MXPA06011023A - Herbicide-safener combination - Google Patents
Herbicide-safener combinationInfo
- Publication number
- MXPA06011023A MXPA06011023A MXPA/A/2006/011023A MXPA06011023A MXPA06011023A MX PA06011023 A MXPA06011023 A MX PA06011023A MX PA06011023 A MXPA06011023 A MX PA06011023A MX PA06011023 A MXPA06011023 A MX PA06011023A
- Authority
- MX
- Mexico
- Prior art keywords
- alkyl
- halogen
- alkoxy
- case
- iii
- Prior art date
Links
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 157
- 239000001257 hydrogen Substances 0.000 claims abstract description 111
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 111
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 106
- 150000002367 halogens Chemical class 0.000 claims abstract description 106
- 125000003545 alkoxy group Chemical group 0.000 claims abstract description 82
- 150000002431 hydrogen Chemical class 0.000 claims abstract description 67
- 150000001875 compounds Chemical class 0.000 claims abstract description 65
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 58
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 49
- 125000001188 haloalkyl group Chemical group 0.000 claims abstract description 38
- 125000004414 alkyl thio group Chemical group 0.000 claims abstract description 29
- 125000003282 alkyl amino group Chemical group 0.000 claims abstract description 25
- 125000000753 cycloalkyl group Chemical group 0.000 claims abstract description 24
- 150000003839 salts Chemical class 0.000 claims abstract description 24
- 125000003342 alkenyl group Chemical group 0.000 claims abstract description 23
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 17
- 125000004453 alkoxycarbonyl group Chemical group 0.000 claims abstract description 16
- 125000004448 alkyl carbonyl group Chemical group 0.000 claims abstract description 15
- 125000004644 alkyl sulfinyl group Chemical group 0.000 claims abstract description 14
- 125000004390 alkyl sulfonyl group Chemical group 0.000 claims abstract description 14
- 125000003118 aryl group Chemical group 0.000 claims abstract description 14
- 125000004663 dialkyl amino group Chemical group 0.000 claims abstract description 13
- 125000004457 alkyl amino carbonyl group Chemical group 0.000 claims abstract description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 10
- 125000004183 alkoxy alkyl group Chemical group 0.000 claims abstract description 7
- 125000003710 aryl alkyl group Chemical group 0.000 claims abstract description 5
- 125000002947 alkylene group Chemical group 0.000 claims abstract description 4
- 125000001316 cycloalkyl alkyl group Chemical group 0.000 claims abstract description 4
- MWKVXOJATACCCH-UHFFFAOYSA-N isoxadifen-ethyl Chemical group C1C(C(=O)OCC)=NOC1(C=1C=CC=CC=1)C1=CC=CC=C1 MWKVXOJATACCCH-UHFFFAOYSA-N 0.000 claims description 158
- 239000000729 antidote Substances 0.000 claims description 77
- 239000004009 herbicide Substances 0.000 claims description 73
- 229940075522 antidotes Drugs 0.000 claims description 72
- 239000000203 mixture Substances 0.000 claims description 39
- 239000013543 active substance Substances 0.000 claims description 38
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 32
- 238000009472 formulation Methods 0.000 claims description 23
- 125000000304 alkynyl group Chemical group 0.000 claims description 21
- 239000000463 material Substances 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 20
- 230000009261 transgenic effect Effects 0.000 claims description 14
- MKQSWTQPLLCSOB-UHFFFAOYSA-N benzyl 2-chloro-4-(trifluoromethyl)-1,3-thiazole-5-carboxylate Chemical compound N1=C(Cl)SC(C(=O)OCC=2C=CC=CC=2)=C1C(F)(F)F MKQSWTQPLLCSOB-UHFFFAOYSA-N 0.000 claims description 12
- YNQSILKYZQZHFJ-UHFFFAOYSA-N R-29148 Chemical compound CC1CN(C(=O)C(Cl)Cl)C(C)(C)O1 YNQSILKYZQZHFJ-UHFFFAOYSA-N 0.000 claims description 11
- RFMQOHXWHFHOJF-UHFFFAOYSA-N cyano thiocyanate Chemical compound N#CSC#N RFMQOHXWHFHOJF-UHFFFAOYSA-N 0.000 claims description 10
- PFJJMJDEVDLPNE-UHFFFAOYSA-N Benoxacor Chemical compound C1=CC=C2N(C(=O)C(Cl)Cl)C(C)COC2=C1 PFJJMJDEVDLPNE-UHFFFAOYSA-N 0.000 claims description 8
- YRMLFORXOOIJDR-UHFFFAOYSA-N Dichlormid Chemical compound ClC(Cl)C(=O)N(CC=C)CC=C YRMLFORXOOIJDR-UHFFFAOYSA-N 0.000 claims description 8
- HRRDCWDFRIJIQZ-UHFFFAOYSA-N naphthalene-1,8-dicarboxylic acid Chemical compound C1=CC(C(O)=O)=C2C(C(=O)O)=CC=CC2=C1 HRRDCWDFRIJIQZ-UHFFFAOYSA-N 0.000 claims description 8
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 8
- DOFZAZXDOSGAJZ-UHFFFAOYSA-N disulfoton Chemical compound CCOP(=S)(OCC)SCCSCC DOFZAZXDOSGAJZ-UHFFFAOYSA-N 0.000 claims description 7
- 239000000654 additive Substances 0.000 claims description 6
- 239000003905 agrochemical Substances 0.000 claims description 6
- 150000008064 anhydrides Chemical class 0.000 claims description 6
- OPGCOAPTHCZZIW-UHFFFAOYSA-N diethyl 1-(2,4-dichlorophenyl)-5-methyl-4h-pyrazole-3,5-dicarboxylate Chemical group CCOC(=O)C1(C)CC(C(=O)OCC)=NN1C1=CC=C(Cl)C=C1Cl OPGCOAPTHCZZIW-UHFFFAOYSA-N 0.000 claims description 6
- COYBRKAVBMYYSF-UHFFFAOYSA-N heptan-2-yl [(5-chloroquinolin-8-yl)oxy]acetate Chemical group C1=CN=C2C(OCC(=O)OC(C)CCCCC)=CC=C(Cl)C2=C1 COYBRKAVBMYYSF-UHFFFAOYSA-N 0.000 claims description 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 6
- 244000045561 useful plants Species 0.000 claims description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- 235000013311 vegetables Nutrition 0.000 claims description 4
- 239000002671 adjuvant Substances 0.000 claims description 3
- JCHMGYRXQDASJE-UHFFFAOYSA-N metcamifen Chemical compound C1=CC(NC(=O)NC)=CC=C1S(=O)(=O)NC(=O)C1=CC=CC=C1OC JCHMGYRXQDASJE-UHFFFAOYSA-N 0.000 claims description 3
- NYDKNJDNBUFWRJ-UHFFFAOYSA-N n-[4-(dimethylcarbamoylamino)phenyl]sulfonyl-2-methoxybenzamide Chemical compound COC1=CC=CC=C1C(=O)NS(=O)(=O)C1=CC=C(NC(=O)N(C)C)C=C1 NYDKNJDNBUFWRJ-UHFFFAOYSA-N 0.000 claims description 3
- OAWUUPVZMNKZRY-UHFFFAOYSA-N cyprosulfamide Chemical compound COC1=CC=CC=C1C(=O)NS(=O)(=O)C1=CC=C(C(=O)NC2CC2)C=C1 OAWUUPVZMNKZRY-UHFFFAOYSA-N 0.000 claims 1
- -1 cyano, thiocyanato Chemical group 0.000 abstract description 143
- 125000006193 alkinyl group Chemical group 0.000 abstract 2
- 241000196324 Embryophyta Species 0.000 description 91
- 150000003254 radicals Chemical class 0.000 description 75
- 230000002363 herbicidal effect Effects 0.000 description 28
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 22
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 17
- 125000000623 heterocyclic group Chemical group 0.000 description 16
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 16
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 15
- 239000002253 acid Substances 0.000 description 14
- 125000004438 haloalkoxy group Chemical group 0.000 description 14
- 235000010469 Glycine max Nutrition 0.000 description 13
- 244000068988 Glycine max Species 0.000 description 12
- 125000004093 cyano group Chemical group *C#N 0.000 description 12
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 12
- 125000005843 halogen group Chemical group 0.000 description 12
- 229910052760 oxygen Inorganic materials 0.000 description 12
- 125000005842 heteroatom Chemical group 0.000 description 11
- 239000000126 substance Substances 0.000 description 11
- 229910052717 sulfur Inorganic materials 0.000 description 11
- 125000004494 ethyl ester group Chemical group 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 125000006272 (C3-C7) cycloalkyl group Chemical group 0.000 description 9
- 240000008042 Zea mays Species 0.000 description 9
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 9
- 235000013339 cereals Nutrition 0.000 description 9
- 125000001309 chloro group Chemical group Cl* 0.000 description 9
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 9
- 239000000843 powder Substances 0.000 description 9
- 240000007594 Oryza sativa Species 0.000 description 8
- 235000007164 Oryza sativa Nutrition 0.000 description 8
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 description 8
- ICJSJAJWTWPSBD-UHFFFAOYSA-N cloquintocet Chemical compound C1=CN=C2C(OCC(=O)O)=CC=C(Cl)C2=C1 ICJSJAJWTWPSBD-UHFFFAOYSA-N 0.000 description 8
- 125000001153 fluoro group Chemical group F* 0.000 description 8
- 239000008187 granular material Substances 0.000 description 8
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 8
- 235000009566 rice Nutrition 0.000 description 8
- 239000002689 soil Substances 0.000 description 8
- 244000075850 Avena orientalis Species 0.000 description 7
- 235000007319 Avena orientalis Nutrition 0.000 description 7
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 7
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 7
- 239000000460 chlorine Substances 0.000 description 7
- 229910052801 chlorine Inorganic materials 0.000 description 7
- 235000005822 corn Nutrition 0.000 description 7
- 125000002147 dimethylamino group Chemical group [H]C([H])([H])N(*)C([H])([H])[H] 0.000 description 7
- 230000008569 process Effects 0.000 description 7
- 125000006413 ring segment Chemical group 0.000 description 7
- 229920006395 saturated elastomer Polymers 0.000 description 7
- 229910052708 sodium Inorganic materials 0.000 description 7
- 239000011734 sodium Substances 0.000 description 7
- 125000001424 substituent group Chemical group 0.000 description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- 240000002791 Brassica napus Species 0.000 description 6
- 235000004977 Brassica sinapistrum Nutrition 0.000 description 6
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 6
- 244000062793 Sorghum vulgare Species 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 125000001559 cyclopropyl group Chemical group [H]C1([H])C([H])([H])C1([H])* 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 150000002148 esters Chemical class 0.000 description 6
- 125000002485 formyl group Chemical group [H]C(*)=O 0.000 description 6
- 238000005507 spraying Methods 0.000 description 6
- 125000000229 (C1-C4)alkoxy group Chemical group 0.000 description 5
- 239000005631 2,4-Dichlorophenoxyacetic acid Substances 0.000 description 5
- 241000219310 Beta vulgaris subsp. vulgaris Species 0.000 description 5
- 229920000742 Cotton Polymers 0.000 description 5
- 244000299507 Gossypium hirsutum Species 0.000 description 5
- 235000007340 Hordeum vulgare Nutrition 0.000 description 5
- 240000005979 Hordeum vulgare Species 0.000 description 5
- 235000007238 Secale cereale Nutrition 0.000 description 5
- 244000082988 Secale cereale Species 0.000 description 5
- 235000021536 Sugar beet Nutrition 0.000 description 5
- 235000021307 Triticum Nutrition 0.000 description 5
- 241000209140 Triticum Species 0.000 description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Substances CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 5
- 150000007513 acids Chemical class 0.000 description 5
- 150000001335 aliphatic alkanes Chemical group 0.000 description 5
- IWEDIXLBFLAXBO-UHFFFAOYSA-N dicamba Chemical compound COC1=C(Cl)C=CC(Cl)=C1C(O)=O IWEDIXLBFLAXBO-UHFFFAOYSA-N 0.000 description 5
- 230000012010 growth Effects 0.000 description 5
- 235000019713 millet Nutrition 0.000 description 5
- 239000011814 protection agent Substances 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 238000003892 spreading Methods 0.000 description 5
- 230000007480 spreading Effects 0.000 description 5
- 125000000565 sulfonamide group Chemical group 0.000 description 5
- WMMQJAQJAPXWDO-UHFFFAOYSA-N (4-chlorophenyl) n-methylcarbamate Chemical compound CNC(=O)OC1=CC=C(Cl)C=C1 WMMQJAQJAPXWDO-UHFFFAOYSA-N 0.000 description 4
- YIVXMZJTEQBPQO-UHFFFAOYSA-N 2,4-DB Chemical compound OC(=O)CCCOC1=CC=C(Cl)C=C1Cl YIVXMZJTEQBPQO-UHFFFAOYSA-N 0.000 description 4
- OHXLAOJLJWLEIP-UHFFFAOYSA-N 2-(dichloromethyl)-2-methyl-1,3-dioxolane Chemical compound ClC(Cl)C1(C)OCCO1 OHXLAOJLJWLEIP-UHFFFAOYSA-N 0.000 description 4
- IAJOBQBIJHVGMQ-UHFFFAOYSA-N 2-amino-4-[hydroxy(methyl)phosphoryl]butanoic acid Chemical compound CP(O)(=O)CCC(N)C(O)=O IAJOBQBIJHVGMQ-UHFFFAOYSA-N 0.000 description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 4
- VYNOULHXXDFBLU-UHFFFAOYSA-N Cumyluron Chemical compound C=1C=CC=CC=1C(C)(C)NC(=O)NCC1=CC=CC=C1Cl VYNOULHXXDFBLU-UHFFFAOYSA-N 0.000 description 4
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 4
- 239000005562 Glyphosate Substances 0.000 description 4
- 240000007049 Juglans regia Species 0.000 description 4
- 235000009496 Juglans regia Nutrition 0.000 description 4
- 240000000111 Saccharum officinarum Species 0.000 description 4
- 235000007201 Saccharum officinarum Nutrition 0.000 description 4
- 238000005520 cutting process Methods 0.000 description 4
- 235000013399 edible fruits Nutrition 0.000 description 4
- 125000004430 oxygen atom Chemical group O* 0.000 description 4
- 238000009331 sowing Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 235000020234 walnut Nutrition 0.000 description 4
- 125000005913 (C3-C6) cycloalkyl group Chemical group 0.000 description 3
- MCNOFYBITGAAGM-UHFFFAOYSA-N 2,2-dichloro-1-[5-(furan-2-yl)-2,2-dimethyl-1,3-oxazolidin-3-yl]ethanone Chemical compound C1N(C(=O)C(Cl)Cl)C(C)(C)OC1C1=CC=CO1 MCNOFYBITGAAGM-UHFFFAOYSA-N 0.000 description 3
- 239000002794 2,4-DB Substances 0.000 description 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- VRODIKIAQUNGJI-UHFFFAOYSA-N 5-phenyl-4,5-dihydro-1,2-oxazole-3-carboxylic acid Chemical compound C1C(C(=O)O)=NOC1C1=CC=CC=C1 VRODIKIAQUNGJI-UHFFFAOYSA-N 0.000 description 3
- 125000000882 C2-C6 alkenyl group Chemical group 0.000 description 3
- 239000005504 Dicamba Substances 0.000 description 3
- 239000005561 Glufosinate Substances 0.000 description 3
- 244000020551 Helianthus annuus Species 0.000 description 3
- 235000003222 Helianthus annuus Nutrition 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 3
- 239000005574 MCPA Substances 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 240000003768 Solanum lycopersicum Species 0.000 description 3
- 235000002595 Solanum tuberosum Nutrition 0.000 description 3
- 244000061456 Solanum tuberosum Species 0.000 description 3
- WHKUVVPPKQRRBV-UHFFFAOYSA-N Trasan Chemical compound CC1=CC(Cl)=CC=C1OCC(O)=O WHKUVVPPKQRRBV-UHFFFAOYSA-N 0.000 description 3
- 125000002252 acyl group Chemical group 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 125000005225 alkynyloxycarbonyl group Chemical group 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- MXWJVTOOROXGIU-UHFFFAOYSA-N atrazine Chemical compound CCNC1=NC(Cl)=NC(NC(C)C)=N1 MXWJVTOOROXGIU-UHFFFAOYSA-N 0.000 description 3
- 239000003995 emulsifying agent Substances 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 239000000417 fungicide Substances 0.000 description 3
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 description 3
- 229940097068 glyphosate Drugs 0.000 description 3
- 125000000262 haloalkenyl group Chemical group 0.000 description 3
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 3
- 239000002917 insecticide Substances 0.000 description 3
- ITGSCCPVERXFGN-UHFFFAOYSA-N isoxadifen Chemical compound C1C(C(=O)O)=NOC1(C=1C=CC=CC=1)C1=CC=CC=C1 ITGSCCPVERXFGN-UHFFFAOYSA-N 0.000 description 3
- 125000004433 nitrogen atom Chemical group N* 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 239000000575 pesticide Substances 0.000 description 3
- 230000000885 phytotoxic effect Effects 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000004659 sterilization and disinfection Methods 0.000 description 3
- 239000004575 stone Substances 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 3
- SODPIMGUZLOIPE-UHFFFAOYSA-N (4-chlorophenoxy)acetic acid Chemical compound OC(=O)COC1=CC=C(Cl)C=C1 SODPIMGUZLOIPE-UHFFFAOYSA-N 0.000 description 2
- 125000006652 (C3-C12) cycloalkyl group Chemical group 0.000 description 2
- AJFKCJRMHHBFNS-UHFFFAOYSA-N 1-(2,4-dichlorophenyl)-5-phenylpyrazole-3-carboxylic acid Chemical compound C=1C=C(Cl)C=C(Cl)C=1N1N=C(C(=O)O)C=C1C1=CC=CC=C1 AJFKCJRMHHBFNS-UHFFFAOYSA-N 0.000 description 2
- DYPQUENOGZXOGE-UHFFFAOYSA-N 1-(4-chlorophenyl)-2,2,2-trifluoroethanone Chemical compound FC(F)(F)C(=O)C1=CC=C(Cl)C=C1 DYPQUENOGZXOGE-UHFFFAOYSA-N 0.000 description 2
- QWWHRELOCZEQNZ-UHFFFAOYSA-N 2,2-dichloro-1-(1-oxa-4-azaspiro[4.5]decan-4-yl)ethanone Chemical compound ClC(Cl)C(=O)N1CCOC11CCCCC1 QWWHRELOCZEQNZ-UHFFFAOYSA-N 0.000 description 2
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 2
- 125000004201 2,4-dichlorophenyl group Chemical group [H]C1=C([H])C(*)=C(Cl)C([H])=C1Cl 0.000 description 2
- WNTGYJSOUMFZEP-UHFFFAOYSA-N 2-(4-chloro-2-methylphenoxy)propanoic acid Chemical compound OC(=O)C(C)OC1=CC=C(Cl)C=C1C WNTGYJSOUMFZEP-UHFFFAOYSA-N 0.000 description 2
- AXHCGXRBOHBEQA-UHFFFAOYSA-N 2-(5-chloro-2-methylphenoxy)acetic acid Chemical compound CC1=CC=C(Cl)C=C1OCC(O)=O AXHCGXRBOHBEQA-UHFFFAOYSA-N 0.000 description 2
- JAXUXISKXAOIDD-UHFFFAOYSA-N 2-(5-chloroquinolin-8-yl)oxypropanedioic acid Chemical compound C1=CN=C2C(OC(C(=O)O)C(O)=O)=CC=C(Cl)C2=C1 JAXUXISKXAOIDD-UHFFFAOYSA-N 0.000 description 2
- CAAMSDWKXXPUJR-UHFFFAOYSA-N 3,5-dihydro-4H-imidazol-4-one Chemical compound O=C1CNC=N1 CAAMSDWKXXPUJR-UHFFFAOYSA-N 0.000 description 2
- IWEDIXLBFLAXBO-UHFFFAOYSA-M 3,6-dichloro-2-methoxybenzoate Chemical compound COC1=C(Cl)C=CC(Cl)=C1C([O-])=O IWEDIXLBFLAXBO-UHFFFAOYSA-M 0.000 description 2
- SIYAHZSHQIPQLY-UHFFFAOYSA-N 4-(4-chlorophenoxy)butanoic acid Chemical compound OC(=O)CCCOC1=CC=C(Cl)C=C1 SIYAHZSHQIPQLY-UHFFFAOYSA-N 0.000 description 2
- HBAQYPYDRFILMT-UHFFFAOYSA-N 8-[3-(1-cyclopropylpyrazol-4-yl)-1H-pyrazolo[4,3-d]pyrimidin-5-yl]-3-methyl-3,8-diazabicyclo[3.2.1]octan-2-one Chemical class C1(CC1)N1N=CC(=C1)C1=NNC2=C1N=C(N=C2)N1C2C(N(CC1CC2)C)=O HBAQYPYDRFILMT-UHFFFAOYSA-N 0.000 description 2
- 240000006995 Abutilon theophrasti Species 0.000 description 2
- 235000005254 Allium ampeloprasum Nutrition 0.000 description 2
- 240000006108 Allium ampeloprasum Species 0.000 description 2
- 244000291564 Allium cepa Species 0.000 description 2
- 235000002732 Allium cepa var. cepa Nutrition 0.000 description 2
- 235000013479 Amaranthus retroflexus Nutrition 0.000 description 2
- 244000237956 Amaranthus retroflexus Species 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 235000003911 Arachis Nutrition 0.000 description 2
- 244000105624 Arachis hypogaea Species 0.000 description 2
- 235000006463 Brassica alba Nutrition 0.000 description 2
- 244000140786 Brassica hirta Species 0.000 description 2
- 240000007124 Brassica oleracea Species 0.000 description 2
- 235000003899 Brassica oleracea var acephala Nutrition 0.000 description 2
- 235000011301 Brassica oleracea var capitata Nutrition 0.000 description 2
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 description 2
- 125000003601 C2-C6 alkynyl group Chemical group 0.000 description 2
- 244000144786 Chrysanthemum segetum Species 0.000 description 2
- 235000005470 Chrysanthemum segetum Nutrition 0.000 description 2
- 240000007154 Coffea arabica Species 0.000 description 2
- NNYRZQHKCHEXSD-UHFFFAOYSA-N Daimuron Chemical compound C1=CC(C)=CC=C1NC(=O)NC(C)(C)C1=CC=CC=C1 NNYRZQHKCHEXSD-UHFFFAOYSA-N 0.000 description 2
- 244000000626 Daucus carota Species 0.000 description 2
- 235000002767 Daucus carota Nutrition 0.000 description 2
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Abstract
A herbicide-safener combination contains (A) one or more compounds of formula (I) or their salts, and (B) one or more safeners. In the formula (I), A stands for nitrogen or a CR11 group, R11 designating hydrogen, alkyl, halogen and haloalkyl;R1 stands for hydrogen or an optionally substituted residue from the series composed of alkyl, alkoxy, alkoxyalkyl, alkenyl, alkinyl, cycloalkyl, cycloalkylalkyl, aralkyl and aryl;R2 stands for hydrogen, halogen or optionally halogen-substituted alkyl, alkoxy, alkylthio, alkylamino or dialkylamino having 1-6 carbon atoms;R3 stands for hydrogen, halogen or optionally halogen-substituted alkyl, alkoxy, alkylthio, alkylamino or dialkylamino having 1-6 carbon atoms;R4-R7 independently stand for hydrogen, halogen, cyano, thiocyanato or optionally halogen-substituted alkyl, alkoxy, alkylthio, alkylsulfinyl, alkylsulfonyl, alkylamino, alkylcarbonyl, alkoxycarbonyl, alkylaminocarbonyl having 1-3 carbon atoms;and R8 stands for hydrogen, halogen, cyano, thiocyanato or optionally halogen-substituted alkyl, alkoxy, alkylthio, alkylsulfinyl, alkylsulfonyl, alkylamino, alkylcarbonyl, alkoxycarbonyl, alkylaminocarbonyl having 1-3 carbon atoms. In the above-mentioned residues, each of the alkyl and alkylene groups can have 1-6 C atoms, each of the alkenyl and alkinyl groups can have 2-6 C atoms, each of the cycloalkyl groups can have 3-6 C atoms and each of the aryl groups can have 6-10 C atoms.
Description
COMBINATION OF HERBICIDES AND ANTIDOTES
DESCRIPTIVE MEMORY
The invention relates to the technical sector of plant protection agents (crop protection), in particular combinations of herbicides and antidotes, which are outstandingly suitable for use against harmful plants in the presence of crops of useful plants. From the U.S. patent document US 5,476,936 herbicidal active substances are known, which combat a broad spectrum of weeds. However, these active substances are not in part fully compatible with some important cultivated plants, such as cereals. Therefore, they can not be used in some crops in a way that ensures the desired broad herbicidal activity against harmful plants. It was the object of the present invention to find herbicidal agents, in which the selectivity of the aforementioned herbicides is increased against important cultivated plants. The problem posed by this mission is solved in a surprising way by the combination of herbicides and antidotes of the present invention. The subject of the present invention is a combination of herbicides and antidotes, which contains (A) one or more compounds of the formula (I) or their salts
where it represents nitrogen or a CR 11 grouping
with R, 11 hydrogen, alkyl, halogen and haloalkyl, R 1 represents hydrogen or an optionally substituted radical selected from the group consisting of alkyl, alkoxy, alkoxyalkyl, alkenyl, alkynyl, cycloalkyl, cycloalkylalkyl, aralkyl and aryl, R 2 represents hydrogen, halogen, or alkyl, alkoxy, alkylthio, alkylamino or dialkylamino, in each case with 1 to 6 carbon atoms, optionally substituted in each case with halogen, R3 represents hydrogen, halogen, or alkyl, alkoxy, alkylthio, alkylamino or dialkylamino, each case with 1 to 6 carbon atoms, optionally substituted in each case with halogen, R4-R7 independently of one another, represent hydrogen, halogen, cyano, thiocyanate, or alkyl, alkoxy, alkylthio, alkylsulfinyl, alkylsulfonyl, alkylamino, alkylcarbonyl , alkoxycarbonyl, alkylaminocarbonyl, in each case with 1 to 3 carbon atoms, optionally substituted in each case with halogen no, R8 represents hydrogen, halogen, cyano, thiocyanate, or alkyl, alkoxy, alkylthio, alkylsulfinyl, alkylsulfonyl, alkylamino, alkylcarbonyl, alkoxycarbonyl or alkylaminocarbonyl, each having 1 to 3 carbon atoms, optionally substituted in each case with halogen , which may contain, in the aforementioned radicals, the alkyl and alkylene groups in each case of 1 to 6 carbon atoms, the alkenyl and alkynyl groups in each case of 2 to 6 carbon atoms, the cycloalkyl groups in each case at 6 C atoms and the aryl groups in each case 6 or 10 C atoms; Y
(B) One or several antidotes. The combinations of herbicides and antidotes ading to the invention can contain other additional components, eg active substances of other crop protection agents and / or additives and / or formulation aids customary in the protection of plants can be used, or together with these.
The herbicides (A) and the antidotes (B) can be applied in a known manner, eg in common (for example as a joint formulation or as a tank mixture) or else in an out-of-phase manner over time (in English Spiitting = dissociation), eg on plants, parts of plants, seeds of plants or the surface on which plants grow. It is possible, for example, to apply the individual active substances or the combination of herbicides and antidotes in several portions (sequential application), eg ading to pre-emergence applications, followed by applications after the outbreak, or ading to early applications after the outbreak, followed by medium or late applications after the outbreak. In this case, the application in common or close to the time of the active substances of the respective combination is preferred. It is also possible to apply the individual active substances or the combination of herbicides and antidotes for the treatment of the seeds. The aforementioned formula (I) covers all stereoisomers and their mixtures, in particular also racemic mixtures, and - provided that enantiomers are possible - the enantiomer which in each case is biologically effective. The compounds of the formula (I) and their salts are known, as well as their preparation, for example from US Pat. No. 5,476,936, which is hereby incorporated by reference in the present specification. As the herbicide (A), preferred are compounds of the formula (I) and their salts, in which A represents nitrogen or a CH group, R 1 represents hydrogen or a radical optionally substituted with halogen, selected from the group consisting of alkyl, alkoxy, alkoxyalkyl , alkenyl and alkynyl in each case with up to 3 carbon atoms, R 2 represents hydrogen, halogen or alkyl, alkoxy, alkylthio, alkylamino or dialkylamino each with 1 to 3 carbon atoms in the alkyl radicals, optionally substituted with halogen, R3 represents hydrogen, halogen or alkyl, alkoxy, alkylthio, alkylamino or dialkylamino each having 1 to 3 carbon atoms in the alkyl radicals, each optionally substituted with halogen, R 4 -R 7 independently of others represent hydrogen, halogen, cyano, thiocyanate or alkyl, alkoxy, alkylthio, alkylsulfinyl, alkylsulfonyl, alkylamino, alkylcarbonyl, alkoxycarboni or alkylaminocarbonyl each having 1 to 3 carbon atoms in the alkyl radicals, each optionally substituted with halogen, R8 represents hydrogen, halogen, cyano, thiocyanate or alkyl, alkoxy, alkylthio, alkylsulfinyl, alkylsulfonyl, alkylamino, alkylcarbonyl , alkoxycarbonyl or alkylaminocarbonyl in each case with 1 to 3 carbon atoms in the alkyl radicals, each possibly substituted by halogen. As the herbicide (A), salts which are obtained according to customary processes from compounds of the formula (I) and bases, such as, for example, the hydroxides, hydrides, amides and carbonates of sodium, potassium or calcium, the alkanolatos CC of sodium or potassium, ammonia, alkyl CC-amines, di- (alkyl C? -C4) -aminas or tri- (alkyl CrC4) -aminas. As the herbicide (A), compounds of the formula (I) and their salts, in which A represents nitrogen or a CH group, R 1 represent hydrogen, methyl, ethyl, methoxy, methoxymethyl or ethoxy, R 2 represents hydrogen, chlorine, methyl are especially preferred. , ethyl, trifluoromethyl, methoxy, ethoxy, difluoromethoxy, methylthio, methylamino or dimethylamino, R 3 represents hydrogen, chlorine, methyl, ethyl, trifluoromethyl, methoxy, ethoxy, difluoromethoxy, methylthio, methylamino or dimethylamino, R 4 -R 7 independently of each other , they represent hydrogen, fluoro, chloro, cyano, or methyl, methylthio, methylisulfinyl, methylsulfonyl, methoxycarbonyl and ethoxycarbonyl, preferably hydrogen, in each case optionally substituted with chloro or fluoro, R8 represents hydrogen, fluoro, chloro, bromo, cyano or methyl, methoxy, ethoxy, methylthio, ethylthio, methylisulfinyl, ethiisulfinyl, methylsulfonyl, ethylsulfonyl, methyl- or dimethylamino, preferably hydrogen, in each case optionally substituted with chlorine or fluoro. As the herbicide (A), especially preferred are compounds of the formula (I) and their salts, in particular their alkali metal salts, in which A represents nitrogen, R 1 represents hydrogen or methyl, R 2 represents hydrogen, chlorine, methyl, ethyl, trifluoromethyl. , methoxy, ethoxy, difluoromethoxy, methylthio, methylamino or dimethylamino, R3 represents hydrogen, chloro, methyl, ethyl, trifluoromethyl, methoxy, ethoxy, difluoromethoxy, methylthio, methylamino or dimethylamino, R4-R7 represent hydrogen, R8 represents hydrogen. As the herbicide (A), compounds of the formula (I) and their salts, in particular their alkali metal salts, in which A represents a CH group, R 1 represents hydrogen or methyl, R 2 represents hydrogen, chlorine, methyl, are also especially preferred. ethyl, trifluoromethyl, methoxy, ethoxy, difluoromethoxy, methylthio, methylamino or dimethylamino, R3 represents hydrogen, chloro, methyl, ethyl, trifluoromethyl, methoxy, ethoxy, difluoromethoxy, methylthio, methylamino or dimethylamino, R4-R7 represent hydrogen, R8 represents hydrogen.
The definitions of radicals discussed above, or exposed at preferred ranges, can be combined arbitrarily with each other, therefore also among the preferred ones indicated. The hydrocarbyl radicals mentioned in the definitions of radicals, such as alkyl, alkenyl or alkynyl, also in combinations with heteroatoms, such as in alkoxy, alkylthio, haloalkyl or alkylamino, are linear or branched also when this is not expressly indicated. From the compounds of the general formula (I), salts, eg metal salts such as alkali metal salts (eg Na, K) or alkaline earth metal salts (e.g. Ca, Mg) or ammonium salts or amines. Such salts are obtained in a simple manner according to customary methods of salt formation, for example by dissolving or dispersing a compound of the formula (I) in an appropriate diluting agent, such as, for example, methylene chloride, acetone. , tert-butyl-methyl-ether or toluene, and addition of an appropriate base. The salts can then be isolated - optionally after prolonged stirring - by evaporation or filtration with suction. Examples of compounds used as herbicide (A) are mentioned in the following Table 1, in which the following abbreviations are used: P.f .: = Melting point Desc. or D. = with decomposition (+) = The indicated melting point (pf) refers in each case to the corresponding sodium salt, that is to say the corresponding compound, in which the hydrogen of the group -S02-NH- is replaced for sodium. Table 1: Examples of compounds of the formula (I) with R 4 = R 5 = R 6 = R 7 = R 8 = H:
The herbicides (A) inhibit the enzyme acetolactatosynthase (ALS) and thus the synthesis of proteins in plants. The amount consumed of the herbicides (A) can vary over a wide range with external conditions such as temperature, humidity, the type of herbicide used, for example, between 0.001 g and 500 g of SA / ha (SA / ha means in this case hereinafter "active substance per hectare" = referred to the active substance at 100%). In the case of applications with consumed quantities of 0.01 g to 200 g of SA / ha of the herbicides (A), preferably of the compounds 1-1 to 1-145, a pre- and post-emergence process is combated. a relatively broad spectrum of harmful plants, eg annual and perennial mono- or di-cotyledonous weeds as well as undesired cultivated plants. In the case of the combinations according to the invention, the quantities consumed are generally lower, for example in the range from 0.001 g to 100 g of SA / ha, preferably 0.005 g a
50 g of SA, especially preferably from 0.01 g to 9 g of SA / ha.
The herbicides (A) are suitable for the control of harmful plants, eg in crops of useful plants, for example in economically important agricultural crops, eg agricultural crops of monocotyledonous plants such as cereals (eg wheat). , barley, rye, oats), rice, corn, millet, or agricultural crops of dicotyledonous plants such as sugar beet, rapeseed, cotton, sunflower and legumes, eg from the genera Glycine (eg Glycine max. ) such as non-transgenic Glycine max (eg conventional types such as STS types) or transgenic Glycine max (eg soybean RR or soybean LL) and their crosses), Phaseolus, Pisum, Vicia and Arachis, or vegetable crops of different botanical groups such as potato, leek, cabbage, carrot, tomato, onion, as well as permanent and plantation crops such as those of pome fruits and stone fruits, berries, vines, hevea, bananas, sugarcane, coffee, tea, citrus fruits, plantations d walnut and walnut fruits, lawns, palm crops and forest crops. For the application of the combinations of herbicides and antidotes (A) + (B) according to the invention, these crops are also preferred., use in cereals (eg wheat, barley, rye, oats), rice, corn, millet, sugar beet, sugar cane, sunflower, rapeseed and cotton is especially preferred. The combinations of herbicides and antidotes (A) + (B) can also be used in cultures of tolerant and non-tolerant mutants and tolerant and non-tolerant transgenic crops, preferably those of corn, rice, cereals, rapeseed and soybeans, e.g. eg those that are resistant to imidazolinone, atrazine, glufosinate or glyphosate herbicides.
As the antidotes contained as component (B) are meant compounds, which are suitable for reducing the phytotoxic effects of active substances of phyto-protective agents such as herbicides in the presence of cultivated plants. The antidotes (B) are preferably selected from the group consisting of: a) Compounds of formulas (II) to (IV)
(II) (lü) (IV)
wherein the symbols and indices have the following meanings n 'is a natural number from 0 to 5, preferably from 0 to
3; T is an alkane chain (Ci or C2) -diyl, which is unsubstituted or substituted with one or two alkyl radicals (CrC4) or with [(C3) alkoxy] -carbonyl; W is a divalent heterocyclic radical unsubstituted or substituted one selected from the group of heterocycles with rings of five partially unsaturated or aromatic rings with 1 to 3 ring heteroatoms of the N or O type, with at least one N atom and at most one ring atom being contained in the ring. Or, preferably a radical selected from the group formed by (W1) to (W4),
m 'is O or l; R17, R19 are, same or different, halogen, alkyl (C C), alkoxy (C C), nitro or haloalkyl (C C4); R18, R20 are, equal or different, OR24, SR24 or NR2 R25 or a saturated or unsaturated heterocycle of 3 to 7 members, with at least one N atom and with up to 3 heteroatoms, which is attached through the N with the carbonyl group existing in (II) or (III) and is unsubstituted or substituted with radicals selected from the group consisting of alkyl (C- | -C), (C4) alkoxy, or optionally substituted phenyl, so Preferred a radical of the formula OR24, NHR25 or N (CH3) 2, in particular of the formula OR24, R24 is hydrogen or an unsubstituted or substituted aliphatic hydrocarbyl radical, preferably having 1 to 18 carbon atoms in total; R25 is hydrogen, (C6) alkyl, (C6) alkoxy or substituted or unsubstituted phenyl; Rx is H, (C? -C8) alkyl, haloalkyl (C8), (C4) alkoxy-alkyl (C ^ C ^, cyano or COOR26, wherein R26 is hydrogen, alkyl (Cs), halo -alkyl (C -? - C8), alkoxy (C -? - C4) -alkyl (C -? - C4), hydroxy (C3-C6) alkyl, (C3-C12) cycloalkyl or tri-alkyl ( C? -C) -silyl, R27, R28, R29 are, same or different, hydrogen, (C8) alkyl, haloalkyl (CrC8), (C3-C12) cycloalkyl or substituted or unsubstituted phenyl; (C C4), haloalkyl (C4), alkenyl (C2-C4), haloalkenyl (C2-C4), cycloalkyl (C3-C7), preferably dichloromethyl; R22, R23 are different or different , hydrogen, alkyl (CrC4), alkenyl (C2-C), alkynyl (C2-C4), haloalkyl (CrC4), halo-alkenyl (C2-C4), alkyl (CrC4) -carbamoyl-(C1-C4) alkyl ), (C2-C4) alkenylcarbamoyl-(C1-C4) alkyl, (C1-C4) alkoxy-(C1-C4) alkyl, dioxolanyl-(C1-C4) alkyl, thiazolyl, furyl, furyl-alkyl, thienyl , piperidyl, substituted or unsubstituted phenyl, or R22 and R23 form in common a heterocyclic ring or substituted or unsubstituted, preferably an oxazolidine, thiazolidine, piperidine, morpholine, hexahydropyrimidine or benzoxazine ring; b) one or more compounds selected from the group consisting of: 1,8-naphthalic acid anhydride, methyl diphenyl methoxy acetate, 1- (2-chlorobenzyl) -3- (1-methyl-1-phenylethyl) urea (cumyluron), OO-diethyl S-2-ethylthioethyl phosphodithioate (disulfoton), 4-chlorophenyl methylcarbamate (mephenate), 0,0-diethyl-O-phenyl phosphorothioate (dietolato), 4-carboxy-3,4-acid -dihydro-2H-1-benzopyran-4-acetic acid (CL-304415, CAS-Regno: 31541-57-8), cyanomethoxyimino (phenyl) acetonitrile (cyometrinil), 1,3-dioxolan-2-ylmethoxyimin (phenyl) acetonitrile (oxabetrinyl), 0-1, 3- dioxolan-2-ylmethyl oxime of 4'-chloro-2,2,2-trifluoro-acetophenone (fluxofenim), 4,6-dichloro-2-phenylpyrimidine ( phenclorima), 2-chloro-4-trifluoromethyl-1,3-thiazole-5-benzyl carboxylate (flurazole), 2-dichloromethyl-2-methyl-1,3-dioxolane (MG-191), N- (4- methylphenyl) -N '- (1-methyl-1-phenylethyl) urea (dimron), (2,4-dichlorophenoxy) acetic acid (2,4-D), (4-chlorophenoxy) acetic acid, acid (R, S ) -2- (4-chloro-o-tolyloxy) p ropionic (mecoprop), 4- (2,4-dichlorophenoxy) butyric acid (2,4-DB), (4-chloro-o-tolyloxy) acetic acid (MCPA), 4- (4-chloro-o-tolyloxy) ) butyric, 4- (4-chlorophenoxy) butyric acid, 3,6-dichloro-2-methoxybenzoic acid (dicamba), 3,6-dichloro-2-methoxybenzoate of 1- (ethoxycarbonyl) ethyl (lactidiclor) and their salts and esters, preferably from (C C8); b) N-acyl sulfonamides of the formula (V) and their salts,
wherein R 30 denotes hydrogen, a hydrocarbyl radical, a hydrocarbyloxy radical, a hydrocarbyl thio radical or a heterocyclyl radical, wherein each of the 4 radicals mentioned above is ultimately unsubstituted or substituted by one or more radicals, Equal or different, selected from the group consisting of halogen, cyano, nitro, amino, hydroxy, carboxy, formyl, carboxamido, sulfonamido and radicals of the formula -Za-Ra, wherein each hydrocarbyl part is preferably 1 at 20 C atoms and that a R 30 radical containing C, including substituents, preferably has from 1 to 30 C atoms; R31 means hydrogen or (C) alkyl, preferably hydrogen, or R30 and R31 in common with the group of the formula -CO-N- signifies the radical of a saturated or unsaturated ring of 3 to 8 members; R 32 is identical or different, meaning halogen, cyano, nitro, amino, hydroxy, carboxy, formyl, CONH2, S02NH2 or a radical of the formula -Zb-R b; R33 means hydrogen or (C4) alkyl, preferably hydrogen; R34 which is the same or different, means halogen, cyano, nitro, amino, hydroxy, carboxy, CHO, CONH2, S02NH2 or a radical of the formula -Zc-Rc; Ra means a hydrocarbyl radical or a heterocyclyl radical, each of the two radicals mentioned being ultimately unsubstituted or substituted with one or more radicals or different, selected from the group consisting of halogen, cyano, nitro, amino, hydroxy , mono- and di- [alkyl (C? -C)] -amino, or an alkyl radical, in which several, preferably 2 or 3, non-contiguous CH2 groups are each replaced by an oxygen atom; . Rb, Rc or different, mean a hydrocarbyl radical or a heterocyclyl radical, it being realized that each of the two radicals mentioned in the last term is unsubstituted or substituted by one or several radicals, the same or different, selected from the group formed by halogen, cyano, nitro, amino, hydroxy, phosphoryl, halogen-alkoxy (CrC), mono- and di- [alkyl (CC)] - amino, or an alkyl radical, in which several, preferably 2 or 3, noncontiguous CH2 groups are replaced in each case by an oxygen atom; Za means a divalent group of the formulas -O-, -S-, -CO-, -CS-, -CO-O-, -CO-S-, -O-CO-, -S-CO-, -SO -, -S02-, -NR * -, -CO-NR * -, -NR * -CO-, -S02-NR * - or -NR * -S02-, being carried out that the link indicated to the right of the respective group divalent is the bond with the radical Ra, and it is realized that the R * in the radicals mentioned last, independently of each other, mean in each case H, (C 1 -C 4) alkyl or halo (C 4 C) alkyl; Zb, Zc independently of each other, means a direct bond or a divalent group of the formulas -O-, -S-, -CO-, -CS-, -CO-O-, -CO-S-, -O- CO-, -S-CO-, -SO-, -S02-, -NR * -, -CO-NR * -, -NR * -CO-, -S02-NR * - or -NR * -S02-, it being realized that the link indicated to the right of the respective divalent group is the link with the radical Rb or RQ respectively, and it is realized that the R * in the radicals mentioned last, independently of each other, mean in each case H, alkyl (C C4) or haloalkyl (C C4); n means an integer from 0 to 4, preferably 0,
1 or 2, in particular 0 or 1, and m means an integer from 0 to 5, preferably 0, 1, 2 or 3, in particular 0, 1 or 2;
d) acyl-sulphamoyl-benzoic acid amides of the general formula (VI), optionally also in the form of a salt
where X means CH or N; R35 means hydrogen, heterocyclyl or a hydrocarbyl radical, it being realized that the two radicals mentioned in the last term are optionally substituted with one or more radicals, the same or different, selected from the group consisting of halogen, cyano, nitro, amino, hydroxy, carboxy, CHO, CONH2, S02NH2 and Za-Ra; R36 means hydrogen, hydroxy, alkyl (CrC6), alkenyl (d-C6), alkynyl (C2-C6), alkoxy (CrC6), alkenyl (C2-C6) -oxi, whereby the five radicals mentioned above are ultimately optionally substituted with one or more radicals, different or different, selected from the group consisting of halogen, hydroxy, alkyl (CrC4), alkoxy (CC) and alkyl (CrC4) -thi, or R35 and R36 in common with the Nitrogen atom that carries them, mean a saturated or unsaturated ring of 3 to 8 members; R37 means halogen, cyano, nitro, amino, hydroxy, carboxy, CHO, CONH2, S02NH2 or Za-Ra;
R38 means hydrogen, (C? -C4) alkyl, (C2-C4) alkenyl or (C2-C) alkynyl; R39 means halogen, cyano, nitro, amino, hydroxy, carboxy, phosphoryl, CHO, CONH2, S02NH2 or Za-Ra; Ra means an (C2-C20) alkyl radical, whose carbon chain is interrupted once or multiplied by oxygen atoms, or means heterocyclyl or a hydrocarbyl radical, wherein the two radicals mentioned above are eventually substituted with one or several radicals, the same or different, selected from the group consisting of halogen, cyano, nitro, amino, hydroxy, mono- and di- [alkyl (CC)] -amino; Rb, Rc, which are different or different, mean an alkyl radical (C2-C or), whose carbon chain is interrupted once or multiplied by oxygen atoms, or means heterocyclyl or a hydrocarbyl radical, wherein the two radicals mentioned in FIG. The last term is optionally substituted by one or more radicals, the same or different, selected from the group consisting of halogen, cyano, nitro, amino, hydroxy, phosphoryl, haloalkoxy (CC), mono- and di- [alkyl (CC) ]-Not me; Za means a divalent unit selected from the set consisting of O, S, CO, CS, C (0) 0, C (0) S, SO, S02, NRd, C (0) NRd or S02NRd;
Zb, Zc equal or different, means a direct bond or a divalent unit selected from the set consisting of O, S, CO, CS, C (0) 0, C (0) S, SO, S02, NRd, C (0 ) NRd or S02NRd; Rd means hydrogen, (C-1-C4) alkyl or halo-alkyl (C C); r means an integer from 0 to 4; and q for the case, that X3 represents CH, means an integer from 0 to 5, and in the case that X3 represents N, it means an integer from 0 to 4; e) Compounds of the type of the amides of acyl sulphamoylbenzoic acids, for example of the following formula (VII), which are known, for example, from WO 99/16744,
eg those in which R21 is = cyclopropyl and R22 is = H (S3-1 = 4-cyclopropylaminocarbonyl-N- (2-methoxybenzoyl) benzenesulfonamide), R21 = cyclopropyl and R22 is = 5-CI (S3-2), R21 is = ethyl and R22 is = H (S3-3), R21 is = iso-propyl and R22 is = 5-CI (S3-4) and R21 is = so-propyl and R22 is = H (S3-5);
f) Compounds of the type of the N-acylsulphamoyl phenyl ureas of the formula (VIII), which are known, for example, from European patent application EP-A-365484,
in which represents a radical selected from the set formed by
oder = or RD and RD independently of one another, represent hydrogen, CrC8 alkyl, C3-C8 cycloalkyl, C3-C6 alkenyl C3-C6 alkynyl,
or alkoxy d-C substituted with C 1 alkoxy or with
RD and RD in common represent a C4-C6 alkylene bridge or a C4-C6 alkylene bridge interrupted by oxygen, sulfur, SO, S02, NH or
- N (CrC4 alkyl) -, RD represents hydrogen or CrC4 alkyl, Ra and Rb independently of each other, represent hydrogen, halogen, cyano, nitro, trifluoromethyl, C1-C4 alkyl, CrC4 alkoxy, C4 alkylthio, C4 alkyl sulfinyl, C4-alkyl sulfonyl, -COORj, -CONRkRm, -COR ", - S02NRkRm or -OSO2- C4-alkyl, or Ra and Rb in common represent a C3-C4 alkylene bridge, which may be substituted by halogen or I rent
C1-C4, or a C3-C4 alkenylene bridge, which may be substituted with halogen or C1-C4 alkyl, or a C4 alkydienylene bridge, which may be substituted with halogen or C1-C4 alkyl, and R9 and Rh independently on the other, they represent hydrogen, halogen, C -? - C alkyl, trifluoromethyl, methoxy, methylthio or -COORj, meaning
Rc hydrogen, halogen, C1-C4 alkyl or methoxy, Rd hydrogen, halogen, nitro, C1-C4 alkyl, C1-C4 alkoxy, C1-C4 alkylthio, CrC4-sulfinyl alkyl, CrC4-sulphonyl alkyl, -COORj or - CONRkRm, Re hydrogen, halogen, C1-C4 alkyl, -COOR ', trifluoromethyl or methoxy, or with Rd and Re representing in common a C3-C4 alkylene bridge, with Rf meaning hydrogen, halogen or C1-C4 alkyl, Rx and R? independently of one another, hydrogen, halogen, C4 alkyl, CC alkoxy, C1-C4 alkylthio, -COOR4, trifluoromethyl, nitro or cyano, Rj, Rk and Rm independently of each other, hydrogen or C1-C4 alkyl, Rk and Rm in common an alkylene bridge C4-C6 or a C4-C6 alkylene bridge interrupted by oxygen, NH or -N (C1-C4 alkyl) -, and Rp alkyl CrC4, phenyl, or phenyl substituted with halogen, CC alkyl, methoxy, nitro or trifluoromethyl, preferred mode 1- [4- (N-2-methoxybenzoylsulfamoyl) phenyl] -3-methylurea, 1 - [4- (N-2-methoxybenzoylsulfamoyl) phenyl] -3,3-dimethylurea, 1- [4- (N- 4,5-dimethylbenzoylsulfamoyl) phenyl] -3-methyl-lurea, 1- [4- (N-naphthoyl sulphamoyl) phenyl] -3,3-dimethylurea, including stereoisomers and the salts customary in agriculture. The combinations of herbicides and antidotes are preferred, which contain (A) an herbicidally effective amount of one or more compounds of the formula (I) or their salts, and (B) an antidotal effective amount of one or more antidotes.
An effective amount as a herbicide means in the meaning of the invention an amount of one or more herbicides, which is suitable to negatively influence the growth of the plants. An antidotally effective amount in the meaning of the invention means an amount of one or more antidotes, which is suitable for reducing the phytotoxic effect of active substances of crop protection agents (eg herbicides) in the presence of cultivated plants. Provided that nothing else is defined in particular, the following definitions are valid for the existing radicals in the formulas from (I) to (VIII) and in the subsequent formulas. The alkyl, alkoxy, haloalkyl, haloalkoxy, alkylamino and alkylthio radicals as well as the corresponding unsaturated and / or substituted radicals can in each case be linear or branched in the carbon framework. Alkyl radicals, also in the compound meanings, such as alkoxy, haloalkyl, etc., preferably have from 1 to 4 C atoms and, for example, methyl, ethyl, n- or i-propyl, -, i-, t- or 2-butyl. The alkenyl and alkynyl radicals have the meanings of the possible unsaturated radicals corresponding to the alkyl radicals; alkenyl means, for example, allyl, 1-methyl-prop-2-en-yl, 2-methyl-prop-2-en-1-yl, but-2-en-1-yl, but-3-en- 1-yl, 1-methyl-but-3-en-1-yl and 1-methyl-but-2-en-1-yl; Alkynyl means, for example, propargyl, but-2-yn-1-yl, but-3-yn-1-yl, 1-methyl-but-3-yn-1-yl. "Alkyl (C C4)" is the abbreviated designation for alkyl with 1 to 4 C atoms; the corresponding is valid for other general definitions of radicals with ranges indicated in parentheses for the possible number of C atoms. Cycloalkyl preferably means a cyclic alkyl radical with 3 to 8, preferably 3 to 7, in particular preferred with 3 to 6 C atoms, for example cyclopropyl, cyclobutyl, cyclopentyl and cyclohexyl. Cycloalkenyl and cycloalkynyl designate corresponding unsaturated compounds. Halogen means fluoro, chloro, bromo or iodo. The haloalkyl, haloalkenyl and haloalkynyl mean alkyl, alkenyl or alkynyl partially or wholly substituted with halogen, preferably with fluoro, chloro and / or bromine, in particular with fluoro or chloro, eg CF3, CHF, CH2F, CF2CF3, CH2CHFCI CCI3, CHCI2, CH2CH2CI. The haloalkoxy is, for example, OCF3, OCHF2, OCH2F, OCF2CF3, OCH2CF3 and OCH2CH2CI. The corresponding is valid for other radicals substituted with halogen. A hydrocarbyl radical can be an aromatic hydrocarbyl radical or an aliphatic hydrocarbyl radical, it being realized that an aliphatic hydrocarbyl radical is generally a saturated or unsaturated hydrocarbyl radical, linear or branched, preferably 1 to 18, particularly preferably 1 to 12 C atoms, eg alkyl, alkenyl or alkynyl. Preferably, an aliphatic hydrocarbyl radical means alkyl, alkenyl or alkynyl with up to 12 carbon atoms; the corresponding is valid for an aliphatic hydrocarbyl radical in a hydrocarbyloxy radical.
An aryl is generally a mono-, bi- or polycyclic aromatic system preferably with 6-20 C atoms, preferably with 6 to 14 C atoms, eg phenyl, naphthyl, tetrahydronaphthyl, indenyl, indanyl, pentalenyl and fluorenyl, especially phenyl. A heterocyclic ring, a heterocyclic radical or a heterocyclyl means a mono-, bi- or poly-cyclic ring system, which is saturated, unsaturated and / or aromatic, and which contains one or more, preferably 1 to 4, heteroatoms, preferably selected from the group consisting of N, S and O. Preferred are heterocycles saturated with 3 to 7 ring atoms and with one or two heteroatoms selected from the group consisting of N, O and S, wherein the chalcogens are not they are contiguous. Especially preferred are monocyclic rings with 3 to 7 ring atoms and with one heteroatom selected from the group consisting of N, O and S, as well as those of morpholine, dioxolane, piperazine, imidazoline and oxazolidine. Especially preferred saturated heterocycles are oxirane, pyrrolidone, morpholine and tetrahydrofuran. Partially unsaturated heterocycles with 5 to 7 ring atoms and with one or two heteroatoms selected from the group consisting of N, O and S are also preferred. Particularly preferred are partially unsaturated heterocycles with 5 to 6 ring atoms and with one heteroatom selected from the group consisting of N, O and S. Partially highly preferred unsaturated heterocycles are pyrazoline, imidazoline and isoxazoline. Also preferred is a heteroaryl, for example mono- or bi-cyclic aromatic heterocycles with 5 to 6 ring atoms, containing from one to four heteroatoms selected from the group consisting of N, O, S, wherein the chalcogens are not they are contiguous. Especially preferred are monocyclic aromatic heterocycles with 5 to 6 ring atoms, containing a heteroatom selected from the group consisting of N, O and S, as well as pyrimidine, pyrazine, pyridazine, oxazole, thiazole, thiadiazole, oxadiazole, pyrazole, triazole. and isoxazole. Pyrazole, thiazole, triazole and furan are very especially preferred. Substituted radicals, such as substituted hydrocarbyl radicals, eg alkyl, alkenyl, alkynyl, aryl such as phenyl and arylalkyl such as benzyl, substituted, or a substituted heterocyclyl, mean a substituted radical derived from the unsubstituted basic structure, wherein the substituents preferably mean one or more, preferably 1, 2 or 3, in the case of Cl and F also up to the maximum possible number of substituents selected from the group consisting of halogen, alkoxy, haloalkoxy, alkylthio, hydroxy, amino, nitro, carboxy, cyano, azido, alkoxycarbonyl, alkylcarbonyl, formyl, carbamoyl, mono- and di-alkylaminocarbonyl, substituted amino such as acylamino, mono- and di-alkyl-amino and alkylsulfinyl, haloalkylsulfinyl, alkylsulfonyl, haloalkylsulfonyl and, in the case of cyclic radicals, also alkyl and haloalkyl, as well as the unsaturated aliphatic radicals corresponding to the aforementioned substitutes saturated acids containing hydrocarbyl, preferably alkenyl, alkynyl, alkenyloxy and alkynyloxy. In the case of radicals with C atoms, preferred are those having from 1 to 4 C atoms, in particular 1 or 2 C atoms. Substituents selected from the group consisting of halogen, e.g. fluoro or chloro, (C 1 -C 4) alkyl, preferably methyl or ethyl, halo (C 4) alkyl, preferably trifluoromethyl, (C 1 -C 4) alkoxy, preferably methoxy or ethoxy, halo-alkoxy (C1-C4), nitro and cyano. Especially preferred in this case are methyl, methoxy and chloro substituents. A mono- or di-substituted amino means a chemically stable radical, selected from the group consisting of the substituted amino radicals, which are N-substituted for example with one or two identical or different radicals selected from the group consisting of alkyl, alkoxy , acyl and aryl; preferably monoalkylamino, dialkylamino, acylamino, arylamino, N-alkyl-N-arylamino and also heterocycles with N. In this case, alkyl radicals having 1 to 4 carbon atoms are preferred. An aryl is thus preferred. phenyl. A substituted aryl is in this case, preferably substituted phenyl. For an acyl, the definition mentioned below, preferably alkanoyl (C-1-C4), is valid in this case. The corresponding is valid for hydroxylamino or substituted hydrazino. An optionally substituted phenyl is preferably phenyl, which is unsubstituted or substituted once or multiple times, preferably up to three times, in the case of a halogen, such as Cl and F, also up to five times, with the same radicals or different, selected from the group consisting of halogen, (C 1 -C 4) alkyl, (C 1 -C 4) alkoxy, halo (C 1 -C 4) alkyl, halo (C 4 C) alkoxy and nitro, e.g. o-, m- and p-tolyl, dimethyl-phenyls, 2-, 3-and 4-chloro-phenyls, 2-, 3- and 4-trifluoro and -trichloro-phenyls, 2,4-, 3,5- , 2,5- and 2,3-dichloro-phenyls, o-, m- and p-methoxy-phenyls. An acyl radical means the radical of an organic acid having, preferably, up to 6 carbon atoms, for example the radical of a carboxylic acid and acid radicals derived therefrom, such as thio-carboxylic acid , iminocarboxylic acids optionally substituted in N, or the radical of monoesters of carbonic acid, carbamic acids optionally substituted in N, sulphonic acids, sulfinic acids, phosphonic acids and phosphinic acids. An acyl means, for example, formyl, alkylcarbonyl, such as alkyl (CrC) -carbonyl, phenylcarbonyl, wherein the phenyl ring may be substituted, eg as indicated above for phenyl, or alkyloxycarbonyl, phenyloxycarbonyl, benzyloxycarbonyl, alkylsulfonyl, alkylsulfinyl or N-alkyl-1-iminoalkyl. By the formulas (I) to (VIII) are also encompassed all the stereoisomers, which have the same topological bond of the atoms, and their mixtures. Such compounds contain one or more asymmetric C atoms or double bonds, which are not indicated separately in the general formulas. The possible stereoisomers, which are defined by their specific spatial form, such as enantiomers, diastereoisomers, Z and E isomers, can be obtained according to usual methods from mixtures of the stereoisomers or can be prepared by selective reactions stereoactively in combination with the use of stereochemically pure starting materials. The compounds of the formula (II) are known, for example, from European patent application documents EP-A-0,333,131 (-Japanese document ZA-89/1960), EP-A-0,269,806 (= document US-A-4,891,057), EP-A-0,346,620 (= Australian patent application document AU-A-89/34951), EP-A-0,174,562, EP-A-0,346,620 (= international patent application document WO-A-91 / 08,202), WO-A-91 / 07,874 and WO-A 95 / 07,897 (= ZA 94 / 7,120) and the literature cited therein, or can be prepared in accordance with, or analogous to, the procedures described therein. The compounds of the formula (III) are known from EP-A-0,086,750, EP-A-094,349 (= US-A-4,902,340), EP-A-0,191, 736 (US-A-4,881, 966). ) and EP-A-0,492,366 and the literature cited therein, or can be prepared according to or analogously to the processes described therein. Some compounds are further described in EP-A-0,582,198 and WO 2002/34048. The compounds of the formula (IV) are known from numerous patent applications, for example from documents US-A-4,021, 224 and US-A-4,021, 229. The compounds of set B (b) are furthermore known from the Chinese patent application documents CN-A-87/102789, EP-A-0,365,484, as well as from "The Pesticide Manual" [The manual of pesticides] , The British Crop Protection Council and the Royal Society of
Chemistry, 11th edition, Farnham 1997. The compounds of set B (c) are described in the document
WO-A-97 / 45,016, those of set B (d) are described in WO-A-99/16744, and those in set B (e) are described in EP-A-365,484. The cited documents contain detailed data about preparation procedures and starting materials and mention preferred compounds. These documents are expressly referred to, they are considered by citation as a constituent part of this specification. Preferred are combinations of herbicides and antidotes, containing antidotes of the formulas (II) and / or (III) in which the symbols and indices have the following meanings: R24 is hydrogen, alkyl (CC? 8), cycloalkyl (C3-) C12), (C2-C8) alkenyl and (C2-C18) alkynyl, the C-containing groups may be substituted with one or more, preferably up to three, R50 radicals; the R50 are, same or different, halogen, hydroxy, alkoxy (C -? - C8), Iquiltio
(C? -C8), alkenylthio (C2-C8), alkynylthio (C2-C8), alkenlloxy (C2-C8), alkynyloxy (C2-C8), cycloalkyl (C3-C7), cycloalkoxy (C3-C7), cyano , mono- and di- (alkyl (dC4)) - amino, carboxy, alkoxycarbonyl (CrC8), alkenyloxycarbonyl (C2-C8), alkylthiocarbonyl (C -? - C8), alkynyloxycarbonyl (C2-C8), alkylcarbonyl (C - | -C8), alkenylcarbonyl (C2-C8), alkynylcarbonyl (C2-C8), 1- (hydroxyimino) -alkyl (Cr C6), 1 - [(C? -C4) alkyl -imino] -alkyl ( C C4), 1 - [(C -? - C4) alkoxy] -alkyl (d-C6), (C? -C8) alkylcarbonylamino, (C2-C8) alkenylcarbonylamino, alkynyl C2-C8) -carbonylamino, aminocarbonyl, alkyl (CrC8) -aminocarbonyl, di- ((C- | C6) alkyl) amino-carbonyl, (C2-C6) alkenyl-aminocarbonyl, (C2-C6) alkynyl-aminocarbonyl alkoxy (CrC8) -carbonylamino, (C8) alkyl-aminocarbonylamino, (C? -C6) alkylcarbonyloxy, which is unsubstituted or substituted with R50, (C2-C6) alkenyl-carbonyloxy, (C2-C6) alkynyl -carbonylloxy, alkyl (C 8) -sulfonyl, phenyl, phenyl-alkoxy (C C 6) ), phenyl (C -? - C6) alkoxycarbonyl, phenoxy, phenoxy (C-? - C6) alkoxy, phenoxy-alkoxy (CrC6) -carbonyl, phenylcarbonyloxy, phenylcarbonylamino, phenyl-(C1-C6) alkyl- carbonylamino, the 9 radicals mentioned being ultimately unsubstituted or substituted one or more times, preferably up to three times, with radicals R52 on the phenyl ring; or are SiR'3, -0-SiR'3, R'3S-alkoxy (C8), -CO-0-NR'2, -0-N = CR'2, -N = CR'2, - 0-NR'2, -NR'2, CH (OR ') 2, -0- (CH2) m, -CH (OR') 2, -CR, "(OR,) 2, -O- (CH2) mCR ", (OR") 2 or with R "0-CHR '" CHCOR "-alcoxy (C C6), R51 are, different or different, halogen, nitro, (C1-C4) alkoxy and unsubstituted phenyl or substituted with one or more, preferably up to three, radicals R51; the R52 are, the same or different, halogen, (C1-C4) alkyl, (C-1-C4) alkoxy, (C-1-C4) haloalkyl, (C1-C4) haloalkoxy or nitro; the R 'are, the same or different, hydrogen, alkyl (CrC), phenyl unsubstituted or substituted with one or more, preferably up to three radicals R52, or two radicals R' form in common an alkane chain (C2-C6) ) -diílo; the R "are, the same or different, alkyl (C C4), or two radicals R" form in common an alkane chain (C2-C6) -diyl; R "" is hydrogen or (C4) alkyl, m is 0, 1, 2, 3, 4, 5 or 6. Especially preferred are combinations of herbicides and antidotes according to the invention, which contain antidotes of the formulas (II) and / o (lll), in which the symbols and indices have the following meanings: R24 is hydrogen, alkyl (C? -8) or cycloalkyl (C3-C7), it being realized that the preceding radicals containing C are unsubstituted or substituted once or multiple times with halogen, or once or twice, preferably once, with R50 radicals, R50 are, same or different, hydroxy, alkoxy (CrC), carboxy, alkoxy (C -? - C) ) -carbonyl, (C2-C6) alkenyl-oxycarbonyl, (C2-C6) alkynyloxycarbonyl, l- (hydroxyimino) -alkyl (C4), 1 - [(C? -C4) alkyl -imino] ] -alkyl (C C4) and 1 - [alkoxy (C -? - C4) -iminoj-alkyl (C C4); -SiR'3, -0-N = CR2, -N = CR'2, -NR2 and -0-NR'2, in which the R ', equal or different, mean hydrogen, alkyl (CC) or mean by pairs an alkane chain (C4-C5) -diyl; R27, R28, R29 are, same or different, hydrogen, (C -? - C8) alkyl, halo (C -? - C6) alkyl, (C3 - C7) cycloalkyl or phenyl, which is unsubstituted or substituted with one or more radicals selected from the group consisting of halogen, cyano, nitro, amino, mono- and di- [(C 1 -C 4) alky] amino, (C 4) alkyl, halo (C 4) alkyl, (C 4) alkoxy, halo (C 4 C) alkoxy, alkyl (C 4) alkyl and (C 4) alkylsulphonyl; Rx is hydrogen or COOR26, wherein R26 means hydrogen, (C-? - C8) alkyl, halo (C8-C8) alkyl, (C4-C4 alkoxy) -alkyl (CrC), hydroxy-alkyl (C? -C6) ), (C3-C7) cycloalkyl or tri-alkyl (CrC4) -silyl, the R17, R19 are, different or different, hydrogen, halogen, methyl, ethyl, methoxy, ethoxy, haloalkyl (Ci or C2), preferably hydrogen, halogen or haloalkyl (Ci or C2). Antidotes in which the symbols and indices in formula (II) have the following meanings are especially preferred: R17 is halogen, nitro or haloalkyl (C4); n 'is 0, 1, 2 0 3; R18 is a radical of the formula OR24; R 24 is hydrogen, (C 8) alkyl or (C 3 -C 7) cycloalkyl, it being realized that the preceding C-containing radicals are unsubstituted or substituted once or multiple times, preferably up to three times, with halogen-containing radicals, the same or different, or up to twice, preferably once, with the same or different radicals selected from the group consisting of hydroxy, (C -? - C4) alkoxy, (CC) alkoxycarbonyl, (C2 - C6) alkenyl. -oxi-carbonyl, (C2-C6) alkynyloxycarbonyl, 1- (hydroxyimino) -alkyl (CC), 1- [(C4-alkyl) -imino] -alkyl (CrC4), 1- [alkoxy (C -? - C) -imin] -alkyl (C C4) and radicals of the formulas -SiR'3, -0-N = R'2, -N = CR'2, -NR'2 and - 0-NR'2, it being realized that the radicals R 'in the mentioned formulas, equal or different, mean hydrogen, alkyl (C C4), or by pairs of alkane (C4 or C5) -diyl; R27, R28, R29 are, same or different, hydrogen, (C8) alkyl, haloalkyl (Cr6), cyclo (C3-C7) cycloalkyl or phenyl, which is unsubstituted or substituted by one or more of the radicals selected from the group consisting of halogen, alkyl (CrC), alkoxy (C -? - C), nitro, halo-alkyl (C? -C4) and halo-alkoxy (C4) .Rx is hydrogen or COOR26, in which R, 26 means hydrogen, (C 8) alkyl, halo (C 8) alkyl, (C 1 - C 4) alkoxy (C 1 -C 4) alkyl, hydroxy (C 6 -C 6) alkyl, (C 3 -C 7) cycloalkyl or tri- alkyl (C -? - C4) -silyl. Also very particularly preferred are antidotes of the formula (III), in which the symbols and indices have the following meanings: R19 is halogen or haloalkyl (C4); n 'is 0, 1, 2 or 3, wherein (R19) n- is preferably 5-CI; R20 is a radical of the formula OR24; T is CH2 or CH (COO- (C3 alkyl)) and R24 is hydrogen, alkyl (CrCs), haloalkyl (C8) or (C3-4) alkoxy-(C1-C4) alkyl, preferably hydrogen or alkyl (CrC8). Particularly preferred in this case are antidotes of the formula (II), in which the symbols and indices have the following meanings: W is (W1); R 7 is halogen or haloalkyl (CrC 2); n 'is 0, 1, 2 or 3, wherein (R17) n' is preferably 2,4-CI2; R18 is a radical of the formula OR24; R24 is hydrogen, alkyl (CrC8), haloalkyl (C4), hydroxy (CC), cycloalkyl (C3-C7), alkoxy (C4) -alkyl (CrC4) or tri-alkyl (C- | - C2) -silyl, preferably alkyl (CrC); R27 is hydrogen, (C8) alkyl, halo (C4) alkyl or (C3-C7) cycloalkyl, preferably hydrogen or (C- | -C4) alkyl, and Rx is COOR26, wherein R26 is hydrogen, (C 8) alkyl, halo (C 4) alkyl, hydroxy (C 4) alkyl, (C 3 -C 7) cycloalkyl, (C 1 -C 4) alkoxy (C 1 -C 4) alkyl or tri-alkyl (C) ? -C4) -silyl, preferably hydrogen or (C4) alkyl? Particularly preferred are also the herbicidal agents, which contain an antidote of the formula (II), in which the symbols and indices have the following meanings: W is (W2); R17 is halogen or haloalkyl (C2); n 'is 0, 1, 2 or 3, wherein (R17) n' is preferably 2,4-CI2; R18 is a radical of the formula OR24; R24 is hydrogen, (C8) alkyl, halo (C4) alkyl, hydroxyalkyl (CC), (C3-C7) cycloalkyl, (CC) alkoxy-(C4) alkyl or tri-alkyl, preferably alkyl (C) C4); and R27 is hydrogen, alkyl (CrC8), haloalkyl (C? -C4), cycloalkyl (C3-C7) or substituted phenyl, preferably hydrogen, alkyl
(C -? - C) or phenyl, which is unsubstituted or substituted by one or more of the radicals selected from the group consisting of halogen, (C4) alkyl, haloalkyl (CrC), nitro, cyano or alkoxy ( C C4). Particularly preferred are also antidotes of the formula (II), in which the symbols and indices have the following meanings: W is (W3);
R 17 is hydrogen, halogen or haloalkyl (C C 2); n 'is 0, 1, 2 or 3, wherein (R17) n- is preferably 2,4-CI2; R18 is a radical of the formula OR24; R 24 is hydrogen, (C 8) alkyl, halo (C 4) alkyl, hydroxyalkyl (C 1 -C 4), cycloalkyl (C 3 -C 7), alkoxy (CrC 4) -akyl (CC) or tri-alkyl (CrC 2) - silyl, preferably alkyl (C4), and R28 is alkyl (CrC8) or haloalkyl (C-1-C4), preferably halo-C1alkyl. Particularly preferred are also antidotes of the formula (II), in which the symbols and indices have the following meanings: W is (W4); R 17 is halogen, nitro, (C 1 -C 4) alkyl, halo (C 1 - C 2) alkyl, preferably CF 3, or alkoxy (CrC 4); n 'is 0, 1, 2 0 3, m' is O or l; R18 is a radical of the formula OR24; R24 is hydrogen, (C4) alkyl, carboxy-alkyl (CC), alkoxy (CrC4) -carbonyl-(C4) alkyl, preferably (C-? -C) -CO-CH2- alkoxy, alkoxy (C) C4) -CO-C (CH3) H-, HO-CO-CH2- or HO-CO-C (CH3) H-, and R29 is hydrogen, (C4) alkyl, halo (C1-C4) alkyl, (C3-C7) cycloalkyl or phenyl, which is unsubstituted or substituted with one or more of the radicals selected from the group consisting of halogen, (C-1-C4) alkyl, halo-C4 alkyl, nitro, cyano and (C 4 C) alkoxy. The following groups of compounds are particularly suitable as antidotes for the herbicidal active substances of the formula (I): a) Dichlorophenylpyrazoline-3-carboxylic acid type compounds (ie of the formula (II), in which W = (W1) and (R17) n '= 2,4-CI2), preferably compounds, such as the ethyl ester of 1- (2,4-dichlorophenyl) -5- (ethoxycarbonyl) -5-methyl ester. -2-p -razoline-3-carboxylic acid (11-1, mefenpyr-diethyl), mefenpyr-dimethyl and mefenpyr (11-O), and related compounds, as described in WO-A 91/07874; b) Derivatives of dichlorophenylpyrazolecarboxylic acid (ie of the formula (II), in which W = (W2) and (R17) n> is = 2,4-CI2), preferably compounds, such as the ethyl ester of 1- (2,4-dichlorophenol) -5-methyl-pyrazole-3-carboxylic acid (II-2), the ethyl ester of 1- (2,4-dichlorophenyl) -5-isopropyl-pyrazole- 3-carboxylic acid (II-3), the ethyl ester of 1- (2,4-dichlorophenyl) -5- (1,1-dimethyl-ethyl) -pyrazzo-3-carboxylic acid (II-4), the ethyl ester of 1- (2,4-dichloro-phenyl) -5-phenyl-pyrazole-3-carboxylic acid (II-5) and related compounds, such as described in EP-A-0,333,131 and EP-A -0.269.806. c) Compounds of the triazolecarboxylic acid type (ie of the formula (II), in which W = (W3) and (R17) n 'is = 2,4-CI2), preferably compounds, such as phenclorazol ethyl, ie the ethyl ester of 1- (2,4-dichlorophenyl) -5-trichloromethyl- (1 H) -1, 2,4-triazole-3-carboxylic acid (II-6), and related compounds ( see EP-A-0, 174,562 and EP-A-0,346,620); d) Compounds of the 5-benzyl- or 5-phenyl-2-isoxazoline-3-carboxylic acid or 5,5-diphenyl-2-isoxazoline-3-carboxylic acid type such as isoxadifen (11-12), (in those W is = (W4)), preferably compounds such as the 5- (2,4-dichloro-benzyl) -2-isoxazoline-3-carboxylic acid ethyl ester (II-7) or the ethyl ester of 5-phenyl-2-isoxazoline-3-carboxylic acid (II-8) and related compounds, as described in WO-A-91/08202, or of ethyl esters (II-9, isoxadifen-ethyl) or n-propyl (11-10) of 5,5-diphenyl-2-isoxazoline-3-carboxylic acid, or 5- (4-fluoro-phenyl) -5-phenyl-2-isoxazoline-3-ethyl ester -carboxylic (11-11), as described in WO-A-95/07897. e) Compounds of the 8-quinoline-oxy-acetic acid type, eg those of the formula (III), wherein (R19) n- is = 5-CI, R20 is = OR24 and T is = CH2, preferably the ester compounds (1-methyl-hexyl) of (5-chloro-8-quinolinoxy) acetic acid (111-1, cloquintocet-mexyl), (1, 3-dimethyl-but-1-yl) ester (5-chloro-8-quinolinoxy) acetic acid (III-2), 4-allyloxy-butyl acid ester (5-chloro-8-quinolinoxy) acetic (III-3), 1-allyloxy-prop-2-yl ester of (5-chloro-8-quinolinoxy) acetic acid (III-4), ethyl ester of -chloro-8-quinolinoxy) acetic acid (III-5), methyl ester of (5-chloro-8-quinolinoxy) acetic acid (III-6), allyl ester of (5-chloro-8-quinolinoxy) acetic acid (III -7) 2- (2-propylidene-iminooxy) -1-ethyl ester of (5-chloro-8-quinolinoxy) acetic acid (III-8), 2-oxo-prop-1-yl ester of acid (5-chloro-8-quinolinoxy) acetic (III-9) (5-chloro-8-quinolinoxy) acetic acid (111-10) and its salts as described, for example, in WO-A-2002 / 34048, and related compounds, as described in documents E P-A-0,860,750, EP-A-0,094,349 and EP-A-0,191, 736 or EP-A-0,492,366. f) Compounds of the type of (5-cyoro-8-quinolyloxy) -malonic acid, ie those of the formula (III), in which (R19) n 'is = 5-CI, R20 is =
OR24 and T is = -CH- (COO-alkyl), preferably the compounds diethyl ester of (5-chloro-8-quinolinoxy) -malonic acid (111-11), diallyl ester of acid (5-chloro-8) -quinolinoxy) malonic, methyl and ethyl ester of (5-chloro-8-quinolinoxy) malonic acid and related compounds, as described in EP-A-0,582,198. g) Compounds of the type of the dichloroacetamides, ie of the formula (IV), preferably N, N-diallyl-2,2-dichloroacetamide (dichloromide (IV-1), of US-A-4,137,070) , 4-dichloroacetyl-3,4-dihydro-3-methyl-2H-1,4-benzoxazine (IV-2, benoxacor, from EP 0,149,974), N1, N2-diallyl-N2-dichloroacetylgluccinamide (DKA-24) , from Hungarian patent document HU 2143821), 4-dichloroacetyl-1-oxa-4-aza-spiro [4,5] decane (AD-67), 2,2-dichloro-N- (1,3-dioxolan- 2-ylmethyl) -N- (2-propenyl) -acetamide (PPG-1292), 3-dichloroacetyl-2,2,5-trimethyloxazolidine (R-29148, IV-4), 3-dichloroacetyl-2,2-dimethyl -5-phenyloxazolidine, 3-dichloroacetyl-2,2-dimethyl-5- (2-thienyl) oxazolidine, 3-dichloroacetyl-5- (2-furanyl) -2,2-dimethyloxazolidine (furilazole (IV-5), MON 13900), 1-dichloroacetyl-hexahydro-3,3,8a-trimethyl-pyrrolo [1,2-a] pyrimidine-6- (2H) -one
(dicyclone, BAS 145138), h) Compounds of the group of B (b), preferably anhydride of 1,8-naphthalic acid (b-1), methyl diphenylmethoxyacetate (b-2), cyanomethoxyimino (phenyl) aceton trilo (ciometrinil) (b-3), 1- (2-chlorobenzyl) -3- (1-methyl-1-phenylethyl) urea (cumyluron) (b-4), 0.0-diethyl phosphorodithioate S-2- ethylthioethyl (disulfoton) (b-5), 4-chlorophenyl methylcarbamate (mephenate) (b-6), 0,0-diethyl-O-phenyl phosphorothioate (dietolato) (b-7), 4-carboxy-3 acid , 4-dihydro-2H-1-benzopyran-4-acetic acid (CL-304415, CAS-Regno: 31541-57-8) (b-8), 1,3-dioxolan-2-ylmethoxyimino (phenyl) acetonitrile (oxabetrinil ) (b-9), 0-1, 3-dioxolan-2-ylmethyl oxime of 4'-chloro-2,2,2-trifluoroacetophenone (fluxofenima) (b-10), 4,6-dichloro-2-phenylpyrimidine ( phenclorima) (b-11), 2-chloro-4-trifluoromethyl-1,3-thiazole-5-carboxylic acid benzyl ester (flurazole) (b-12), 2-dichloromethyl-2-methyl-1,3-dioxolane ( MG-191) (b-13), N- (4-methylphenyl) -N '- (1-methyl-1-phenylethyl) urea (dimron) (b-14), acid (2,4-dichlorophen oxy) acetic acid (2,4-D), (4-chlorophenoxy) acetic acid, (R, S) -2- (4-chloro-o-tolyloxy) propionic acid (mecoprop), acid 4- (2,4-) dichlorophenoxy) butyric acid (2,4-DB), (4-chloro-o-tolyloxy) acetic acid (MCPA), 4- (4-chloro-o-tolyloxy) butyric acid, 4- (4-chlorophenoxy) butyric acid, 3,6-dichloro-2-methoxybenzoic acid (dicamba), 3,6-dichloro-2-methoxybenzoate of 1- (ethoxycarbonyl) ethyl (lactidychlor) as well as its salts and esters, preferably (C1-C8). In addition, compounds of the formula are preferred as antidotes.
(V) or its salts, in which R30 means hydrogen, (C6) alkyl, (C3-C6) cycloalkyl, furanyl or thienyl, each of the 4 radicals mentioned being ultimately unsubstituted or substituted with one or several substituents selected from the group consisting of halogen, alkoxy (CrC), alkoxy (C6) alkoxy and alkyl (CrC4) -thio and, in the case of cyclic radicals, also with alkyl (dC) and halo-alkyl ( CC); R31 means hydrogen; R32 means halogen, halogen-alkyl (CC), halogenoalkoxy (C1-C4), alkyl (CrC4), alkoxy (C -? - C), alkyl (CrC) -sulfonyl, alkoxy (CrC) -carbonyl or alkyl (CrC) -carbonyl, preferably halogen, halogen-(C-C-C) alkyl, such as trifluoromethyl, alkoxy (CrC4), halogen-alkoxy (C4), alkoxy (C4) -carbonyl or alkyl (d-C4) -sulfonyl; R33 means hydrogen; R34 means halogen, (C1-C4) alkyl, halogen-alkyl (dC), halogen-alkoxy (dC), (C3-C6) cycloalkyl, phenyl, (C4) alkoxy, cyano, alkyl (d-C4) -thio , alkyl (C? -C4) -sulfinyl, alkyl (CrC) -sulfonyl, (C? -C4) alkoxycarbonyl or alkyl (CrC) -carbonyl, preferably halogen, alkyl (CC), halogen-alkyl (CrC) ), such as trifluoromethyl, halogen-alkoxy (C4), alkoxy (C4) or alkyl (d-C4) -thi, n means 0, 1 or 2 and m means 1 or 2. Especially preferred are compounds of the formula (V), where R30 = H3C-0-CH2-, R31 = R33 = H, R34 = 2-OMe (V-1), R30 = H3C-0-CH2-, R31 = R33 = H, R34 = 2-OMe-5-CI (V-2), R30 = cyclopropyl, R31 = R33 = H, R34 = 2-OMe (V-3), R30 = cyclopropyl, R31 = R33 = H, R34 = 2- OMe-5-CI (V-4), R30 = cyclopropyl, R31 = R33 = H, R34 = 2-Me (V-5), R30 = tere, butyl, R31 = R33 = H, R34 = 2-OMe ( V-6). In addition, antidotes of the formula (VI), in which X3 means CH, are preferred.; R35 means hydrogen, (C6) alkyl, (C3-C6) cycloalkyl, (C2-C6) alkenyl, (C5-C6) cycloalkenyl, phenyl or 3-6 membered heterocyclyl with up to three heteroatoms selected from the group consisting of nitrogen , oxygen and sulfur, it being realized that the six mentioned radicals are eventually substituted with one or more substituents, the same or different, selected from the group consisting of halogen, alkoxy (d-C6), halo-alkoxy (d-C6) , alkyl (d-C2) -sulfinyl, alkyl (d-C2) -sulfonyl, cycloalkyl (C3-C6), alkoxy (d-C4) -carbonyl, alkyl (d-C4) -carbonyl and phenyl and , in the case of cyclic radicals, also with alkyl (d-C4) and haloalkyl (dd); R36 means hydrogen, (C6-C6) alkyl, (C2-C6) alkenyl, (C2-C6) alkynyl, it being realized that the three mentioned radicals are eventually substituted with one or more substituents, the same or different, selected from the group consisting of compound formed by halogen, hydroxy, alkyl (d-C4), alkoxy (dd) and alkyl (dC) -thio;
R means halogen, haloalkyl (C4), haloalkoxy (C4), nitro, alkyl (d-C4), alkoxy (C4), alkyl (d-C4) -sulfonyl, alkoxy (C4) - carbonyl or (C 4 C) alkylcarbonyl; R38 means hydrogen; R means halogen, nitro, alkyl (CrC4), haloalkyl (C
C4), haloalkoxy (d-C4), cycloalkyl (C3-C6), phenyl, alkoxy (d-C4), cyano, alkyl (CrC4) -thio, alkyl (d-C4) -sulfinyl, alkyl (d-) C4) -sulfonyl, alkoxy (d-C4) -carbonyl or alkyl (C? -d) -carbonyl; n means 0, 1 or 2 and m means 1 or 2. Preferred antidotes of the formula (VII) are (S3-1), (S3-2), (S3-3), (S3-4) and (S3-5) ). Preferred antidotes of formula (VIII) are: 1- [4- (N-2-methoxybenzoylsulfamoyl) phenyl] -3-methylurea (h-1), 1- [4- (N-2-methoxybenzoylsulfamoyl) phenyl] -3 , 3-dimethylurea (h-2), 1 - [4- (N-4,5-dimethylbenzoylsulfamoyl) phenyl] -3-methylurea (h-3) and 1- [4- (N-naphthoyl sulphamoyl) phenyl] -3 , 3-dimethylurea. Especially preferred antidotes are dimron (b-14), phenchlorima (b-11), cumiluron (b-4), isoxadifen-ethyl (II-9), mefenpyr-diethyl (11-1), cloquintocet-mexyl (111-1) ), S3-1, h-1, h-2, h-3, dietolato (b-7), disulfoton (b-5), anhydride of 1,8-naphthalic acid (b-1), fluxofenima (b-) 10), dichloromide (IV-1), benoxacor (IV-2), flurazole (b-12), R-29148 (IV-4). For the application in rice, dimron, phenchlorima, cumiluron, isoxadifen-ethyl are especially preferred.
Especially preferred for the application in cereals are mefenpyr-diethyl, cloquintocet-mexyl, and in maize in particular isoxadifen-ethyl, (S3-1), (h-1), (h-2), (h-3), anhydride of 1,8-naphthalic acid, fluxofenim, dichloromide, benoxacor, flurazole and R-29148. For the application in sugar cane, isoxadiphen-ethyl is preferred. Examples of preferred combinations of active herbicidal substances (A) and antidotes (B) are: (1-1) + (ll-O), (1-1) + (11-1), (1-1) + (II -2), (1-1) + (II-3), (1-1) + (II-4), (1-1) + (II-5), (1-1) + (II-6) ), (1-1) + (II-9), (1-1) + (11-12), (1-1) + (111-1), (1-1) + (III-4), (1-1) + (111-10), (1-1) + (111-11), (1-1) + (IV-1), (1-1) + (IV-2), (1 -1) + (IV-3), (1-1) + (IV-4), (1-1) + (IV-5), (1-1) + (b-1), (1-1 ) + (b-2), (1-1) + (b-3), (1-1) + (b-4), (1-1) + (b-5), (1-1) + (b-6), (1-1) + (b-7), (1-1) + (b-8), (1-1) + (b-9), (I-1) + (b -10), (1-1) + (b-11), (1-1) + (b-12), (1-1) + (b-13), (1-1) + (b-14) ), (1-1) + (S3-1), (1-1) + (S3-2), (1-1) + (S3-3), (1-1) + (S3-4), (1-1) + (S3-5), (1-1) + (h-1), (1-1) + (h-2), (1-1) + (V-1), (1 -1) + (V-2), (1-1) + (V-3), (1-1) + (V-4), (1-1) + (V-5), (1-1 ) + (V-6). (I-2) + (ll-O), (I-2) + (11-1), (I-2) + (II-2), (I-2) + (II-3), (I -2) + (II-4), (I-2) + (II-5), (I-2) + (II-6), (I-2) + (II-9), (I-2) ) + (11-12), (I-2) + (111-1), (I-2) + (III-4), (I-2) + (111-10), (I-2) + (111-11), (I-2) + (IV-1), (I-2) + (IV-2), (I-2) + (IV-3), (I-2) + (IV -4), (I-2) + (IV-5), (I-2) + (b-1), (I-2) + (b-2), (I-2) + (b-3) ), (I-2) + (b-4), (I-2) + (b-5), (I-2) + (b-6), (I-2) + (b-7), (I-2) + (b-8), (I-2) + (b-9), (I-2) + (b-10), (I-2) + (b-11), (I -2) + (b-12), (I-2) + (b-13), (I-2) + (b-14), (I-2) + (S3-1), (I-2) ) + (S3-2), (I-2) + (S3-3), (I-2) + (S3-4), (I-2) + (S3-5), (I-2) + (h-1), (I-2) + (h-2), (I-2) + (V-1), (I-2) + (V-2), (I-2) + (V -3), (I-2) + (V-4), (I-2) + (V-5), (I-2) + (V-6).
(1-3) + (ll-O), (1-3) + (11-1), (I-3) + (II-2), (I-3) + (II-3), (I -3) + (II-4), (I-3) + (II-5), (I-3) + (II-6), (I-3) + (II-9), (I-3) ) + (|| -12), (I-3) + (111-1), (I-3) + (III-4), (I-3) + (111-10), (I-3) + (111-11), (I-3) + (IV-1), (I-3) + (IV-2), (I-3) + (IV-3), (I-3) + ( IV-4), (I-3) + (IV-5), (I-3) + (b-1), (I-3) + (b-2), (I-3) + (b- 3), (I-3) + (b-4), (I-3) + (b-5), (I-3) + (b-6), (I-3) + (b-7) , (I-3) + (b-8), (I-3) + (b-9), (I-3) + (b-10), (I-3) + (b-11), ( I-3) + (b-12), (I-3) + (b-13), (I-3) + (b-14), (I-3) + (S3-1), (I- 3) + (S3-2), (I-3) + (S3-3), (I-3) + (S3-4), (I-3) + (S3-5), (I-3) + (h-1), (I-3) + (h-2), (I-3) + (V-1), (I-3) + (V-2), (I-3) + ( V-3), (I-3) + (V-4), (I-3) + (V-5), (I-3) + (V-6). (I-4) + (ll-O), (I-4) + (11-1), (I-4) + (II-2), (I-4) + (II-3), (I -4) + (II-4), (I-4) + (II-5), (I-4) + (II-6), (I-4) + (II-9), (I-4) + (11-12), ( I-4) + (111-1), (I-4) + (III-4), (I-4) + (111-10), (I-4) + (111-11), (I- 4) + (IV-1), (I-4) + (IV-2), (I-4) + (IV-3), (I-4) + (IV-4), (I-4) + (IV-5), (I-4) + (b-1), (I-4) + (b-2), (I-4) + (b-3), (I-4) + ( b-4), (I-4) + (b-5), (I-4) + (b-6), (I-4) + (b-7), (I-4) + (b- 8), (I-4) + (b-9), (I-4) + (b-10), (I-4) + (b-11), (I-4) + (b-12) , (I-4) + (b-13), (I-4) + (b-14), (I-4) + (S3-1), (I-4) + (S3-2), ( I-4) + (S3-3), (I-4) + (S3-4), (I-4) + (S3-5), (I-4) + (h-1), (I- 4) + (h-2), (I-4) + (V-1), (I-4) + (V-2), (I-4) + (V-3), (I-4) + (V-4), (I-4) + (V-5), (I-4) + (V-6). (I-5) + (ll-O), (I-5) + (11-1), (I-5) + (II-2), (I-5) + (II-3), (I -5) + (II-4), (I-5) + (II-5), (I-5) + (II-6), (I-5) + (II-9), (I-5) ) + (11-12), (I-5) + (111-1), (I-5) + (Hl-4), (I-5) + (111-10), (I-5) + (111-11), (I-5) + (IV-1), (I-5) + (IV-2), (I-5) + (IV-3), (I-5) + (IV -4), (I-5) + (IV-5), (I-5) + (b-1), (I-5) + (b-2), (I-5) + (b-3) ), (I-5) + (b-4), (I-5) + (b-5), (I-5) + (b-6), (I-5) + (b-7), (I-5) + (b-8), (I-5) + (b-9), (I-5) + (b-10), (I-5) + (b-11), (I -5) + (b-12), (I-5) + (b-13), (I-5) + (b-14), (I-5) + (S3-1), (I-5) ) + (S3-2), (1-5) + (S3-3), (1-5) + (S3-4), (1-5) + (S3-5), (1-5) + (h-1), (I-5) + (h-2), (I-5) + (V-1), (I-5) + (V-2), (I-5) + (V -3), (I-5) + (V-4), (I-5) + (V-5), (I-5) + (V-6). (I-6) + (ll-O), (I-6) + (11-1), (I-6) + (II-2), (I-6) + (II-3), (I -6) + (II-4), (I-6) + (II-5), (I-6) + (II-6), (I-6) + (II-9), (I-6) ) + (11-12), (I-6) + (111-1), (I-6) + (III-4), (I-6) + (111-10), (I-6) + (111-11), (I-6) + (IV-1), (I-6) + (IV-2), (I-6) + (IV-3), (I-6) + (IV -4), (I-6) + (IV-5), (I-6) + (b-1), (I-6) + (b-2), (I-6) + (b-3) ), (I-6) + (b-4), (I-6) + (b-5), (I-6) + (b-6), (I-6) + (b-7), (I-6) + (b-8), (I-6) + (b-9), (I-6) + (b-10), (I-6) + (b-11), (I -6) + (b-12), (I-6) + (b-13), (I-6) + (b-14), (I-6) + (S3-1), (I-6) ) + (S3-2), (I-6) + (S3-3), (I-6) + (S3-4), (I-6) + (S3-5), (I-6) + (h-1), (I-6) + (h-2), (I-6) + (V-1), (I-6) + (V-2), (I-6) + (V -3), (I-6) + (V-4), (I-6) + (V-5), (I-6) + (V-6). (I-7) + (ll-O), (I-7) + (11-1), (I-7) + (II-2), (I-7) + (II-3), (I -7) + (II-4), (I-7) + (|| -5), (I-7) + (II-6), (I-7) + (II-9), (I- 7) + (11-12), (i-7) + (111-1), (I-7) + (III-4), (I-7) + (111-10), (I-7) + (111-11), (I-7) + (IV-1), (I-7) + (IV-2), (I-7) + (IV-3), (I-7) + ( IV-4), (I-7) + (IV-5), (I-7) + (b-1), (I-7) + (b-2), (I-7) + (b- 3), (I-7) + (b-4), (I-7) + (b-5), (I-7) + (b-6), (I-7) + (b-7) , (I-7) + (b-8), (I-7) + (b-9), (I-7) + (b-10), (I-7) + (b-11), ( I-7) + (b-12), (I-7) + (b-13), (I-7) + (b-14), (I-7) + (S3-1), (I- 7) + (S3-2), (I-7) + (S3-3), (I-7) + (S3-4), (I-7) + (S3-5), (I-7) + (h-1), (I-7) + (h-2), (I-7) + (V-1), (I-7) + (V-2), (I-7) + ( V-3), (I-7) + (V-4), (I-7) + (V-5), (I-7) + (V-6). (I-8) + (ll-O), (I-8) + (11-1), (I-8) + (II-2), (I-8) + (II-3), (I -8) + (|| -4), (I-8) + (li-5), (I-8) + (II-6), (I-8) + (II-9), (I- 8) + (11-12), (I-8) + (111-1), (I-8) + (III-4), (I-8) + (111-10), (I-8) + (111-11), (I-8) + (IV-1), (I-8) + (IV-2), (I-8) + (IV-3), (I-8) + ( IV-4), (I-8) + (IV-5), (I-8) + (b-1), (I-8) + (b-2), (I-8) + (b- 3), (I-8) + (b-4), (I-8) + (b-5), (I-8) + (b-6), (I-8) + (b-7) , (I-8) + (b-8), (I-8) + (b-9), (I-8) + (b-10), (I-8) + (b-11), ( I-8) + (b-12), (I-8) + (b-13), (I-8) + (b-14), (I-8) + (S3-1), (I- 8) + (S3-2), (I-8) + (S3-3), (I-8) + (S3-4), (I-8) + (S3-5), (I-8) + (h-1), (I-8) + (h-2), (I-8) + (V-1), (I-8) + (V-2), (I-8) + ( V-3), (I-8) + (V-4), (I-8) + (V-5), (I-8) + (V-6). (I-9) + (ll-O), (I-9) + (11-1), (I-9) + (II-2), (I-9) + (II-3), (I -9) + (II-4), (I-9) + (II-5), (I-9) + (II-6), (I-9) + (II-9), (I-9) ) + (11-12), (I-9) + (111-1), (I-9) + (III-4), (I-9) + (111-10), (I-9) + (111-11), (I-9) + (IV-1), (I-9) + (IV-2), (I-9) + (IV-3), (I-9) + (IV -4), (I-9) + (IV-5), (I-9) + (b-1), (I-9) + (b-2), (I-9) + (b-3) ), (I-9) + (b-4), (I-9) + (b-5), (I-9) + (b-6), (I-9) + (b-7), (I-9) + (b-8), (I-9) + (b-9), (I-9) + (b-10), (I-9) + (b-11), (I -9) + (b-12), (I-9) + (b-13), (I-9) + (b-14), (I-9) + (S3-1), (I-9) + (S3-2), ( I-9) + (S3-3), (I-9) + (S3-4), (I-9) + (S3-5), (I-9) + (h-1), (I- 9) + (h-2), (I-9) + (V-1), (I-9) + (V-2), (I-9) + (V-3), (I-9) + (V-4), (I-9) + (V-5), (I-9) + (V-6). (1-10) + (ll-O), (1-10) + (11-1), (1-10) + (II-2), (1-10) + (II-3), (1 -10) + (II-4), (1-10) + (II-5), (1-10) + (II-6), (1-10) + (II-9), (1-10) ) + (11-12), (1-10) + (111-1), (1-10) + (III-4), (1-10) + (111-10), (1-10) + (111-11), (1-10) + (IV-1), (1-10) + (IV-2), (I-10) + (IV-3), (1-10) + (IV -4), (1-10) + (IV-5), (1-10) + (b-1), (1-10) + (b-2), (1-10) + (b-3) ), (1-10) + (b-4), (1-10) + (b-5), (1-10) + (b-6), (1-10) + (b-7), (1-10) + (b-8), (I-10) + (b-9), (1-10) + (b-10), (1-10) + (b-11), (1 -10) + (b-12), (1-10) + (b-13), (1-10) + (b-14), (1-10) + (S3-1), (1-10) ) + (S3-2), (1-10) + (S3-3), (1-10) + (S3-4), (1-10) + (S3-5), (1-10) + (h-1), (1-10) + (h-2), (1-10) + (V-1), (1-10) + (V-2), (1-10) + (V -3), (1-10) + (V-4), (1-10) + (V-5), (1-10) + (V-6). (1-11) + (ll-O), (1-11) + (11-1), (1-11) + (II-2), (1-11) + (II-3), (1 -11) + (II-4), (1-11) + (II-5), (1-11) + (II-6), (1-11) + (II-9), (1-11) ) + (11-12), (1-11) + (111-1), (1-11) + (III-4), (1-11) + (111-10), (1-11) + (111-11), (1-11) + (IV-1), (1-11) + (IV-2), (I-11) + (IV-3), (1-11) + (IV -4), (1-11) + (IV-5), (1-11) + (b-1), (1-11) + (b-2), (1-11) + (b-3) ), (1-11) + (b-4), (1-11) + (b-5), (1-11) + (b-6), (1-11) + (b-7), (1-11) + (b-8), (I-11) + (b-9), (1-11) + (b-10), (1-11) + (b-11), (1 -11) + (b-12), (1-11) + (b-13), (1-11) + (b-14), (1-11) + (S3-1), (1-11) ) + (S3-2), (1-11) + (S3-3), (1-11) + (S3-4), (1-11) + (S3-5), (1-11) + (h-1), (1-11) + (h-2), (1-11) + (V-1), (1-11) + (V-2), (1-11) + (V -3), (1-11) + (V-4), (1-11) + (V-5), (1-11) + (V-6). (1-12) + (ll-O), (1-12) + (11-1), (1-12) + (II-2), (1-12) + (II-3), (1 -12) +
(II-4), (1-12) + (II-5), (1-12) + (II-6), (1-12) + (II-9), (1-12) + (11 -12), (1-12) + (111-1),
(1-12) + (III-4), (1-12) + (111-10), (1-12) + (111-11), (1-12) + (IV-1), (1 -12) + (IV-2), (I-12) + (IV-3), (1-12) + (IV-4), (1-12) + (IV-5), (1-12) ) + (b-1), (1-12) + (b-2), (1-12) +
(b-3), (1-12) + (b-4), (1-12) + (b-5), (1-12) + (b-6), (1-12) + (b -7), (1-12) + (b-8), (I-12) + (b-9), (1-12) + (b-10), (1-12) + (b-11) ), (1-12) + (b-12), (1-12) + (b-13), (1-12) + (b-14), (1-12) + (S3-1), (1-12) + (S3-2), (1-12) + (S3-3), (1-12) + (S3-4), (1-12) + (S3-5), (1 -12) + (h-1), (1-12) + (h-2), (1-12) + (V-1), (1-12) + (V-2), (1-12) ) + (V-3), (1-12) + (V-4), (1-12) + (V-5), (1-12) + (V-6). (1-13) + (ll-O), (1-13) + (11-1), (1-13) + (II-2), (1-13) + (II-3), (1 -13) + (II-4), (1-13) + (II-5), (1-13) + (II-6), (1-13) + (II-9), (1-13) ) + (11-12), (1-13) + (111-1), (1-13) + (III-4), (1-13) + (111-10), (1-13) + (111-11), (1-13) + (IV-1), (1-13) + (IV-2), (I-13) + (IV-3), (1-13) + (IV -4), (1-13) + (IV-5), (1-13) + (b-1), (1-13) + (b-2), (1-13) + (b-3) ), (1-13) + (b-4), (1-13) + (b-5), (1-13) + (b-6), (1-13) + (b-7), (1-13) + (b-8), (I-13) + (b-9), (1-13) + (b-10), (1-13) + (b-11), (1 -13) + (b-12), (1-13) + (b-13), (1-13) + (b-14), (1-13) + (S3-1), (1-13) ) + (S3-2), (1-13) + (S3-3), (1-13) + (S3-4), (1-13) + (S3-5), (1-13) + (h-1), (1-13) + (h-2), (1-13) + (V-1), (1-13) + (V-2), (1-13) + (V -3), (1-13) + (V-4), (1-13) + (V-5), (1-13) + (V-6). (1-14) + (ll-O), (1-14) + (11-1), (1-14) + (II-2), (1-14) + (II-3), (1 -14) +
(II-4), (1-14) + (II-5), (1-14) + (II-6), (1-14) + (II-9), (1-14) + (11 -12), (1-14) + (111-1), (1-14) + (III-4), (1-14) + (111-10), (1-14) + (111-11) ), (1-14) + (IV-1), (1-14) + (IV-2), (I-14) + (IV-3), (1-14) + (IV-4), (1-14) + (IV-5), (1-14) + (b-1), (1-14) + (b-2), (1-14) +
(b-3), (1-14) + (b-4), (1-14) + (b-5), (1-14) + (b-6), (1-14) + (b -7), (1-14) + (b-8), (I-14) + (b-9), (1-14) + (b-10), (1-14) + (b-11) ), (1-14) + (b-12), (1-14) + (b-13), (1-14) + (b-14), (1-14) + (S3-1), (1-14) + (S3-2), (1-14) + (S3-3), (1-14) + (S3-4), (1-14) + (S3-5), (1 -14) + (h-1), (1-14) + (h-2), (1-14) + (V-1), (1-14) + (V-2), (1-14) ) + (V-3),
(1-14) + (V-4), (1-14) + (V-5), (1-14) + (V-6). (1-15) + (ll-O), (1-15) + (11-1), (1-15) + (II-2), (1-15) + (II-3), (1 -15) +
(II-4), (1-15) + (II-5), (1-15) + (II-6), (1-15) + (II-9), (1-15) + (11 -12), (1-15) + (111-1),
(1-15) + (III-4), (1-15) + (111-10), (1-15) + (111-11), (1-15) + (IV-1), (1 -15) + (IV-2), (I-15) + (IV-3), (1-15) + (IV-4), (1-15) + (IV-5), (1-15) ) + (b-1), (1-15) + (b-2), (1-15) +
(b-3), (1-15) + (b-4), (1-15) + (b-5), (1-15) + (b-6), (1-15) + (b -7), (1-15) + (b-8), (I-15) + (b-9), (1-15) + (b-10), (1-15) + (b-11) ), (1-15) + (b-12), (1-15) + (b-13), (1-15) + (b-14), (1-15) + (S3-1), (1-15) + (S3-2), (1-15) + (S3-3), (1-15) + (S3-4), (1-15) + (S3-5), (1 -15) + (h-1), (1-15) + (h-2), (1-15) + (V-1), (1-15) + (V-2), (1-15) ) + (V-3), (1-15) + (V-4), (1-15) + (V-5), (1-15) + (V-6). (1-16) + (ll-O), (1-16) + (11-1), (1-16) + (II-2), (1-16) + (II-3), (1 -16) + (II-4), (1-16) + (II-5), (1-16) + (II-6), (1-16) + (II-9), (1-16) ) + (11-12), (1-16) + (111-1), (1-16) + (III-4), (1-16) + (111-10), (1-16) + (111-11), (1-16) + (IV-1), (1-16) + (IV-2), (I- 16) + (IV-3), (1-16) + (IV -4), (1-16) + (IV-5), (1-16) + (b-1), (1-16) + (b-2), (1-16) + (b-3) ), (1-16) + (b-4), (1-16) + (b-5), (1-16) + (b-6), (1-16) + (b-7), (1-16) + (b-8), (I- 16) + (b-9), (1-16) + (b-10), (1-16) + (b-11), (1 -16) + (b-12), (1-16) + (b-13), (1-16) + (b-14), (1-16) + (S3-1), (1-16) ) + (S3-2), (1-16) + (S3-3), (1-16) + (S3-4), (1-16) + (S3-5), (1-16) + (h-1), (1-16) + (h-2), (1-16) + (V-1), (1-16) + (V-2), (1-16) + (V -3), (1-16) + (V-4), (1-16) + (V-5), (1-16) + (V-6). (1-17) + (ll-O), (1-17) + (11-1), (1-17) + (II-2), (1-17) + (II-3), (1 -17) +
(II-4), (1-17) + (II-5), (1-17) + (II-6), (1-17) + (II-9), (1-17) + (11 -12), (1-17) + (111-1),
(1-17) + (III-4), (1-17) + (111-10), (1-17) + (111-11), (1-17) + (IV-1), (1 -17) + (IV-2), (I-17) + (IV-3), (1-17) + (IV-4), (1-17) + (I V-5), (1- 17) + (b-1), (1-17) + (b-2), (1-17) +
(b-3), (1-17) + (b-4), (1-17) + (b-5), (1-17) + (b-6), (1-17) + (b -7), (1-17) + (b-8), (I- 17) + (b-9), (1-17) + (b-10), (1-17) + (b-11) ), (1-17) + (b-12), (1-17) + (b-13), (1-17) + (b-14), (1-17) + (S3-1), (1-17) + (S3-2), (1-17) + (S3-3), (1-17) + (S3-4), (1-17) + (S3-5), (1 -17) + (h-1), (1-17) + (h-2), (1-17) + (V-1), (1-17) + (V-2), (1-17) ) + (V-3), (1-17) + (V-4), (1-17) + (V-5), (1-17) + (V-6). (1-18) + (ll-O), (1-18) + (11-1), (1-18) + (II-2), (1-18) + (II-3), (1 -18) + (II-4), (1-18) + (II-5), (1-18) + (II-6), (1-18) + (II-9), (1-18) ) + (11-12), (1-18) + (111-1), (1-18) + (III-4), (1-18) + (111-10), (1-18) + (111-11), (1-18) + (IV-1), (1-18) + (IV-2), (I-18) + (IV-3), (1-18) + (IV -4), (1-18) + (IV-5), (1-18) + (b-1), (1-18) + (b-2), (1-18) + (b-3) ), (1-18) + (b-4), (1-18) + (b-5), (1-18) + (b-6), (1-18) + (b-7), (1-18) + (b-8), (I-18) + (b-9), (1-18) + (b-10), (1-18) + (b-11), (1 -18) + (b-12), (1-18) + (b-13), (1-18) + (b-14), (1-18) + (S3-1), (1-18) ) + (S3-2), (1-18) + (S3-3), (1-18) + (S3-4), (1-18) + (S3-5), (1-18) + (h-1), (1-18) + (h-2), (1-18) + (V-1), (1-18) + (V-2), (1-18) + (V -3), (1-18) + (V-4), (1-18) + (V-5), (1-18) + (V-6). (1-19) + (ll-O), (1-19) + (11-1), (1-19) + (II-2), (1-19) + (II-3), (1 -19) +
(II-4), (1-19) + (II-5), (1-19) + (II-6), (1-19) + (II-9), (1-19) + (11 -12), (1-19) + (111-1), (1-19) + (III-4), (1-19) + (111-10), (1-19) + (111-11) ), (1-19) + (1V-1), (1-19) + (IV-2), (I-19) + (IV-3), (1-19) + (IV-4), (1-19) + (IV-5), (1-19) + (b-1), (1-19) + (b-2), (1-19) +
(b-3), (1-19) + (b-4), (1-19) + (b-5), (1-19) + (b-6), (1-19) + (b -7), (1-19) + (b-8), (I-19) + (b-9), (1-19) + (b-10), (1-19) + (b-11) ), (1-19) + (b-12), (1-19) + (b-13), (1-19) + (b-14), (1-19) + (S3-1), (1-19) + (S3-2), (1-19) + (S3-3), (1-19) + (S3-4), (1-19) + (S3-5), (1 -19) + (h-1), (1-19) + (h-2), (1-19) + (V-1), (1-19) + (V-2), (1-19) ) + (V-3),
(1-19) + (V-4), (1-19) + (V-5), (1-19) + (V-6). (I-20) + (ll-O), (I-20) + (11-1), (I-20) + (II-2), (I-20) + (II-3), (I -20) +
(II-4), (I-20) + (II-5), (I-20) + (II-6), (I-20) + (II-9), (I-20) + (11 -12), (I-20) + (111-1),
(I-20) + (IH-4), (I-20) + (111-10), (I-20) + (111-11), (I-20) + (IV-1), (I -20) + (IV-2), (I-20) + (IV-3), (I-20) + (IV-4), (I-20) + (IV-5), (I-20) ) + (b-1), (I-20) + (b-2), (I-20) +
(b-3), (I-20) + (b-4), (I-20) + (b-5), (I-20) + (b-6), (I-20) + (b -7), (I-20) + (b-8), (I-20) + (b-9), (I-20) + (b-10), (I-20) + (b-11) ), (I-20) + (b-12), (I-20) + (b-13), (I-20) + (b-14), (I-20) + (S3-1), (I-20) + (S3-2), (I-20) + (S3-3), (I-20) + (S3-4), (I-20) + (S3-5), (I -20) + (h-1), (I-20) + (h-2), (I-20) + (V-1), (I-20) + (V-2), (I-20) ) + (V-3), (I-20) + (V-4), (I-20) + (V-5), (I-20) + (V-6). (1-21) + (ll-O), (1-21) + (11-1), (1-21) + (ll-2), (1-21) + (II-3), (1 -21) + (II-4), (1-21) + (II-5), (1-21) + (II-6), (1-21) + (II-9), (1-21) ) + (11-12), (1-21) + (111-1), (1-21) + (III-4), (1-21) + (111-10), (1-21) + (111-11), (1-21) + (IV-1), (1-21) + (IV-2), (I-21) + (IV-3), (1-21) + (IV -4), (1-21) + (IV-5), (1-21) + (b-1), (1-21) + (b-2), (1-21) + (b-3) ), (1-21) + (b-4), (1-21) + (b-5), (1-21) + (b-6), (1-21) + (b-7), (1-21) + (b-8), (I-21) + (b-9), (1-21) + (b-10), (1-21) + (b-11), (1 -21) + (b-12), (1-21) + (b-13), (1-21) + (b-14), (1-21) + (S3-1), (1-21) ) + (S3-2), (1-21) + (S3-3), (1-21) + (S3-4), (1-21) + (S3-5), (1-21) + (h-1), (1-21) + (h-2), (1-21) + (V-1), (1-21) + (V-2), (1-21) + (V -3), (1-21) + (V-4), (1-21) + (V-5), (1-21) + (V-6). (I-22) + (ll-O), (I-22) + (11-1), (I-22) + (II-2), (I-22) + (II-3), (I -22) +
(II-4), (I-22) + (II-5), (I-22) + (II-6), (I-22) + (II-9), (I-22) + (11 -12), (I-22) + (111-1),
(I-22) + (III-4), (I-22) + (111-10), (I-22) + (111-11), (I-22) + (IV-1), (I -22) + (IV-2), (I-22) + (IV-3), (I-22) + (IV-4), (I-22) + (IV-5), (I-22) ) + (b-1), (I-22) + (b-2), (I-22) +
(b-3), (I-22) + (b-4), (I-22) + (b-5), (I-22) + (b-6), (I-22) + (b -7), (I-22) + (b-8), (I-22) + (b-9), (I-22) + (b-10), (I-22) + (b-11) ), (I-22) + (b-12), (I-22) + (b-13), (i-22) + (b-14), (I-22) + (S3-1), (I-22) + (S3-2), ( I-22) + (S3-3), (I-22) + (S3-4), (I-22) + (S3-5), (I-22) + (h-1), (I- 22) + (h-2), (I-22) + (V-1), (I-22) + (V-2), (I-22) + (V-3), (I-22) + (V-4), (I-22) + (V-5), (I-22) + (V-6). (I-23) + (ll-O), (I-23) + (11-1), (I-23) + (II-2), (I-23) + (II-3), (I -23) + (II-4), (I-23) + (II-5), (I-23) + (II-6), (I-23) + (II-9), (I-23) ) + (11-12), (I-23) + (111-1), (I-23) + (III-4), (I-23) + (111-10), (I-23) + (111-11), (I-23) + (IV-1), (I-23) + (IV-2), (I-23) + (IV-3), (I-23) + (IV -4), (I-23) + (IV-5), (I-23) + (b-1), (I-23) + (b-2), (I-23) + (b-3) ), (I-23) + (b-4), (I-23) + (b-5), (I-23) + (b-6), (I-23) + (b-7), (I-23) + (b-8), (I-23) + (b-9), (I-23) + (b-10), (I-23) + (b-11), (I -23) + (b-12), (I-23) + (b-13), (I-23) + (b-14), (I-23) + (S3-1), (I-23) ) + (S3-2), (I-23) + (S3-3), (I-23) + (S3-4), (I-23) + (S3-5), (1-23) + (h-1), (I-23) + (h-2), (I-23) + (V-1), (I-23) + (V-2), (I-23) + (V -3), (I-23) + (V-4), (I-23) + (V-5), (I-23) + (V-6). (I-24) + (ll-O), (I-24) + (11-1), (I-24) + (II-2), (I-24) + (II-3), (I -24) +
(II-4), (I-24) + (II-5), (I-24) + (II-6), (I-24) + (II-9), (I-24) + (11 -12), (I-24) + (111-1), (I-24) + (ill-4), (I-24) + (111-10), (I-24) + (111-11) ), (I-24) + (IV-1), (I-24) + (IV-2), (I-24) + (IV-3), (I-24) + (IV-4), (I-24) + (IV-5), (I-24) + (b-1), (I-24) + (b-2), (I-24) +
(b-3), (I-24) + (b-4), (I-24) + (b-5), (I-24) + (b-6), (I-24) + (b -7), (I-24) + (b-8), (I-24) + (b-9), (I-24) + (b-10), (I-24) + (b-11) ), (I-24) + (b-12), (I-24) + (b-13), (I-24) + (b-14), (I-24) + (S3-1), (I-24) + (S3-2), (I-24) + (S3-3), (I-24) + (S3-4), (I-24) + (S3-5), (I -24) + (h-1), (I-24) + (h-2), (I-24) + (V-1), (I-24) + (V-2), (I-24) ) + (V-3),
(I-24) + (V-4), (I-24) + (V-5), (I-24) + (V-6). (I-25) + (ll-O), (I-25) + (11-1), (I-25) + (II-2), (I-25) + (II-3), (I -25) +
(II-4), (I-25) + (II-5), (I-25) + (II-6), (I-25) + (II-9), (I-25) + (11 -12), (I-25) + (111-1),
(I-25) + (III-4), (I-25) + (111-10), (I-25) + (111-11), (I-25) + (IV-1), (I -25) + (IV-2), (I-25) + (IV-3), (I-25) + (IV-4), (I-25) + (IV-5), (I-25) ) + (b-1), (I-25) + (b-2), (I-25) +
(b-3), (I-25) + (b-4), (I-25) + (b-5), (I-25) + (b-6), (I-25) + (b -7), (I-25) + (b-8), (I-25) + (b-9), (I-25) + (b-10), (I-25) + (b-11) ), (I-25) + (b-12), (I-25) + (b-13), (I-25) + (b-14), (I-25) + (S3-1), (I-25) + (S3-2), (I-25) + (S3-3), (I-25) + (S3-4), (I-25) + (S3-5), (I -25) + (h-1), (I-25) + (h-2), (I-25) + (V-1), (I-25) + (V-2), (I-25) ) + (V-3), (I-25) + (V-4), (I-25) + (V-5), (I-25) + (V-6). (I-26) + (ll-O), (I-26) + (11-1), (I-26) + (II-2), (I-26) + (II-3), (I -26) + (II-4), (I-26) + (II-5), (I-26) + (II-6), (I-26) + (II-9), (I-26) ) + (11-12), (I-26) + (111-1), (I-26) + (III-4), (I-26) + (111-10), (I-26) + (111-11), (I-26) + (IV-1), (I-26) + (IV-2), (I- 26) + (IV-3), (I-26) + (IV -4), (I-26) + (IV-5), (I-26) + (b-1), (I-26) + (b-2), (I-26) + (b-3) ), (I-26) + (b-4), (I-26) + (b-5), (I-26) + (b-6), (I-26) + (b-7), (I-26) + (b-8), (I- 26) + (b-9), (I-26) + (b-10), (I-26) + (b-11), (I -26) + (b-12), (I-26) + (b-13), (I-26) + (b-14), (I-26) + (S3-1), (I-26) ) + (S3-2), (I-26) + (S3-3), (I-26) + (S3-4), (I-26) + (S3-5), (I-26) + (h-1), (I-26) + (h-2), (I-26) + (V-1), (I-26) + (V-2), (I-26) + (V -3), (I-26) + (V-4), (I-26) + (V-5), (I-26) + (V-6). (I-27) + (ll-O), (I-27) + (11-1), (I-27) + (II-2), (I-27) + (II-3), (I -27) +
(II-4), (I-27) + (II-5), (I-27) + (II-6), (I-27) + (II-9), (I-27) + (11 -12), (I-27) + (111-1),
(I-27) + (III-4), (I-27) + (111-10), (I-27) + (111-1 1), (I-27) + (IV-1), ( I-27) + (IV-2), (I-27) + (IV-3), (I-27) + (IV-4), (I-27) + (IV-5), (I- 27) + (b-1), (I-27) + (b-2), (I-27) +
(b-3), (I-27) + (b-4), (I-27) + (b-5), (I-27) + (b-6), (I-27) + (b -7), (I-27) + (b-8), (I- 27) + (b-9), (I-27) + (b-10), (I-27) + (b-11) ), (I-27) + (b-12), (I-27) + (b-13), (I-27) + (b-14), (I-27) + (S3-1), (I-27) + (S3-2), (I-27) + (S3-3), (I-27) + (S3-4), (I-27) + (S3-5), (I -27) + (h-1), (I-27) + (h-2), (I-27) + (V-1), (I-27) + (V-2), (I-27) ) + (V-3), (I-27) + (V-4), (I-27) + (V-5), (I-27) + (V-6). (I-28) + (ll-O), (I-28) + (11-1), (I-28) + (II-2), (I-28) + (II-3), (1 -28) + (II-4), (I-28) + (II-5), (I-28) + (II-6), (I-28) + (II-9), (I-28) ) + (11-12), (I-28) + (111-1), (I-28) + (III-4), (I-28) + (111-10), (I-28) + (111-11), (I-28) + (IV-1), (I-28) + (IV-2), (I-28) + (IV-3), (1-28) + (IV -4), (I-28) + (IV-5), (I-28) + (b-1), (I-28) + (b-2), (I-28) + (b-3) ), (I-28) + (b-4), (I-28) + (b-5), (I-28) + (b-6), (I-28) + (b-7), (I-28) + (b-8), (I-28) + (b-9), (I-28) + (b-10), (I-28) + (b-11), (I -28) + (b-12), (I-28) + (b-13), (I-28) + (b-14), (I-28) + (S3-1), (I-28) ) + (S3-2), (I-28) + (S3-3), (I-28) + (S3-4), (I-28) + (S3-5), (1-28) + (h-1), (I-28) + (h-2), (I-28) + (V-1), (I-28) + (V-2), (I-28) + (V -3), (I-28) + (V-4), (I-28) + (V-5), (I-28) + (V-6). (I-29) + (ll-O), (I-29) + (11-1), (I-29) + (II-2), (I-29) + (II-3), (I -29) +
(II-4), (I-29) + (II-5), (I-29) + (II-6), (I-29) + (II-9), (I-29) + (11 -12), (I-29) + (111-1), (I-29) + (III-4), (I-29) + (111-10), (I-29) + (111-11) ), (I-29) + (IV-1), (I-29) + (IV-2), (I-29) + (IV-3), (I-29) + (IV-4), (I-29) + (IV-5), (I-29) + (b-1), (I-29) + (b-2), (I-29) +
(b-3), (I-29) + (b-4), (I-29) + (b-5), (I-29) + (b-6), (I-29) + (b -7), (I-29) + (b-8), (I-29) + (b-9), (I-29) + (b-10), (1-29) + (b-11) ), (I-29) + (b-12), (I-29) + (b-13), (I-29) + (b-14), (I-29) + (S3-1), (I-29) + (S3-2), (I-29) + (S3-3), (I-29) + (S3-4), (I-29) + (S3-5), (I -29) + (h-1), (I-29) + (h-2), (I-29) + (V-1), (I-29) + (V-2), (I-29) ) + (V-3),
(1-29) + (V-4), (I-29) + (V-5), (I-29) + (V-6). (I-30) + (ll-O), (I-30) + (11-1), (I-30) + (II-2), (I-30) + (II-3), (I -30) +
(II-4), (I-30) + (II-5), (I-30) + (II-6), (I-30) + (II-9), (I-30) + (11 -12), (I-30) + (III-1),
(I-30) + (III-4), (I-30) + (111-10), (I-30) + (111-11), (I-30) + (IV-1), (I -30) + (IV-2), (I-30) + (IV-3), (I-30) + (IV-4), (I-30) + (IV-5), (I-30) ) + (b-1), (I-30) + (b-2), (I-30) +
(b-3), (I-30) + (b-4), (I-30) + (b-5), (I-30) + (b-6), (I-30) + (b -7), (I-30) + (b-8), (I-30) + (b-9), (I-30) + (b-10), (I-30) + (b-11) ), (I-30) + (b-12), (I-30) + (b-13), (I-30) + (b-14), (I-30) + (S3-1), (I-30) + (S3-2), (I-30) + (S3-3), (I-30) + (S3-4), (I-30) + (S3-5), (I -30) + (h-1), (I-30) + (h-2), (I-30) + (V-1), (I-30) + (V-2), (I-30) ) + (V-3), (I-30) + (V-4), (I-30) + (V-5), (I-30) + (V-6). (1-31) + (ll-O), (1-31) + (11-1), (1-31) + (II-2), (1-31) + (II-3), (1 -31) + (II-4), (1-31) + (II-5), (1-31) + (II-6), (1-31) + (II-9), (1-31) ) + (11-12), (1-31) + (111-1), (1-31) + (III-4), (1-31) + (111-10), (1-31) + (111-11), (1-31) + (IV-1), (1-31) + (IV-2), (I-31) + (IV-3), (1-31) + (IV -4), (1-31) + (IV-5), (1-31) + (b-1), (1-31) + (b-2), (1-31) + (b-3) ), (1-31) + (b-4), (1-31) + (b-5), (1-31) + (b-6), (1-31) + (b-7), (1-31) + (b-8), (I- 31) + (b-9), (1-31) + (b-10), (1-31) + (b-11), (1 -31) + (b-12), (1-31) + (b-13), (1-31) + (b-14), (1-31) + (S3-1), (1-31) ) + (S3-2), (1-31) + (S3-3), (1-31) + (S3-4), (1-31) + (S3-5), (1-31) + (h-1), (1-31) + (h-2), (1-31) + (V-1), (1-31) + (V-2), (1-31) + (V -3), (1-31) + (V-4), (1-31) + (V-5), (1-31) + (V-6). (I-32) + (ll-O), (I-32) + (11-1), (I-32) + (II-2), (I-32) + (II-3), (I -32) +
(II-4), (I-32) + (II-5), (I-32) + (II-6), (I-32) + (II-9), (I-32) + (11 -12), (I-32) + (111-1),
(I-32) + (III-4), (I-32) + (111-10), (I-32) + (111-1 1), (I-32) + (IV-1), ( 1-32) + (IV-2), (I-32) + (IV-3), (I-32) + (IV-4), (I-32) + (IV-5), (I- 32) + (b-1), (I-32) + (b-2), (I-32) +
(b-3), (I-32) + (b-4), (I-32) + (b-5), (I-32) + (b-6), (I-32) + (b -7), (I-32) + (b-8), (I-32) + (b-9), (I-32) + (b-10), (I-32) + (b-11) ), (I-32) + (b-12), (I-32) + (b-13), (I-32) + (b-14), (I-32) + (S3-1), (I-32) + (S3-2), (I-32) + (S3-3), (I-32) + (S3-4), (I-32) + (S3-5), (I -32) + (h-1), (I-32) + (h-2), (I-32) + (V-1), (I-32) + (V-2), (I-32) ) + (V-3), (I-32) + (V-4), (I-32) + (V-5), (I-32) + (V-6). (I-33) + (ll-O), (I-33) + (11-1), (I-33) + (II-2), (I-33) + (II-3), (I -33) + (II-4), (I-33) + (II-5), (I-33) + (II-6), (I-33) + (II-9), (I-33) ) + (11-12), (I-33) + (111-1), (I-33) + (III-4), (I-33) + (111-10), (I-33) + (111-11), (I-33) + (IV-1), (I-33) + (IV-2), (I-33) + (IV-3), (I-33) + (IV -4), (I-33) + (IV-5), (I-33) + (b-1), (I-33) + (b-2), (I-33) + (b-3) ), (I-33) + (b-4), (I-33) + (b-5), (I-33) + (b-6), (I-33) + (b-7), (I-33) + (b-8), (I-33) + (b-9), (I-33) + (b-10), (I-33) + (b-11), (I -33) + (b-12), (I-33) + (b-13), (I-33) + (b-14), (I-33) + (S3-1), (I-33) ) + (S3-2), (I-33) + (S3-3), (I-33) + (S3-4), (I-33) + (S3-5), (1-33) + (h-1), (I-33) + (h-2), (I-33) + (V-1), (I-33) + (V-2), (I-33) + (V -3), (I-33) + (V-4), (I-33) + (V-5), (I-33) + (V-6). (I-34) + (ll-O), (I-34) + (11-1), (I-34) + (II-2), (I-34) + (II-3), (I -34) +
(II-4), (I-34) + (II-5), (I-34) + (II-6), (I-34) + (II-9), (I-34) + (11 -12), (I-34) + (111-1), (I-34) + (III-4), (I-34) + (111-10), (I-34) + (111-11) ), (I-34) + (IV-1), (I-34) + (IV-2), (I-34) + (IV-3), (I-34) + (IV-4), (I-34) + (IV-5), (I-34) + (b-1), (I-34) + (b-2), (I-34) +
(b-3), (I-34) + (b-4), (I-34) + (b-5), (I-34) + (b-6), (I-34) + (b -7), (I-34) + (b-8), (I-34) + (b-9), (I-34) + (b-10), (I-34) + (b-11) ), (I-34) + (b-12), (I-34) + (b-13), (I-34) + (b-14), (I-34) + (S3-1), (I-34) + (S3-2), (I-34) + (S3-3), (I-34) + (S3-4), (I-34) + (S3-5), (I -34) + (h-1), (I-34) + (h-2), (I-34) + (V-1), (I-34) + (V-2), (I-34) ) + (V-3),
(I-34) + (V-4), (I-34) + (V-5), (I-34) + (V-6). . (I-35) + (ll-O), (I-35) + (11-1), (I-35) + (II-2), (I-35) + (II-3), (I -35) +
(II-4), (I-35) + (II-5), (I-35) + (II-6), (I-35) + (II-9), (I-35) + (11 -12), (I-35) + (111-1),
(I-35) + (III-4), (I-35) + (111-10), (I-35) + (111-11), (I-35) + (IV-1), (I -35) + (IV-2), (I-35) + (IV-3), (I-35) + (IV-4), (I-35) + (IV-5), (I-35) ) + (b-1), (1-35) + (b-2), (I-35) +
(b-3), (I-35) + (b-4), (I-35) + (b-5), (I-35) + (b-6), (I-35) + (b -7), (I-35) + (b-8), (I-35) + (b-9), (I-35) + (b-10), (I-35) + (b-11) ), (I-35) + (b-12), (I-35) + (b-13), (I-35) + (b-14), (I-35) + (S3-1), (I-35) + (S3-2), (I-35) + (S3-3), (I-35) + (S3-4), (I-35) + (S3-5), (I -35) + (h-1), (I-35) + (h-2), (I-35) + (V-1), (I-35) + (V-2), (I-35) ) + (V-3), (I-35) + (V-4), (I-35) + (V-5), (I-35) + (V-6). (I-36) + (ll-O), (I-36) + (11-1), (I-36) + (II-2), (I-36) + (II-3), (I -36) + (II-4), (I-36) + (II-5), (I-36) + (II-6), (I-36) + (II-9), (I-36) ) + (11-12), (I-36) + (111-1), (I-36) + (III-4), (I-36) + (111-10), (I-36) + (111-11), (I-36) + (IV-1), (I-36) + (IV-2), (I-36) + (IV-3), (1-36) + (IV -4), (1-36) + (IV-5), (1-36) + (b-1), (I-36) + (b-2), (I-36) + (b-3) ), (I-36) + (b-4), (I-36) + (b-5), (I-36) + (b-6), (I-36) + (b-7), (I-36) + (b-8), (I-36) + (b-9), (I-36) + (b-10), (I-36) + (b-11), (I -36) + (b-12), (I-36) + (b-13), (I-36) + (b-14), (I-36) + (S3-1), (I-36) ) + (S3-2), (I-36) + (S3-3), (I-36) + (S3-4), (I-36) + (S3-5), (I-36) + (h-1), (I-36) + (h-2), (I-36) + (V-1), (I-36) + (V-2), (I-36) + (V -3), (I-36) + (V-4), (I-36) + (V-5), (I-36) + (V-6). (I-37) + (ll-O), (I-37) + (11-1), (I-37) + (II-2), (I-37) + (II-3), (I -37) +
(II-4), (I-37) + (II-5), (I-37) + (II-6), (I-37) + (II-9), (I-37) + (11 -12), (I-37) + (111-1),
(I-37) + (III-4), (I-37) + (111-10), (I-37) + (111-11), (I-37) + (IV-1), (I -37) + (IV-2), (I-37) + (IV-3), (I-37) + (IV-4), (I-37) + (IV-5), (I-37) ) + (b-1), (I-37) + (b-2), (i-37) +
(b-3), (I-37) + (b-4), (I-37) + (b-5), (I-37) + (b-6), (I-37) + (b -7), (I-37) + (b-8), (I-37) + (b-9), (I-37) + (b-10), (I-37) + (b-11) ), (I-37) + (b-12), (I-37) + (b-13), (I-37) + (b-14), (I-37) + (S3-1), (I-37) + (S3-2), (I-37) + (S3-3), (I-37) + (S3-4), (I-37) + (S3-5), (I -37) + (h-1), (I-37) + (h-2), (I-37) + (V-1), (I-37) + (V-2), (I-37) ) + (V-3), (I-37) + (V-4), (I-37) + (V-5), (I-37) + (V-6). (I-38) + (ll-O), (I-38) + (11-1), (I-38) + (II-2), (I-38) + (II-3), (I -38) + (II-4), (I-38) + (II-5), (I-38) + (II-6), (I-38) + (II-9), (I-38) ) + (11-12), (I-38) + (111-1), (I-38) + (III-4), (I-38) + (111-10), (I-38) + (111-11), (I-38) + (IV-1), (I-38) + (IV-2), (I-38) + (IV-3), (I-38) + (IV -4), (I-38) + (IV-5), (I-38) + (b-1), (I-38) + (b-2), (I-38) + (b-3) ), (I-38) + (b-4), (I-38) + (b-5), (I-38) + (b-6), (I-38) + (b-7), (I-38) + (b-8), (I-38) + (b-9), (I-38) + (b-10), (I-38) + (b-11), (I -38) + (b-12), (I-38) + (b-13), (1-38) + (b-14), (I-38) + (S3-1), (I-38) ) + (S3-2), (I-38) + (S3-3), (I-38) + (S3-4), (I-38) + (S3-5), (1-38) + (h-1), (I-38) + (h-2), (I-38) + (V-1), (I-38) + (V-2), (I-38) + (V -3), (I-38) + (V-4), (I-38) + (V-5), (I-38) + (V-6). (I-39) + (ll-O), (I-39) + (11-1), (I-39) + (II-2), (I-39) + (II-3), (I -39) +
(II-4), (I-39) + (II-5), (I-39) + (II-6), (I-39) + (II-9), (I-39) + (11 -12), (I-39) + (111-1), (I-39) + (III-4), (I-39) + (111-10), (I-39) + (111-11) ), (I-39) + (IV-1), (I-39) + (IV-2), (I-39) + (IV-3), (I-39) + (IV-4), (I-39) + (IV-5), (I-39) + (b-1), (I-39) + (b-2), (I-39) +
(b-3), (I-39) + (b-4), (I-39) + (b-5), (I-39) + (b-6), (I-39) + (b -7), (I-39) + (b-8), (I- 39) + (b-9), (I-39) + (b-10), (I-39) + (b-11) ), (I-39) + (b-12), (I-39) + (b-13), (1-39) + (b-14), (I-39) + (S3-1), (I-39) + (S3-2), (I-39) + (S3-3), (I-39) + (S3-4), (I-39) + (S3-5), (I -39) + (h-1), (I-39) + (h-2), (I-39) + (V-1), (I-39) + (V-2), (I-39) ) + (V-3),
(I-39) + (V-4), (I-39) + (V-5), (I-39) + (V-6). (I-40) + (ll-O), (I-40) + (11-1), (I-40) + (II-2), (I-40) + (II-3), (I -40) +
(II-4), (I-40) + (II-5), (I-40) + (II-6), (I-40) + (II-9), (I-40) + (11 -12), (I-40) + (111-1),
(I-40) + (III-4), (I-40) + (111-10), (I-40) + (111-11), (I-40) + (IV-1), (I -40) + (IV-2), (I-40) + (IV-3), (I-40) + (IV-4), (I-40) + (IV-5), (I-40) ) + (b-1), (I-40) + (b-2), (I-40) +
(b-3), (I-40) + (b-4), (I-40) + (b-5), (I-40) + (b-6), (I-40) + (b -7), (I-40) + (b-8), (I-40) + (b-9), (I-40) + (b-10), (I-40) + (b-11) ), (I-40) + (b-12), (I-40) + (b-13), (1-40) + (b-14), (I-40) + (S3-1), (I-40) + (S3-2), (I-40) + (S3-3), (I-40) + (S3-4), (I-40) + (S3-5), (I -40) + (h-1), (I-40) + (h-2), (I-40) + (V-1), (I-40) + (V-2), (I-40) ) + (V-3), (I-40) + (V-4), (I-40) + (V-5), (I-40) + (V-6). (1-41) + (ll-O), (1-41) + (11-1), (1-41) + (II-2), (1-41) + (ll-3), (1 -41) + (II-4), (1-41) + (II-5), (1-41) + (II-6), (1-41) + (II-9), (1-41) ) + (11-12), (1-41) + (111-1), (1-41) + (III-4), (1-41) + (111-10), (1-41) + (111-11), (1-41) + (IV-1), (1-41) + (IV-2), (I- 41) + (IV-3), (1-41) + (IV -4), (1-41) + (IV-5), (1-41) + (b-1), (1-41) + (b-2), (1-41) + (b-3) ), (1-41) + (b-4), (1-41) + (b-5), (1-41) + (b-6), (1-41) + (b-7), (1-41) + (b-8), (I-41) + (b-9), (1-41) + (b-10), (1-41) + (b-11), (1 -41) + (b-12), (1-41) + (b-13), (1-41) + (b-14), (1-41) + (S3-1), (1-41) ) + (S3-2), (1-41) + (S3-3), (1-41) + (S3-4), (1-41) + (S3-5), (1-41) + (h-1), (1-41) + (h-2), (1-41) + (V-1), (1-41) + (V-2), (1-41) + (V -3), (1-41) + (V-4), (1-41) + (V-5), (1-41) + (V-6). (I-42) + (ll-O), (I-42) + (11-1), (I-42) + (II-2), (I-42) + (II-3), (I -42) +
(II-4), (I-42) + (II-5), (I-42) + (II-6), (I-42) + (II-9), (I-42) + (11 -12), (I-42) + (111-1),
(I-42) + (III-4), (I-42) + (111-10), (I-42) + (111-11), (I-42) + (IV-1), (I -42) + (IV-2), (I-42) + (IV-3), (I-42) + (IV-4), (I-42) + (IV-5), (I-42) ) + (b-1), (I-42) + (b-2), (I-42) +
(b-3), (I-42) + (b-4), (I-42) + (b-5), (I-42) + (b-6), (I-42) + (b -7), (I-42) + (b-8), (I-42) + (b-9), (I-42) + (b-10), (I-42) + (b-11) ), (I-42) + (b-12), (I-42) + (b-13), (I-42) + (b-14), (I-42) + (S3-1), (I-42) + (S3-2), (I-42) + (S3-3), (I-42) + (S3-4), (I-42) + (S3-5), (I -42) + (h-1), (I-42) + (h-2), (I-42) + (V-1), (I-42) + (V-2), (I-42) ) + (V-3), (I-42) + (V-4), (I-42) + (V-5), (I-42) + (V-6). (I-43) + (ll-O), (I-43) + (11-1), (I-43) + (II-2), (I-43) + (II-3), (I -43) + (II-4), (I-43) + (II-5), (I-43) + (II-6), (I-43) + (II-9), (I-43) ) + (11-12), (I-43) + (111-1), (I-43) + (III-4), (I-43) + (111-10), (I-43) + (111-11), (I-43) + (IV-1), (I-43) + (IV-2), (I-43) + (IV-3), (I-43) + (IV -4), (I-43) + (IV-5), (I-43) + (b-1), (I-43) + (b-2), (I-43) + (b-3) ), (I-43) + (b-4), (I-43) + (b-5), (I-43) + (b-6), (I-43) + (b-7), (I-43) + (b-8), (I-43) + (b-9), (I-43) + (b-10), (I-43) + (b-11), (I -43) + (b-12), (I-43) + (b-13), (I-43) + (b-14), (I-43) + (S3-1), (I-43) ) + (S3-2), (I-43) + (S3-3), (I-43) + (S3-4), (I-43) + (S3-5), (1-43) + (h-1), (I-43) + (h-2), (I-43) + (V-1), (I-43) + (V-2), (I-43) + (V -3), (I-43) + (V-4), (I-43) + (V-5), (I-43) + (V-6). (I-44) + (ll-O), (I-44) + (11-1), (I-44) + (II-2), (I-44) + (II-3), (I -44) +
(|| -4), (| _44) + (|| -5), (I-44) + (II-6), (I-44) + (II-9), (I-44) + ( 11-12), (I-44) + (III-1), (I-44) + (III-4), (I-44) + (111-10), (I-44) + (111-) 11), (I-44) + (IV-1), (I-44) + (IV-2), (I-44) + (IV-3), (I-44) + (IV-4) , (I-44) + (IV-5), (I-44) + (b-1), (I-44) + (b-2), (I-44) +
(b-3), (I-44) + (b-4), (I-44) + (b-5), (I-44) + (b-6), (I-44) + (b -7), (I-44) + (b-8), (I- 44) + (b-9), (I-44) + (b-10), (I-44) + (b-11) ), (I-44) + (b-12), (I-44) + (b-13), (I-44) + (b-14), (I-44) + (S3-1), (I-44) + (S3-2), (I-44) + (S3-3), (I-44) + (S3-4), (I-44) + (S3-5), (I -44) + (h-1), (I-44) + (h-2), (I-44) + (V-1), (I-44) + (V-2), (I-44) ) + (V-3),
(I-44) + (V-4), (I-44) + (V-5), (I-44) + (V-6). (I-45) + (ll-O), (I-45) + (11-1), (I-45) + (II-2), (I-45) + (li-3), (I -45) +
(II-4), (I-45) + (II-5), (I-45) + (II-6), (I-45) + (II-9), (I-45) + (11 -12), (I-45) + (111-1),
(I-45) + (III-4), (I-45) + (111-10), (I-45) + (111-11), (I-45) + (IV-1), (I -45) + (IV-2), (I-45) + (IV-3), (I-45) + (IV-4), (I-45) + (IV-5), (I-45) ) + (b-1), (I-45) + (b-2), (I-45) +
(b-3), (I-45) + (b-4), (I-45) + (b-5), (I-45) + (b-6), (I-45) + (b -7), (I-45) + (b-8), (I-45) + (b-9), (I-45) + (b-10), (I-45) + (b-11) ), (I-45) + (b-12), (I-45) + (b-13), (I-45) + (b-14), (I-45) + (S3-1), (I-45) + (S3-2), (I-45) + (S3-3), (I-45) + (S3-4), (I-45) + (S3-5), (I -45) + (h-1), (I-45) + (h-2), (I-45) + (V-1), (I-45) + (V-2), (I-45) ) + (V-3), (I-45) + (V-4), (I-45) + (V-5), (I-45) + (V-6). (I-46) + (ll-O), (I-46) + (11-1), (I-46) + (II-2), (I-46) + (II-3), (I -46) + (II-4), (I-46) + (II-5), (I-46) + (II-6), (I-46) + (II-9), (I-46) ) + (11-12), (I-46) + (111-1), (I-46) + (III-4), (I-46) + (111-10), (I-46) + (111-11), (I-46) + (IV-1), (I-46) + (IV-2), (I-46) + (IV-3), (1-46) + (IV -4), (1-46) + (IV-5), (1-46) + (b-1), (I-46) + (b-2), (I-46) + (b-3) ), (I-46) + (b-4), (I-46) + (b-5), (I-46) + (b-6), (I-46) + (b-7), (I-46) + (b-8), (I-46) + (b-9), (I-46) + (b-10), (I-46) + (b-11), (I -46) + (b-12), (I-46) + (b-13), (I-46) + (b-14), (I-46) + (S3-1), (I-46) ) + (S3-2), (I-46) + (S3-3), (I-46) + (S3-4), (I-46) + (S3-5), (I-46) + (h-1), (I-46) + (h-2), (I-46) + (V-1), (I-46) + (V-2), (I-46) + (V -3), (I-46) + (V-4), (I-46) + (V-5), (I-46) + (V-6). (I-47) + (ll-O), (I-47) + (11-1), (I-47) + (II-2), (I-47) + (II-3), (I -47) +
(II-4), (I-47) + (II-5), (I-47) + (II-6), (I-47) + (II-9), (I-47) + (11 -12), (I-47) + (111-1),
(I-47) + (III-4), (I-47) + (111-10), (I-47) + (111-11), (I-47) + (IV-1), (I -47) + (IV-2), (I-47) + (IV-3), (I-47) + (IV-4), (I-47) + (IV-5), (I-47) ) + (b-1), (I-47) + (b-2), (I-47) +
(b-3), (I-47) + (b-4), (I-47) + (b-5), (I-47) + (b-6), (I-47) + (b -7), (I-47) + (b-8), (I-47) + (b-9), (I-47) + (b-10), (I-47) + (b-11) ), (I-47) + (b-12), (I-47) + (b-13), (I-47) + (b-14), (I-47) + (S3-1), (I-47) + (S3-2), (I-47) + (S3-3), (I-47) + (S3-4), (I-47) + (S3-5), (I -47) + (h-1), (I-47) + (h-2), (I-47) + (V-1), (I-47) + (V-2), (I-47) ) + (V-3), (I-47) + (V-4), (I-47) + (V-5), (I-47) + (V-6). (I-48) + (ll-O), (I-48) + (11-1), (I-48) + (II-2), (I-48) + (II-3), (I -48) + (II-4), (I-48) + (II-5), (I-48) + (II-6), (I-48) + (II-9), (I-48) ) + (11-12), (I-48) + (111-1), (I-48) + (III-4), (I-48) + (111-10), (I-48) + (111-11), (I-48) + (IV-1), (I-48) + (IV-2), (I-48) + (IV-3), (I-48) + (IV -4), (I-48) + (IV-5), (I-48) + (b-1), (I-48) + (b-2), (I-48) + (b-3) ), (I-48) + (b-4), (I-48) + (b-5), (I-48) + (b-6), (I-48) + (b-7), (I-48) + (b-8), (I-48) + (b-9), (I-48) + (b-10), (I-48) + (b-11), (I -48) + (b-12), (I-48) + (b-13), (I-48) + (b-14), (I-48) + (S3-1), (I-48) ) + (S3-2), (I-48) + (S3-3), (I-48) + (S3-4), (I-48) + (S3-5), (1-48) + (h-1), (I-48) + (h-2), (I-48) + (V-1), (I-48) + (V-2), (I-48) + (V -3), (I-48) + (V-4), (I-48) + (V-5), (I-48) + (V-6). (I-49) + (ll-O), (I-49) + (11-1), (I-49) + (II-2), (I-49) + (II-3), (I -49) +
(II-4), (I-49) + (II-5), (I-49) + (II-6), (I-49) + (II-9), (I-49) + (11 -12), (I-49) + (111-1), (I-49) + (III-4), (I-49) + (111-10), (I-49) + (111-11) ), (I-49) + (IV-1), (I-49) + (IV-2), (I-49) + (IV-3), (I-49) + (IV-4), (I-49) + (IV-5), (I-49) + (b-1), (I-49) + (b-2), (I-49) +
(b-3), (I-49) + (b-4), (I-49) + (b-5), (I-49) + (b-6), (I-49) + (b -7), (I-49) + (b-8), (I-49) + (b-9), (I-49) + (b-10), (I-49) + (b-11) ), (I-49) + (b-12), (I-49) + (b-13), (I-49) + (b-14), (I-49) + (S3-1), (I-49) + (S3-2), (I-49) + (S3-3), (I-49) + (S3-4), (I-49) + (S3-5), (I -49) + (h-1), (I-49) + (h-2), (I-49) + (V-1), (I-49) + (V-2), (I-49) ) + (V-3),
(I-49) + (V-4), (I-49) + (V-5), (I-49) + (V-6). (I-50) + (ll-O), (I-50) + (11-1), (I-50) + (II-2), (I-50) + (II-3), (I -50) +
(II-4), (I-50) + (II-5), (I-50) + (II-6), (I-50) + (II-9), (I-50) + (11 -12), (I-50) + (111-1),
(I-50) + (III-4), (I-50) + (111-10), (I-50) + (111-11), (I-50) + (IV-1), (I -50) + (IV-2), (I-50) + (IV-3), (I-50) + (IV-4), (I-50) + (IV-5), (I-50) ) + (b-1), (I-50) + (b-2), (I-50) +
(b-3), (I-50) + (b-4), (I-50) + (b-5), (I-50) + (b-6), (I-50) + (b -7), (I-50) + (b-8), (I-50) + (b-9), (I-50) + (b-10), (I-50) + (b-11) ), (I-50) + (b-12), (I-50) + (b-13), (I-50) + (b-14), (I-50) + (S3-1), (I-50) + (S3-2), ( I-50) + (S3-3), (I-50) + (S3-4), (I-50) + (S3-5), (I-50) + (h-1), (I- 50) + (h-2), (I-50) + (V-1), (I-50) + (V-2), (I-50) + (V-3), (I-50) + (V-4), (I-50) + (V-5), (I-50) + (V-6). (1-51) + (ll-O), (1-51) + (11-1), (1-51) + (II-2), (1-51) + (II-3), (1 -51) + (II-4), (1-51) + (II-5), (1-51) + (II-6), (1-51) + (II-9), (1-51) ) + (11-12), (1-51) + (111-1), (1-51) + (III-4), (1-51) + (111-10), (1-51) + (111-11), (1-51) + (IV-1), (1-51) + (IV-2), (I-51) + (IV-3), (1-51) + (IV -4), (1-51) + (IV-5), (1-51) + (b-1), (1-51) + (b-2), (1-51) + (b-3) ), (1-51) + (b-4), (1-51) + (b-5), (1-51) + (b-6), (1-51) + (b-7), (1-51) + (b-8), (I-51) + (b-9), (1-51) + (b-10), (1-51) + (b-11), (1 -51) + (b-12), (1-51) + (b-13), (1-51) + (b-14), (1-51) + (S3-1), (1-51) ) + (S3-2), (1-51) + (S3-3), (1-51) + (S3-4), (1-51) + (S3-5), (1-51) + (h-1), (1-51) + (h-2), (1-51) + (V-1), (1-51) + (V-2), (1-51) + (V -3), (1-51) + (V-4), (1-51) + (V-5), (1-51) + (V-6). (I-52) + (ll-O), (I-52) + (11-1), (I-52) + (II-2), (I-52) + (II-3), (I -52) +
(II-4), (I-52) + (II-5), (I-52) + (II-6), (I-52) + (II-9), (I-52) + (11 -12), (I-52) + (111-1),
(I-52) + (lli-4), (I-52) + (111-10), (I-52) + (111-11), (I-52) + (IV-1), (I -52) + (IV-2), (I-52) + (IV-3), (I-52) + (IV-4), (I-52) + (IV-5), (I-52) ) + (b-1), (I-52) + (b-2), (I-52) +
(b-3), (I-52) + (b-4), (I-52) + (b-5), (I-52) + (b-6), (I-52) + (b -7), (I-52) + (b-8), (I-52) + (b-9), (I-52) + (b-10), (I-52) + (b-11) ), (I-52) + (b-12), (I-52) + (b-13), (I-52) + (b-14), (I-52) + (S3-1), (I-52) + (S3-2), (I-52) + (S3-3), (I-52) + (S3-4), (I-52) + (S3-5), (I -52) + (h-1), (I-52) + (h-2), (I-52) + (V-1), (I-52) + (V-2), (I-52) ) + (V-3), (I-52) + (V-4), (I-52) + (V-5), (I-52) + (V-6). (I-53) + (ll-O), (I-53) + (11-1), (I-53) + (II-2), (I-53) + (II-3), (1 -53) + (II-4), (I-53) + (II-5), (I-53) + (II-6), (I-53) + (II-9), (I-53) ) + (11-12), (I-53) + (111-1), (I-53) + (III-4), (I-53) + (111-10), (I-53) + (111-11), (I-53) + (IV-1), (I-53) + (IV-2), (I-53) + (IV-3), (I-53) + (IV -4), (I-53) + (IV-5), (I-53) + (b-1), (I-53) + (b-2), (I-53) + (b-3) ), (I-53) + (b-4), (I-53) + (b-5), (i-53) + (b-6), (I-53) + (b-7), (I-53) + (b-8), (I-53) + (b-9), (I-53) + (b-10), (I-53) + (b-11), (I -53) + (b-12), (I-53) + (b-13), (I-53) + (b-14), (I-53) + (S3-1), (I-53) ) + (S3-2), (I-53) + (S3-3), (I-53) + (S3-4), (I-53) + (S3-5), (1-53) + (h-1), (I-53) + (h-2), (I-53) + (V-1), (I-53) + (V-2), (I-53) + (V -3), (I-53) + (V-4), (I-53) + (V-5), (I-53) + (V-6). (I-54) + (ll-O), (I-54) + (11-1), (I-54) + (II-2), (I-54) + (II-3), (I -54) +
(II-4), (I-54) + (II-5), (I-54) + (II-6), (I-54) + (II-9), (I-54) + (11 -12), (I-54) + (111-1), (1-54) + (III-4), (1-54) + (111-10), (I-54) + (111-11) ), (I-54) + (IV-1), (I-54) + (IV-2), (I-54) + (IV-3), (I-54) + (IV-4), (I-54) + (IV-5), (I-54) + (b-1), (I-54) + (b-2), (I-54) +
(b-3), (I-54) + (b-4), (I-54) + (b-5), (I-54) + (b-6), (I-54) + (b -7), (I-54) + (b-8), (I-54) + (b-9), (I-54) + (b-10), (I-54) + (b-11) ), (I-54) + (b-12), (I-54) + (b-13), (I-54) + (b-14), (I-54) + (S3-1), (I-54) + (S3-2), (I-54) + (S3-3), (I-54) + (S3-4), (I-54) + (S3-5), (I -54) + (h-1), (I-54) + (h-2), (I-54) + (V-1), (I-54) + (V-2), (I-54) ) + (V-3),
(I-54) + (V-4), (I-54) + (V-5), (I-54) + (V-6). (I-55) + (ll-O), (I-55) + (11-1), (I-55) + (II-2), (I-55) + (II-3), (I -55) +
(II-4), (I-55) + (II-5), (I-55) + (II-6), (I-55) + (II-9), (I-55) + (11 -12), (I-55) + (111-1),
(I-55) + (III-4), (I-55) + (111-10), (I-55) + (111-11), (I-55) + (IV-1), (I -55) + (IV-2), (I-55) + (IV-3), (I-55) + (IV-4), (I-55) + (IV-5), (I-55) ) + (b-1), (I-55) + (b-2), (I-55) +
(b-3), (I-55) + (b-4), (I-55) + (b-5), (I-55) + (b-6), (I-55) + (b -7), (I-55) + (b-8), (I-55) + (b-9), (I-55) + (b-10), (I-55) + (b-11) ), (1-55) + (b-12), (I-55) + (b-13), (I-55) + (b-14), (I-55) + (S3-1), (I-55) + (S3-2), (I-55) + (S3-3), (I-55) + (S3-4), (I-55) + (S3-5), (I -55) + (h-1), (I-55) + (h-2), (I-55) + (V-1), (I-55) + (V-2), (I-55) ) + (V-3), (I-55) + (V-4), (I-55) + (V-5), (I-55) + (V-6). (I-56) + (ll-O), (I-56) + (11-1), (I-56) + (II-2), (I-56) + (II-3), (I -56) + (II-4), (I-56) + (II-5), (I-56) + (II-6), (I-56) + (II-9), (I-56) ) + (11-12), (I-56) + (111-1), (I-56) + (III-4), (I-56) + (111-10), (I-56) + (111-11), (I-56) + (IV-1), (I-56) + (IV-2), (I-56) + (IV-3), (1-56) + (IV -4), (1-56) + (IV-5), (1-56) + (b-1), (I-56) + (b-2), (I-56) + (b-3) ), (I-56) + (b-4), (I-56) + (b-5), (I-56) + (b-6), (I-56) + (b-7), (I-56) + (b-8), (I-56) + (b-9), (I-56) + (b-10), (I-56) + (b-11), (I -56) + (b-12), (I-56) + (b-13), (I-56) + (b-14), (I-56) + (S3-1), (I-56) ) + (S3-2), (I-56) + (S3-3), (I-56) + (S3-4), (I-56) + (S3-5), (I-56) + (h-1), (I-56) + (h-2), (I-56) + (V-1), (I-56) + (V-2), (I-56) + (V -3), (I-56) + (V-4), (I-56) + (V-5), (I-56) + (V-6). (I-57) + (ll-O), (I-57) + (11-1), (I-57) + (II-2), (I-57) + (II-3), (I -57) +
(II-4), (I-57) + (II-5), (I-57) + (II-6), (I-57) + (II-9), (I-57) + (11 -12), (I-57) + (111-1),
(I-57) + (III-4), (I-57) + (111-10), (I-57) + (111-11), (I-57) + (IV-1), (I -57) + (IV-2), (I-57) + (IV-3), (I-57) + (IV-4), (I-57) + (IV-5), (I-57) ) + (b-1), (I-57) + (b-2), (I-57) +
(b-3), (I-57) + (b-4), (I-57) + (b-5), (I-57) + (b-6), (I-57) + (b -7), (I-57) + (b-8), (I-57) + (b-9), (I-57) + (b-10), (I-57) + (b-11) ), (I-57) + (b-12), (I-57) + (b-13), (I-57) + (b-14), (I-57) + (S3-1), (I-57) + (S3-2), (I-57) + (S3-3), (I-57) + (S3-4), (1-57) + (S3-5), (I -57) + (h-1), (I-57) + (h-2), (I-57) + (V-1), (I-57) + (V-2), (I-57) ) + (V-3), (I-57) + (V-4), (I-57) + (V-5), (I-57) + (V-6). (I-58) + (ll-O), (I-58) + (11-1), (I-58) + (II-2), (I-58) + (II-3), (I -58) + (II-4), (I-58) + (II-5), (I-58) + (II-6), (I-58) + (II-9), (I-58) ) + (11-12), (I-58) + (111-1), (I-58) + (III-4), (I-58) + (111-10), (I-58) + (111-11), (I-58) + (IV-1), (I-58) + (IV-2), (I-58) + (IV-3), (I-58) + (IV -4), (I-58) + (IV-5), (I-58) + (b-1), (I-58) + (b-2), (I-58) + (b-3) ), (I-58) + (b-4), (I-58) + (b-5), (I-58) + (b-6), (I-58) + (b-7), (I-58) + (b-8), (I-58) + (b-9), (I-58) + (b-10), (I-58) + (b-11), (I -58) + (b-12), (I-58) + (b-13), (I-58) + (b-14), (I-58) + (S3-1), (I-58) ) + (S3-2), (I-58) + (S3-3), (I-58) + (S3-4), (I-58) + (S3-5), (1-58) + (h-1), (I-58) + (h-2), (I-58) + (V-1), (I-58) + (V-2), (I-58) + (V -3), (I-58) + (V-4), (I-58) + (V-5), (I-58) + (V-6). (I-59) + (ll-O), (I-59) + (11-1), (I-59) + (II-2), (I-59) + (II-3), (I -59) +
(II-4), (I-59) + (II-5), (I-59) + (II-6), (I-59) + (II-9), (I-59) + (11 -12), (I-59) + (111-1), (I-59) + (III-4), (I-59) + (111-10), (I-59) + (111-11) ), (I-59) + (IV-1), (I-59) + (IV-2), (I-59) + (IV-3), (I-59) + (IV-4), (I-59) + (IV-5), (I-59) + (b-1), (I-59) + (b-2), (I-59) +
(b-3), (I-59) + (b-4), (I-59) + (b-5), (I-59) + (b-6), (I-59) + (b -7), (I-59) + (b-8), (I-59) + (b-9), (I-59) + (b-10), (I-59) + (b-11) ), (I-59) + (b-12), (I-59) + (b-13), (I-59) + (b-14), (I-59) + (S3-1), (I-59) + (S3-2), (I-59) + (S3-3), (I-59) + (S3-4), (I-59) + (S3-5), (I -59) + (h-1), (I-59) + (h-2), (I-59) + (V-1), (I-59) + (V-2), (I-59) ) + (V-3),
(I-59) + (V-4), (I-59) + (V-5), (I-59) + (V-6). (I-60) + (ll-O), (I-60) + (11-1), (I-60) + (II-2), (I-60) + (II-3), (I -60) +
(II-4), (I-60) + (II-5), (I-60) + (II-6), (I-60) + (II-9), (I-60) + (11 -12), (I-60) + (111-1),
(I-60) + (III-4), (I-60) + (111-10), (I-60) + (111-11), (I-60) + (IV-1), (I -60) + (lV-2), (I-60) + (IV-3), (I-60) + (IV-4), (I-60) + (IV-5), (I-60) ) + (b-1), (I-60) + (b-2), (I-60) +
(b-3), (I-60) + (b-4), (I-60) + (b-5), (I-60) + (b-6), (I-60) + (b -7), (I-60) + (b-8), (I-60) + (b-9), (I-60) + (b-10), (I-60) + (b-11) ), (I-60) + (b-12), (I-60) + (b-13), (I-60) + (b-14), (I-60) + (S3-1), (I-60) + (S3-2), (I-60) + (S3-3), (I-60) + (S3-4), (I-60) + (S3-5), (I -60) + (h-1), (I-60) + (h-2), (I-60) + (V-1), (I-60) + (V-2), (I-60) ) + (V-3), (I-60) + (V-4), (I-60) + (V-5), (I-60) + (V-6). (1-61) + (ll-O), (1-61) + (11-1), (1-61) + (II-2), (1-61) + (II-3), (1 -61) + (II-4), (1-61) + (II-5), (1-61) + (II-6), (1-61) + (II-9), (1-61) ) + (11-12), (1-61) + (111-1), (1-61) + (III-4), (1-61) + (111-10), (1-61) + (111-11), (1-61) + (IV-1), (1-61) + (IV-2), (I- 61) + (IV-3), (1-61) + (IV -4), (1-61) + (IV-5), (1-61) + (b-1), (1-61) + (b-2), (1-61) + (b-3) ), (1-61) + (b-4), (1-61) + (b-5), (1-61) + (b-6), (1-61) + (b-7), (1-61) + (b-8), (I-61) + (b-9), (1-61) + (b-10), (1-61) + (b-11), (1 -61) + (b-12), (1-61) + (b-13), (1-61) + (b-14), (1-61) + (S3-1), (1-61) ) + (S3-2), (1-61) + (S3-3), (1-61) + (S3-4), (1-61) + (S3-5), (1-61) + (h-1), (1-61) + (h-2), (1-61) + (V-1), (1-61) + (V-2), (1-61) + (V -3), (1-61) + (V-4), (1-61) + (V-5), (1-61) + (V-6). (I-62) + (ll-O), (I-62) + (11-1), (I-62) + (II-2), (I-62) + (II-3), (I -62) +
(II-4), (I-62) + (II-5), (I-62) + (II-6), (I-62) + (II-9), (I-62) + (11 -12), (I-62) + (111-1),
(I-62) + (III-4), (I-62) + (111-10), (I-62) + (111-11), (I-62) + (IV-1), (I -62) + (IV-2), (I-62) + (IV-3), (I-62) + (IV-4), (I-62) + (IV-5), (I-62) ) + (b-1), (I-62) + (b-2), (I-62) +
(b-3), (I-62) + (b-4), (I-62) + (b-5), (I-62) + (b-6), (I-62) + (b -7), (I-62) + (b-8), (I-62) + (b-9), (I-62) + (b-10), (I-62) + (b-11), (I-62) + (b-12), (I-62) + (b-13), (I-62) + (b-14), ( I-62) + (S3-1), (I-62) + (S3-2), (I-62) + (S3-3), (I-62) + (S3-4), (I- 62) + (S3-5), (I-62) + (h-1), (I-62) + (h-2), (I-62) + (V-1), (I-62) + (V-2), (I-62) + (V-3), (I-62) + (V-4), (I-62) + (V-5), (I-62) + ( V-6). (I-63) + (ll-O), (I-63) + (11-1), (I-63) + (II-2), (I-63) + (II-3), (I -63) + (II-4), (I-63) + (II-5), (I-63) + (II-6), (I-63) + (II-9), (I-63) ) + (11-12), (I-63) + (111-1), (I-63) + (Hl-4), (I-63) + (111-10), (I-63) + (111-11), (I-63) + (IV-1), (I-63) + (IV-2), (I-63) + (IV-3), (I-63) + (IV -4), (I-63) + (IV-5), (I-63) + (b-1), (I-63) + (b-2), (I-63) + (b-3) ), (I-63) + (b-4), (I-63) + (b-5), (I-63) + (b-6), (I-63) + (b-7), (I-63) + (b-8), (I-63) + (b-9), (I-63) + (b-10), (I-63) + (b-11), (I -63) + (b-12), (I-63) + (b-13), (I-63) + (b-14), (I-63) + (S3-1), (I-63) ) + (S3-2), (I-63) + (S3-3), (I-63) + (S3-4), (I-63) + (S3-5), (1-63) + (h-1), (I-63) + (h-2), (I-63) + (V-1), (I-63) + (V-2), (I-63) + (V -3), (I-63) + (V-4), (I-63) + (V-5), (I-63) + (V-6). (I-64) + (ll-O), (I-64) + (11-1), (1-64) + (II-2), (I-64) + (II-3), (I -64) +
(II-4), (I-64) + (II-5), (i-64) + (II-6), (I-64) + (II-9), (I-64) + (11 -12), (I-64) + (111-1), (I-64) + (III-4), (I-64) + (111-10), (I-64) + (111-11) ), (I-64) + (IV-1), (I-64) + (IV-2), (I-64) + (IV-3), (I-64) + (IV-4), (I-64) + (IV-5), (I-64) + (b-1), (I-64) + (b-2), (I-64) +
(b-3), (I-64) + (b-4), (I-64) + (b-5), (I-64) + (b-6), (I-64) + (b -7), (I-64) + (b-8), (I-64) + (b-9), (I-64) + (b-10), (I-64) + (b-11) ), (I-64) + (b-12), (I-64) + (b-13), (I-64) + (b-14), (I-64) + (S3-1), (I-64) + (S3-2), (I-64) + (S3-3), (I-64) + (S3-4), (I-64) + (S3-5), (I -64) + (h-1), (I-64) + (h-2), (I-64) + (V-1), (I-64) + (V-2), (1-64) ) + (V-3),
(I-64) + (V-4), (I-64) + (V-5), (I-64) + (V-6). (I-65) + (ll-O), (I-65) + (11-1), (I-65) + (II-2), (I-65) + (II-3), (I -65) +
(II-4), (I-65) + (II-5), (I-65) + (II-6), (I-65) + (II-9), (I-65) + (11 -12), (I-65) + (111-1),
(I-65) + (III-4), (I-65) + (111-10), (I-65) + (111-11), (I-65) + (IV-1), (I -65) + (IV-2), (I-65) + (IV-3), (I-65) + (IV-4), (I-65) + (IV-5), (I-65) ) + (b-1), (I-65) + (b-2), (I-65) +
(b-3), (I-65) + (b-4), (I-65) + (b-5), (I-65) + (b-6), (I-65) + (b -7), (I-65) + (b-8), (I-65) + (b-9), (I-65) + (b-10), (1-65) + (b-11) ), (I-65) + (b-12), (I-65) + (b-13), (I-65) + (b-14), (I-65) + (S3-1), (I-65) + (S3-2), (I-65) + (S3-3), (I-65) + (S3-4), (I-65) + (S3-5), (I -65) + (h-1), (I-65) + (h-2), (i-65) + (V-1), (I-65) + (V-2), (I-65) ) + (V-3), (I-65) + (V-4), (I-65) + (V-5), (I-65) + (V-6). (I-66) + (ll-O), (I-66) + (11-1), (I-66) + (II-2), (I-66) + (II-3), (I -66) + (II-4), (I-66) + (II-5), (I-66) + (II-6), (I-66) + (II-9), (I-66) ) + (11-12), (I-66) + (111-1), (I-66) + (III-4), (I-66) + (111-10), (I-66) + (111-11), (I-66) + (IV-1), (I-66) + (IV-2), (I-66) + (IV-3), (1-66) + (IV -4), (1-66) + (IV-5), (1-66) + (b-1), (I-66) + (b-2), (I-66) + (b-3) ), (I-66) + (b-4), (I-66) + (b-5), (I-66) + (b-6), (I-66) + (b-7), (I-66) + (b-8), (I-66) + (b-9), (I-66) + (b-10), (I-66) + (b-11), (I -66) + (b-12), (I-66) + (b-13), (I-66) + (b-14), (I-66) + (S3-1), (I-66) ) + (S3-2), (I-66) + (S3-3), (I-66) + (S3-4), (I-66) + (S3-5), (I-66) + (h-1), (I-66) + (h-2), (I-66) + (V-1), (I-66) + (V-2), (I-66) + (V -3), (I-66) + (V-4), (I-66) + (V-5), (I-66) + (V-6). (I-67) + (ll-O), (I-67) + (11-1), (I-67) + (II-2), (I-67) + (II-3), (I -67) +
(II-4), (I-67) + (II-5), (I-67) + (II-6), (I-67) + (II-9), (I-67) + (11 -12), (I-67) + (111-1),
(I-67) + (III-4), (I-67) + (111-10), (I-67) + (111-11), (I-67) + (IV-1), (I -67) + (IV-2), (I-67) + (IV-3), (I-67) + (IV-4), (I-67) + (IV-5), (I-67) ) + (b-1), (I-67) + (b-2), (I-67) +
(b-3), (I-67) + (b-4), (I-67) + (b-5), (I-67) + (b-6), (I-67) + (b -7), (I-67) + (b-8), (I-67) + (b-9), (I-67) + (b-10), (I-67) + (b-11) ), (I-67) + (b-12), (I-67) + (b-13), (I-67) + (b-14), (I-67) + (S3-1), (I-67) + (S3-2), (I-67) + (S3-3) ', (I-67) + (S3-4), (I-67) + (S3-5), ( I-67) + (h-1), (I-67) + (h-2), (I-67) + (V-1), (I-67) + (V-2), (I- 67) + (V-3), (I-67) + (V-4), (I-67) + (V-5), (I-67) + (V-6). (I-68) + (ll-O), (I-68) + (11-1), (I-68) + (II-2), (I-68) + (II-3), (I -68) + (II-4), (I-68) + (II-5), (I-68) + (II-6), (I-68) + (II-9), (I-68) ) + (11-12), (I-68) + (111-1), (I-68) + (HI-4), (I-68) + (111-10), (I-68) + (111-11), (I-68) + (IV-1), (I-68) + (IV-2), (I- 68) + (IV-3), (I-68) + (IV -4), (I-68) + (IV-5), (I-68) + (b-1), (I-68) + (b-2), (I-68) + (b-3) ), (I-68) + (b-4), (I-68) + (b-5), (I-68) + (b-6), (I-68) + (b-7), (I-68) + (b-8), (I-68) + (b-9), (I-68) + (b-10), (I-68) + (b-11), (I -68) + (b-12), (I-68) + (b-13), (I-68) + (b-14), (I-68) + (S3-1), (I-68) ) + (S3-2), (I-68) + (S3-3), (I-68) + (S3-4), (I-68) + (S3-5), (1-68) + (h-1), (I-68) + (h-2), (I-68) + (V-1), (I-68) + (V-2), (I-68) + (V -3), (I-68) + (V-4), (I-68) + (V-5), (I-68) + (V-6). (I-69) + (ll-O), (I-69) + (11-1), (I-69) + (II-2), (I-69) + (II-3), (I -69) +
(II-4), (I-69) + (II-5), (I-69) + (II-6), (I-69) + (II-9), (I-69) + (11 -12), (I-69) + (111-1), (I-69) + (III-4), (I-69) + (111-10), (I-69) + (111-11) ), (I-69) + (IV-1), (I-69) + (IV-2), (I-69) + (IV-3), (I-69) + (IV-4), (I-69) + (IV-5), (I-69) + (b-1), (I-69) + (b-2), (I-69) +
(b-3), (I-69) + (b-4), (I-69) + (b-5), (I-69) + (b-6), (I-69) + (b -7), (I-69) + (b-8), (I-69) + (b-9), (I-69) + (b-10), (I-69) + (b-11) ), (I-69) + (b-12), (I-69) + (b-13), (I-69) + (b-14), (I-69) + (S3-1), (I-69) + (S3-2), (I-69) + (S3-3), (I-69) + (S3-4), (I-69) + (S3-5), (I -69) + (h-1), (I-69) + (h-2), (I-69) + (V-1), (I-69) + (V-2), (I-69) ) + (V-3),
(I-69) + (V-4), (I-69) + (V-5), (I-69) + (V-6). (I-70) + (ll-O), (I-70) + (11-1), (I-70) + (II-2), (I-70) + (II-3), (I -70) +
(II-4), (I-70) + (II-5), (I-70) + (II-6), (I-70) + (II-9), (I-70) + (11 -12), (I-70) + (111-1),
(I-70) + (III-4), (I-70) + (111-10), (I-70) + (111-11), (I-70) + (IV-1), (I -70) + (IV-2), (I-70) + (IV-3), (I-70) + (IV-4), (I-70) + (IV-5), (I-70) ) + (b-1), (I-70) + (b-2), (I-70) +
(b-3), (I-70) + (b-4), (I-70) + (b-5), (I-70) + (b-6), (I-70) + (b -7), (I-70) + (b-8), (I- 70) + (b-9), (I-70) + (b-10), (I-70) + (b-11) ), (I-70) + (b-12), (I-70) + (b-13), (1-70) + (b-14), (I-70) + (S3-1), (I-70) + (S3-2), (I-70) + (S3-3), (I-70) + (S3-4), (I-70) + (S3-5), (I -70) + (h-1), (I-70) + (h-2), (I-70) + (V-1), (I-70) + (V-2), (I-70) ) + (V-3), (I-70) + (V-4), (I-70) + (V-5), (I-70) + (V-6). (1-71) + (ll-O), (1-71) + (11-1), (1-71) + (II-2), (1-71) + (II-3), (1 -71) + (II-4), (1-71) + (II-5), (1-71) + (II-6), (1-71) + (II-9), (1-71) ) + (11-12), (1-71) + (111-1), (1-71) + (III-4), (1-71) + (111-10), (1-71) + (111-11), (1-71) + (IV-1), (1-71) + (IV-2), (I- 71) + (IV-3), (1-71) + (IV -4), (1-71) + (IV-5), (1-71) + (b-1), (1-71) + (b-2), (1-71) + (b-3) ), (1-71) + (b-4), (1-71) + (b-5), (1-71) + (b-6), (1-71) + (b-7), (1-71) + (b-8), (I- 71) + (b-9), (1-71) + (b-10), (1-71) + (b-11), (1 -71) + (b-12), (1-71) + (b-13), (1-71) + (b-14), (1-71) + (S3-1), (1-71) ) + (S3-2), (1-71) + (S3-3), (1-71) + (S3-4), (1-71) + (S3-5), (1-71) + (h-1), (1-71) + (h-2), (1-71) + (V-1), (1-71) + (V-2), (1-71) + (V -3), (1-71) + (V-4), (1-71) + (V-5), (1-71) + (V-6). (I-72) + (ll-O), (I-72) + (11-1), (I-72) + (II-2), (I-72) + (II-3), (I -72) +
(II-4), (I-72) + (II-5), (I-72) + (II-6), (I-72) + (II-9), (I-72) + (11 -12), (I-72) + (111-1),
(I-72) + (III-4), (I-72) + (111-10), (I-72) + (111-11), (I-72) + (IV-1), (I -72) + (IV-2), (I-72) + (IV-3), (I-72) + (IV-4), (I-72) + (IV-5), (I-72) ) + (b-1), (I-72) + (b-2), (I-72) +
(b-3), (I-72) + (b-4), (I-72) + (b-5), (I-72) + (b-6), (I-72) + (b -7), (I-72) + (b-8), (I- 72) + (b-9), (I-72) + (b-10), (I-72) + (b-11) ), (I-72) + (b-12), (I-72) + (b-13), (I-72) + (b-14), (I-72) + (S3-1), (I-72) + (S3-2), (I-72) + (S3-3), (I-72) + (S3-4), (I-72) + (S3-5), (I -72) + (h-1), (I-72) + (h-2), (I-72) + (V-1), (I-72) + (V-2), (I-72) ) + (V-3), (I-72) + (V-4), (I-72) + (V-5), (I-72) + (V-6). (I-73) + (ll-O), (I-73) + (11-1), (I-73) + (II-2), (I-73) + (ll-3), (I -73) + (II-4), (I-73) + (II-5), (I-73) + (II-6), (I-73) + (II-9), (I-73) ) + (11-12), (I-73) + (111-1), (I-73) + (III-4), (I-73) + (111-10), (I-73) + (111-11), (I-73) + (IV-1), (I-73) + (IV-2), (I- 73) + (IV-3), (I-73) + (IV -4), (I-73) + (IV-5), (I-73) + (b-1), (I-73) + (b-2), (I-73) + (b-3) ), (I-73) + (b-4), (I-73) + (b-5), (I-73) + (b-6), (I-73) + (b-7), (I-73) + (b-8), (I-73) + (b-9), (I-73) + (b-10), (I-73) + (b-11), (I -73) + (b-12), (I-73) + (b-13), (I-73) + (b-14), (I-73) + (S3-1), (I-73) ) + (S3-2), (I-73) + (S3-3), (I-73) + (S3-4), (I-73) + (S3-5), (1-73) + (h-1), (I-73) + (h-2), (I-73) + (V-1), (I-73) + (V-2), (I-73) + (V -3), (I-73) + (V-4), (I-73) + (V-5), (I-73) + (V-6). (I-74) + (ll-O), (I-74) + (11-1), (I-74) + (II-2), (I-74) + (II-3), (I -74) +
(II-4), (I-74) + (II-5), (I-74) + (II-6), (I-74) + (II-9), (I-74) + (11 -12), (I-74) + (111-1), (1-74) + (III-4), (I-74) + (111-10), (I-74) + (111-11) ), (I-74) + (IV-1), (I-74) + (IV-2), (I-74) + (IV-3), (I-74) + (IV-4), (I-74) + (IV-5), (I-74) + (b-1), (I-74) + (b-2), (I-74) +
(b-3), (I-74) + (b-4), (I-74) + (b-5), (I-74) + (b-6), (I-74) + (b -7), (I-74) + (b-8), (I-74) + (b-9), (I-74) + (b-10), (I-74) + (b-11) ), (I-74) + (b-12), (I-74) + (b-13), (I-74) + (b-14), (I-74) + (S3-1), (I-74) + (S3-2), (I-74) + (S3-3), (I-74) + (S3-4), (I-74) + (S3-5), (I -74) + (h-1), (I-74) + (h-2), (I-74) + (V-1), (I-74) + (V-2), (I-74) ) + (V-3),
(I-74) + (V-4), (I-74) + (V-5), (I-74) + (V-6). (I-75) + (ll-O), (I-75) + (11-1), (I-75) + (II-2), (I-75) + (II-3), (I -75) +
(II-4), (I-75) + (II-5), (I-75) + (II-6), (I-75) + (II-9), (I-75) + (11 -12), (I-75) + (111-1),
(I-75) + (III-4), (I-75) + (111-10), (I-75) + (111-11), (I-75) + (IV-1), (I -75) + (IV-2), (I-75) + (IV-3), (I-75) + (IV-4), (I-75) + (IV-5), (I-75) ) + (b-1), (I-75) + (b-2), (I-75) +
(b-3), (I-75) + (b-4), (I-75) + (b-5), (I-75) + (b-6), (I-75) + (b -7), (I-75) + (b-8), (I-75) + (b-9), (I-75) + (b-10), (I-75) + (b-11) ), (I-75) + (b-12), (I-75) + (b-13), (I-75) + (b-14), (I-75) + (S3-1), (I-75) + (S3-2), (I-75) + (S3-3), (I-75) + (S3-4), (I-75) + (S3-5), (I -75) + (h-1), (I-75) + (h-2), (I-75) + (V-1), (I-75) + (V-2), (I-75) ) + (V-3), (I-75) + (V-4), (I-75) + (V-5), (I-75) + (V-6). (I-76) + (ll-O), (I-76) + (11-1), (I-76) + (II-2), (I-76) + (II-3), (I -76) + (II-4), (I-76) + (II-5), (I-76) + (II-6), (I-76) + (II-9), (I-76) ) + (11-12), (I-76) + (111-1), (I-76) + (III-4), (I-76) + (111-10), (I-76) + (111-11), (I-76) + (IV-1), (I-76) + (IV-2), (I-76) + (IV-3), (I-76) + (IV -4), (I-76) + (IV-5), (I-76) + (b-1), (I-76) + (b-2), (I-76) + (b-3) ), (I-76) + (b-4), (I-76) + (b-5), (I-76) + (b-6), (I-76) + (b-7), (I-76) + (b-8), (I-76) + (b-9), (I-76) + (b-10), (I-76) + (b-11), (I -76) + (b-12), (I-76) + (b-13), (I-76) + (b-14), (I-76) + (S3-1), (I-76) ) + (S3-2), (I-76) + (S3-3), (I-76) + (S3-4), (I-76) + (S3-5), (I-76) + (h-1), (1-76) + (h-2), (I-76) + (V-1), (I-76) + (V-2), (1-76) + (V -3), (I-76) + (V-4), (I-76) + (V-5), (I-76) + (V-6). (I-77) + (ll-O), (I-77) + (11-1), (I-77) + (II-2), (I-77) + (II-3), (I -77) +
(II-4), (I-77) + (II-5), (I-77) + (II-6), (I-77) + (II-9), (I-77) + (11 -12), (I-77) + (111-1),
(I-77) + (III-4), (I-77) + (111-10), (I-77) + (111-11), (I-77) + (IV-1), (I -77) + (IV-2), (I-77) + (IV-3), (I-77) + (IV-4), (I-77) + (IV-5), (I-77) ) + (b-1), (I-77) + (b-2), (I-77) +
(b-3), (I-77) + (b-4), (I-77) + (b-5), (I-77) + (b-6), (I-77) + (b -7), (I-77) + (b-8), (I-77) + (b-9), (I-77) + (b-10), (I-77) + (b-11) ), (I-77) + (b-12), (I-77) + (b-13), (I-77) + (b-14), (I-77) + (S3-1), (I-77) + (S3-2), (I-77) + (S3-3), (I-77) + (S3-4), (I-77) + (S3-5), (I -77) + (h-1), (I-77) + (h-2), (I-77) + (V-1), (I-77) + (V-2), (I-77) ) + (V-3), (I-77) + (V-4), (I-77) + (V-5), (I-77) + (V-6). (I-78) + (ll-O), (I-78) + (11-1), (I-78) + (II-2), (I-78) + (II-3), (I -78) + (II-4), (I-78) + (II-5), (I-78) + (II-6), (I-78) + (II-9), (I-78) ) + (11-12), (I-78) + (111-1), (I-78) + (III-4), (I-78) + (111-10), (I-78) + (111-11), (I-78) + (IV-1), (I-78) + (IV-2), (I-78) + (IV-3), (I-78) + (IV -4), (I-78) + (IV-5), (I-78) + (b-1), (I-78) + (b-2), (I-78) + (b-3) ), (I-78) + (b-4), (I-78) + (b-5), (I-78) + (b-6), (I-78) + (b-7), (I-78) + (b-8), (I-78) + (b-9), (I-78) + (b-10), (I-78) + (b-11), (I -78) + (b-12), (I-78) + (b-13), (I-78) + (b-14), (I-78) + (S3-1), (I-78) ) + (S3-2), (I-78) + (S3-3), (I-78) + (S3-4), (I-78) + (S3-5), (1-78) + (h-1), (I-78) + (h-2), (I-78) + (V-1), (I-78) + (V-2), (I-78) + (V -3), (I-78) + (V-4), (I-78) + (V-5), (I-78) + (V-6). (I-79) + (ll-O), (I-79) + (11-1), (I-79) + (II-2), (I-79) + (II-3), (I -79) +
(II-4), (I-79) + (II-5), (I-79) + (II-6), (I-79) + (II-9), (I-79) + (11 -12), (I-79) + (111-1), (I-79) + (III-4), (1-79) + (111-10), (I-79) + (111-11) ), (1-79) + (IV-1), (1-79) + (IV-2), (I-79) + (IV-3), (I-79) + (IV-4), (I-79) + (IV-5), (I-79) + (b-1), (I-79) + (b-2), (I-79) +
(b-3), (I-79) + (b-4), (I-79) + (b-5), (I-79) + (b-6), (I-79) + (b -7), (I-79) + (b-8), (I- 79) + (b-9), (I-79) + (b-10), (I-79) + (b-11) ), (I-79) + (b-12), (I-79) + (b-13), (I-79) + (b-14), (I-79) + (S3-1), (I-79) + (S3-2), (I-79) + (S3-3), (I-79) + (S3-4), (I-79) + (S3-5), (I -79) + (h-1), (I-79) + (h-2), (I-79) + (V-1), (I-79) + (V-2), (I-79) ) + (V-3),
(I-79) + (V-4), (I-79) + (V-5), (1-79) + (V-6). (I-80) + (ll-O), (I-80) + (11-1), (I-80) + (II-2), (I-80) + (II-3), (I -80) +
(II-4), (I-80) + (II-5), (I-80) + (II-6), (I-80) + (II-9), (I-80) + (11 -12), (I-80) + (111-1),
(I-80) + (III-4), (I-80) + (111-10), (I-80) + (111-11), (I-80) + (IV-1), (I -80) + (IV-2), (I-80) + (IV-3), (I-80) + (IV-4), (I-80) + (IV-5), (I-80) ) + (b-1), (I-80) + (b-2), (I-80) +
(b-3), (I-80) + (b-4), (I-80) + (b-5), (I-80) + (b-6), (I-80) + (b -7), (I-80) + (b-8), (I-80) + (b-9), (I-80) + (b-10), (I-80) + (b-11) ), (I-80) + (b-12), (I-80) + (b-13), (I-80) + (b-14), (I-80) + (S3-1), (I-80) + (S3-2), (I-80) + (S3-3), (I-80) + (S3-4), (I-80) + (S3-5), (I -80) + (h-1), (I-80) + (h-2), (I-80) + (V-1), (I-80) + (V-2), (I-80) ) + (V-3), (I-80) + (V-4), (I-80) + (V-5), (I-80) + (V-6). (1-81) + (ll-O), (1-81) + (11-1), (1-81) + (II-2), (1-81) + (II-3), (1 -81) + (II-4), (1-81) + (II-5), (1-81) + (II-6), (1-81) + (II-9), (1-81) ) + (11-12), (1-81) + (111-1), (1-81) + (III-4), (1-81) + (111-10), (1-81) + (111-11), (1-81) + (IV-1), (1-81) + (IV-2), (I-81) + (IV-3), (1-81) + (IV -4), (1-81) + (IV-5), (1-81) + (b-1), (1-81) + (b-2), (1-81) + (b-3) ), (1-81) + (b-4), (1-81) + (b-5), (1-81) + (b-6), (1-81) + (b-7), (1-81) + (b-8), (I-81) + (b-9), (1-81) + (b-10), (1-81) + (b-11), (1 -81) + (b-12), (1-81) + (b-13), (1-81) + (b-14), (1-81) + (S3-1), (1-81) ) + (S3-2), (1-81) + (S3-3), (1-81) + (S3-4), (1-81) + (S3-5), (1-81) + (h-1), (1-81) + (h-2), (1-81) + (V-1), (1-81) + (V-2), (1-81) + (V -3), (1-81) + (V-4), (1-81) + (V-5), (1-81) + (V-6). (I-82) + (ll-O), (I-82) + (11-1), (I-82) + (II-2), (I-82) + (II-3), (I -82) +
(II-4), (I-82) + (II-5), (I-82) + (II-6), (I-82) + (II-9), (I-82) + (11 -12), (I-82) + (111-1),
(I-82) + (III-4), (I-82) + (111-10), (I-82) + (111-11), (I-82) + (IV-1), (I -82) + (IV-2), (I-82) + (IV-3), (I-82) + (IV-4), (I-82) + (IV-5), (I-82) ) + (b-1), (I-82) + (b-2), (I-82) +
(b-3), (I-82) + (b-4), (I-82) + (b-5), (I-82) + (b-6), (I-82) + (b -7), (I-82) + (b-8), (I-82) + (b-9), (I-82) + (b-10), (I-82) + (b-11) ), (I-82) + (b-12), (I-82) + (b-13), (I-82) + (b-14), (I-82) + (S3-1), (I-82) + (S3-2), (I-82) + (S3-3), (I-82) + (S3-4), (I-82) + (S3-5), (I -82) + (h-1), (I-82) + (h-2), (I-82) + (V-1), (I-82) + (V-2), (I-82) ) + (V-3), (I-82) + (V-4), (I-82) + (V-5), (I-82) + (V-6). (I-83) + (ll-O), (I-83) + (11-1), (I-83) + (II-2), (I-83) + (II-3), (I -83) + (II-4), (I-83) + (II-5), (I-83) + (II-6), (I-83) + (II-9), (I-83) ) + (11-12), (I-83) + (111-1), (I-83) + (III-4), (I-83) + (111-10), (I-83) + (111-11), (I-83) + (IV-1), (I-83) + (IV-2), (I-83) + (IV-3), (I-83) + (IV -4), (I-83) + (IV-5), (I-83) + (b-1), (I-83) + (b-2), (I-83) + (b-3) ), (I-83) + (b-4), (I-83) + (b-5), (I-83) + (b-6), (I-83) + (b-7), (I-83) + (b-8), (I-83) + (b-9), (1-83) + (b-10), (I-83) + (b-11), (I -83) + (b-12), (I-83) + (b-13), (I-83) + (b-14), (I-83) + (S3-1), (I-83) ) + (S3-2), (I-83) + (S3-3), (I-83) + (S3-4), (I-83) + (S3-5), (1-83) + (h-1), (I-83) + (h-2), (I-83) + (V-1), (I-83) + (V-2), (I-83) + (V -3), (I-83) + (V-4), (I-83) + (V-5), (I-83) + (V-6). (I-84) + (ll-O), (I-84) + (11-1), (I-84) + (II-2), (I-84) + (II-3), (I -84) +
(II-4), (I-84) + (II-5), (I-84) + (II-6), (I-84) + (II-9), (I-84) + (11 -12), (1-84) + (111-1), (I-84) + (III-4), (I-84) + (111-10), (I-84) + (111-11) ), (I-84) + (IV-1), (I-84) + (IV-2), (I-84) + (IV-3), (I-84) + (IV-4), (I-84) + (IV-5), (I-84) + (b-1), (I-84) + (b-2), (I-84) +
(b-3), (I-84) + (b-4), (I-84) + (b-5), (I-84) + (b-6), (I-84) + (b -7), (I-84) + (b-8), (I-84) + (b-9), (I-84) + (b-10), (I-84) + (b-11) ), (1-84) + (b-12), (I-84) + (b-13), (I-84) + (b-14), (I-84) + (S3-1), (I-84) + (S3-2), (I-84) + (S3-3), (I-84) + (S3-4), (I-84) + (S3-5), (I -84) + (h-1), (I-84) + (h-2), (I-84) + (V-1), (I-84) + (V-2), (I-84) ) + (V-3),
(I-84) + (V-4), (I-84) + (V-5), (I-84) + (V-6). (I-85) + (ll-O), (I-85) + (11-1), (I-85) + (II-2), (I-85) + (II-3), (I -85) +
(II-4), (I-85) + (il-5), (I-85) + (II-6), (I-85) + (II-9), (I-85) + (11 -12), (I-85) + (111-1),
(I-85) + (III-4), (I-85) + (111-10), (I-85) + (111-11), (I-85) + (IV-1), (I -85) + (IV-2), (I-85) + (IV-3), (I-85) + (IV-4), (I-85) + (IV-5), (I-85) ) + (b-1), (I-85) + (b-2), (I-85) +
(b-3), (I-85) + (b-4), (I-85) + (b-5), (I-85) + (b-6), (I-85) + (b -7), (I-85) + (b-8), (I-85) + (b-9), (I-85) + (b-10), (I-85) + (b-11) ), (I-85) + (b-12), (I-85) + (b-13), (I-85) + (b-14), (I-85) + (S3-1), (I-85) + (S3-2), (I-85) + (S3-3), (I-85) + (S3-4), (I-85) + (S3-5), (I -85) + (h-1), (I-85) + (h-2), (I-85) + (V-1), (I-85) + (V-2), (I-85) ) + (V-3), (I-85) + (V-4), (I-85) + (V-5), (I-85) + (V-6). (I-86) + (ll-O), (I-86) + (11-1), (I-86) + (II-2), (I-86) + (II-3), (I -86) + (II-4), (I-86) + (II-5), (I-86) + (II-6), (I-86) + (II-9), (I-86) ) + (11-12), (I-86) + (111-1), (I-86) + (III-4), (I-86) + (111-10), (I-86) + (111-11), (I-86) + (IV-1), (I-86) + (IV-2), (I-86) + (IV-3), (1-86) + (IV -4), (1-86) + (IV-5), (1-86) + (b-1), (I-86) + (b-2), (I-86) + (b-3) ), (I-86) + (b-4), (I-86) + (b-5), (I-86) + (b-6), (I-86) + (b-7), (I-86) + (b-8), (I-86) + (b-9), (I-86) + (b-10), (I-86) + (b-11), (I -86) + (b-12), (I-86) + (b-13), (I-86) + (b-14), (I-86) + (S3-1), (I-86) ) + (S3-2), (I-86) + (S3-3), (I-86) + (S3-4), (I-86) + (S3-5), (I-86) + (h-1), (I-86) + (h-2), (I-86) + (V-1), (I-86) + (V-2), (I-86) + (V -3), (I-86) + (V-4), (I-86) + (V-5), (I-86) + (V-6). (I-87) + (ll-O), (I-87) + (11-1), (I-87) + (II-2), (I-87) + (II-3), (I -87) +
(II-4), (I-87) + (II-5), (I-87) + (II-6), (I-87) + (II-9), (I-87) + (11 -12), (I-87) + (111-1),
(I-87) + (III-4), (I-87) + (111-10), (I-87) + (111-11), (I-87) + (IV-1), (I -87) + (IV-2), (I-87) + (IV-3), (I-87) + (IV-4), (I-87) + (IV-5), (I-87) ) + (b-1), (I-87) + (b-2), (I-87) +
(b-3), (I-87) + (b-4), (I-87) + (b-5), (I-87) + (b-6), (I-87) + (b -7), (I-87) + (b-8), (I-87) + (b-9), (I-87) + (b-10), (I-87) + (b-11) ), (I-87) + (b-12), (I-87) + (b-13), (I-87) + (b-14), (I-87) + (S3-1), (I-87) + (S3-2), (I-87) + (S3-3), (I-87) + (S3-4), (I-87) + (S3-5), (I -87) + (h-1), (I-87) + (h-2), (I-87) + (V-1), (I-87) + (V-2), (I-87) ) + (V-3), (I-87) + (V-4), (I-87) + (V-5), (I-87) + (V-6). (I-88) + (ll-O), (I-88) + (11-1), (I-88) + (II-2), (I-88) + (II-3), (I -88) + (II-4), (I-88) + (II-5), (I-88) + (II-6), (I-88) + (II-9), (I-88) ) + (11-12), (I-88) + (111-1), (I-88) + (III-4), (I-88) + (111-10), (I-88) + (111-11), (I-88) + (IV-1), (I-88) + (IV-2), (I-88) + (IV-3), (1-88) + (IV -4), (I-88) + (IV-5), (I-88) + (b-1), (I-88) + (b-2), (I-88) + (b-3) ), (I-88) + (b-4), (I-88) + (b-5), (I-88) + (b-6), (I-88) + (b-7), (I-88) + (b-8), (I-88) + (b-9), (I-88) + (b-10), (I-88) + (b-11), (I -88) + (b-12), (I-88) + (b-13), (I-88) + (b-14), (I-88) + (S3-1), (I-88) ) + (S3-2), (I-88) + (S3-3), (I-88) + (S3-4), (I-88) + (S3-5), (1-88) + (h-1), (I-88) + (h-2), (I-88) + (V-1), (I-88) + (V-2), (I-88) + (V -3), (I-88) + (V-4), (I-88) + (V-5), (I-88) + (V-6). (I-89) + (ll-O), (I-89) + (11-1), (I-89) + (II-2), (1-89) + (II-3), (I -89) +
(II-4), (I-89) + (II-5), (I-89) + (II-6), (I-89) + (II-9), (I-89) + (11 -12), (I-89) + (111-1), (I-89) + (II1-4), (I-89) + (111-10), (I-89) + (111-11) ), (I-89) + (1V-1), (I-89) + (IV-2), (I-89) + (IV-3), (I-89) + (IV-4), (I-89) + (IV-5), (I-89) + (b-1), (I-89) + (b-2), (I-89) +
(b-3), (I-89) + (b-4), (I-89) + (b-5), (I-89) + (b-6), (I-89) + (b -7), (I-89) + (b-8), (I-89) + (b-9), (I-89) + (b-10), (I-89) + (b-11) ), (I-89) + (b-12), (I-89) + (b-13), (I-89) + (b-14), (I-89) + (S3-1), (I-89) + (S3-2), (I-89) + (S3-3), (I-89) + (S3-4), (I-89) + (S3-5), (I -89) + (h-1), (I-89) + (h-2), (I-89) + (V-1), (I-89) + (V-2), (I-89) ) + (V-3),
(I-89) + (V-4), (I-89) + (V-5), (I-89) + (V-6). (I-90) + (ll-O), (I-90) + (11-1), (I-90) + (II-2), (I-90) + (II-3), (I -90) +
(II-4), (I-90) + (II-5), (I-90) + (II-6), (I-90) + (II-9), (I-90) + (11 -12), (I-90) + (111-1),
(I-90) + (III-4), (I-90) + (111-10), (I-90) + (111-11), (I-90) + (IV-1), (I -90) + (IV-2), (I-90) + (IV-3), (I-90) + (IV-4), (I-90) + (IV-5), (I-90) ) + (b-1), (I-90) + (b-2), (I-90) +
(b-3), (I-90) + (b-4), (I-90) + (b-5), (I-90) + (b-6), (I-90) + (b -7), (I-90) + (b-8), (I-90) + (b-9), (I-90) + (b-10), (I-90) + (b-11) ), (I-90) + (b-12), (I-90) + (b-13), (I-90) + (b-14), (I-90) + (S3-1), (I-90) + (S3-2), (I-90) + (S3-3), ( I-90) + (S3-4), (I-90) + (S3-5), (I-90) + (h-1), (I-90) + (h-2), (I- 90) + (V-1), (I-90) + (V-2), (I-90) + (V-3), (I-90) + (V-4), (I-90) + (V-5), (I-90) + (V-6). (1-91) + (ll-O), (1-91) + (11-1), (1-91) + (II-2), (1-91) + (II-3), (1 -91) + (II-4), (1-91) + (II-5), (1-91) + (II-6), (1-91) + (II-9), (1-91) ) + (11-12), (1-91) + (111-1), (1-91) + (III-4), (1-91) + (111-10), (1-91) + (111-11), (1-91) + (IV-1), (1-91) + (IV-2), (I-91) + (IV-3), (1-91) + (IV -4), (1-91) + (IV-5), (1-91) + (b-1), (1-91) + (b-2), (1-91) + (b-3) ), (1-91) + (b-4), (1-91) + (b-5), (1-91) + (b-6), (1-91) + (b-7), (1-91) + (b-8), (I-91) + (b-9), (1-91) + (b-10), (1-91) + (b-11), (1 -91) + (b-12), (1-91) + (b-13), (1-91) + (b-14), (1-91) + (S3-1), (1-91) ) + (S3-2), (1-91) + (S3-3), (1-91) + (S3-4), (1-91) + (S3-5), (1-91) + (h-1), (1-91) + (h-2), (1-91) + (V-1), (1-91) + (V-2), (1-91) + (V -3), (1-91) + (V-4), (1-91) + (V-5), (1-91) + (V-6). (I-92) + (ll-O), (I-92) + (11-1), (I-92) + (II-2), (I-92) + (II-3), (I -92) +
(II-4), (I-92) + (II-5), (I-92) + (II-6), (I-92) + (II-9), (I-92) + (11 -12), (I-92) + (111-1),
(I-92) + (III-4), (I-92) + (111-10), (I-92) + (111-11), (I-92) + (IV-1), (I -92) + (IV-2), (I-92) + (IV-3), (I-92) + (IV-4), (I-92) + (IV-5), (I-92) ) + (b-1), (I-92) + (b-2), (I-92) +
(b-3), (I-92) + (b-4), (I-92) + (b-5), (I-92) + (b-6), (I-92) + (b -7), (I-92) + (b-8), (I-92) + (b-9), (I-92) + (b-10), (I-92) + (b-11) ), (I-92) + (b-12), (I-92) + (b-13), (I-92) + (b-14), (I-92) + (S3-1), (I-92) + (S3-2), (I-92) + (S3-3), (I-92) + (S3-4), (I-92) + (S3-5), (I -92) + (h-1), (I-92) + (h-2), (I-92) + (V-1), (I-92) + (V-2), (I-92) ) + (V-3), (I-92) + (V-4), (I-92) + (V-5), (I-92) + (V-6). (I-93) + (ll-O), (I-93) + (11-1), (I-93) + (II-2), (I-93) + (II-3), (I -93) + (II-4), (I-93) + (II-5), (I-93) + (II-6), (I-93) + (II-9), (I-93) ) + (11-12), (I-93) + (111-1), (I-93) + (III-4), (I-93) + (111-10), (I-93) + (111-11), (I-93) + (IV-1), (I-93) + (IV-2), (I-93) + (IV-3), (I-93) + (IV -4), (I-93) + (IV-5), (I-93) + (b-1), (I-93) + (b-2), (I-93) + (b-3) ), (I-93) + (b-4), (I-93) + (b-5), (I-93) + (b-6), (I-93) + (b-7), (I-93) + (b-8), (I-93) + (b-9), (I-93) + (b-10), (I-93) + (b-11), (I -93) + (b-12), (I-93) + (b-13), (I-93) + (b-14), (I-93) + (S3-1), (I-93) ) + (S3-2), (I-93) + (S3-3), (I-93) + (S3-4), (I-93) + (S3-5), (1-93) + (h-1), (I-93) + (h-2), (I-93) + (V-1), (I-93) + (V-2), (I-93) + (V -3), (I-93) + (V-4), (I-93) + (V-5), (I-93) + (V-6). (I-94) + (ll-O), (I-94) + (11-1), (I-94) + (II-2), (I-94) + (II-3), (I -94) +
(II-4), (i-94) + (II-5), (I-94) + (II-6), (I-94) + (II-9), (I-94) + (11 -12), (I-94) + (111-1), (I-94) + (III-4), (I-94) + (111-10), (I-94) + (111-11) ), (I-94) + (IV-1), (I-94) + (IV-2), (I-94) + (IV-3), (I-94) + (IV-4), (I-94) + (IV-5), (I-94) + (b-1), (I-94) + (b-2), (I-94) +
(b-3), (I-94) + (b-4), (I-94) + (b-5), (I-94) + (b-6), (I-94) + (b -7), (I-94) + (b-8), (I-94) + (b-9), (I-94) + (b-10), (I-94) + (b-11) ), (I-94) + (b-12), (I-94) + (b-13), (I-94) + (b-14), (I-94) + (S3-1), (I-94) + (S3-2), (I-94) + (S3-3), (I-94) + (S3-4), (I-94) + (S3-5), (I -94) + (h-1), (I-94) + (h-2), (I-94) + (V-1), (I-94) + (V-2), (I-94) ) + (V-3),
(I-94) + (V-4), (I-94) + (V-5), (I-94) + (V-6). (I-95) + (ll-O), (I-95) + (11-1), (I-95) + (II-2), (I-95) + (II-3), (I -95) +
(II-4), (I-95) + (II-5), (I-95) + (II-6), (I-95) + (II-9), (I-95) + (11 -12), (I-95) + (111-1),
(I-95) + (III-4), (I-95) + (111-10), (I-95) + (111-11), (I-95) + (IV-1), (I -95) + (IV-2), (I-95) + (IV-3), (I-95) + (IV-4), (I-95) + (IV-5), (I-95) ) + (b-1), (I-95) + (b-2), (I-95) +
(b-3), (I-95) + (b-4), (I-95) + (b-5), (I-95) + (b-6), (I-95) + (b -7), (I-95) + (b-8), (I-95) + (b-9), (I-95) + (b-10), (I-95) + (b-11) ), (I-95) + (b-12), (I-95) + (b-13), (I-95) + (b-14), (I-95) + (S3-1), (I-95) + (S3-2), (I-95) + (S3-3), (I-95) + (S3-4), (I-95) + (S3-5), (I -95) + (h-1), (I-95) + (h-2), (I-95) + (V-1), (I-95) + (V-2), (I-95) ) + (V-3), (I-95) + (V-4), (I-95) + (V-5), (I-95) + (V-6). (I-96) + (ll-O), (I-96) + (11-1), (I-96) + (ll-2), (I-96) + (H-3), (I -96) + (II-4), (I-96) + (II-5), (I-96) + (II-6), (I-96) + (II-9), (I-96) ) + (11-12), (I-96) + (111-1), (I-96) + (III-4), (I-96) + (111-10), (I-96) + (111-11), (I-96) + (IV-1), (I-96) + (IV-2), (I-96) + (IV-3), (1-96) + (IV -4), (1-96) + (IV-5), (1-96) + (b-1), (I-96) + (b-2), (I-96) + (b-3) ), (I-96) + (b-4), (I-96) + (b-5), (I-96) + (b-6), (I-96) + (b-7), (I-96) + (b-8), (I-96) + (b-9), (I-96) + (b-10), (I-96) + (b-11), (I -96) + (b-12), (I-96) + (b-13), (I-96) + (b-14), (I-96) + (S3-1), (I-96) ) + (S3-2), (I-96) + (S3-3), (I-96) + (S3-4), (I-96) + (S3-5), (I-96) + (h-1), (1-96) + (h-2), (I-96) + (V-1), (I-96) + (V-2), (I-96) + (V -3), (I-96) + (V-4), (I-96) + (V-5), (I-96) + (V-6). (I-97) + (ll-O), (I-97) + (11-1), (I-97) + (II-2), (I-97) + (II-3), (I -97) +
(II-4), (I-97) + (II-5), (I-97) + (II-6), (I-97) + (II-9), (I-97) + (11 -12), (I-97) + (111-1),
(I-97) + (III-4), (I-97) + (111-10), (I-97) + (111-11), (I-97) + (IV-1), (I -97) + (IV-2), (I-97) + (IV-3), (I-97) + (IV-4), (I-97) + (IV-5), (I-97) ) + (b-1), (I-97) + (b-2), (I-97) +
(b-3), (1-97) + (b-4), (I-97) + (b-5), (I-97) + (b-6), (I-97) + (b -7), (I-97) + (b-8), (I-97) + (b-9), (I-97) + (b-10), (I-97) + (b-11) ), (I-97) + (b-12), (I-97) + (b-13), (I-97) + (b-14), (I-97) + (S3-1), (I-97) + (S3-2), (I-97) + (S3-3), (I-97) + (S3-4), (I-97) + (S3-5), (I -97) + (h-1), (I-97) + (h-2), (I-97) + (V-1), (I-97) + (V-2), (I-97) ) + (V-3), (I-97) + (V-4), (I-97) + (V-5), (I-97) + (V-6). (I-98) + (ll-O), (I-98) + (11-1), (i-98) + (il-2), (I-98) + (II-3), (I -98) + (II-4), (I-98) + (II-5), (I-98) + (II-6), (I-98) + (II-9), (I-98) ) + (11-12), (I-98) + (111-1), (I-98) + (III-4), (I-98) + (111-10), (I-98) + (111-11), (I-98) + (IV-1), (I-98) + (IV-2), (I-98) + (IV-3), (I-98) + (IV -4), (I-98) + (IV-5), (I-98) + (b-1), (I-98) + (b-2), (I-98) + (b-3) ), (I-98) + (b-4), (I-98) + (b-5), (I-98) + (b-6), (I-98) + (b-7), (I-98) + (b-8), (I-98) + (b-9), (I-98) + (b-10), (I-98) + (b-11), (I -98) + (b-12), (I-98) + (b-13), (I-98) + (b-14), (I-98) + (S3-1), (I-98) ) + (S3-2), (I-98) + (S3-3), (I-98) + (S3-4), (I-98) + (S3-5), (1-98) + (h-1), (I-98) + (h-2), (I-98) + (V-1), (I-98) + (V-2), (I-98) + (V -3), (I-98) + (V-4), (I-98) + (V-5), (I-98) + (V-6). (I-99) + (11-O), (I-99) + (11-1), (I-99) + (II-2), (I-99) + (II-3), (I -99) +
(II-4), (I-99) + (II-5), (I-99) + (II-6), (I-99) + (II-9), (I-99) + (11 -12), (I-99) + (111-1), (I-99) + (HI-4), (I-99) + (111-10), (I-99) + (111-11) ), (I-99) + (IV-1), (I-99) + (IV-2), (I-99) + (IV-3), (I-99) + (IV-4), (I-99) + (IV-5), (I-99) + (b-1), (I-99) + (b-2), (I-99) +
(b-3), (I-99) + (b-4), (I-99) + (b-5), (I-99) + (b-6), (I-99) + (b -7), (I-99) + (b-8), (I-99) + (b-9), (I-99) + (b-10), (I-99) + (b-11) ), (I-99) + (b-12), (I-99) + (b-13), (I-99) + (b-14), (I-99) + (S3-1), (I-99) + (S3-2), (I-99) + (S3-3), (I-99) + (S3-4), (I-99) + (S3-5), (I -99) + (h-1), (I-99) + (h-2), (I-99) + (V-1), (I-99) + (V-2), (1-99) ) + (V-3), (I-99) + (V-4), (I-99) + (V-5), (I-99) + (V-6). (1-100) + (ll-O), (1-100) + (11-1), (1-100) + (II-2), (1-100) + (II-3), (I - 100) + (II-4), (1-100) + (II-5), (1-100) + (II-6), (1-100) + (II-9), (1-100) ) + (11-12), (I-100) + (111-1), (1-100) + (III-4), (1-100) + (111-10), (1-100) + (111-11), (1-100) + (IV-1), (1-100) + (IV-2), (1-100) + (IV-3), (1-100) + (IV -4), (1-100) + (IV-5), (1-100) + (b-1), (1-100) + (b-2), (1-100) + (b-3) ), (1-100) + (b-4), (1-100) + (b-5), (1-100) + (b-6), (1-100) + (b-7), (1-100) + (b-8), (1-100) + (b-9), (1-100) + (b-10), (1-100) + (b-11), (1 -100) + (b-12), (1-100) + (b-13), (1-100) + (b-14), (1-100) + (S3-1), (I- 100) ) + (S3-2), (1-100) + (S3-3), (1-100) + (S3-4), (1-100) + (S3-5), (1-100) + (h-1), (1-100) + (h-2), (1-100) + (V-1), (1-100) + (V-2), (1-100) + (V -3), (1-100) + (V-4), (1-100) + (V-5), (1-100) + (V-6). (1-101) + (ll-O), (1-101) + (11-1), (1-101) + (II-2), (1-101) + (II-3), (I - 101) + (II-4), (1-101) + (II-5), (1-101) + (II-6), (1-101) + (II-9), (1-101) ) + (11-12), (I- 101) + (111-1), (1-101) + (III-4), (1-101) + (111-10), (1-101) + (111-11), (1-101) + (IV-1), (1-101) + (IV-2), (1-101) + (IV-3), (1-101) + (IV -4), (1-101) + (IV-5), (1-101) + (b-1), (1-101) + (b-2), (1-101) + (b-3) ), (1-101) + (b-4), (1-101) + (b-5), (1-101) + (b-6), (1-101) + (b-7), (1-101) + (b-8), (1-101) + (b-9), (1-101) + (b-10), (1-101) + (b-11), (1 -101) + (b-12), (1-101) + (b-13), (1-101) + (b-14), (1-101) + (S3-1), (I-101) ) + (S3-2), (1-101) + (S3-3), (1-101) + (S3-4), (1-101) + (S3-5), (1-101) + (h-1), (1-101) + (h-2), (1-101) + (V-1), (1-101) + (V-2), (1-101) + (V -3), (1-101) + (V-4), (1-101) + (V-5), (1-101) + (V-6). (1-102) + (11-O), (1-102) + (11-1), (1-102) + (II-2), (1-102) + (II-3), (I - 102) + (II-4), (1-102) + (II-5), (1-102) + (II-6), (1-102) + (II-9), (1-102) ) + (11-12), (I- 102) + (111-1), (1-102) + (III-4), (1-102) + (111-10), (1-102) + (111-11), (1-102) + (IV-1), (1-102) + (IV-2), (1-102) + (IV-3), (1-102) + (lV -4), (1-102) + (IV-5), (1-102) + (b-1), (1-102) + (b-2), (1-102) + (b-3) ), (1-102) + (b-4), (1-102) + (b-5), (1-102) + (b-6), (1-102) + (b-7), (1-102) + (b-8), (1-102) + (b-9), (1-102) + (b-10), ( 1-102) + (b-11), (1-102) + (b-12), (1-102) + (b-13), (1-102) + (b-14), (1- 102) + (S3-1), (I- 102) + (S3-2), (1-102) + (S3-3), (1-102) + (S3-4), (1-102) + (S3-5), (1-102) + (h-1), (1-102) + (h-2), (1-102) + (V-1), (1-102) + ( V-2), (1-102) + (V-3), (1-102) + (V-4), (1-102) + (V-5), (1-102) + (V- 6). (1-103) + (ll-O), (1-103) + (11-1), (1-103) + (II-2), (1-103) + (II-3), (I -103) + (II-4), (1-103) + (II-5), (1-103) + (II-6), (1-103) + (II-9), (1-103) ) + (11-12), (I-103) + (111-1), (1-103) + (III-4), (1-103) + (111-10), (1-103) + (111-11), (1-103) + (IV-1), (1-103) + (IV-2), (1-103) + (IV-3), (1-103) + (IV -4), (1-103) + (IV-5), (1-103) + (b-1), (1-103) + (b-2), (1-103) + (b-3) ), (1-103) + (b-4), (1-103) + (b-5), (1-103) + (b-6), (1-103) + (b-7), (1-103) + (b-8), (1-103) + (b-9), (1-103) + (b-10), (1-103) + (b-11), (1 -103) + (b-12), (1-103) + (b-13), (1-103) + (b-14), (1-103) + (S3-1), (I-103) ) + (S3-2), (1-103) + (S3-3), (1-103) + (S3-4), (1-103) + (S3-5), (1-103) + (h-1), (1-103) + (h-2), (1-103) + (V-1), (1-103) + (V-2), (1-103) + (V -3), (1-103) + (V-4), (1-103) + (V-5), (1-103) + (V-6). (1-104) + (ll-O), (1-104) + (11-1), (1-104) + (II-2), (1-104) + (II-3), (I - 104) + (II-4), (1-104) + (II-5), (1-104) + (II-6), (1-104) + (II-9), (1-104) ) + (11-12), (I-104) + (111-1), (1-104) + (III-4), (1-104) + (111-10), (1-104) + (111-11), (1-104) + (IV-1), (1-104) + (IV-2), (1-104) + (IV-3), (1-104) + (IV -4), (1-104) + (IV-5), (1-104) + (b-1), (1-104) + (b-2), (1-104) + (b-3) ), (1-104) + (b-4), (1-104) + (b-5), (1-104) + (b-6), (1-104) + (b-7), (1-104) + (b-8), (1-104) + (b-9), (1-104) + (b-10), (1-104) + (b-11), (1 -104) + (b-12), (1-104) + (b-13), (1-104) + (b-14), (1-104) + (S3-1), (I-104) ) + (S3-2), (1-104) + (S3-3), (1-104) + (S3-4), (1-104) + (S3-5), (1-104) + (h-1), (1-104) + (h-2), (1-104) + (V-1), (1-104) + (V-2), (1-104) + (V -3), (1-104) + (V-4), (1-104) + (V-5), (1-104) + (V-6). (1-105) + (ll-O), (1-105) + (11-1), (1-105) + (II-2), (1-105) + (II-3), (I - 105) + (II-4), (1-105) + (II-5), (1-105) + (II-6), (1-105) + (II-9), (1-105) ) + (11-12), (I-105) + (111-1), (1-105) + (III-4), (1-105) + (111-10), (1-105) + (111-11), (1-105) + (IV-1), (1-105) + (iV-2), (1-105) + (IV-3), (1-105) + (IV -4), (1-105) + (IV-5), (1-105) + (b-1), (1-105) + (b-2), (1-105) + (b-3) ), (1-105) + (b-4), (1-105) + (b-5), (1-105) + (b-6), (1-105) + (b-7), (1-105) + (b-8), (1-105) + (b-9), (1-105) + (b-10), (1-105) + (b-11), (1 -105) + (b-12), (1-105) + (b-13), (1-105) + (b-14), (1-105) + (S3-1), (I-105) ) + (S3-2), (1-105) + (S3-3), (1-105) + (S3-4), (1-105) + (S3-5), (1-105) + (h-1), (1-105) + (h-2), (1-105) + (V-1), (1-105) + (V-2), (1-105) + (V -3), (1-105) + (V-4), (1-105) + (V-5), (1-105) + (V-6). (1-106) + (ll-O), (1-106) + (11-1), (1-106) + (II-2), (1-106) + (II-3), (I - 106) + (II-4), (1-106) + (II-5), (1-106) + (II-6), (1-106) + (II-9), (1-106) ) + (11-12), (I- 106) + (111-1), (1-106) + (III-4), (1-106) + (111-10), (1-106) + (111-11), (1-106) + (IV-1), (1-106) + (IV-2), (1-106) + (IV-3), (1-106) + (IV -4), (1-106) + (IV-5), (1-106) + (b-1), (1-106) + (b-2), (1-106) + (b-3) ), (1-106) + (b-4), (1-106) + (b-5), (1-106) + (b-6), (1-106) + (b-7), (1-106) + (b-8), (1-106) + (b-9), (1-106) + (b-10), (1-106) + (b-11), (1 -106) + (b-12), (1-106) + (b-13), (1-106) + (b-14), (1-106) + (S3-1), (I-106) ) + (S3-2), (1-106) + (S3-3), (1-106) + (S3-4), (1-106) + (S3-5), (1-106) + (h-1), (1-106) + (h-2), (1-106) + (V-1), (1-106) + (V-2), (1-106) + (V -3), (1-106) + (V-4), (1-106) + (V-5), (1-106) + (V-6). (1-107) + (ll-O), (1-107) + (11-1), (1-107) + (II-2), (1-107) + (II-3), (I - 107) + (II-4), (1-107) + (II-5), (1-107) + (II-6), (1-107) + (II-9), (1-107) ) + (11-12), (I-107) + (111-1), (1-107) + (III-4), (1-107) + (111-10), (1-107) + (111-11), (1-107) + (IV-1), (1-107) + (IV-2), (1-107) + (IV-3), (1-107) + (IV -4), (1-107) + (IV-5), (1-107) + (b-1), (1-107) + (b-2), (1-107) + (b-3) ), (1-107) + (b-4), (1-107) + (b-5), (1-107) + (b-6), (1-107) + (b-7), (1-107) + (b-8), ( 1-107) + (b-9), (1-107) + (b-10), (1-107) + (b-11), (1-107) + (b-12), (1- 107) + (b-13), (1-107) + (b-14), (1-107) + (S3-1), (I-107) + (S3-2), (1-107) + (S3-3), (1-107) + (S3-4), (1-107) + (S3-5), (1-107) + (h-1), (1-107) + ( h-2), (1-107) + (V-1), (1-107) + (V-2), (1-107) + (V-3), (1-107) + (V- 4), (1-107) + (V-5), (1-107) + (V-6).
(1-108) + (ll-O), (1-108) + (11-1), (1-108) + (II-2), (1-108) + (II-3), (I -108) + (II-4), (1-108) + (II-5), (1-108) + (II-6), (1-108) + (II-9), (1-108) ) + (11-12), (I-108) + (111-1), (1-108) + (III-4), (1-108) + (111-10), (1-108) + (111-11), (1-108) + (IV-1), (1-108) + (IV-2), (1-108) + (IV-3), (1-108) + (IV -4), (1-108) + (IV-5), (1-108) + (b-1), (1-108) + (b-2), (1-108) + (b-3) ), (1-108) + (b-4), (1-108) + (b-5), (1-108) + (b-6), (1-108) + (b-7), (1-108) + (b-8), (1-108) + (b-9), (1-108) + (b-10), (1-108) + (b-11), (1 -108) + (b-12), (1-108) + (b-13), (1-108) + (b-14), (1-108) + (S3-1), (I-108) ) + (S3-2), (1-108) + (S3-3), (1-108) + (S3-4), (1-108) + (S3-5), (1-108) + (h-1), (1-108) + (h-2), (1-108) + (V-1), (1-108) + (V-2), (1-108) + (V -3), (1-108) + (V-4), (1-108) + (V-5), (1-108) + (V-6). (1-109) + (ll-O), (1-109) + (11-1), (1-109) + (II-2), (1-109) + (II-3), (I - 109) + (II-4), (1-109) + (II-5), (1-109) + (II-6), (1-109) + (II-9), (1-109) ) + (11-12), (I-109) + (111-1), (1-109) + (III-4), (1-109) + (111-10), (1-109) + (111-11), (1-109) + (IV-1), (1-109) + (IV-2), (1-109) + (IV-3), (1-109) + (IV -4), (1-109) + (IV-5), (1-109) + (b-1), (1-109) + (b-2), (1-109) + (b-3) ), (1-109) + (b-4), (1-109) + (b-5), (1-109) + (b-6), (1-109) + (b-7), (1-109) + (b-8), (1-109) + (b-9), (1-109) + (b-10), (1-109) + (b-11), (1 -109) + (b-12), (1-109) + (b-13), (1-109) + (b-14), (1-109) + (S3-1), (I-109) ) + (S3-2), (1-109) + (S3-3), (1-109) + (S3-4), (1-109) + (S3-5), (1-109) + (h-1), (1-109) + (h-2), (1-109) + (V-1), (1-109) + (V-2), (1-109) + (V -3), (1-109) + (V-4), (1-109) + (V-5), (1-109) + (V-6). (1-110) + (ll-O), (1-110) + (11-1), (1-110) + (II-2), (1-110) + (II-3), tino) + (II-4), (1-110) + (II-5), (1-110) + (II-6), (1-110) + (II-9), (1-110) + ( 11-12), (I-1 10) + (111-1), (1-110) + (III-4), (1-110) + (111-10), (1-110) + (111 -11), (1-110) + (IV-1), (1-110) + (IV-2), (1-110) + (IV-3), (1-110) + (IV-4) ), (1-110) + (IV-5), (1-110) + (b-1), (1-110) + (b-2), (1-110) + (b-3), (1-110) + (b-4), (1-110) + (b-5), (1-110) + (b-6), (1-110) + (b-7), (1 -110) + (b-8), (1-110) + (b-9), (1-110) + (b-10), (1-110) + (b-11), (1-110) ) + (b-12), (1-110) + (b-13), (1-110) + (b-14), (1-110) + (S3-1), (I-110) + (S3-2), (1-110) + (S3-3), (1-110) + (S3-4), (1-110) + (S3-5), (1-110) + (h - 1), (1-110) + (h-2), (1-110) + (V-1), (1-110) + (V-2), (1-110) + (V-3) ), (1-110) + (V-4), (1-110) + (V-5), (1-110) + (V-6). (1-111) + (ll-O), (1-111) + (11-1), (1-111) + (II-2), (1-111) + (II-3), (I - 111) + (II-4), (1-111) + (II-5), (1-111) + (II-6), (1-111) + (II-9), (1-111) ) + (11-12), (I-111) + (111-1), (1-111) + (III-4), (1-111) + (111-10), (1-111) + (111-11), (1-111) + (IV-1), (1-111) + (IV-2), (1-111) + (IV-3), (1-111) + (IV -4), (1-111) + (IV-5), (1-111) + (b-1), (1-111) + (b-2), (1-111) + (b-3) ), (1-111) + (b-4), (1-111) + (b-5), (1-111) + (b-6), (1-111) + (b-7), (1-111) + (b-8), (1-111) + (b-9), (1-111) + (b-10), (1-111) + (b-11), (1 -111) + (b-12), (1-111) + (b-13), (1-111) + (b-14), (1-111) + (S3-1), (I-111) ) + (S3-2), (1-111) + (S3-3), (1-111) + (S3-4), (1-111) + (S3-5), (1-111) + (h-1), (1-111) + (h-2), (1-111) + (V-1), (1-111) + (V-2), (1-111) + (V -3), (1-111) + (V-4), (1-111) + (V-5), (1-111) + (V-6). (1-112) + (ll-O), (1-112) + (11-1), (1-112) + (II-2), (1-112) + (II-3), (I - 112) + (II-4), (1-112) + (II-5), (1-112) + (II-6), (1-112) + (II-9), (1-112) ) + (11-12), (I-112) + (111-1), (1-112) + (III-4), (1-112) + (111-10), (1-112) + (111-11), (1-112) + (IV-1), (1-112) + (IV-2), (1-112) + (IV-3), (1-112) + (IV -4), (1-112) + (IV-5), (1-112) + (b-1), (1-112) + (b-2), (1-112) + (b-3) ), (1-112) + (b-4), (1-112) + (b-5), (1-112) + (b-6), (1-112) + (b-7), (1-112) + (b-8), (1-112) + (b-9), (1-112) + (b-10), (1-112) + (b-11), (1 -112) + (b-12), (1-112) + (b-13), (1-112) + (b-14), (1-112) + (S3-1), (I-112) ) + (S3-2), (1-112) + (S3-3), (1-112) + (S3-4), (1-112) + (S3-5), (1-112) + (h-1), (1-112) + (h-2), (1-112) + (V-1), (1-112) + (V-2), (1-112) + (V -3), (1-112) + (V-4), (1-112) + (V-5), (1-112) + (V-6). (1-113) + (ll-O), (1-113) + (11-1), (1-113) + (II-2), (1-113) + (II-3), (I - 113) + (II-4), (1-113) + (II-5), (1-113) + (II-6), (1-113) + (II-9), (1-113) ) + (11-12), (I- 113) + (111-1), (1-113) + (III-4), (1-113) + (111-10), (1-113) + (111-11), (1-113) + (IV-1), (1-113) + (IV-2), (1-113) + (IV-3), (1-113) + (IV -4), (1-113) + (IV-5), (1-113) + (b-1), (1-113) + (b-2), (1-113) + (b-3) ), (1-113) + (b-4), (1-113) + (b-5), (1-113) + (b-6), (1-113) + (b-7), (1-113) + (b-8), (1-113) + (b-9), (1-113) + (b-10), (1-113) + (b-11), (1 -113) + (b-12), (1-113) + (b-13), (1-113) + (b-14), (1-113) + (S3-1), (I-113) ) + (S3-2), (1-113) + (S3-3), (1-113) + (S3-4), (1-113) + (S3-5), (1-113) + (h-1), (1-113) + (h-2), (1-113) + (V-1), (1-113) + (V-2), (1-113) + (V -3), (1-113) + (V-4), (1-113) + (V-5), (1-113) + (V-6). (1-114) + (ll-O), (1-114) + (11-1), (1-114) + (II-2), (1-114) + (II-3), (I - 114) + (II-4), (1-114) + (II-5), (1-114) + (II-6), (1-114) + (II-9), (1-114) ) + (11-12), (I-114) + (111-1), (1-114) + (III-4), (1-114) + (111-10), (1-114) + (111-11), (1-114) + (IV-1), (1-114) + (IV-2), (1-114) + (IV-3), (1-114) + (IV -4), (1-114) + (IV-5), (1-114) + (b-1), (1-114) + (b-2), (1-114) + (b-3) ), (1-114) + (b-4), (1-114) + (b-5), (1-114) + (b-6), (1-114) + (b-7), (1-114) + (b-8), (1-114) + (b-9), (1-114) + (b-10), (1-114) + (b-11), (1 -114) + (b-12), (1-114) + (b-13), (1-114) + (b-14), (1-1 4) + (S3-1), (I- 114) + (S3-2), (1-114) + (S3-3), (1-114) + (S3-4), (1-114) + (S3-5), (1-114) + (h-1), (1-114) + (h-2), (1-114) + (V-1), (1-114) + (V-2), (1-114) + ( V-3), (1-114) + (V-4), (1-114) + (V-5), (1-114) + (V-6). (1-115) + (ll-O), (1-115) + (11-1), (1-115) + (II-2), (1-115) + (II-3), (I - 115) + (II-4), (1-115) + (II-5), (1-115) + (II-6), (1-115) + (II-9), (1-115) ) + (11-12), (I-115) + (111-1), (1-115) + (III-4), (1-115) + (111-10), (1-115) + (111-11), (1-115) + (IV-1), (1-115) + (IV-2), (1-115) + (IV-3), (1-115) + (IV -4), (1-115) + (IV-5), (1-115) + (b-1), (1-115) + (b-2), (1-115) + (b-3) ), (1-115) + (b-4), (1-115) + (b-5), (1-115) + (b-6), (1-115) + (b-7), (1-115) + (b-8), (1-115) + (b-9), (1-115) + (b-10), (1-115) + (b-11), (1 -115) + (b-12), (1-115) + (b-13), (1-115) + (b-14), (1-115) + (S3-1), (I-115) ) + (S3-2), (1-115) + (S3-3), (1-115) + (S3-4), (1-115) + (S3-5), (1-115) + (h-1), (1-115) + (h-2), (1-115) + (V-1), (1-115) + (V-2), (1-115) + (V -3), (1-115) + (V-4), (1-115) + (V-5), (l-115) + (V-6). (1-116) + (ll-O), (1-116) + (11-1), (1-116) + (II-2), (1-116) + (II-3), (I - 1 16) + (II-4), (1-116) + (II-5), (1-116) + (II-6), (1-116) + (II-9), (1- 116) + (11-12), (I-116) + (111-1), (1-116) + (III-4), (1-116) + (111-10), (1-116) + (111-11), (1-116) + (IV-1), (1-116) + (IV-2), (1-116) + (IV-3), (1-116) + ( IV-4), (1-116) + (IV-5), (1-116) + (b-1), (1-116) + (b-2), (1-116) + (b- 3), (1-116) + (b-4), (1-116) + (b-5), (1-116) + (b-6), (1-116) + (b-7) , (1-116) + (b-8), (1-116) + (b-9), (1-116) + (b-10), (1-116) + (b-11), ( 1-116) + (b-12), (1-116) + (b-13), (1-116) + (b-14), (1-116) + (S3-1), (I- 1 16) + (S3-2), (1-116) + (S3-3), (1-116) + (S3-4), (1-116) + (S3-5), (1-116) ) + (h-1), (1-116) + (h-2), (1-116) + (V-1), (1-116) + (V-2), (1-116) + (V-3), (1-116) + (V-4), (1-166) + (V-5), (1-116) + (V-6).
(1-117) + (ll-O), (1-117) + (11-1), (1-117) + (II-2), (1-117) + (II-3), (I - 117) + (II-4), (1-117) + (II-5), (1-117) + (II-6), (1-117) + (II-9), (1-117) ) + (11-12), (I- 117) + (111-1), (1-117) + (III-4), (1-117) + (111-10), (1-117) + (111-11), (1-117) + (IV-1), (1-117) + (IV-2), (1-117) + (IV-3), (1-117) + (IV -4), (1-117) + (IV-5), (1-117) + (b-1), (1-117) + (b-2), (1-117) + (b-3) ), (1-117) + (b-4), (1-117) + (b-5), (1-117) + (b-6), (1-117) + (b-7), (1-117) + (b-8), (1-117) + (b-9), (1-117) + (b-10), (1-117) + (b-11), (1 -117) + (b-12), (1-117) + (b-13), (1-117) + (b-14), (1-117) + (S3-1), (I- 17) ) + (S3-2), (1-117) + (S3-3), (1-117) + (S3-4), (1-117) + (S3-5), (1-117) + (h-1), (1-117) + (h-2), (1-117) + (V-1), (1-117) + (V-2), (1-117) + (V -3), (1-117) + (V-4), (1-117) + (V-5), (1-117) + (V-6). (1-118) + (ll-O), (1-118) + (11-1), (1-118) + (II-2), (1-118) + (II-3), (I - 118) + (II-4), (1-118) + (II-5), (1-118) + (II-6), (1-118) + (II-9), (1-118) ) + (11-12), (I-1 18) + (111-1), (1-118) + (lll-4), (1-118) + (111-10), (1-118) + (111-11), (1-118) + (IV-1), (1-118) + (IV-2), (1-118) + (IV-3), (1-118) + ( IV-4), (1-118) + (IV-5), (1-118) + (b-1), (1-118) + (b-2), (1-118) + (b- 3), (1-118) + (b-4), (1-118) + (b-5), (1-118) + (b-6), (1-118) + (b-7) , (1-118) + (b-8), (1-118) + (b-9), (1-118) + (b-10), (1-118) + (b-11), ( 1-118) + (b-12), (1-118) + (b-13), (1-118) + (b-14), (1-118) + (S3-1), (I- 1 18) + (S3-2), (1-118) + (S3-3), (1-118) + (S3-4), (1-118) + (S3-5), (1-118) ) + (h-1), (1-118) + (h-2), (1-118) + (V-1), (1-118) + (V-2), (1-118) + (V-3), (1-118) + (V-4), (1-118) + (V-5), (1-118) + (V-6). (1-119) + (ll-O), (1-119) + (11-1), (1-119) + (II-2), (1-119) + (II-3), (I - 119) + (II-4), (1-119) + (II-5), (1-119) + (II-6), (1-119) + (II-9), (1-119) ) + (11-12), (l-1 19) + (111-1), (1-119) + (lll-4), (1-119) + (111-10), (1-119) + (111-11), (1-119) + (IV-1), (1-119) + (IV-2), (1-119) + (IV-3), (1-119) + ( IV-4), (1-119) + (IV-5), (1-119) + (b-1), (1-119) + (b-2), (1-119) + (b- 3), (1-119) + (b-4), (1-119) + (b-5), (1-119) + (b-6), (1-119) + (b-7) , (1-119) + (b-8), (1-119) + (b-9), (1-119) + (b-10), (1-119) + (b-11), ( 1-119) + (b-12), (1-119) + (b-13), (1-119) + (b-14), (1-119) + (S3-1), (I- 119) + (S3-2), (1-119) + (S3-3), (1-119) + (S3-4), (1-119) + (S3-5), (1-119) + (h-1), (1-119) + (h-2), (1-119) + (V-1), (1-119) + (V-2), (1-119) + ( V-3), (1-119) + (V-4), (1-119) + (V-5), (1-119) + (V-6). (1-120) + (ll-O), (1-120) + (11-1), (1-120) + (II-2), (1-120) + (II-3), (I - 120) + (II-4), (1-120) + (II-5), (1-120) + (II-6), (1-120) + (II-9), (1-120 ) + (11-12), (I-120) + (111-1), (1-120) + (III-4), (1-120) + (111-10), (1-120) + (111-11), (1-120) + (IV-1), (1-120) + (IV-2), (1-120) + (IV-3), (1-120) + (IV -4), (1-120) + (IV-5), (1-120) + (b-1), (1-120) + (b-2), (1-120) + (b-3) ), (1-120) + (b-4), (1-120) + (b-5), (1-120) + (b-6), (1-120) + (b-7), (1-120) + (b-8), (1-120) + (b-9), (1-120) + (b-10), (1-120) + (b-11), (1 -120) + (b-12), (1-120) + (b-13), (1-120) + (b-14), (1-120) + (S3-1), (I-120) ) + (S3-2), (1-120) + (S3-3), (1-120) + (S3-4), (1-120) + (S3-5), (1-120) + (h-1), (1-120) + (h-2), (1-120) + (V-1), (1-120) + (V-2), (1-120) + (V -3), (1-120) + (V-4), (1-120) + (V-5), (1-120) + (V-6). (1-121) + (ll-O), (1-121) + (11-1), (1-121) + (II-2), (1-121) + (II-3), (I - 121) + (II-4), (1-121) + (II-5), (1-121) + (II-6), (1-121) + (II-9), (1-121) ) + (11-12), (I-121) + (111-1), (1-121) + (III-4), (1-121) + (111-10), (1-121) + (111-11), (1-121) + (IV-1), (1-121) + (IV-2), (1-121) + (lV-3), (1-121) + (IV -4), (1-121) + (IV-5), (1-121) + (b-1), (1-121) + (b-2), (1-121) + (b-3) ), (1-121) + (b-4), (1-121) + (b-5), (1-121) + (b-6), (1-121) + (b-7), (1-121) + (b-8), (1-121) + (b-9), (1-121) + (b-10), (1-121) + (b-11), (1 -121) + (b-12), (1-121) + (b-13), (1-121) + (b-14), (1-121) + (S3-1), (I-121) ) + (S3-2), (1-121) + (S3-3), (1-121) + (S3-4), (1-121) + (S3-5), (1-121) + (h-1), (1-121) + (h-2), (1-121) + (V-1), (1-121) + (V-2), (1-121) + (V-3), (1-121) + (V-4), (1-121) + (V-5), ( 1-121) + (V-6). (1-122) + (ll-O), (1-122) + (11-1), (1-122) + (II-2), (1-122) + (II-3), (I - 122) + (II-4), (1-122) + (II-5), (1-122) + (II-6), (1-122) + (II-9), (1-122) ) + (11-12), (I-122) + (111-1), (1-122) + (III-4), (1-122) + (111-10), (1-122) + (111-11), (1-122) + (IV-1), (1-122) + (IV-2), (1-122) + (IV-3), (1-122) + (IV -4), (1-122) + (IV-5), (1-122) + (b-1), (1-122) + (b-2), (1-122) + (b-3) ), (1-122) + (b-4), (1-122) + (b-5), (1-122) + (b-6), (1-122) + (b-7), (1-122) + (b-8), (1-122) + (b-9), (1-122) + (b-10), (1-122) + (b-11), (1 -122) + (b-12), (1-122) + (b-13), (1-122) + (b-14), (1-122) + (S3-1), (I-122) ) + (S3-2), (1-122) + (S3-3), (1-122) + (S3-4), (1-122) + (S3-5), (1-122) + (h-1), (1-122) + (h-2), (1-122) + (V-1), (1-122) + (V-2), (1-122) + (V -3), (1-122) + (V-4), (1-122) + (V-5), (1-122) + (V-6). (1-123) + (ll-O), (1-123) + (11-1), (1-123) + (II-2), (1-123) + (II-3), (I - 123) + (II-4), (1-123) + (II-5), (1-123) + (II-6), (1-123) + (II-9), (1-123) ) + (11-12), (I-123) + (111-1), (1-123) + (III-4), (1-123) + (111-10), (1-123) + (111-11), (1-123) + (IV-1), (1-123) + (IV-2), (1-123) + (IV-3), (1-123) + (IV -4), (1-123) + (IV-5), (1-123) + (b-1), (1-123) + (b-2), (1-123) + (b-3) ), (1-123) + (b-4), (1-123) + (b-5), (1-123) + (b-6), (1-123) + (b-7), (1-123) + (b-8), (1-123) + (b-9), (1-123) + (b-10), (1-123) + (b-11), (1 -123) + (b-12), (1-123) + (b-13), (1-123) + (b-14), (1-123) + (S3-1), (I-123) ) + (S3-2), (1-123) + (S3-3), (1-123) + (S3-4), (1-123) + (S3-5), (1-123) + (h-1), (1-123) + (h-2), (1-123) + (V-1), (1-123) + (V-2), (1-123) + (V -3), (1-123) + (V-4), (1-123) + (V-5), (1-123) + (V-6). (1-124) + (ll-O), (1-124) + (11-1), (1-124) + (II-2), (1-124) + (II-3), (I - 124) + (II-4), (1-124) + (II-5), (1-124) + (II-6), (1-124) + (II-9), (1-124) ) + (11-12), (I- 124) + (111-1), (1-124) + (III-4), (1-124) + (111-10), (1-124) + (111-11), (1-124) + (IV-1), (1-124) + (IV-2), (1-124) + (IV-3), (1-124) + (IV -4), (1-124) + (IV-5), (1-124) + (b-1), (1-124) + (b-2), (1-124) + (b-3) ), (1-124) + (b-4), (1-124) + (b-5), (1-124) + (b-6), (1-124) + (b-7), (1-124) + (b-8), (1-124) + (b-9), (1-124) + (b-10), (1-124) + (b-11), (1 -124) + (b-12), (1-124) + (b-13), (1-124) + (b-14), (1-124) + (S3-1), (I-124) ) + (S3-2), (1-124) + (S3-3), (1-124) + (S3-4), (1-124) + (S3-5), (1-124) + (h-1), (1-124) + (h-2), (1-124) + (V-1), (1-124) + (V-2), (1-124) + (V -3), (1-124) + (V-4), (1-124) + (V-5), (1-124) + (V-6). (1-125) + (ll-O), (1-125) + (11-1), (1-125) + (II-2), (1-125) + (II-3), (I - 125) + (II-4), (1-125) + (II-5), (1-125) + (II-6), (1-125) + (II-9), (1-125) ) + (11-12), (I-125) + (lil-1), (1-125) + (III-4), (1-125) + (111-10), (1-125) + (111-11), (1-125) + (IV-1), (1-125) + (IV-2), (1-125) + (IV-3), (1-125) + (lV -4), (1-125) + (IV-5), (1-125) + (b-1), (1-125) + (b-2), (1-125) + (b-3) ), (1-125) + (b-4), (1-125) + (b-5), (1-125) + (b-6), (1-125) + (b-7), (1-125) + (b-8), (1-125) + (b-9), (1-125) + (b-10), (1-125) + (b-11), (1 -125) + (b-12), (1-125) + (b-13), (1-125) + (b-14), (1-125) + (S3-1), (I-125) ) + (S3-2), (1-125) + (S3-3), (1-125) + (S3-4), (1-125) + (S3-5), (1-125) + (h-1), (1-125) + (h-2), (1-125) + (V-1), (1-125) + (V-2), (1-125) + (V -3), (1-125) + (V-4), (1-125) + (V-5), (1-125) + (V-6).
(1-126) + (ll-O), (1-126) + (11-1), (1-126) + (II-2), (1-126) + (II-3), (I - 126) + (II-4), (1-126) + (II-5), (1-126) + (II-6), (1-126) + (II-9), (1-126) ) + (11-12), (I- 126) + (111-1), (1-126) + (III-4), (1-126) + (111-10), (1-126) + (111-11), (1-126) + (IV-1), (1-126) + (IV-2), (1-126) + (IV-3), (1-126) + (IV -4), (1-126) + (IV-5), (1-126) + (b-1), (1-126) + (b-2), (1-126) + (b-3) ), (1-126) + (b-4), (1-126) + (b-5), (1-126) + (b-6), (1-126) + (b-7), (1-126) + (b-8), (1-126) + (b-9), (1-126) + (b-10), (1-126) + (b-11), (1 -126) + (b-12), (1-126) + (b-13), (1-126) + (b-14), (1-126) + (S3-1), (I-126) ) + (S3-2), (1-126) + (S3-3), (1-126) + (S3-4), (1-126) + (S3-5), (1-126) + (h-1), (1-126) + (h-2), (1-126) + (V-1), (1-126) + (V-2), (1-126) + (V -3), (1-126) + (V-4), (1-126) + (V-5), (1-126) + (V-6). (1-127) + (ll-O), (1-127) + (11-1), (1-127) + (II-2), (1-127) + (II-3), (I - 127) + (M-4), (1-127) + (II-5), (1-127) + (II-6), (1-127) + (II-9), (1-127) ) + (11-12), (I-127) + (111-1), (1-127) + (III-4), (1-127) + (111-10), (1-127) + (111-11), (1-127) + (IV-1), (1-127) + (IV-2), (1-127) + (IV-3), (1-127) + (IV -4), (1-127) + (IV-5), (1-127) + (b-1), (1-127) + (b-2), (1-127) + (b-3) ), (1-127) + (b-4), (1-127) + (b-5), (1-127) + (b-6), (1-127) + (b-7), (1-127) + (b-8), (1-127) + (b-9), (1-127) + (b-10), (1-127) + (b-11), (1 -127) + (b-12), (1-127) + (b-13), (1-127) + (b-14), (1-127) + (S3-1), (I-127) ) + (S3-2), (1-127) + (S3-3), (1-127) + (S3-4), (1-127) + (S3-5), (1-127) + (h-1), (1-127) + (h-2), (1-127) + (V-1), (1-127) + (V-2), (1-127) + (V -3), (1-127) + (V-4), (1-127) + (V-5), (1-127) + (V-6). (1-128) + (ll-O), (1-128) + (11-1), (1-128) + (II-2), (1-128) + (II-3), (I - 128) + (II-4), (1-128) + (II-5), (1-128) + (II-6), (1-128) + (II-9), (1-128) ) + (11-12), (I-128) + (111-1), (i-128) + (III-4), (1-128) + (111-10), (1-128) + (111-11), (1-128) + (IV-1), (1-128) + (IV-2), (1-128) + (IV-3), (1-128) + (IV -4), (1-128) + (IV-5), (1-128) + (b-1), (1-128) + (b-2), (1-128) + (b-3) ), (1-128) + (b-4), (1-128) + (b-5), (1-128) + (b-6), (1-128) + (b-7), (1-128) + (b-8), (1-128) + (b-9), (1-128) + (b-10), (1-128) + (b-11), (1 -128) + (b-12), (1-128) + (b-13), (1-128) + (b-14), (1-128) + (S3-1), (I-128) ) + (S3-2), (1-128) + (S3-3), (1-128) + (S3-4), (1-128) + (S3-5), (1-128) + (h-1), (1-128) + (h-2), (1-128) + (V-1), (1-128) + (V-2), (1-128) + (V -3), (1-128) + (V-4), (1-128) + (V-5), (1-128) + (V-6). (1-129) + (ll-O), (1-129) + (11-1), (1-129) + (II-2), (1-129) + (II-3), (I - 129) + (II-4), (1-129) + (II-5), (1-129) + (II-6), (1-129) + (II-9), (1-129) ) + (11-12), (I- 129) + (111-1), (1-129) + (III-4), (1-129) + (111-10), (1-129) + (111-11), (1-129) + (IV-1), (1-129) + (IV-2), (1-129) + (IV-3), (1-129) + (IV -4), (1-129) + (IV-5), (1-129) + (b-1), (1-129) + (b-2), (1-129) + (b-3) ), (1-129) + (b-4), (1-129) + (b-5), (1-129) + (b-6), (1-129) + (b-7), (1-129) + (b-8), (1-129) + (b-9), (1-129) + (b-10), (1-129) + (b-11), (1 -129) + (b-12), (1-129) + (b-13), (1-129) + (b-14), (1-129) + (S3-1), (I-129) ) + (S3-2), (1-129) + (S3-3), (1-129) + (S3-4), (1-129) + (S3-5), (1-129) + (h-1), (1-129) + (h-2), (1-129) + (V-1), (1-129) + (V-2), (1-129) + (V -3), (1-129) + (V-4), (1-129) + (V-5), (1-129) + (V-6). (1-130) + (ll-O), (1-130) + (11-1), (1-130) + (II-2), (1-130) + (II-3), (I - 130) + (II-4), (1-130) + (II-5), (1-130) + (II-6), (1-130) + (II-9), (1-130) ) + (11-12), (I-130) + (111-1), (1-130) + (III-4), (1-130) + (111-10), (1-130) + (111-11), (1-130) + (IV-1), (1-130) + (IV-2), (1-130) + (IV-3), (1-130) + (IV -4), (1-130) + (IV-5), (1-130) + (b-1), (1-130) + (b-2), (1-130) + (b-3) ), (1-130) + (b-4), (1-130) + (b-5), (1-130) + (b-6), (1-130) + (b-7), (1-130) + (b-8), (1-130) + (b-9), (1-130) + (b-10), (1-130) + (b-11), (1 -130) + (b-12), (1-130) + (b-13), (1-130) + (b-14), (1-130) + (S3-1), (I-130) ) + (S3-2), (1-130) + (S3-3), (1-130) + (S3-4), (1-130) + (S3-5), (1-130) + (h-1), (1-130) + (h-2), (1-130) + (V-1), (1-130) + (V-2), (1-130) + (V -3), (1-130) + (V-4), (1-130) + (V-5), (1-130) + (V-6). (1-131) + (11-O), (1-131) + (11-1), (1-131) + (II-2), (1-131) + (II-3), (I - 131) + (II-4), (1-131) + (II-5), (1-131) + (II-6), (1-131) + (II-9), (1-131) ) + (11-12), (I-131) + (111-1), (1-131) + (III-4), (1-131) + (111-10), (1-131) + (111-11), (1-131) + (IV-1), (1-131) + (IV-2), (1-131) + (IV-3), (1-131) + (IV -4), (1-131) + (IV-5), (1-131) + (b-1), (1-131) + (b-2), (1-131) + (b-3) ), (1-131) + (b-4), (1-131) + (b-5), (1-131) + (b-6), (1-131) + (b-7), (1-131) + (b-8), (1-131) + (b-9), (1-131) + (b-10), (1-131) + (b-11), (1 -131) + (b-12), (1-131) + (b-13), (1-131) + (b-14), (1-131) + (S3-1), (I-131) ) + (S3-2), (1-131) + (S3-3), (1-131) + (S3-4), (1-131) + (S3-5), (1-131) + (h-1), (1-131) + (h-2), (1-131) + (V-1), (1-131) + (V-2), (1-131) + (V -3), (1-131) + (V-4), (1-131) + (V-5), (1-131) + (V-6). (1-132) + (ll-O), (1-132) + (11-1), (1-132) + (II-2), (1-132) + (II-3), (I - 132) + (II-4), (1-132) + (II-5), (1-132) + (II-6), (1-132) + (II-9), (1-132) ) + (11-12), (I-132) + (111-1), (1-132) + (III-4), (1-132) + (111-10), (1-132) + (111-11), (1-132) + (IV-1), (1-132) + (IV-2), (1-132) + (IV-3), (1-132) + (IV -4), (1-132) + (IV-5), (1-132) + (b-1), (1-132) + (b-2), (1-132) + (b-3) ), (1-132) + (b-4), (1-132) + (b-5), (1-132) + (b-6), (1-132) + (b-7), (1-132) + (b-8), (1-132) + (b-9), (1-132) + (b-10), (1-132) + (b-11), (1 -132) + (b-12), (1-132) + (b-13), (1-132) + (b-14), (1-132) + (S3-1), (I-132) ) + (S3-2), (1-132) + (S3-3), (1-132) + (S3-4), (1-132) + (S3-5), (1-132) + (h-1), (1-132) + (h-2), (1-132) + (V-1), (1-132) + (V-2), (1-132) + (V -3), (1-132) + (V-4), (1-132) + (V-5), (1-132) + (V-6). (1-133) + (ll-O), (1-133) + (11-1), (1-133) + (II-2), (1-133) + (II-3), (I - 133) + (II-4), (1-133) + (II-5), (1-133) + (li-6), (1-133) + (II-9), (1-133) ) + (11-12), (I-133) + (111-1), (1-133) + (III-4), (1-133) + (111-10), (1-133) + (111-11), (1-133) + (IV-1), (1-133) + (IV-2), (1-133) + (IV-3), (1-133) + (IV -4), (1-133) + (IV-5), (1-133) + (b-1), (1-133) + (b-2), (1-133) + (b-3) ), (1-133) + (b-4), (1-133) + (b-5), (1-133) + (b-6), (1-133) + (b-7), (1-133) + (b-8), (1-133) + (b-9), (1-133) + (b-10), (1-133) + (b-11), (1 -133) + (b-12), (1-133) + (b-13), (1-133) + (b-14), (1-133) + (S3-1), (I-133) ) + (S3-2), (1-133) + (S3-3), (1-133) + (S3-4), (1-133) + (S3-5), (1-133) + (h-1), (1-133) + (h-2), (1-133) + (V-1), (1-133) + (V-2), (1-133) + (V -3), (1-133) + (V-4), (1-133) + (V-5), (1-133) + (V-6). (1-134) + (ll-O), (1-134) + (11-1), (1-134) + (II-2), (1-134) + (II-3), (I - 134) + (II-4), (1-134) + (II-5), (1-134) + (II-6), (1-134) + (II-9), (1-134) ) + (11-12), (I-134) + (111-1), (1-134) + (III-4), (1-134) + (111-10), (1-134) + (111-11), (1-134) + (IV-1), (1-134) + (IV-2), (1-134) + (IV-3), (1-134) + (IV -4), (1-134) + (IV-5), (1-134) + (b-1), (1-134) + (b-2), (1-134) + (b-3) ), (1-134) + (b-4), (1-134) + (b-5), (1-134) + (b-6), (1-134) + (b-7), (1-134) + (b-8), (1-134) + (b-9), (1-134) + (b-10), (1-134) + (b-11), (1 -134) + (b-12), (1-134) + (b-13), (1-134) + (b-14), (1-134) + (S3-1), (I-134) ) + (S3-2), (1-134) + (S3-3), (1-134) + (S3-4), (1-134) + (S3-5), (1-134) + (h-1), (1-134) + (h-2), (1-134) + (V-1), (1-134) + (V-2), (1-134) + (V -3), (1-134) + (V-4), (1-134) + (V-5), (1-134) + (V-6).
(1-135) + (ll-O), (1-135) + (11-1), (1-135) + (II-2), (1-135) + (II-3), (I - 135) + (II-4), (1-135) + (II-5), (1-135) + (II-6), (1-135) + (II-9), (1-135) ) + (11-12), (I- 135) + (111-1), (1-135) + (ill-4), (1-135) + (111-10), (1-135) + (111-11), (1-135) + (IV-1), (1-135) + (IV-2), (1-135) + (IV-3), (1-135) + (IV -4), (1-135) + (IV-5), (1-135) + (b-1), (1-135) + (b-2), (1-135) + (b-3) ), (1-135) + (b-4), (1-135) + (b-5), (1-135) + (b-6), (1-135) + (b-7), (1-135) + (b-8), (1-135) + (b-9), (1-135) + (b-10), (1-135) + (b-11), (1 -135) + (b-12), (1-135) + (b-13), (1-135) + (b-14), (1-135) + (S3-1), (I-135) ) + (S3-2), (1-135) + (S3-3), (1-135) + (S3-4), (1-135) + (S3-5), (1-135) + (h-1), (1-135) + (h-2), (1-135) + (V-1), (1-135) + (V-2), (1-135) + (V -3), (1-135) + (V-4), (1-135) + (V-5), (1-135) + (V-6). (1-136) + (ll-O), (1-136) + (11-1), (1-136) + (II-2), (1-136) + (II-3), (I - 136) + (II-4), (1-136) + (II-5), (1-136) + (II-6), (1-136) + (II-9), (1-136) ) + (11-12), (I-136) + (111-1), (1-136) + (III-4), (1-136) + (111-10), (1-136) + (111-11), (1-136) + (IV-1), (1-136) + (IV-2), (1-136) + (IV-3), (1-136) + (IV -4), (1-136) + (IV-5), (1-136) + (b-1), (1-136) + (b-2), (1-136) + (b-3) ), (1-136) + (b-4), (1-136) + (b-5), (1-136) + (b-6), (1-136) + (b-7), (1-136) + (b-8), (1-136) + (b-9), (1-136) + (b-10), (1-136) + (b-11), (1 -136) + (b-12), (1-136) + (b-13), (1-136) + (b-14), (1-136) + (S3-1), (I-136) ) + (S3-2), (1-136) + (S3-3), (1-136) + (S3-4), (1-136) + (S3-5), (1-136) + (h-1), (1-136) + (h-2), (1-136) + (V-1), (1-136) + (V-2), (1-136) + (V -3), (1-136) + (V-4), (1-136) + (V-5), (1-136) + (V-6). (1-137) + (ll-O), (1-137) + (11-1), (1-137) + (II-2), (1-137) + (II-3), (I - 137) + (II-4), (1-137) + (II-5), (1-137) + (II-6), (1-137) + (II-9), (1-137) ) + (11-12), (I-137) + (111-1), (1-137) + (III-4), (1-137) + (111-10), (1-137) + (111-11), (1-137) + (IV-1), (1-137) + (IV-2), (1-137) + (IV-3), (1-137) + (IV -4), (1-137) + (IV-5), (1-137) + (b-1), (1-137) + (b-2), (1-137) + (b-3) ), (1-137) + (b-4), (1-137) + (b-5), (1-137) + (b-6), (1-137) + (b-7), (1-137) + (b-8), (1-137) + (b-9), (1-137) + (b-10), (1-137) + (b-11), (1 -137) + (b-12), (1-137) + (b-13), (1-137) + (b-14), (1-137) + (S3-1), (I- 137) ) + (S3-2), (1-137) + (S3-3), (1-137) + (S3-4), (1-137) + (S3-5), (1-137) + (h-1), (1-137) + (h-2), (1-137) + (V-1), (1-137) + (V-2), (1-137) + (V -3), (1-137) + (V-4), (1-137) + (V-5), (1-137) + (V-6). (1-138) + (ll-O), (1-138) + (11-1), (1-138) + (II-2), (1-138) + (II-3), (I - 138) + (II-4), (1-138) + (II-5), (1-138) + (II-6), (1-138) + (II-9), (1-138) ) + (11-12), (I-138) + (111-1), (1-138) + (III-4), (1-138) + (111-10), (1-138) + (111-11), (1-138) + (IV-1), (1-138) + (IV-2), (1-138) + (IV-3), (1-138) + (IV -4), (1-138) + (IV-5), (1-138) + (b-1), (1-138) + (b-2), (1-138) + (b-3) ), (1-138) + (b-4), (1-138) + (b-5), (1-138) + (b-6), (1-138) + (b-7), (1-138) + (b-8), (1-138) + (b-9), (1-138) + (b-10), (1-138) + (b-11), (1 -138) + (b-12), (1-138) + (b-13), (1-138) + (b-14), (1-138) + (S3-1), (I-138) ) + (S3-2), (1-138) + (S3-3), (1-138) + (S3-4), (1-138) + (S3-5), (1-138) + (h-1), (1-138) + (h-2), (1-138) + (V-1), (1-138) + (V-2), (1-138) + (V -3), (1-138) + (V-4), (1-138) + (V-5), (1-138) + (V-6). (1-139) + (ll-O), (1-139) + (11-1), (1-139) + (ll-2), (1-139) + (II-3), (I - 139) + (II-4), (1-139) + (II-5), (1-139) + (II-6), (1-139) + (II-9), (1-139) ) + (11-12), (I-139) + (111-1), (1-139) + (III-4), (1-139) + (111-10), (1-139) + (111-11), (1-139) + (IV-1), (1-139) + (IV-2), (1-139) + (IV-3), (1-139) + (IV -4), (1-139) + (IV-5), (1-139) + (b-1), (1-139) + (b-2), (1-139) + (b-3) ), (1-139) + (b-4), (1-139) + (b-5), (1-139) + (b-6), (1-139) + (b-7), (1-139) + (b-8), (1-139) + (b-9), (1-139) + (b-10), (1-139) + (b-11), (1 -139) + (b-12), (1-139) + (b-13), (1-139) + (b-14), (1-139) + (S3-1), (I- 139) ) + (S3-2), (1-139) + (S3-3), (1-139) + (S3-4), (1-139) + (S3-5), (1-139) + (h-1), (1-139) + (h-2), (1-139) + (V-1), (1-139) + (V-2), (1-139) + (V -3), (1-139) + (V-4), (1-139) + (V-5), (1-139) + (V-6). (1-140) + (ll-O), (1-140) + (11-1), (1-140) + (II-2), (1-140) + (II-3), (I - 140) + (|| -4), (1-140) + (II-5), (1-140) + (II-6), (1-140) + (II-9), (1- 140) + (11-12), (I-140) + (III-1), (1-140) + (III-4), (1-140) + (111-10), (1-140) + (111-11), (1-140) + (IV-1), (1-140) + (IV-2), (1-140) + (IV-3), (1-140) + ( IV-4), (1-140) + (IV-5), (1-140) + (b-1), (1-140) + (b-2), (1-140) + (b- 3), (1-140) + (b-4), (1-140) + (b-5), (1-140) + (b-6), (1-140) + (b-7) , (1-140) + (b-8), (1-140) + (b-9), (1-140) + (b-10), (1-140) + (b-11), ( 1-140) + (b-12), (1-140) + (b-13), (1-140) + (b-14), (1-140) + (S3-1), (I- 140) + (S3-2), (1-140) + (S3-3), (1-140) + (S3-4), (1-140) + (S3-5), (1-140) + (h-1), (1-140) + (h-2), (1-140) + (V-1), (1-140) + (V-2), (1-140) + ( V-3), (1-140) + (V-4), (1-140) + (V-5), (1-140) + (V-6). (1-141) + (ll-O), (1-141) + (11-1), (1-141) + (II-2), (1-141) + (II-3), (I - 141) + (|| -4), (1-141) + (II-5), (1-141) + (II-6), (1-141) + (II-9), (1- 141) + (11-12), (I-141) + (111-1), (1-141) + (III-4), (1-141) + (111-10), (1-141) + (111-11), (1-141) + (IV-1), (1-141) + (IV-2), (1-141) + (IV-3), (1-141) + ( IV-4), (1-141) + (IV-5), (1-141) + (b-1), (1-141) + (b-2), (1-141) + (b- 3), (1-141) + (b-4), (1-141) + (b-5), (1-141) + (b-6), (1-141) + (b-7) , (1-141) + (b-8), (1-141) + (b-9), (1-141) + (b-10), (1-141) + (b-11), ( 1-141) + (b-12), (1-141) + (b-13), (1-141) + (b-14), (1-141) + (S3-1), (I- 141) + (S3-2), (1-141) + (S3-3), (1-141) + (S3-4), (1-141) + (S3-5), (1-141) + (h-1), (1-141) + (h-2), (1-141) + (V-1), (1-141) + (V-2), (1-141) + ( V-3), (1-141) + (V-4), (1-141) + (V-5), (1-141) + (V-6). (1-142) + (ll-O), (1-142) + (11-1), (1-142) + (II-2), (1-142) + (II-3), (I - 142) + (II-4), (1-142) + (II-5), (1-142) + (II-6), (1-142) + (II-9), (1-142) ) + (11-12), (I- 142) + (111-1), (1-142) + (III-4), (1-142) + (111-10), (1-142) + (111-11), (1-142) + (IV-1), (1-142) + (IV-2), (1-142) + (IV-3), (1-142) + (IV -4), (1-142) + (IV-5), (1-142) + (b-1), (1-142) + (b-2), (1-142) + (b-3) ), (1-142) + (b-4), (1-142) + (b-5), (1-142) + (b-6), (1-142) + (b-7), (1-142) + (b-8), (1-142) + (b-9), (1-142) + (b-10), (1-142) + (b-11), (1 -142) + (b-12), (1-142) + (b-13), (1-142) + (b-14), (1-142) + (S3-1), (I-142) ) + (S3-2), (1-142) + (S3-3), (1-142) + (S3-4), (1-142) + (S3-5), (1-142) + (h-1), (1-142) + (h-2), (1-142) + (V-1), (1-142) + (V-2), (1-142) + (V -3), (1-142) + (V-4), (1-142) + (V-5), (1-142) + (V-6). (1-143) + (ll-O), (1-143) + (11-1), (1-143) + (II-2), (1-143) + (II-3), (I - 143) + (II-4), (1-143) + (II-5), (1-143) + (II-6), (1-143) + (II-9), (1-143) ) + (11-12), (I-143) + (111-1), (1-143) + (III-4), (1-143) + (111-10), (1-143) + (111-11), (1-143) + (IV-1), (1-143) + (IV-2), (1-143) + (IV-3), (1-143) + (IV -4), (1-143) + (IV-5), (1-143) + (b-1), (1-143) + (b-2), (1-143) + (b-3) ), (1-143) + (b-4), (1-143) + (b-5), (1-143) + (b-6), (1-143) + (b-7), (1-143) + (b-8), (1-143) + (b-9), (1-143) + (b-10), (1-143) + (b-11), (1 -143) + (b-12), (1-143) + (b-13), (1-143) + (b-14), (1-143) + (S3-1), (I-143) ) + (S3-2), (1-143) + (S3-3), (1-143) + (S3-4), (1-143) + (S3-5), (1-143) + (h-1), (1-143) + (h-2), (1-143) + (V-1), (1-143) + (V-2), (1-143) + (V -3), (1-143) + (V-4), (1-143) + (V-5), (1-143) + (V-6).
(1-144) + (ll-O), (1-144) + (11-1), (1-144) + (II-2), (1-144) + (II-3), (I - 144) + (|| -4), (1-144) + (II-5), (1-144) + (II-6), (1-144) + (II-9), (1- 144) + (11-12), (I- 144) + (| U-1), (1-144) + (III-4), (1-144) + (111-10), (1-144) ) + (111-11), (1-144) + (IV-1), (1-144) + (IV-2), (1-144) + (IV-3), (1-144) + (IV-4), (1-144) + (IV-5), (1-144) + (b-1), (1-144) + (b-2), (1-144) + (b -3), (1-144) + (b-4), (1-144) + (b-5), (1-144) + (b-6), (1-144) + (b-7) ), (1-144) + (b-8), (1-144) + (b-9), (1-144) + (b-10), (1-144) + (b-11), (1-144) + (b-12), (1-144) + (b-13), (1-144) + (b-14), (1-144) + (S3-1), (I - 144) + (S3-2), (1-144) + (S3-3), (1-144) + (S3-4), (1-144) + (S3-5), (1-144) ) + (h-1), (1-144) + (h-2), (1-144) + (V-1), (1-144) + (V-2), (1-144) + (V-3), (1-144) + (V-4), (1-144) + (V-5), (1-144) + (V-6). (1-145) + (ll-O), (1-145) + (11-1), (1-145) + (II-2), (1-145) + (II-3), (I - 145) + (II-4), (1-145) + (II-5), (1-145) + (II-6), (1-145) + (II-9), (1-145) ) + (11-12), (I-145) + (111-1), (1-145) + (III-4), (1-145) + (111-10), (1-145) + (111-11), (1-145) + (IV-1), (1-145) + (IV-2), (1-145) + (IV-3), (1-145) + (IV -4), (1-145) + (IV-5), (1-145) + (b-1), (1-145) + (b-2), (1-145) + (b-3) ), (1-145) + (b-4), (1-145) + (b-5), (1-145) + (b-6), (1-145) + (b-7), (1-145) + (b-8), (1-145) + (b-9), (1-145) + (b-10), (1-145) + (b-11), (1 -145) + (b-12), (1-145) + (b-13), (1-145) + (b-14), (1-145) + (S3-1), (I-145) ) + (S3-2), (1-145) + (S3-3), (1-145) + (S3-4), (1-145) + (S3-5), (1-145) + (h-1), (1-145) + (h-2), (1-145) + (V-1), (1-145) + (V-2), (1-145) + (V -3), (1-145) + (V-4), (1-145) + (V-5), (1-145) + (V-6). The antidotes (insurers) of the formulas (II) - (VIII) as well as the compounds of the group (B) (b), for example antidotes of the preferred groups a) to h), are suitable for the reduction of phytotoxic effects, which may appear in the case of using the herbicides (A) in crops of useful plants, without essentially impairing the activity of herbicidal active substances against harmful plants. With this, the employment sector of the usual crop protection agents can be expanded very considerably, eg to crops, in which until now it was not possible, or only a limited use of the herbicides was possible. The amounts consumed of the antidotes can fluctuate within wide limits depending on the indication and the herbicide active substance used and are generally in the range of 0.001 to 5 kg, preferably 0.005 to 2.5 kg of active substance. hectare. The active herbicidal substances (A) and the antidotes (B) can be spread (eg as a finished formulation or according to the tank-mix procedure) or consecutively in any order of succession, p .ej by application by atomization, pouring and spraying or by spreading granules. The weight ratio of herbicide (A): antidote (B) can vary within wide limits and is preferably located in the range of 1: 10,000 to 10,000: 1, in particular 1: 1,000 to 1,000. :1. The optimum quantities of the herbicidal active substance and the antidote in each case are dependent on the type of herbicidal active substance used or on the antidote used, as well as on the type and stage of development of the existence of plants to be treated, and they can be determined for each particular case by means of simple routine preliminary tests.
The antidotes (B) contained in the combination according to the invention of herbicides and antidotes can be used depending on their properties for the pretreatment of the seed material of the cultivated plant (eg for the disinfection of the seed material) or before sowing they can be incorporated in the sowing furrows or they can be applied in common with the herbicide before or after the sprouting of the plants. A treatment before the outbreak includes both the treatment of the cultivated area (including eventually the water that is next to the cultivated area)., eg in the case of applications to rice) before sowing as well as the treatment of the cultivated areas that are sown but not yet covered with vegetation. The use in common with the herbicide is preferred. For this, tank mixtures or finished formulations can be used. In a preferred embodiment, seed material (eg grains, seeds or vegetative reproductive organs such as tubers or parts of shoots with shoots) or seedlings and cuttings, can be pretreated with antidotes (B) , possibly in combination with other agrochemical active substances. For pretreatment of the seed material, the active substances can be added eg by disinfection to the seed material, or the active substances and the seed material can be added to water or other solvents, and the active substances can be added to the seed material. collect for example by deposition or diffusion according to the immersion procedure or by swelling or previous germination. For pre-treatment of seedlings and cuttings, young plants can be contacted, eg by spraying, immersion or pouring, with the antidotes, possibly in combination with other agrochemical active substances, and then transplanted and eventually treated with the herbicides (A). The treatment of the seed material - or seedlings and cuttings can be carried out with the antidotes (B) alone or in common with other agrochemical active substances - such as herbicides, in particular the herbicides (A), fungicides, insecticides or agents for the strengthening of the plants, fertilization or for the acceleration of the swelling and germination processes. In this case the antidotes can be applied, after application by pre-treatment treatment, then again before, after, or in common with the herbicides (A). By pretreating the seed material or the seedlings and cuttings, an improved long-term effect of the antidotes can be achieved. The object of the present invention is therefore also a method for the control of unwanted plants in plant crops, which is characterized in that components (A) and (B) of the combination are spread, for example in common or separately. according to the invention of herbicides and antidotes on plants (eg harmful plants such as mono- or di-cotyledonous weeds, or undesired cultivated plants), the seed material (eg grains, seeds or vegetative reproductive organs) such as tubers or parts of shoots with shoots) or the surface, on which the plants grow (eg the cultivated surface). In this case, one or more antidotes (B), preferably one or several, in particular a compound (s) of the formulas (II), (III), (IV), (V), (VI), ( Vil), (VIII), and / or from set B (b) may be applied before, after or simultaneously with the herbicide (s) (A) on the plants, the seed material or the surface, on the growth of plants (eg the cultivated area). In a preferred embodiment, the antidotes (B) are used for the treatment of the seed material. By the concept of unwanted plants all plants must be understood, which grow in places where they are unwanted. These may be, for example, harmful plants (eg, mono- or di-cotyledonous weeds or undesired cultivated plants), eg also those which are resistant to certain herbicidal active substances such as glyphosate, atrazine, glufosinate. or imidazolinone herbicides. Monocotyledonous weeds come, for example, from generaEchinochloa, Setaria, Panicum, Digitaria, Phleum, Poa, Festuca, Eleusine, Brachiaria, Lolium, Bromus, Oats, Cyperus, Sorghum, Agropyron, Cynodon, Monochoria, Fimbristylis, Sagittaria, Eleocharis, Scirpus, Paspalum, Ischaemum, Sphenoclea, Dactyloctenium, Agrostis, Alopecurus, Apera. Dicotyledonous weeds come, for example, from the genera Sinapis, Lepidium, Galium, Stellaria, Matricaria, Anthemis, Galinsoga, Chenopodium, Urtica, Senecio, Amaranthus, Portulaca, Xanthium, Convolvulus, Ipomoea, Polygonum, Sesbania, Ambrosia, Cirsium, Carduus. , Sonchus, Solanum, Rorippa, Rotala, Lindernia, Lamium, Veronica, Abutilon, Emex, Datura, Viola, Galeopsis, Papaver, Centaurea, Trifolium, Ranunculus, Taraxacum, Euphorbia. Preferably, in the process according to the invention, an effective amount of the components (A) and (B) is applied for the control of harmful plants in crops of plants, for example in economically important agricultural crops, eg agricultural crops. of monocotyledonous plants such as cereals (eg wheat, barley, rye, oats), rice, maize, millet, or agricultural crops of dicotyledonous plants such as sugar beet, rapeseed, cotton, sunflower and legumes, eg from Glycine genera (eg, Glycine max. (soy) such as non-transgenic Glycine max (eg conventional types such as STS types) or transgenic Glycine max (eg soybean RR or soybean LL) and its crosses), Phaseolus, Pisum, Vicia and Arachis, or vegetable crops of different botanical groups such as potatoes, leeks, cabbage, carrots, tomatoes, onions, as well as permanent and plantation crops such as pome fruits and bone, berries, vines, hevea, ba nanas, sugar cane, coffee, tea, citrus fruits, walnut and walnut plantations, lawns, palm crops and forest crops. The invention also relates to the use of the combinations according to the invention of herbicides and antidotes for the control of vegetation of unwanted plants, preferably in crops of useful plants.
The combinations according to the invention of herbicides and antidotes can be prepared according to processes known, for example, as mixed formulations of the individual components, optionally with other active substances, additives and / or customary formulation aids, which are then carried out. it is usually applied in diluted form with water, or as the so-called tank mixtures by dilution with water in common of the individual components formulated separately or partially formulated separately. It is also possible to use the time-phased application (dissociated application) of the individual components formulated separately or partially formulated separately. It is also possible to apply the individual components or combinations of herbicides and antidotes in several portions (sequential application), eg according to pre-emergence applications, followed by applications after the outbreak, or according to early applications after the outbreak, followed by medium or late applications after the outbreak. In this case, the application in common or close to the time of the active substances of the respective combination is preferred. The combination according to the invention of herbicides and antidotes can also be used for the control of harmful plants in crops of plants modified by genetic technology, which are known or still have to be developed. Transgenic plants are generally distinguished by special advantageous properties, for example by resistance to certain plant protection agents, resistance to plant diseases or pathogens of plant diseases, such as certain insects or microorganisms such as fungi, bacteria or virus. Other special properties relate, for example, to the harvested material in terms of quantity, quality, storage capacity, composition and special constituent substances. Thus, transgenic plants with an increased content of starch or with a modified quality of starch or those having a different composition of fatty acids from the harvested material are known. The use of the combinations according to the invention is preferred in economically important transgenic crops of useful and ornamental plants, eg cereals (eg wheat, barley, rye, oats), millet, rice, cassava and corn. or also of crops of sugar beet, cotton, soybean, rapeseed, potato, tomato, peas and other species of vegetables. In the case of the application of the combinations according to the invention in transgenic crops, together with the effects against harmful plants that can be observed in other crops, there are frequently effects that are specific for the application in the respective transgenic crop, for example a weed spectrum that has been modified or expanded in a special way, that can be combated, modified quantities to be consumed, that can be used for the application, preferably a good aptitude for the combination with the herbicides, compared to what is resistant transgenic crop, as well as an influence on the growth and yield of transgenic cultivated plants. The object of the invention, therefore, is also the use of the combination according to the invention for the control of harmful plants in transgenic cultivated plants or in cultivated plants, which exhibit tolerance by selective cultivation. The herbicides (A) and the antidotes (B) can be converted into common or separate into customary formulations eg for spray application, pouring and spraying and disinfection of seed material, such as solutions, emulsions, suspensions , powders, foams, pastes, granulates, aerosols, natural and synthetic substances impregnated with active substances, very fine encapsulations in polymeric substances. The formulations may contain the usual adjuvant and additive substances. These formulations are prepared in a known manner, for example by mixing the active substances with spreading agents, ie liquid solvents, pressurized liquefied gases and / or solid support materials, optionally by using surface active agents, say emulsifying agents and / or dispersing agents and / or foaming agents. In the case of the use of water as an extender, for example organic solvents can also be used as auxiliary solvents. Suitable solvents are essentially liquid solvents: aromatic compounds, such as xylene, toluene, alkylnaphthalenes, chlorinated aromatics or aliphatic hydrocarbons, such as chlorobenzenes, chloroethylenes, or methylene chloride, aliphatic hydrocarbons, such as cyclohexane or paraffins, p. eg petroleum fractions, mineral and vegetable oils, alcohols, such as butanol or glycol as well as their ethers and esters, ketones, such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents, such as dimethylformamide or dimethyl sulfoxide, as well as water . Suitable solid support materials are in question: eg ammonium salts and fine powders of natural stones, such as kaolins, clays, talcum, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth and fine powders of synthetic stones, such as such as highly dispersed silicic acid, aluminum oxide and silicates; as solid support materials for granules come into question: eg crushed and fractionated natural stones such as calcite, marble, pumice, sepiolite, dolomite as well as synthetic granules based on inorganic and organic fine powders as well as granules based on an organic material such as wood sawdust, coconut husks, corn cobs and tobacco stems; as emulsifying agents and / or foam generators they come into question: eg non-ionogenic and anionic emulsifiers, such as poly (oxyethylene)-fatty acid esters, poly (oxyethylene) -ethers of fatty alcohols, eg alkylaryl -polyglycol ethers, alkyl sulphonates, alkyl sulphates, aryl sulphonates as well as protein hydrolysates; as dispersing agents they come into question: eg residual liquors from the process for obtaining lignin with sulphate and methylcellulose. Adhesive agents such as carboxymethylcellulose, natural and synthetic polymers, powders, granules or in the form of latex, such as gum arabic, polyvinyl alcohol, polyvinyl acetate, as well as natural phospholipids, can be used in the formulations. such as cephalins and lecithins and synthetic phospholipids. Other additives can be mineral and vegetable oils. Dyes such as inorganic pigments can be used, eg an iron oxide, titanium oxide, ferrocyanide blue and organic dyes, such as alizarin, azo and metal-phthalocyanine dyes and trace nutrients such as iron salts , manganese, boron, copper, cobalt, molybdenum and zinc. The formulations generally contain between 0.1 and 95 percent by weight of an active substance, preferably between 0.5 and 90% by weight. The herbicides (A) and the antidotes (B) can find use as such or in their formulations also in admixture with other agrochemical active substances such as known herbicides for the control of a vegetation of unwanted plants, eg for the repression of weeds or for the control of undesired cultivated plants, eg, finished formulations or tank mixtures being possible.
Mixtures with other known active substances such as fungicides, insecticides, acaricides, nematicides, antidotes, protective substances against damage caused by birds, nutritive substances for plants and soil structure improving agents, as well as additive substances customary in the protection of plants, and formulation aids. The herbicides (A) and the antidotes (B) can be applied as such, in the form of their formulations or of the forms of application prepared therefrom by further dilution, such as solutions, suspensions, emulsions, powders, pastes and granules ready for use. The application is carried out in a usual manner, for example by pouring, spraying, spraying and spreading. The active substances can be spread on the plants, the parts of plants, the seed material or the cultivated surface (agricultural soil), preferably on the seed material or green plants and the parts of such plants and eventually additional on agricultural land. One possibility of the application is the common spreading of the active substances in the form of tank mixtures, whereby the concentrated, optimally formulated formulations of the individual active substances are mixed in common with water in the tank and the obtained broth to project. A common formulation of the combination according to the invention of active substances (A) and (B) has the advantage of being easier to apply, since the amounts of the components can already be adjusted in the optimum ratio between them. In addition, the adjuvants in the formulation can be optimally adapted to each other. As partners in the combinations for the combination according to the invention of herbicides and antidotes in mixture formulations or in a tank mixture, for example known agrochemical active substances, such as herbicides, fungicides or insecticides, as described, for example, can be used. in Weed Research 26, 441-445 (1986) or "The Pesticide Manual" 13th edition, The British Crop Protection Council, 2003 and the bibliography cited therein. As herbicides known from the literature, which can be combined with the mixtures according to the invention, there can be mentioned, for example, the following active substances (Note: the compounds are designated either with the "common name" according to the International Organization for Normalization (ISO, of International Organization for Standartization) or with the chemical name, possibly together with a usual code number, and they always include all forms of application such as acids, salts, esters and isomers such as stereoisomers and optical isomers. In this context, one, and partly also several, of the forms of application are mentioned). 2,4-D, acetochlor, acifluorfen, acifluorfen-sodium, aclonifen, alachlor, aloxidime, alloxydima-sodium, ametrin, amicarbazone, amidosulfuron, aminopyralid, amitrol, anilofos, asulam, atrazine, azaphenidine, azimsulfuron, beflubutamide, benazoline, benazoline- ethyl, benfuresate, bensulfuron-methyl, bentazone, benzofendizone, benzo-benzyl, benzophenap, bifenox, bilanafos, bispyribac-sodium, bromacil, bromobutide, bromophenoxime, bromoxynil, butachlor, butafenacil, butenacloro, butralin, butroxidime, butylate, cafenstrole, carbetamide, carfentrazone- ethyl, clometoxifen, chloridazone, chlorimuron-ethyl, chloronitrofen, chlorotoluron, chlorosulfuron, cinidon-ethyl, cinmetilin, cinosulfuron, clefoxidime, clethodima, clodinafop-propargyl, clomapropone, clomeprop, clopyralide, cloransulam-methyl, cumiluron, cyanazine, cyclosulfamuron, cyclodexid, cyhalofop-butyl, desmedifam, dicamba, diclobenil, dichloroprop, dichloroprop-P, diclofop-methyl, diclosulam, difenzoquat, diflufenican, diflufenzopi r, dikegulaco-sodium, dimefuron, dimepiperate, dimethachlor, dimethamethrin, dimethenamid, triaziflam, diquat-dibromide, dithiopyr, diuron, dimron, EPTC, esprocarb, ethalfluralin, etametsulfuron-methyl, etofumesate, ethoxifen, ethoxysulfuron, ethobenzanide, fenoxaprop-ethyl, fenoxaprop-P-ethyl, fentrazamide, flamprop-M-isopropyl, flamprop-M -methyl, flazasulfuron, florasulam, fluazifop, fluazifop-butyl, fluazifop-butyl, fluazolate, flucarbazone-sodium, flucetosulfuron, flucloraline, flufenacet, flufenpir, flumetsulam, flumicloraco-pentyl, flumioxazine, fluometuron, fluorochloridone, fluoroglycofen-ethyl, flupoxam, flupirsulfuron -methyl-sodium, fluridone, fluroxypyr, fluroxypyr-butoxypropyl, fluroxypyr-meptyl, flurprimidol, flurtamone, flutiacet-methyl, fomesafen, foramsulfuron, glufosinate, glufosinate-ammonium, glyphosate, halosulfuron-methyl, haloxifop, haloxifop-ethoxyethyl, haloxyfop-methyl , haloxifop-P-methyl, hexazinone, imazametabenz-methyl, mazamox, imazapic, imazapyr, imazaquin, imazetapir, mazosulfuron, indanofan, iodosulfuron-methyl-sodium, ioxinil, isoproturon, sourón, isoxaben, isoxaclortol, isoxaflutol, ketospiradox, lactofen, lenacil, linuron, MCPA, mecoprop-P, mefenacet, mesosulfuron-methyl, mesotrione, metamifop, metamitron, metazachlor, metabenzothiazuron, metildimron, metobromuron, metolachlor, metosulam, methoxuron, metribuzin, metsulfuron-methyl, molinate, monolinuron, naproanilide, napropamide, neburon, nicosulfuron, norflurazone, orbencarb, orizaline, oxadiargyl, oxadiazone, oxasulfuron, oxaziclomephone, oxyfluorfen, paraquat, pelargonic acid, pendimethalin, pendralin, penoxsulam, pentoxazone, petoxamide, fenmedifam , picloram, picolinafen, pinoxaden, piperophos, pretilachlor, primisulfuron-methyl, profluazol, profoxidime, prometrin, propachlor, propanil, propaquizafop, propisocloro, propoxycarbazone-sodium, propizamide, prosulfocarb, prosulfuron, pyraclonil, pyraflufen-ethyl, pyrazolate, pyrazosulfuron-ethyl , pirazoxifen, piribenzoxima, piributicarb, piridafol, pyridate, piriftalida, piriminobaco-methyl, piritiobaco-sodium, quincloraco, quinmeraco, quinoclamine, quizalofop-ethyl, quizalofop-P-ethyl, quizalofop-P-tefuril, rimsulfuron, sethoxydim, simazine, symmetry, S-metolachlor, sulcotrione, sulfentrazone, sulfometuron-methyl, sulfosate, sulfosulfuron, tebutiurón, tepraloxidima, terbutilazina, terbutrin, tenilcloro, thiazopir, tifensulfuron-methyl, thiobencarb, thiocarbazil, tralcoxidima, trialato, triasulfuron, tribenuron-methyl, triclopir, tridifano, trifloxisulfuron, trifluralina, triflusulfuron-methyl and tritosulfuron. For their application, the formulations present in a commercially available form can optionally be diluted in a conventional manner, for example by water. Formulations in the form of fine powders, granules for the soil or for spreading as well as sprayable solutions, before the application are usually no longer diluted with other inert substances.
BIOLOGICAL EXAMPLES
1. Effect on weeds before emergence Seeds or pieces of rhizomes of mono-and di-cotyledonous weed plants were placed in a sandy silt floor inside cardboard pots and covered with soil. The active substances (A) and (B), formulated in the form of wettable powders or concentrates for emulsification, were then applied as suspensions or emulsions with a consumed quantity of water, converted by calculation, from 600 to 800 l / ha in different dosages on the surface of the covering earth. After the treatment, the pots were placed in a greenhouse and kept in good growth conditions for the weeds. The optical assessment of damage to the plants or to the outbreak was made after the outbreak of the plants tested after a test period of 3 to 4 weeks compared to untreated controls. As the results show, the tested combinations of herbicides and antidotes present good pre-emergence herbicidal activity against a broad spectrum of weeds and weeds. For example, the combinations of herbicides and antidotes of the NoS compounds. 1-1, I-3, I-8, I-9, 1-10, 1-11, 1-12, 1-14, 1-21, I-22, I-23, I-29, I- 30, 1-51, I-52, I-60, I-70, 1-142, I-143, 1-145 and other compounds from Table 1 with the antidotes dimron (b-14), fenchlorima (b) -11), cumiluron (b-4), isoxadifen-ethyl (II-9), mefenpyr-diethyl (11-1), cloquintocet-mexyl (111-1), S3-1, h-1, h-2, h-3, dietolato (b-7), disulfoton (b-5), anhydride of 1,8-naphthalic acid (b-1), fluxofenima (b-10), dichloromide (IV-1), benoxacor (IV-) 2), flurazole (b-12) and R-29148 (IV-4) have a very good herbicidal effect against harmful plants such as Sinapis alba, Chrysanthemum segetum, Avena sativa, Stellaria media, Echinochloa crus-galli, Lolium multiflorum, Setaria viridis, Abutilon theophrasti, Amaranthus retroflexus and Panicum miliaceum according to the pre-emergence procedure with an consumed amount of 100 and less g of herbicide (A) per hectare.
2. Effect on weeds after the outbreak Seeds or pieces of rhizomes of mono- and dicotyledonous weeds were placed in a soil of sandy silt inside plastic pots, covered with soil and cultivated in a greenhouse in good growth conditions. At three weeks after sowing, the test plants were treated in the three-leaf stage. The compounds according to the invention, formulated as spraying powders or as concentrates for emulsification, were atomized in different dosages with an consumed quantity of water, converted by calculation, from 600 to 800 l / ha on the green parts of the plants. After a period of time of 3 to 4 weeks of permanence of the plants tested in the greenhouse under optimum growth conditions, the effect of the formulations was visually evaluated in comparison with untreated controls. The combinations according to the invention of herbicides and antidotes also have good herbicidal activity against the broad spectrum of economically important weeds and weeds after emergence. For example, combinations of herbicides and antidotes of compounds NoS 1-1, I-3, I-8, I-9, 1-10, 1-11, 1-12, 1-14, 1-21, I -22, I-23, I-29, I-30, 1-51, I-52, I-60, I-70, 1-142, 1-143, 1-145 and other compounds from Table 1 with the antidotes dimrón (b-14), fenclorima (b-11), cumiluron (b-4), isoxadifen-etil (II-9), mefenpir-dietilo (11-1), cloquintocet-mexilo (111-1) , S3-1, h-1, h-2, h-3, dietolato (b-7), disulfoton (b-5), anhydride of 1,8-naphthalic acid (b-1), fluxofenima (b-10) ), dichloromide (IV-1), benoxacor (IV-2), flurazole (b-12) and R-29148 (IV-4) have a very good herbicidal effect against harmful plants such as Sinapis alba, Echinochloa crus-galli, Lolium multiflorum, Chrysanthemum segetum, Setaria viridis, Abutilon theophrasti, Amaranthus retroflexus, Panicum miliaceum and Avena sativa according to the post-emergence procedure with a consumed amount of 100 and less g of herbicide (A) per hectare.
3. Compatibility with the cultivated plants In other tests carried out in a greenhouse, seeds of a large number of cultivated plants and weeds were placed in a soil of sandy silt and covered with soil. A part of the pots was treated immediately as described in paragraph 1, the others were placed in the greenhouse, until the plants had developed two to three true leaves and then sprayed, as described in paragraph 2 with the combinations according to the invention of herbicides and antidotes in different dosages. Four to five weeks after the application and the period of time spent in the greenhouse, it was verified by optical evaluation that the tested combinations of herbicides and antidotes, for example of the compounds NoS 1-1, I-3, I-8, I-9, I-10, 1-11, 1-12, 1-14, 1-21, I-22, I-23, I-29, I-30, 1-51, I- 52, I-60, I-70, 1-142, 1-143, 1-145 and other compounds from Table 1 with the antidotes dimrón (b-14), fenclorima (b-11), cumiluron (b-) 4), isoxad-ethyl (II-9), mefenpyr-diethyl (11-1), cloquintocet-mexyl (111-1), S3-1, h-1, h-2, h-3, dietolato (b-) 7), disulfoton (b-5), 1,8-naphthalic acid anhydride (b-1), fluxofenima (b-10), dichloromide (IV-1), benoxacor (IV-2), flurazole (b-12) ) and R-29148 (IV-4) left undamaged plant crops such as cotton, rapeseed, sugar beet as well as grass crops such as barley, wheat, rye, millet, corn or rice as procedures before and d After the outbreak. For example, corn crops are not damaged in the case of application of 30 g / ha of compound (I-9) with 100 g of isoxad-ethyl (II-9).
Claims (8)
1. Combination of herbicides and antidotes, containing (A) one or more compounds of the formula (I) or their salts wherein A represents nitrogen or a group CR11, R11 representing hydrogen, alkyl, halogen and haloalkyl, R 1 represents hydrogen or an optionally substituted radical selected from the group consisting of alkyl, alkoxy, alkoxyalkyl, alkenyl, alkynyl, cycloalkyl, cycloalkylalkyl, aralkyl and aryl, R 2 represents hydrogen, halogen, or alkyl, alkoxy, alkylthio, alkylamino or dialkylamino, in each case with 1 to 6 carbon atoms, optionally substituted in each case with halogen, R 3 represents hydrogen, halogen, or alkyl , alkoxy, alkylthio, alkylamino or dialkylamino, in each case with 1 to 6 carbon atoms, optionally substituted in each case with halogen, R4-R7 independently of one another, represent hydrogen, halogen, cyano, thiocyanate, or alkyl, alkoxy , alkylthio, alkylsulfinyl, alkylsulfonyl, alkylamino, alkylcarbonyl, alkoxycarbonyl, alkylaminocarbonyl, in each case with 1 to 3 carbon atoms or, optionally substituted in each case with halogen, R 8 represents hydrogen, halogen, cyano, thiocyanate, or alkyl, alkoxy, alkylthio, alkylsulfinyl, alkylsulfonyl, alkylamino, alkylcarbonyl, alkoxycarbonyl or alkylaminocarbonyl, in each case with 1 to 3 carbon atoms. carbon, optionally substituted in each case with halogen, may contain, in the aforementioned radicals, the alkyl and alkylene groups in each case of 1 to 6 carbon atoms, the alkenyl and alkynyl groups in each case of 2 to 6 carbon atoms. , the cycloalkyl groups in each case of 3 to 6 C atoms and the aryl groups in each case 6 or 10 C atoms; and (B) one or more antidotes.
2. The combination of herbicides and antidotes according to claim 1, further characterized in that in the compound of the formula (I), A represents nitrogen or a group CH, R 1 represents hydrogen or a radical optionally substituted with halogen, selected from among the series consisting of alkyl, alkoxy, alkoxyalkyl, alkenyl and alkynyl in each case with up to 3 carbon atoms, R 2 represents hydrogen, halogen or alkyl, alkoxy, alkylthio, alkylamino or dialkylamino each with 1 to 3 carbon atoms in the alkyl radicals, each possibly substituted with halogen, R3 represents hydrogen, halogen or alkyl, alkoxy, alkylthio, alkylamino or dialkylamino each having 1 to 3 carbon atoms in the alkyl radicals, each optionally substituted with halogen, R 4 -R 7 independently of one another, represent hydrogen, halogen, cyano, thiocyanate or alkyl, alkoxy, alkylthio, alkylsul or alternatively substituted by halogen, R8 represents hydrogen, halogen, cyano, thiocyanate or alkyl, alkoxy, alkylthio , alkylsulfinyl, alkylsulfonyl, alkylamino, alkylcarbonyl, alkoxycarbonyl or alkylaminocarbonyl in each case with 1 to 3 carbon atoms in the alkyl radicals, each possibly substituted by halogen.
3. The combination of herbicides and antidotes according to claim 1 or 2, further characterized in that the antidote (s) (B) are selected from the set consisting of: dimrón (b-14), fenclorima (b-11), cumiluron (b-4), isoxadifen-ethyl (II-9), mefenpyr-diethyl (11-1), cloquintocet-mexyl (111-1), 4-cyclopropylaminocarbonyl-N- (2-methoxybenzoyl) -benzene- sulfonamide (S3-1), 1- [4- (N-2-methoxybenzoylsulfamoyl) phenyl] -3-methylurea (h-1), 1- [4- (N-2-methoxybenzoylsulfamoyl) phenyl] -3,3- dimethylurea (h-2), 1- [4- (N-4,5-dimethyl-benzoylsulfamoyl) phenyl] -3-methylurea (h-3), dietolato (b-7), disulfoton (b-5), anhydride of 1, 8-naphthalic acid (b-1), fluxofenima (b-10), dichloromide (IV-1), benoxacor (IV-2), flurazole (b-12), R-29148 (IV-4).
4. The combination of herbicides and antidotes according to one or more of claims 1 to 3, further characterized in that it additionally contains one or more other agrochemical active substances and / or additives and formulation adjuvants customary in the protection of plants. . A method for the control of unwanted plants, preferably in crops of useful plants, wherein the components (A) and (B) of the combination of herbicides and antidotes according to one or more of claims 1 to 4, the seed material or the surface on which the plants grow are applied in common or separately, preferably on the plants. 6. The method according to claim 5, further characterized in that the plant crops come from the set of agricultural crops, vegetable crops or permanent crops and plantations. The method according to claim 5 or 6, further characterized in that the plant cultures are transgenic or exhibit tolerance by selective cultivation. 8. Use of a combination of herbicides and antidotes defined according to one or more of claims 1 to 4, for the control of harmful plants, preferably in crops of useful plants. SUMMARY OF THE INVENTION A combination of herbicides and antidotes contains (A) one or more compounds of the formula (I) or their salts and (B), in formula (I), A represents nitrogen or a group CR 11, R11 representing hydrogen, alkyl, halogen and haloalkyl, R1 represents hydrogen or an optionally substituted radical selected from the group consisting of alkyl, alkoxy, alkoxyalkyl , alkenyl, alkynyl, cycloalkyl, cycloalkylalkyl, aralkyl and aryl, R 2 represents hydrogen, halogen, or alkyl, alkoxy, alkylthio, alkylamino or dialkylamino, each having 1 to 6 carbon atoms, optionally substituted in each case with halogen, R3 represents hydrogen, halogen, or alternatively alkyl, alkoxy, alkylthio, alkylamino or dialkylamino, each having 1 to 6 carbon atoms, optionally substituted each with halogen, R4-R7 independently of one another, represent hydrogen, halogen, cyano, thiocyanate, or alkyl, alkoxy, alkylthio, alkylsulfinyl, alkylsulfonyl, alkylamino, alkylcarbonyl, alkoxycarbonyl, alkylaminocarbonyl, in each case with 1 to 3 carbon atoms, optionally substituted in each case with halogen, and R8 represents hydrogen, halogen, cyano, thiocyanate, or alkyl, alkoxy, alkylthio, alkylsulfinyl, alkylsulfonyl, alkylamino, alkylcarbonyl, alkoxycarbonyl or alkylaminocarbonyl, in each case with 1 to 3 carbon atoms, optionally substituted in each case with halogen; in the above radicals, the alkyl and alkylene groups in each case may have from 1 to 6 C atoms, the alkenyl and alkynyl groups in each case may have from 2 to 6 C atoms, the cycloalkyl groups in each case may have 3 to 6 C atoms and the aryl groups in each case 6 or 10 C atoms. 8A P06 / 1419F
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102004015140.7 | 2004-03-27 | ||
| DE102004031345.8 | 2004-06-30 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MXPA06011023A true MXPA06011023A (en) | 2007-04-20 |
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