not indicate, however, any conclusion about whether these mixtures are really suitable for the treatment of seeds or for which crops it is especially suitable. The activity of these products is good, however, it does not correspond to the high requirements that insecticides are required due to low amounts of application or against some individual pests. DETAILED DESCRIPTION OF THE INVENTION It has now been found that mixtures containing Methiocarb and at least one compound of the series of the .neonicotinoids, mentioned below, have synergistic activity and are suitable for the control of animal pests. Due to this synergism, clearly smaller amounts of the active products can be used, that is to say that the effect of the mixture is greater than the effect of the individual components. Furthermore, it is observed that the combination of Methiocarb and Imidacloprid or of Clothianidin and Methiocarb, which have been disclosed, as such, are especially suitable for the treatment of seeds.

Also the mixtures, which cover the active products Imidacloprid, Clothianidin and Methiocarb, have proved to be especially suitable for the treatment of seeds for protection against pests. Mixtures for the treatment of corn and sunflower seeds are especially suitable. Especially it has been observed that the mixtures cited not only protect the seeds themselves, but also, they can protect, especially the plants in germination against damage, without requiring, as usual in general, the use of agents for the fight against damage immediately after the outbreak of plants, due to its systemic form of action. The compounds mentioned are known, for example, from "The Pesticide Manual", llth Edition, 1997, published by the British Crop Protection Concil. Thiamethoxam has the formula and is known from the publication EP A2 0 580 553. Clothianidin has the formula and is known from the publication EP A2 0 376 279 Thiacloprid has the formula and is known from EP A2 0 235 725, The Dinotefuran has the formula and it is known by the publication EP Al 0 649 845 Acetamiprid has the formula and is known from the publication WO Al 91/04965 The Nitenpyra has the formula and is known from EP A2 publication 0 302 389 Imidacloprid has the formula and is known from the publication EP 0 192 060. The ratio between the active products to each other, as well as the total amounts, to be used, of the mixture, depend on the type and origin of the insects. The proportions and the total quantities, optimum, can be determined for each application respectively by means of series of tests. A particularly preferred mixture according to the invention contains the active compounds Methiocarb and Clothianidin or Methiocarb and Imidacloprid. In these mixtures, the weight ratio between the respective active products is between 1,000 to 1 and 1 to 100, preferably between 125 to 1 and 1 to 50, and particularly preferably between 25 to 1 and 1 to 50. 5, citing - in this case, as, then, first the Methiocarb in the proportions. Another particularly preferred mixture according to the invention contains the active compounds Methiocarb and Acetamiprid. In the mixture, the weight ratio of both active ingredients is between 1,000 to 1 and 1 to 100, preferably between 125 to 1 and 1 to 50 and more preferably, between 25 to 1 and 1 to 5. Another mixture according to the invention, especially preferred, it contains the active compounds Methiocarb and Nitenpyram. In the mixture, the weight ratio of both active ingredients is between 1,000 to 1 and 1 to 100, preferably between 125 to 1 and 1 to 50 and more preferably, between 25 to 1 and 1 to 5. Another mixture according to the invention, which is particularly preferred, contains the active compounds Methiocarb and Dinotefuran. In the mixture, the weight ratio of both active ingredients is between 1,000 to 1 and 1 to 100, preferably between 125 to 1 and 1 to 50 and more preferably, between 25 to 1 and 1 to 5. Another mixture according to the invention, especially preferably, it contains the active compounds Methiocarb and Thiamethoxam. In the mixture, the weight ratio of both active ingredients is between 1,000 to 1 and 1 to 100, preferably between 125 to 1 and 1 to 50 and more preferably, between 25 to 1 and 1 to 5. Another mixture according to the invention, especially preferably, it contains the active compounds Methiocarb and Thiacloprid. In the mixture, the weight ratio of both active products is between 1,000 to 1 and 1 to 100, preferably between 125 to 1 and 1 to 50 and most preferably between 25 to 1 and 1 to 5. A mixture according to the invention, which is especially preferred, contains the active compounds Methiocarb and Clothianidin. In the mixture, which is used for the treatment of the seeds, it is included the weight ratio between each other, between both active products between 1,000 to 1 and 1 to 100, preferably between 125 to 1 and 1 to 50 and in a way especially preferred, between 25 to 1 and 1 to 5, mentioning in this case, as follows, firstly Methiocarb in the proportions. Preferably, the foregoing mixtures, cited as preferred, do not contain any other component of insecticidal action. The combinations of active products are suitable, with a good compatibility with plants and with a favorable toxicity for warm-blooded animals, for the control of animal pests, preferably against insects, arachnids and nematodes, which occur in agriculture, in forestry, for the protection of stored products and materials as well as in the hygiene sector. Preferably, they can be used as agents for the protection of plants in the treatment of leaves and soil. These are active against normally sensitive and resistant species as well as against all or some of the stages of development. The pests mentioned above belong to: From the order of the isopods, for example Oniscus asellus, Armadillidium vulgare, Porcellio scaber. From the order of the diplópodos for example Blaniulus guttulatus. From the order of the chilopoda for example Geophilus carpophagus, Scutigera spp. From the order of the sínfilos example Scutigerella immaculata. From the order of the Thysanides, for example, Lepisma saccharina. From the order of Collembola, for example, Onychiurus armatus. From the order of the orthoptera for example Acheta do esticus, Gryllotalpa spp., Locusta migratoria migratorioides, Melanoplus spp., Schistocerca gregaria. From the order of blatars for example Blatta orientalis, Periplaneta americana, Leucophaea maderae, Blattella germanica. From the order of dermápteros for example Forfícula auricularia. From the order of the isoptera for example Reticulitermes spp. From the order of the phyllostats for example Pediculus humanus corporis, Haematopinus spp. , Linognathus spp. , Trichodectes spp. , Da alinia spp. From the order of Thysanoptera, for example Hercinothrips femoralis, Thrips tabaci, Thrips palmi, Frankliniella occidentalis. From the order of the heteroptera, for example Eurygaster spp., Dysdercus intermedius, Piesma quadrata, Cimex lectularius, Rhodnius prolixus, Triato a spp. From the order of the Homoptera, for example Aleurodes brassicae, Bemisia tabaci, Trialeurodes vaporariorum, Aphis gossypii, Brevicoryne brassicae, Cryptomyzus ribis, Aphie fabae, Aphis pomi, Eriosoma lanigerum, Hyalopterus arundinis, Phylloxera vastatrix, Pemphigus spp., Macrosiphum avenae, Myzus spp. , Phorodon humuli, Rhopalosiphum padi, Empoasca spp., Euscelis bilobatus, Nephotettix cincticeps, Lecanium corni, Saissetia oleae, Laodelphax striatellus, Nilaparvata lugens, Aonidiella aurantii, Aspidiotus hederae, Pseudococcus spp., Psylla spp. From the order of the Lepidoptera, for example, Pectinophora gossypiella, Bupalus piniarius, Chei atobia brumata, Lithocolletis blancardella, Hypono euta padella, Plutella xylostella, Malacosoma neustria, Euproctis chrysorrhoea, Ly anthria spp., Bucculatrix thurberiella, Phyllocnistis citrella, Agrotis spp., Euxoa spp. ., Feltia spp., Earias insulana, Heliothis spp., Mamestra brassicae, Panolis flammea, Spodoptera spp., Trichoplusia ni, Carpocapsa pomonella, Pieris spp., Chilo spp., Pyrausta nubilalis, Ephestia kuehniella, Galleria mellonella, Tineola bisselliella, Tinea pellionella, Hof annophila pseudospretella, Cacoecia podana, Capua reticulana, Choristoneura fumiferana, Clysia ambiguella, Magnanimous hoon, Tortrix viridana, Cnaphalocerus spp., Oulema oryzae. From the order of Coleoptera, for example Anobium punctatum, Rhizopertha dominica, Bruchidius obtectus, Acanthoscelides obtectus, Hylotrupes bajulus, Agelastica alni, Leptinotarsa decemlineata, Phaedon cochleariae, Diabrotica spp., Psylliodes chrysocephala, Epilachna varivestis, Atomaria spp., Oryzaephilus surinamensis, Anthonomus spp. ., Sitophilus spp., Otiorrhynchus sulcatus, Cosmopolites sordidus, Ceuthorrhynchus assimilis, Hypera postica, Dermestes spp., Trogoderma spp. , Anthrenus spp. , Attagenus spp. , Lyctus spp. , Meligethes aeneus, Ptinus spp., Niptus hololeucus, Gibbium psylloides, Tribolium spp., Tenebrio molitor, Agriotes spp., Conoderus spp. , Melolontha melolontha, Amphimallon solstitialis, Costelytra zealandica, Lissorhoptrus oryzophilus. From the order of Hymenoptera, for example Diprion spp., Hoplocampa spp., Lasius spp., Monomorium pharaonis, Vespa spp. From the order of Diptera, for example Aedes spp., Anopheles spp., Culex spp., Drosophila melanogaster, Musca spp., Fannia spp., Calliphora erythrocephala, Lucilia spp., Chrysomyia spp., Cuterebra spp., Gastrophilus spp., Hyppobosca spp., Stomoxys spp., Oestrus spp., Hypoderma spp., Tabanus spp., Tannia spp., Bibio hortulanus, Oscinella frit, Phorbia spp., Pegomyia hyoscyami, Ceratitis capitata, Dacus oleae, Typula paludosa, Hylemyia spp., Lily yza spp .. From the order of the siphonaptera, for example Xenopsylla cheopis, Ceratophyllus spp .. From the class ara arachnids eg Scorpio maurus, Latrodectus mactans, Acarus siró, Argas spp., Ornithodoros spp., Dermanyssus gallinae, Eriophyes ribis, Phyllocoptruta oleivora , Boophilus spp., Rhipicephalus spp., Amblyomma spp., Hyalomma spp., Ixodes spp., Psoroptes spp., Chorioptes spp., Sarcoptes spp., Tarsonemus spp., Bryobia praetiosa, Panonychus spp., Tetranychus spp., Hemitarsonemus spp., Brevipalpus spp. To parasitic nematodes of plants belong, for example, Pratylenchus epp. ., Radopholus similis, Ditylenchus dipsaci, Tylenchulus semipenetrans, Heterodera spp., Globodera spp., Meloidogyne spp., Aphelenchoides spp., Longidorus spp., Xiphinema spp., Trichodorus spp., Bursaphelenchus spp. All plants and parts of plants can be treated according to the invention. By plants, all plants and plant populations, such as desired and unwanted wild plants or crop plants (including crop plants of natural origin), will be understood in this case. The crop plants can be plants that can be obtained by conventional methods of cultivation and optimization or by means of biotechnological and genetic engineering methods or by combinations of these methods, including transgenic planets and including varieties 1.2 protected by the right to protect plant varieties or non-protectable varieties. By parts of the plants all the parts and organs of the aerial and subterranean plants, such as shoots, leaves, flowers and roots, will be understood, being able to indicate in an exemplary way leaves, needles, stems, branches, flowers, body of fruits, fruits and seeds as well as roots, bulbs and rhizomes. The crops as well as the vegetative and generative reproductive material, for example seedlings, bulbs, rhizomes, layering and seeds, also belong to the plant parts. In this case, the particularly advantageous effect of the agent according to the invention with regard to the application to cereals plants, such as for example wheat, oats, barley, spelled, triticale and rye, as well as corn, should be pointed out. , millet, rice, sugar cane, soybeans, sunflower, potatoes, cotton, rapeseed, sugarcane, tobacco, sugar beet, fodder beet, asparagus, hops, as well as fruit tree plantations (including fruits with seed of seeds such as for example apples and pears, fruits with bone seed such as for example peach, nectarines, cherries, plums and apricots, citrus fruits such as for example oranges, grapefruit, limes, lemons, kumquats, tangerines and satsumas, nuts such as for example pistachios, almonds, drupes and pecans, tropical fruits such as mango, papaya, pineapples, dates and bananas, and vines) and vegetables (including green leafy vegetables such as po r example endives, lettuce herb, fennel, head lettuce and lettuce to cut, Swiss chard, spinach and chicory, cabbage such as for example cauliflower, broccoli, Chinese cabbage, green cabbage (winter cabbage or kale), kohlrabi, Brussels sprouts, red cabbage, white cabbage and curly leaf cabbage, fleshy vegetables such as for example aubergines, cucumbers, peppers, cucurbits for consumption, tomatoes, zucchini and sugar corn, root vegetables such as celery, radish, turnip , carrot, yellow turnip, radishes, radish, red turnip, scorzonera and celery, legumes such as, for example, chickpeas and beans as well as bulb vegetables such as for example leeks and consumption onions). The combinations according to the invention are especially suitable for the treatment of corn and sunflower seeds. The treatment according to the invention of the plants and parts of the plants with the combination of active products is carried out directly or by action on the environment, the living space or the storage enclosure in accordance with the conventional treatment methods, for example by dipping, spraying, evaporating, fogging, spreading, brushing and, in the case of reproduction material, especially in the case of seeds, also by coating with one or more layers. Especially the mixtures according to the invention, especially also the combinations of the active compounds Imidachloride and Methiocarb as well as Clothianidin and Methiocarb, are suitable for the treatment of seeds. In this way a large part of the damage produced by pests on the crop plants is already generated by the attack of the seed during storage and after the introduction of the seed into the soil as well as during and immediately after the germination of the seed. the plants. This phase is especially critical since the roots and buds of growing plants are especially sensitive and a slight deterioration can lead to the death of the whole plant. Therefore there is a particularly great interest in the seeds and germinating plants being protected by the use of suitable agents. The fight against pests by treating the seed of plants has been known for a long time and is the subject of permanent improvements. Nevertheless, during the treatment of the seeds, a series of problems that can not always be solved satisfactorily. In this way, the development of procedures for the protection of the seed and of the plant in germination should be sought, which make unnecessary the additional contribution of protective agents of the plants after sowing or after the outbreak of the plants. In addition, it is necessary to optimize the quantity of the active product used in such a way that the seed and the plant in germination are protected in the best possible way against the attack due to pests without, however, the plant itself being damaged by the active product used. . Especially the procedures for the treatment of the plants must also include the intrinsically insecticidal properties of the transgenic plants to achieve an optimum protection of the seed and of the plant in germination with a minimum cost in protective agents of. the plants . The present invention therefore also relates, in particular, to a process for the protection of seeds and for the protection of plants, especially of germinating plants against attack by pests, by treating the seed with an agent according to the invention. The invention also relates to the use of the agent according to the invention for the treatment of seeds for the protection of the seed and the germinating plant against pests. Furthermore, the invention relates to seeds, which have been treated with an agent according to the invention for protection against pests.

One of the advantages of the present invention is that, as a consequence of the especially systemic properties of the agent according to the invention, the treatment of the seeds with these agents not only protects the seed against pests, but also the plants that are born after the outbreak. In this way, the direct treatment of the crops at the time of sowing or shortly afterwards can be eliminated. Another advantage consists in the synergistic increase of the insecticidal activity of the agents according to the invention against the. corresponding individual products, which goes beyond the sum of the activity of both active products used individually. In this way an optimization of the quantity of the active product used is possible. In the same way it can be considered advantageous that the mixtures according to the invention can also be used in particular in the case of transgenic seeds, the plants, which come from these seeds, being able to express a protein directed against pests. By treating such seeds with the agents according to the invention, certain pests can already be controlled by the expression of the protein, for example insecticide, and, surprisingly, a synergistic complement of the activity with the agents according to the invention is produced. invention which further improves the effectiveness of the protection with the attack by the pests. The agents according to the invention are suitable for the protection of seeds of any plant variety, as already mentioned above, which is used in agriculture, in the greenhouse, in forestry, in gardening or in vineyards. Especially in this case corn seeds, peanuts, cañola, rapeseed, poppy, soya, cotton, beet (for example sugar beet and fodder beet), rice, millet, wheat, of barley, oats, rye, sunflower, or tobacco. The agents according to the invention are also suitable for the treatment of the seeds of fruit and vegetable plants as mentioned above. The treatment of corn, soya, cotton, wheat and canola seeds or rape seeds is of special significance. Thus, for example, the mixture according to the invention comprising the active compounds Methiocarb and Imidacloprid or Clothianidin and Methiocarb is suitable, especially for the treatment of corn seeds and sunflower seeds. As already indicated above, the treatment of transgenic seeds with an agent according to the invention also has a special significance. In this case, it is seeds of plants which, as a rule, contain at least one heterologous gene, which controls the expression of a polypeptide with especially insecticidal properties. The heterologous genes in the transgenic seeds can also come from microorganisms such as Bacillus, Rhizobium, Pseudomonas, Serratia, Trichoderma, Clavibacter, Glomus or Gliocladium. The present invention is especially suitable for the treatment of transgenic seeds, which contain at least one heterologous gene derived from Bacillus sp. and whose genetic product shows activity against corn kernel and / or corn hepiálid. In a particularly preferred manner, this is a heterologous gene derived from Bacillus thuringiensis. The combinations according to the invention for maize seeds are also particularly suitable in this case. Within the scope of the present invention, the agent according to the invention will be applied alone or in a suitable formulation on the seeds. Preferably the seeds will be treated in a state in which they are so stable that no deterioration occurs during the treatment. In general, the treatment of the seeds can be carried out at any time between harvesting and sowing. Usually seeds that have been separated from plants and that have been released from appendages, husks, rods, pods, wool or fruit flesh will be used.

In general, it should be taken into consideration at the time of the treatment of the seeds that the quantity of the agent according to the invention, applied to the seed and / or other additives, is selected in such a way that germination of the seeds is not impaired. or the plants that are born from them are not damaged. This must be taken into consideration above all in the case of active products that may have phytotoxic effects with certain application quantities. The agents according to the invention can be applied directly, ie without containing other components and without having been diluted. In general, it is preferred to apply the agents in the form of a suitable formulation on the seeds. Suitable formulations and methods for treating the seeds are known to those skilled in the art and have been described, for example, in the following documents: US 4,272,417 A, US 4,245,432 A, US 4,808,430 A, US 5,876,739 A, US 2003 / 0176428 Al, WO 2002/080675 Al, WO 2002/028186 A2. The active compound combinations can be transformed into the customary formulations, such as solutions, emulsions, sprayable powders, suspensions, powders, dusts, pastes, soluble powders, granules, suspension-emulsion concentrates, natural and synthetic materials impregnated with the product active, as well as microencapsulated in polymer materials.

These formulations are prepared in known manner, for example by mixing the active compounds with extenders, ie with liquid solvents and / or solid excipients, optionally with the use of surfactants, ie emulsifiers and / or dispersants and / or foam generating means. When water is used as an extender, organic solvents can be used, for example, as auxiliary solvents. Preferred liquid solvents are: aromatic hydrocarbons, such as xylene, toluene or alkylnaphthalenes, chlorinated aromatic hydrocarbons and chlorinated aliphatic hydrocarbons, such as chlorobenzenes, chloroethylenes or methylene chloride, aliphatic hydrocarbons, such as cyclohexane or paraffins, for example petroleum fractions, mineral and vegetable oils, alcohols such as butanol or glycol, as well as their ethers and esters, ketones, such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, or strongly polar solvents, such as dimethylformamide and dimethylsulfoxide as well as water. Suitable solid excipients are, for example, ammonium salts and ground natural minerals, such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth and molten synthetic minerals. , such as highly dispersed silicic acid, aluminum oxide and silicates, as solid excipients for granules are considered: for example broken and fractionated natural minerals, such as calcite, marble, pumice, sepiolite and dolomite, as well as synthetic granules of inorganic and organic flours and granulates of organic material, such as wood sawdust, coconut husk shells, corn ears and tobacco stems; Examples of suitable emulsifiers and / or foaming agents are, for example, nonionic and anionic emulsifiers, such as polyoxyethylenated esters of fatty acids, polyoxyethylenated ethers of fatty alcohols, for example, alkylaryl polyglycol ether, alkylsulfonates. , the alkylsulfates, the arylsulfonates, as well as the albumin hydrolysates; Dispersants are suitable as dispersants: for example, sulphite lignin liquors and methylcellulose. In the formulations, adhesives such as carboxymethylcellulose, natural and synthetic polymers that are powdery, granular or in the form of latex, such as gum arabic, polyvinyl alcohol, polyvinyl acetate, as well as natural phospholipids such as ceflino and lecithin, and synthetic phospholipids. Other additives can be mineral and vegetable oils.

Dyes, such as inorganic pigments, for example, iron oxide, titanium oxide, Prussian blue and organic dyes, such as alizarin dyes, azo dyes and metal phthalocyanine dyes as well as trace nutrients, such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc. The formulations contain, in general, between 0.1 and 95% by weight, preferably between 0.5 and 90% of active product. Preferably, the combinations according to the invention do not contain any other active product, in addition to Methiocarb and the said neonicotinoids The active compound combinations according to the invention can be present in their commercially available formulations as well as in the forms of application prepared from these formulations, in admixture with other active products, such as insecticides, baits, sterilants, bactericides, acaricides, nematicides, fungicides, growth regulators or herbicides. Insecticides include, for example, esters of phosphoric acid, carbamates, esters of carbonic acid, chlorinated hydrocarbons, phenylureas, products prepared by means of microorganisms and the like. Particularly favorable mixing components are, for example, the following: Fungicides: Aldimorph, Apropylfos, Apropylfos-potassium, Andoprim, Anilazin, Azaconazole, Azoxystrobin, Benalaxyl, Benodanil, Benomyl, Benzamacril, Benzamacryl-isobutyl, Bialaphos, Binapacryl, Biphenyl, Bitertanol, Blasticidin-S, Bromuconazole, Bupirimat, Buthiobat, Polysulfide Calcium, Capsimycin, Captafol, Captan, Carbendazim, Carboxin, Carvon, Chinomethionat (Chinobenthionat), Chlobenthiazon, Chlorfenazole, Chloroneb, Chloropicrin, Chlorothalonil, Chlozolinat, Clozylacon, Cufraneb, Cymoxanil, Cyproconazole, Cyprodinil, Cyprofuram, Debacarb, Dichlorophen, Diclobutrazol, Diclofluanid, Diclo ezin, Dicloran, Diethofencarb, Difenoconazole, Dimethirimol, Di ethomorph, Diniconazole, Diniconazole-M, Dinocap, Diphenylamin, Dipyrithione, Ditalimphos, Dithianon, Dodemorph, Dodine, Drazoxolon, Ediphenphos, Epoxiconazole, Etaconazole, Ethirimol, Etridiazole, Famoxadon, Fenapanil, Fenarimol, Fenbuconazole, Fenfuram, Fenitropan, Fenpiclonil, Fenpropidin, Fenpropimorph, Fentinacetat, Fentinhydroxyd, Ferba m, F-erimzon, Fluazinam, Flumetover, Fluoromide, Fluquinconazole, Flurprimidol, Flusilazole, Flusulfamid, Flutolanil, Flutriafol, Folpet, Fosetyl-aluminum, Fosetyl-sodium, Fthalid, Fuberidazole, Furalaxyl, Furametpyr, Furcarbonil, Furcona-zol, Furconazol- cis, Furmecyclox, Guazatin, hexachlorobenzene, Hexaconazole, Hy exazol, Imazalil, Imibenconazole, Iminoctadin, I inoctadinealbesilat, Iminoctadinetriacetat, Iodocarb, Ipconazole, Iprobenfos (PPI), Iprodione, Irumamycin, Isoprothiolan, Isovaledione, Kasugamycin, Kresoxim-methyl, copper preparations , such as: copper hydroxide, copper naphthenate, copper oxychloride, copper sulfate, copper oxide, copper oxine and Bordeaux mixture, Mancopper, Mancozeb, Maneb, Meferimzone, Mepanipyrim, Mepronil, Metalaxyl, Metconazole, Methasulfocarb, Methfuroxam, Metiram, Metomeclam, Metsulfovax, Mildiomycin, Myclobutanil, Myclozolin, nickel dimethyldithiocarbamate, Nitrothal-isopropyl, Nuarimol, Ofurace, Oxadixyl, Oxamocarb ', Oxolinicacid, Oxyc Arboxi, Oxyfenthiin, Paclobutrazol, Pefurazoat, Penconazole, Pencycuron, Phosdiphen, Pimaricin, Piperalin, Polyoxin, Polyoxorim, Probenazole, Prochloraz, Procymidon, Propamocarb, Propanosine-sodium, Propiconazole, Propineb, Pyrazophos, Pyrifenox, Pyrimethanil, Pyroquilon, Pyroxyfur, Quinconazole, Quintozen (PCNB), Sulfur and Sulfur Preparations, Tebuconazole, Tecloftalam, Tecnazen, Tetcyclacis, Tetraconazole, Thiabendazole, Thicyofen, Thifluzamide, Thiophanate-methyl, Thiram, Thioxymid, Tolclofos-methyl, Tolylfluanid, Triadimefon, Triadi enol, Triazutilus, Triazoxid, Trichlamid, Tricyclazole, Tridemorph, Triflumizol, Triforin, Triticonazole, Uniconazole, Validamycin A, Vinclozolin, Viniconazole, Zarilamide, Zineb, Ziram as well as Dagger G, OK-8705, OK-8801, a- (1, 1-dimethylethyl) -β- (2-phenoxyethyl) -1H-1, 2,4-triazole-1-ethanol, a- (2,4-dichlorophenyl) -β-fluoro-b-propyl-1H-1,2,4-triazole-1-ethanol, a- (2, 4-dichlorophenyl) ) -β-methoxy-a-methyl-lH-1,2,4-triazole-1-ethanol, a- (5-methyl-1,3-dioxan-5-yl) -β- [[4- (trifluoromethyl) ) -phenyl] -methylene] -1H-1,2,4-triazole-1-ethanol, (5RS, 6RS) -6-hydroxy-2,2,7,7-tetramethyl-5- (1H-1, 2) , 4-triazol-1-yl) -3-octanone, (E) - - (methoxyimino) -N-methyl-2-phenoxy-phenylacetamide,. { 2-methyl-l- [[[1- (4-methylphenyl) -ethyl] -amino] -carbonyl] -propyl} 1-isopropyl carbamidate, 1- (2,4-dichlorophenyl) -2- (1H-1,2,4-triazol-1-yl) -ethanone-0- (phenylmethyl) -oxime, 1- (2-methyl) -l-naphthalenyl) -lH-pyrrole-2, 5-dione, 1- (3,5-dichlorophenyl) -3- (2-propenyl) -2,5-pyrrolidinedione, 1- [(diiodomethyl) -sulfonyl] - 4-methyl-benzene, 1- [[2- (2, 4-dichlorophenyl) -1, 3-dioxolan-2-yl] -methyl] -1H-imidazole, 1- [[2- (4-chlorophenyl) - 3-phenyloxyranyl] -methyl] -lH-1,2,4-triazole, 1- [1- [2- [(2, -dichlorophenyl) -methoxy] -phenyl] -ethenyl] -1H-imidazole, 1-methyl -5-nonyl-2- (phenylmethyl) -3-pyrrolidinol, 2 ', 6'-dibromo-2-methyl-4' -trifluoromethoxy-4'-trifluoro-methyl-1,3-thiazole-5-carboxanilide, , 2-dichloro-N- [1- (4-chlorophenyl) -ethyl] -l-ethyl-3-methyl-cyclopropanecarboxamide, 2,6-dichloro-5- (methylthio) -4-pyrimidinyl-thiocyanate, 2 , 6-dichloro-N- (4-trifluoromethylbenzyl) -benzamide, 2-dichloro-N- [[4- (trifluoromethyl) -phenyl] -methyl] -benzamide, 2- (2,3,3-triyode-2) -propenyl) -2H-tetrazole, 2- [(1-methylethyl) -sulfonyl] -5- (trichloro ethyl) -1,3,4-diaz ol, 2- [[6-deoxy-4-0- (4-O-methyl-β-D-glycopyranosyl) - -D-glucopyranosyl] -amino] -4-methoxy-lH-pyrrolo [2, 3-d ] pyrimidine-5-carbonitrile, 2-aminobutane, 2-bromo-2- (bromoethyl) -pentandinitrile, 2-chloro-N- (2,3-dihydro-1, 1,3-trimethyl-lH-inden-4) -yl) -3-pyridinecarboxamide, 2-chloro-N- (2,6-dimethylphenyl) -N- (isothiocyanatomethyl) -acetamide, 2-phenylphenol (OPP), 3,4-dichloro-1- [4- (difluoromethoxy ) -phenyl] -1H-pyrrole-2,5-dione, 3,5-dichloro-N- [cyano [(1-methyl-2-propynyl) -oxy] -methyl] -benzamide, 3- (1, 1) -dimethylpropyl) -l-oxo-lH-inden-2-carbonitrile, 3- [2- (4-chlorophenyl) -5-ethoxy-3-isoxazolidinyl] -pyridine, 4-chloro-2-cyan-N, N- dimethyl-5- (4-methylphenyl) -1H-imidazole-1-sulfonamide, 4-methyl-tetrazolo [1, 5-a] quinazolin-5 (4H) -one, 8- (1, 1-dimethylethyl) -N -ethyl-N-propyl-1,4-dioxaspiro [4, 5] de-can-2-methanamine, 8-hydroxyquinoline sulfate, 2- [(phenylamino) -carbonyl] -hydrazide of 9H-xanten-9- acid carboxylic, bis- (1-methylethyl) -3-methyl-4- [(3-methylbenzoyl) -oxy] -2,5-thio-fendica rboxylate, cis-l- (4-chlorophenyl) -2- (1H-1,2,4-triazol-1-yl) -cycloheptanol, cis-4- [3- [4- (1,1-dimethylpropyl) hydrochloride] ) -phenyl-2-methylpropyl] -2,6-dimethyl-morpholine, [(4-chlorophenyl) -zo] ethyl cyanoacetate, potassium bicarbonate, Methantethrathiol-sodium salt, 1- (2,3-dihydro-2) , Methyl 2-dimethyl-lH-inden-1-yl) -lH-imide-zol-5-carboxylate, N- (2,6-dimethylphenyl) -N- (5-isoxazolylcarbonyl) -DL-alaninate methyl, N- (chloroacetyl) -N- (2,6-dimethylphenyl) -DL-alaninate-of-methyl, N- (2,3-dichloro-4-hydroxyphenyl) -1-methyl-cyclohexanecarboxamide, N- (2,6) -dimethylphenyl) -2-methoxy-N- (tetra-hydro-2-oxo-3-furanyl) -acetamide, N- (2,6-dimethylphenyl) -2-methoxy-N- (tetrahydro-2-oxo-3) -thienyl) -acetamide, N- (2-chloro-4-nitrophenyl) -4-methyl-3-nitro-benzenesulfonamide, N- (4-cyclohexylphenyl) -1,4,5,6-tetrahydro-2-pyrimidinamine, N- (4-hexylphenyl) -1,4,5,6-tetrahydro-2-pyrimidinamine, N- (5-chloro-2-methylphenyl) -2-methoxy-N- (2-oxo-3-oxazolidinyl) - acetamide, N- (6-methoxy) -3-pyrid inyl) -cyclopropanecarboxamide, N- [2, 2, 2-trichloro-l- [(chloroacetyl) -amino] -ethyl] -benzamide, N- [3-chloro-4,5-bis- (2-propynyloxy) - phenyl] -N1-methoxy-methan-imidamide, N-formyl-N-hydroxy-DL-alanine, sodium salt, [2- (dipropylamino) -2-oxoethyl] -ethylphosphoramidothioate 0.0-diethyl, phenylpropylphosphoramidothioate O- methyl-S-phenyl, S-methyl 1,2,3-benzothiadiazole-7-carbothioate, spiro [2 H] -1-benzopyran-2, 1 '(3'H) -isobenzofuran] -3'-one. Bactericides: Bronopol, Dichlorophen, Nitrapyrin, nickel dimethyldithiocarbamate, yucca asuga, Octhilinon, furanocarboxylic acid, Oxytetracyclin, Probenazol, Streptocin, Tecloftalam, copper sulfate and other copper preparations. Insecticides / acaricides / ne aidates: Abamectin, Acephate, Acetamiprid, Acrinathrin, Alanycarb, Aldicarb, Aldoxycarb, Alpha-cyper ethrin, Alphamethrin, Amitraz, Avermectin, AZ 60541, Azadirachtin, Azamethiphos, Azinphos A, Azinphos M, Azocyclotin, Bacillus popilliae, Bacillus sphaericus, Bacillus subtilis, Bacillus thuringiensis, Baculoviren, Beauveria bassiana, Beauveria tenella, Bendiocarb, Benfuracarb, Bensultap, Benzoximate, Betacyfluthrin, Bifenazate, Bifenthrin, Bioethanomethrin, Biopermethrin, Bistrifluron, BPMC, Bro ophos A, Bufencarb, Buprofezin, Butathiophos, Butocarboxim , Butylpyridaben, Cadusafos, Carbaryl, Carbofuran, Carbophenothion, Carbosulfan, Cartap, Chloethocarb, Chlorethoxyphos, Chlorfenapyr, Chlorfenvinphos, Chlorfluazuron, Chlorphophos, Chlorpyrifos, Chlorpyrifos M, Chlovaporthrin, Chromafenozide, Cis-Resmethrin, Cispermethrin, Clocythrin, Cloethocarb, Clofentezine, Clothianidine , Cyanophos, Cycloprene, Cycloprothrin, Cyfluthrin, Cyhalothrin, Cyhexatin, Cypermet hrin, Cyromazine, Deltamethrin, Demeton M, Demeton S, Demeton-S-methyl, Diafenthiuron, Diazinon, Dichlorvos, Dicofol, Diflubenzuron, Dimethoat, Di ethylvinphos, Diofenolan, Disulfoton, Docusat-sodium, Dofenapyn, Eflusilanate, Emamectin, Empenthrin, Endosulfan , Entomopfthora spp., Esfenvalerate, Ethiophencarb, Ethion, Ethoprophos, Etofenprox, Etoxazole, Etrimphos, Fenamiphos, Fenazaquin, Fenbutatin oxide, Fenitrothion, Fenothiocarb, Fenoxacr, Fenoxycarb, Fenpropathrin, Fenpyrad, Fenpyrithrin, Fenpyroximate, Fenvalerate, Fipronil, Fluazinam, Fluazuron, Flubrocythrinate, Flucycloxuron, Flucythrinate, Flufenoxuron, Flumethrin, Flutenzine, Fluvalinate, Fonophos, Fosmethilan, Fosthiazate, Fubfenprox, Furathiocar-b, granulovirus, Halofenozide, HCH, Heptenophos, Hexaflumuron, Hexythiazox, Hydroprene, Imidacloprid, Indoxacarb, Isazophos, Isofenphos, Isoxathion, Ivermectin, nuclear polyhedrovirus, Lambda-cyhalothrin, Lufenuron, Malathion, Mecarbam, Metaldehyd, Metha idophos, Metharhizium anisop liae, Metharhizium flavoviride, Methidathion, Methiocarb, Methoprene, Methomyl, Methoxyfenozide, Metolcarb, Metoxadiazone, Mevinphos, Milbemectin, Milbemycin, Monocrotophos, Naled, Nitenpyram, Nithiazine, Novaluron, Omethoat, Oxamyl, Oxydemethon M, Paecilomyces fu osoroseus, Parathion A, Parathion M, Permethrin, Phenthoat, Phorat, Phosalone, Phosmet, Phosphamidon, Phoxim, Pirimicarb, Pirimiphos A, Pirimiphos M, Profenofos, Promecarb, Propargite, Propoxur, Prothiophos, Prothoat, Pymetrozine, Pyraclofos, Pyresmethrin, Pyrethrum, Pyridaben, Pyridathion, Pyrimidifen, Pyriproxyfen, Quinalphos, Ribavirin, Salithion, Sebufos, Silafluofen, Spinosad, Spirodiclofen, Sulfotep, Sulprofos, Tau-Fluvalinate, Tebufenozide, Tebufenpyrad, Tebupirimiphos, Teflubenzuron, Tefluthrin, Temephos, Temivinphos, Terbufos, Tetrachlorvinphos, Tetradifon Theta-cypermethrin, Thiacloprid, Thiamethoxa , Thiapronil, Thiatriphos, Thiocyclam hydrogen oxalate, Thiodicarb, Thiofanox, Thuringiensin, Tralocythrin, Tralomet hrin, Triarathene, Triazamate, Triazophos, Triazuron, Trichlophenidine, Trichlorfon, Triflumuron, Trimethacarb, Vamidothion, Vaniliprole, Verticillium lecanii, YI 5302, Zeta-cypermethrin, Zolaprofos, as well as (lR-cis) - [5- (phenylmethyl) -3 -furanyl] -methyl-3- [(dihydro-2-oxo-3 (2H) -furanylidene) -methyl] -2,2-dimethylcyclopropanecarboxylate, (3-phenoxyphenyl) -methyl-2,2,3,3-tetramethylcyclopropanecarboxylate , 1- [(2-chloro-5-thiazolyl) methyl] tetrahydro-3,5-dimethyl-N-nitro-1,3,5,5-triazin-2 (1H) -imine, 2- (2-chloro-6) -fluorophenyl) -4- [4- (1,1-di ethylethyl) phenyl] -4,5-dihydro-oxazole, 2- (acetyloxy) -3-dodecyl-1, -naphthalenedione, 2-chloro-N- [ [[4- (1-phenylethoxy) -phenyl] -amino] -carbonyl] -benzamide, 2-chloro-N- [[[4- (2,2-dichloro-1,1-difluoro-ethoxy) -phenyl] -amino] -carbonyl] -benzamide, 3-methylphenyl propylcarbamate, 4- [4- (4 -ethoxyphenyl) -4-methylpentyl] -l-fluoro-2-phenoxy-benzene, 4-chloro-2- (1,1-dimethylethyl) -5- [[2- (2,6-dimethyl-4-phenoxyphenoxy)) ethyl] -thio] -3 (2H) -pyridazinone, 4-chloro-2- (2-chloro-2-methylpropyl) -5 - [(6-iodo-3-pyridinyl) ethoxy] -3 (2H) -pyridazinone, 4-Chloro-5- [(6-chloro-3-pyridinyl) methoxy] -2- (3,4-dichlorophenyl) -3 (2H) -pyridazinone, Bacillus thuringiensis strain EG-2348, [2-benzoyl-1-] (l, l-dimethyl) -benzoic acid hydrazide, 2,2-dimethyl-3- (2,4-dichlorophenyl) -2-oxo-l-oxaspiro [4.5] dec-3-en-4-yl butanoate , [3- [(6-chloro-3-pyridinyl) methyl] -2-thiazolidinylidene] -cianamide, dihydro-2- (nitromethylene) -2H-1,3-thiazine-3 (4H) -carboxaldehyde, [2- [[1,6-dihydro-6-oxo-l- (phenylmethyl) -4-pyridazinyl] oxy] ethyl] -carbamic acid ethyl ester, N- (3,4,4-trifluoro-l-oxo-3-butenyl) -glycine, N- (4-chlorophenyl) -3- [4- (difluoromethoxy) phenyl] -4,5-dihydro-4- phenyl-lH-pyrazole-l-carboxamide, N-methyl-N '- (1-methyl-2-propenyl) -1, 2-hydrazindicarbotioamide, N-methyl-N' -2-propeni1-1, 2-hydrazindicarbotioamide, [2- (Dipropylamino) -2-oxoethyl] -ethyl-phosphoramidothioate 0.0-diethyl. A mixture with other known active ingredients, such as herbicides or with fertilizers and growth regulators is also possible. The combinations of the active compounds according to the invention can also be present, when used as insecticides, in their customary formulations in commerce as well as in the application forms prepared from these formulations in a mixture with synergists. The synergists are compounds by which the effect of the active product is increased, without the added synergist having to be active in itself. The active product content of the application forms, prepared from the usual commercial formulations, can vary within wide limits. The concentration in active product of the application forms can be from 0.0000001 to 95% by weight of active product, preferably between 0.0001 and 1% by weight. The application is carried out in a usual manner adapted to the application forms. When used against hygiene pests and stored products, the active product is characterized by an excellent residual effect on wood and clay as well as a good alkali stability on whitewashed supports.

The combinations of the active compounds according to the invention are not only active against plant pests, hygiene and stored products, but also in the field of veterinary medicine against animal parasites (ectoparasites) such as hard ticks, soft ticks, scabies mites, migratory mites, flies (suckers and mincers), fly parasitic larvae, lice, hair nits, feathered nits and fleas. The combinations of the active compounds according to the invention are also suitable for the control of arthropods, which attack animals useful in agriculture such as, for example, cows, lambs, goats, horses, pigs, donkeys, camels, buffalos. , rabbits, chickens, turkeys, ducks, geese, bees, other domestic animals such as, for example, dogs, cats, game birds, aquarium fish as well as so-called test animals, such as, for example, hamsters, guinea pigs, rats and mice. Through the fight against these arthropods death cases and yield reductions (in the case of meat, milk, wool, skins, eggs, honey, etc.) will be avoided, so that by using the active products in accordance with the invention is possible a more economical and simple maintenance of the animals. The application of the combinations of the active compounds according to the invention is carried out in the veterinary field in a known manner by enteral administration in the form of, for example, tablets, capsules,. drinks, dragees, granules, pastes, bous, by means of the procedure through the feed-through food, of suppositories, by parenteral administration, such as, for example, by injection (intramuscular, subcutaneous, intravenous, intraperitoneal and the like ), implants, by nasal application, by application through the skin in the form, for example of immersion or bath (Dippen), spray (Spray), surface watering (Pour-on and Spot-on), washing, powdered as well as with the aid of molded bodies containing the active product such as collars, ear tags, tail tags, limb bands, halters, marking devices, etc. When they are used for domestic livestock, poultry, pets etc. the active ingredients can be used as formulations (for example powders, emulsions, agents capable of spreading), containing the active compounds in amounts of 1 to 80% by weight, directly or after dilution of 100 to 10,000 times or can be used as a solvent. chemical bath Furthermore, it has been found that the combinations of the active compounds according to the invention show a high insecticidal effect against the insects that destroy industrial materials. Industrial materials will be understood in the present context as non-living materials, such as, preferably, materials. synthetics, glues, glues, paper and cardboard, leather, wood and woodworking products and paints. In a very special way, the materials to be protected against attack by insects are made of wood and wood products. By wood and wood processing products, which can be protected by means of the agents according to the invention or of the mixtures containing them, it should be understood, for example: construction wood, wooden beams, railway sleepers , parts for bridges, ribs for boats, wooden vehicles, boxes, pallets, containers, telephone poles, wooden coverings, wooden windows and doors, wooden plywood, plywood boards, carpentry works or wood products, which are application, in a very general way, at home or in the construction industry.

The combinations of active products can be used as such, in the form of concentrates or customary formulations in general such as powders, granules, solutions, suspensions, emulsions or pastes. Said formulations can be prepared in a manner known per se, for example by mixing the active ingredients with at least one solvent or diluent, emulsifier, dispersant and / or binder or binding agent, water repellent, optionally drying agents and stabilizers. against UV and, if necessary, dyes and pigments as well as other processing aids. The insecticidal agents or concentrates to be used for the protection of wood and wood materials contain the active compound according to the invention in a concentration of 0.0001 to 95% by weight, in particular 0.001 to 60% by weight. weight. The amounts of the agents or concentrates used depend on the type and origin of the insects and the environment. The optimum application quantities can be determined respectively by means of series of tests prior to the application. In general, however, it is sufficient to employ from 0.0001 to 20% by weight, preferably from 0.001 to 10% by weight of the active compound, referring to the material to be protected. The solvent and / or diluent used is a solvent or a mixture of organochemical solvents and / or a solvent or mixture of organo-chemical, oleaginous or oil-like solvents which are difficult to volatile and / or a solvent or mixture of polar organochemical solvents. and / or water and, if appropriate, an emulsifier and / or humectant. The organochemical solvents used are preferably oleaginous or oleaginous solvents, with an evaporation index above 35 and a flame point above 30 ° C, preferably above 45 ° C. By way of such water-insoluble, oil-soluble or oleaginous-type solvents which are difficult to volatile, corresponding mineral oils or their aromatic fractions or mixtures of solvents containing mineral oils, preferably benzine for tests, petroleum and / or alkylbenzene, will be used. Advantageously, mineral oils with a boiling range of 170 to 220 ° C, benzine for tests with a boiling range of 170 to 220 ° C, spindle oil with a boiling range of 250 to 350 ° C, petroleum or aromatic hydrocarbons with a boiling range of 160 to 280 ° C, terpene oil and the like. In a preferred embodiment, liquid aliphatic hydrocarbons having a boiling range of 180 to 210 ° C or a high-boiling mixture of aromatic and aliphatic hydrocarbons with a boiling range of 180 to 220 ° C and / or oil for use are used. spindles and / or monochloronaphtalin, preferably α-monochloronaphthalene. Organic solvents, which are difficult to volatile, oleaginous or oil-based, with an evaporation index above 35 and with a flame point above 30 ° C, preferably above 45 ° C, can be partially replaced by solvents light or medium volatility organochemicals, provided that the solvent mixture has an evaporation index above 35 and a flame point above 30 ° C, preferably above 45 ° C, and that the insecticidal-fungicidal mixture is soluble or emulsifiable in this mixture of solvents. According to a preferred embodiment, a part of the solvent or mixture of organochemical solvents or a solvent or mixture of aliphatic, polar organochemical solvents will be replaced. Preference is given to using aliphatic organochemical solvents containing hydroxyl groups and / or ester groups and / or ether groups, such as, for example, glycol ethers, esters or the like. As organochemical binders, synthetic resins and / or setting drying oils will be used within the scope of the present invention., known per se, water-dilutable and / or soluble or dispersible or emulsifiable in the organo-chemical solvents used, especially binders consisting of or containing acrylic resin, a vinyl resin, for example polyvinyl acetate, polyester resin, resin polycondensation or polyaddition, polyurethane resin, resin to the udica or. either modified alkyd resin, phenolic resin, hydrocarbon resin such as indeno-coumaron resin, silicone resin, vegetable drying and / or drying oils and / or physical drying binders based on a natural and / or synthetic resin. The synthetic resin used as a binder can be used in the form of an emulsion, dispersion or solution. Bitumen or bituminous substances up to 10% by weight can also be used as binders. In a complementary manner, colorants, pigments, water-repelling agents, odor correctors and inhibitors or anticorrosive agents known per se and the like can be used. It is preferred to use at least one alkyd resin or a modified alkyd resin and / or a drying vegetable oil in the medium or concentrate according to the invention as an organochemical binder. Preferably, alkyd resins having an oil content of greater than 45% by weight, preferably from 50 to 68% by weight, are preferably used according to the invention. The aforementioned binder can be partially or totally replaced by a fixing agent (mixture) or by a plasticizer (mixture). These additives should avoid volatilization of active products as well as crystallization or precipitation. They preferably replace 0.01 to 30% of the binder (based on 100% of the binder used). The plasticizers are of the chemical class of phthalic acid esters such as dibutyl, dioctyl or benzylbutyl phthalate, phosphoric acid esters, such as tributyl phosphate, adipic acid esters, such as di- (D-adipate). 2-ethylhexyl), stearates such as butyl stearate or allyl stearate, oleates such as butyl oleate, glycerin ethers or high molecular weight glycol ethers, glycerin esters as well as esters of p-toluenesulfonic acid. Fixative agents are chemically based on polyvinylalkyl ethers such as polyvinyl methyl ether or ketones such as benzophenone, ethylenebenzophenone. As the solvent or diluent, water, optionally mixed with one or more of the aforementioned solvents or diluents, emulsifier and organochemical dispersants, is particularly suitable. Especially effective protection of the wood is achieved by impregnation processes on an industrial scale, for example vacuum, double vacuum or pressure processes. The agents ready for application can, if necessary, also contain other insecticides and, if necessary, also one or more fungicides. At the same time the combinations of active products according to the invention can be used for the protection against the proliferation of organisms on objects, especially of ship bodies, screens, networks, constructions, port installations and signaling installations, which come into contact with seawater or brackish water. The proliferation of organisms caused by Oligochaeten sessiles, such as calcareous tubulánides as well as by bivalves and types of the group ledamorfos (limpets), such as various types of Lepas and Scalpellum, or due to types of the balanomorphic groups (sea acorns), such as species of Balanus or Pollicipes, increases the resistance to friction of ships and leads, as a result, due to increased energy consumption and, in addition, frequent stays in dry dock, a significant increase in operating costs . In addition to the proliferation caused by algae, for example Ectocarpus sp. and Ceramium sp., has a special significance in particular the proliferation due to the sessile groups of entomostráceos, which are grouped under the name of Cirripedia (cirripedes). The active compound combinations according to the invention are also suitable for the control of animal pests, especially against insects, arachnids and mites, which occur in closed enclosures, such as, for example, houses, factory buildings, offices, cabins of motor vehicles and the like. They can be used for the control of these pests alone or in combination with other active and auxiliary products in insecticide products for the home. They are active against sensitive and resistant types as well as against all stages of development. The application in the field of domestic insecticides can be carried out in combination with other suitable active ingredients such as phosphoric acid esters, carbamates, pyrethroids, growth regulators or active products of other known classes of insecticides. The application is carried out in aerosols, non-pressurized spray agents for example pumping atomizers or sprayers, automatic fogging devices, fog generators, foams, gels, products for evaporators with cellulose or plastic evaporation platelets, evaporators for liquids, gel or membrane evaporators, propeller-driven evaporators, energy-dissipating or passive evaporation systems, moth-proof papers, moth-proof sachets and anti-moth gels formed of granules or powders, in spreadable baits or stations with baits. When the combinations of the active products are used, according to the invention, the application quantities can vary within wide limits according to the type of the application. When treating parts of the plants, the application amounts of the active ingredients are generally between 0.1 and 10,000 g / ha, preferably between 10 and 1,000 g / ha. The good insecticidal effect of the active compound combinations according to the invention can be deduced from the following examples. While the active products individually have flaws in their effect, the combinations show an effect that goes beyond the simple sum of the effects. Formula for the calculation of the degree of destruction of a combination formed by two active products. The expected effect for a given combination of two compounds can be calculated as follows (see COLBY, S.R .: "Calculating Synergistic and Antagonistic Response of Herbicide Combinations"; Weeds 15, pages 20-22, 1967); if X = is the degree of destruction,. expressed in%, of the untreated controls, when the active product A is used with an application amount of m ppm, Y = is the degree of destruction, expressed in%, of the untreated controls, when the active product is used B with an application amount of n ppm, E = is the degree of destruction, expressed in%, of the untreated controls, when active products A and B are used with application amounts of m and n ppm, then? v E = X + Y- -Í2 - 100 If the actual degree of insecticidal destruction is greater than that calculated, then the combination will be superadditive in terms of its destruction, ie a synergistic effect is present. In this case, the degree of destruction, actually observed, must be greater than the calculated value, in accordance with the formula previously indicated for the degree of destruction (E) expected. EXAMPLE A Assay with Myzus Solvent: 7 Parts by Weight of Dimethylformamide. Emulsifier: 2 parts by weight of alkylaryl polyglycol ether. To obtain a suitable preparation of active compound, 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier and the concentrate is diluted with water, containing emulsifier, to the desired concentration.

Cabbage leaves (Brassica olerácea), which are strongly attacked by the green leafhopper of the peach leaf (Myzus persicae), are treated by immersion in the preparation of the active compound of the desired concentration. After the desired time the destruction is determined in percentage. In this case 100% means that all the aphids were destroyed; 0% means that no aphids were destroyed. The determined destruction values are calculated according to the Coiby formula. In this test it shows, for example, the following combination of active products, in accordance with the present application, an activity reinforced in a synergistic manner in comparison with the active products applied individually (tables Al to A3): Table Al Insects harmful to plants Test with Myzus persicae Active product Concentration Degree of destruction in ppm in% after 6 days Methiocarb 100 50 Acetamiprid 0.16 30 Methiocarb + Acetamiprid (625: 1) gef. * Ber. ** 100 + 0.16 85 65 * gef. = activity found ** ber. = activity calculated with the Coiby formula Table A2 Harmful insects for plants Test with Myzus persicae Active product Concentration Degree of destruction in ppm in% after 1 day Methiocarb 20 5 Clothianidin 0,16 0 Methiocarb + Clothianidin (125: 1) gef. * ber. ** 20 + 0.16 70 * gef. = activity found ** ber. = activity calculated with the formula of Coiby Table A3 Insects harmful to plants Test with Myzus persicae Active product Concentration Degree of destruction in ppm in% after 1 day Methiocarb 20 Thiacloprid 0.8 20 Methiocarb + Thiacloprid (25: 1) gef . * ber. ** 20 + 0.8 75 24 * gef. = activity found ** ber. = activity calculated with the Coiby formula Example B Test with Plutella xylostella (normally sensitive strain) Solvent: 7 parts by weight of dimethylformamide. Emulsifier: 2 parts by weight of alkylaryl polyglycol ether. To obtain a suitable preparation of active compound, 1 part by weight of the active compound is mixed with the indicated amounts of solvent and emulsifier and the concentrate is diluted with water, containing emulsifier, to the desired concentration. Cabbage leaves (Brassica olerácea) are treated by immersion in the preparation of active compound of the desired concentration, and are covered with caterpillars of the cabbage moth (Plutella xylostella, normally sensitive strain), as long as the leaves are still wet. After the desired time the destruction is determined in %. In this case 100% means that all caterpillars have been destroyed; 0% means that none of the caterpillars has been destroyed. Destruction values, determined, are calculated according to the Coiby formula (see sheet 1). In this test the following combination of active products, in accordance with the present application, shows a reinforced activity in a synergistic manner in comparison with the active products used individually: Table B Insects harmful to plants Test with Plutella xylostella (normally sensitive strain) Active Product Concentration Degree of destruction in ppm in% after 3 days Methiocarb 20 0 Thiacloprid 20 0 Methiocarb + Thiacloprid (1: 1) gef. * Ber. ** 20 + 20 35 0 * gef. = activity found ** ber. = activity calculated with the formula of Coiby It is stated that, in relation to this date, the best method known by the applicant to carry out the aforementioned invention is that which is clear from the present description of the invention.

Claims (15)

2. Having described the invention as above, the content of the following claims is claimed as property: 1. Agent, characterized in that it encompasses a mixture with synergistic Methiocarb activity of the formula and, at least, a compound chosen from Thiacloprid, Thiamethoxam, Acetamiprid, Nitenpyram and Dinotefuran. 2. Agent, characterized in that it comprises a synergistic mixture of Methiocarb and Thiacloprid.
3. 3. Agent, characterized in that it comprises a synergistic mixture of Methiocarb and Thiamethoxam.
4. 4. Agent, characterized in that it comprises a synergistic mixture of Methiocarb and Acetamiprid.
5. 5. Agent, characterized in that it comprises a synergistic mixture of Methiocarb and Nitenpyram.
6. 6. Agent, characterized in that it comprises a synergistic mixture of Methiocarb and Dinotefuran.
7. 7. - Agent, characterized in that it comprises a synergistic mixture of Methiocarb, Clothianidin, and Imidacloprid.
8. 8. Agent according to one of claims 1 to 7, characterized in that the weight ratio between Methiocarb and the mixture component is between 100 to 1 to 1 to 50.
9. 9.- Use of an agent comprising a mixture with synergistic activity of Imidacloprid and Methiocarb for the treatment of seeds.
10. 10. Use of an agent comprising a mixture with synergistic activity of Clothianidin and Methiocarb for the treatment of seeds.
11. 11. Use of the agents according to one of claims 1 to 8, for the control of animal pests.
12. 12. Use of agents according to one of claims 1 to 8, for the treatment of seeds.
13. 13. - Procedure for the control of pests, characterized in that agents are allowed to act, according to one of claims 1 to 8, on pests and / or on their environment.
14. 14. Process for obtaining pesticidal agents, characterized in that a mixture is combined with synergistic activity, according to one of claims 1 to 8 with extenders and / or surfactants.
15. 15. Seeds, characterized in that they are treated with an agent according to one of claims 1 to 8 or with an agent comprising a mixture with synergistic activity of Imidacloprid and Methiocarb or Clothianidin and Methiocarb.