MXPA02011423A - Procedimiento para la produccion de acetato de vinilo. - Google Patents
Procedimiento para la produccion de acetato de vinilo.Info
- Publication number
- MXPA02011423A MXPA02011423A MXPA02011423A MXPA02011423A MXPA02011423A MX PA02011423 A MXPA02011423 A MX PA02011423A MX PA02011423 A MXPA02011423 A MX PA02011423A MX PA02011423 A MXPA02011423 A MX PA02011423A MX PA02011423 A MXPA02011423 A MX PA02011423A
- Authority
- MX
- Mexico
- Prior art keywords
- product stream
- vinyl acetate
- catalyst
- gaseous
- produce
- Prior art date
Links
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 title abstract 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 3
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 3
- 229910001882 dioxygen Inorganic materials 0.000 abstract 3
- 239000007789 gas Substances 0.000 abstract 3
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 abstract 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
- C07C5/48—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
- C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
- C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/652—Chromium, molybdenum or tungsten
- B01J23/6525—Molybdenum
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/755—Nickel
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/14—Phosphorus; Compounds thereof
- C07C2527/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2527/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
- C07C2527/19—Molybdenum
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
La presente invencion describe la combinacion, en una primera zona de reaccion, de una materia prima gaseosa que comprende sustancialmente etano con un gas que contiene oxigeno molecular en presencia de un catalizador para producir una primera corriente de producto que comprende acido acetico; la combinacion, en una segunda zona de reaccion, de una materia prima gaseosa que comprende sustancialmente etano con un gas que contiene oxigeno molecular en presencia de un catalizador para producir una segunda comente de producto que comprende etileno; la combinacion, en una tercera zona de reaccion, de la primera corriente del producto gaseoso y la segunda corriente del producto gaseoso con un gas que contiene oxigeno molecular en presencia de un catalizador para producir una cuarta comente de producto que comprende acetato de vinilo; la separacion de la comente de producto del paso (3) y la recuperacion de acetato de vinilo de dicha comente de producto del paso (3).
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/EP2000/004545 WO2001090043A1 (en) | 2000-05-19 | 2000-05-19 | Process for the production of vinyl acetate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MXPA02011423A true MXPA02011423A (es) | 2004-09-06 |
Family
ID=8163947
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MXPA02011423A MXPA02011423A (es) | 2000-05-19 | 2000-05-19 | Procedimiento para la produccion de acetato de vinilo. |
Country Status (21)
| Country | Link |
|---|---|
| US (1) | US6852877B1 (es) |
| EP (1) | EP1296925B1 (es) |
| JP (1) | JP3884291B2 (es) |
| CN (1) | CN1241895C (es) |
| AT (1) | ATE334112T1 (es) |
| AU (2) | AU5069000A (es) |
| BR (1) | BR0015870B1 (es) |
| CA (1) | CA2411000C (es) |
| CZ (1) | CZ303683B6 (es) |
| DE (1) | DE60029642T2 (es) |
| ES (1) | ES2265943T3 (es) |
| GC (1) | GC0000284A (es) |
| MX (1) | MXPA02011423A (es) |
| MY (1) | MY126930A (es) |
| NO (1) | NO328074B1 (es) |
| NZ (1) | NZ522267A (es) |
| PL (1) | PL200233B1 (es) |
| RS (1) | RS50337B (es) |
| RU (1) | RU2239626C2 (es) |
| UA (1) | UA72617C2 (es) |
| WO (1) | WO2001090043A1 (es) |
Families Citing this family (66)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB0026243D0 (en) | 2000-10-26 | 2000-12-13 | Bp Chem Int Ltd | Process |
| GB0026241D0 (en) * | 2000-10-26 | 2000-12-13 | Bp Chem Int Ltd | Process |
| GB0200021D0 (en) | 2002-01-02 | 2002-02-13 | Bp Chem Int Ltd | Process |
| GB0205014D0 (en) * | 2002-03-04 | 2002-04-17 | Bp Chem Int Ltd | Process |
| GB0205016D0 (en) * | 2002-03-04 | 2002-04-17 | Bp Chem Int Ltd | Process |
| GB0312965D0 (en) | 2003-06-05 | 2003-07-09 | Bp Chem Int Ltd | Process |
| TW200539941A (en) | 2003-12-19 | 2005-12-16 | Celanese Int Corp | Methods of making alkenyl alkanoates |
| CA2586584C (en) | 2004-12-20 | 2011-01-18 | Celanese International Corporation | Modified support materials for catalysts |
| DE102005054411A1 (de) * | 2005-11-15 | 2007-05-16 | Wacker Chemie Ag | Verfahren zur Herstellung von Vinylacetat unter Nutzung der dabei freiwerdenden Reaktionswärme |
| US8598402B2 (en) * | 2006-02-07 | 2013-12-03 | Celanese International Corporation | Butane absorption system for vent control and ethylene purification |
| US20080132723A1 (en) * | 2006-12-04 | 2008-06-05 | Celanese International Corporation | Process for the production of ethylene, acetic acid and carbon monoxide from ethane |
| JP5237616B2 (ja) * | 2007-11-27 | 2013-07-17 | 石福金属興業株式会社 | 白金族金属又は白金族金属とそれ以外の他の金属との合金を担持してなる酸化チタン担体の製造方法 |
| US8637714B2 (en) | 2008-07-31 | 2014-01-28 | Celanese International Corporation | Process for producing ethanol over catalysts containing platinum and palladium |
| US8501652B2 (en) | 2008-07-31 | 2013-08-06 | Celanese International Corporation | Catalysts for making ethanol from acetic acid |
| US20100197486A1 (en) * | 2008-07-31 | 2010-08-05 | Celanese International Corporation | Catalysts for making ethyl acetate from acetic acid |
| US8309772B2 (en) | 2008-07-31 | 2012-11-13 | Celanese International Corporation | Tunable catalyst gas phase hydrogenation of carboxylic acids |
| US8304586B2 (en) * | 2010-02-02 | 2012-11-06 | Celanese International Corporation | Process for purifying ethanol |
| US8546622B2 (en) | 2008-07-31 | 2013-10-01 | Celanese International Corporation | Process for making ethanol from acetic acid using acidic catalysts |
| US8338650B2 (en) | 2008-07-31 | 2012-12-25 | Celanese International Corporation | Palladium catalysts for making ethanol from acetic acid |
| US8680317B2 (en) * | 2008-07-31 | 2014-03-25 | Celanese International Corporation | Processes for making ethyl acetate from acetic acid |
| US8309773B2 (en) | 2010-02-02 | 2012-11-13 | Calanese International Corporation | Process for recovering ethanol |
| US8471075B2 (en) * | 2008-07-31 | 2013-06-25 | Celanese International Corporation | Processes for making ethanol from acetic acid |
| US7855303B2 (en) * | 2008-11-14 | 2010-12-21 | Celanese International Corporation | Integrated process for the production of vinyl acetate from acetic acid via ethylene |
| US8178715B2 (en) * | 2008-12-31 | 2012-05-15 | Celanese International Corporation | Integrated process for the production of vinyl acetate from acetic acid via acetaldehyde |
| US7820853B2 (en) * | 2008-12-31 | 2010-10-26 | Celanese International Corporation | Integrated process for the production of vinyl acetate from acetic acid via ethyl acetate |
| US8450535B2 (en) | 2009-07-20 | 2013-05-28 | Celanese International Corporation | Ethanol production from acetic acid utilizing a cobalt catalyst |
| US8710277B2 (en) * | 2009-10-26 | 2014-04-29 | Celanese International Corporation | Process for making diethyl ether from acetic acid |
| US8680321B2 (en) * | 2009-10-26 | 2014-03-25 | Celanese International Corporation | Processes for making ethanol from acetic acid using bimetallic catalysts |
| US8211821B2 (en) * | 2010-02-01 | 2012-07-03 | Celanese International Corporation | Processes for making tin-containing catalysts |
| US8222466B2 (en) | 2010-02-02 | 2012-07-17 | Celanese International Corporation | Process for producing a water stream from ethanol production |
| US8932372B2 (en) | 2010-02-02 | 2015-01-13 | Celanese International Corporation | Integrated process for producing alcohols from a mixed acid feed |
| US8680343B2 (en) | 2010-02-02 | 2014-03-25 | Celanese International Corporation | Process for purifying ethanol |
| US8668750B2 (en) | 2010-02-02 | 2014-03-11 | Celanese International Corporation | Denatured fuel ethanol compositions for blending with gasoline or diesel fuel for use as motor fuels |
| US8344186B2 (en) | 2010-02-02 | 2013-01-01 | Celanese International Corporation | Processes for producing ethanol from acetaldehyde |
| US8728179B2 (en) | 2010-02-02 | 2014-05-20 | Celanese International Corporation | Ethanol compositions |
| US8460405B2 (en) * | 2010-02-02 | 2013-06-11 | Celanese International Corporation | Ethanol compositions |
| CN102421521B (zh) | 2010-02-02 | 2015-01-07 | 国际人造丝公司 | 用于生产乙醇的包含结晶载体改性剂的催化剂的制备和用途 |
| US8314272B2 (en) | 2010-02-02 | 2012-11-20 | Celanese International Corporation | Process for recovering ethanol with vapor separation |
| US8858659B2 (en) * | 2010-02-02 | 2014-10-14 | Celanese International Corporation | Processes for producing denatured ethanol |
| US8747492B2 (en) | 2010-02-02 | 2014-06-10 | Celanese International Corporation | Ethanol/fuel blends for use as motor fuels |
| US8541633B2 (en) * | 2010-02-02 | 2013-09-24 | Celanese International Corporation | Processes for producing anhydrous ethanol compositions |
| US8680342B2 (en) | 2010-05-07 | 2014-03-25 | Celanese International Corporation | Process for recovering alcohol produced by hydrogenating an acetic acid feed stream comprising water |
| US8569551B2 (en) | 2010-05-07 | 2013-10-29 | Celanese International Corporation | Alcohol production process integrating acetic acid feed stream comprising water from carbonylation process |
| US8754267B2 (en) | 2010-05-07 | 2014-06-17 | Celanese International Corporation | Process for separating acetaldehyde from ethanol-containing mixtures |
| RS60732B1 (sr) | 2010-10-28 | 2020-09-30 | Celanese Int Corp | Metodi za proizvodnju sastava sa vinil acetatom koji ima nizak sadržaj nečistoća |
| CA2828727A1 (en) | 2011-03-02 | 2012-09-07 | Mark Allen Nunley | Methods for integrated natural gas purification and products produced therefrom |
| US8350098B2 (en) | 2011-04-04 | 2013-01-08 | Celanese International Corporation | Ethanol production from acetic acid utilizing a molybdenum carbide catalyst |
| US8658843B2 (en) | 2011-10-06 | 2014-02-25 | Celanese International Corporation | Hydrogenation catalysts prepared from polyoxometalate precursors and process for using same to produce ethanol while minimizing diethyl ether formation |
| US8536382B2 (en) | 2011-10-06 | 2013-09-17 | Celanese International Corporation | Processes for hydrogenating alkanoic acids using catalyst comprising tungsten |
| US8648220B2 (en) | 2011-10-11 | 2014-02-11 | Celanese International Corporation | Process for producing ethanol using a crude vinyl acetate feed |
| US8703868B2 (en) | 2011-11-28 | 2014-04-22 | Celanese International Corporation | Integrated process for producing polyvinyl alcohol or a copolymer thereof and ethanol |
| US8697802B2 (en) | 2011-11-28 | 2014-04-15 | Celanese International Corporation | Process for producing polyvinyl alcohol or a copolymer thereof |
| US8884052B2 (en) | 2011-12-15 | 2014-11-11 | Celanese International Corporation | Production of diacetoxyethylene by direct acetoxylation |
| US9000234B2 (en) | 2011-12-22 | 2015-04-07 | Celanese International Corporation | Calcination of modified support to prepare hydrogenation catalysts |
| US9233899B2 (en) | 2011-12-22 | 2016-01-12 | Celanese International Corporation | Hydrogenation catalysts having an amorphous support |
| US8907142B2 (en) | 2011-12-29 | 2014-12-09 | Celanese International Corporation | Process for promoting catalyst activity for ethyl acetate conversion |
| EP2892871B1 (en) | 2012-09-06 | 2019-02-27 | Celanese International Corporation | Processes for producing vinyl acetate |
| US8772553B2 (en) | 2012-10-26 | 2014-07-08 | Celanese International Corporation | Hydrogenation reaction conditions for producing ethanol |
| US8729318B1 (en) | 2012-11-20 | 2014-05-20 | Celanese International Corporation | Process for producing ethanol from methyl acetate |
| US9545610B2 (en) * | 2013-03-04 | 2017-01-17 | Nova Chemicals (International) S.A. | Complex comprising oxidative dehydrogenation unit |
| MX2019006874A (es) * | 2016-12-19 | 2019-08-22 | Shell Int Research | Deshidrogenacion oxidativa de etano con coproduccion de acetato de vinilo. |
| EP3339274A1 (de) * | 2016-12-22 | 2018-06-27 | Linde Aktiengesellschaft | Verfahren und anlage zur herstellung von olefinen |
| KR20190121762A (ko) | 2017-02-22 | 2019-10-28 | 쉘 인터내셔날 리써취 마트샤피지 비.브이. | 알칸 산화적 탈수소화 유출물의 가스 정화 |
| US11891357B2 (en) | 2018-03-13 | 2024-02-06 | Nova Chemicals (International) S.A. | Process to produce ethylene and vinyl acetate monomer and derivatives thereof |
| CN113166003B (zh) | 2018-11-02 | 2023-10-03 | 国际壳牌研究有限公司 | 乙烷氧化脱氢流出物的分离 |
| JP7684332B2 (ja) | 2020-06-09 | 2025-05-27 | ノバ ケミカルズ（インターナショナル）ソシエテ アノニム | エタンｏｄｈプロセスにおける酢酸生成の制限 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3972954A (en) * | 1972-02-14 | 1976-08-03 | Phillips Petroleum Company | Process for oxidative dehydrogenation |
| DE69511464T2 (de) * | 1994-06-02 | 1999-12-16 | The Standard Oil Co., Cleveland | Fliessbett-Verfahren zur Acetoxylierung von Äthylen zur Herstellung von Vinylacetat |
| GB9616573D0 (en) * | 1996-08-07 | 1996-09-25 | Bp Chem Int Ltd | Process |
| DE19745902A1 (de) * | 1997-10-17 | 1999-04-22 | Hoechst Ag | Verfahren zur selektiven Herstellung von Essigsäure durch katalytische Oxidation von Ethan |
| US6417422B1 (en) * | 1999-02-22 | 2002-07-09 | Symyx Technologies, Inc. | Ni catalysts and methods for alkane dehydrogenation |
-
2000
- 2000-05-19 US US10/258,956 patent/US6852877B1/en not_active Expired - Lifetime
- 2000-05-19 RS YUP-838/02A patent/RS50337B/sr unknown
- 2000-05-19 PL PL358196A patent/PL200233B1/pl not_active IP Right Cessation
- 2000-05-19 EP EP00935075A patent/EP1296925B1/en not_active Expired - Lifetime
- 2000-05-19 ES ES00935075T patent/ES2265943T3/es not_active Expired - Lifetime
- 2000-05-19 CN CNB008195447A patent/CN1241895C/zh not_active Expired - Fee Related
- 2000-05-19 NZ NZ522267A patent/NZ522267A/en not_active IP Right Cessation
- 2000-05-19 RU RU2002134457/04A patent/RU2239626C2/ru not_active IP Right Cessation
- 2000-05-19 MX MXPA02011423A patent/MXPA02011423A/es active IP Right Grant
- 2000-05-19 AU AU5069000A patent/AU5069000A/xx active Pending
- 2000-05-19 JP JP2001586234A patent/JP3884291B2/ja not_active Expired - Fee Related
- 2000-05-19 DE DE60029642T patent/DE60029642T2/de not_active Expired - Lifetime
- 2000-05-19 BR BRPI0015870-4A patent/BR0015870B1/pt not_active IP Right Cessation
- 2000-05-19 UA UA20021210280A patent/UA72617C2/uk unknown
- 2000-05-19 CA CA002411000A patent/CA2411000C/en not_active Expired - Fee Related
- 2000-05-19 WO PCT/EP2000/004545 patent/WO2001090043A1/en not_active Ceased
- 2000-05-19 CZ CZ20023735A patent/CZ303683B6/cs not_active IP Right Cessation
- 2000-05-19 AT AT00935075T patent/ATE334112T1/de not_active IP Right Cessation
- 2000-05-19 AU AU2000250690A patent/AU2000250690B2/en not_active Ceased
-
2001
- 2001-05-16 GC GCP20011370 patent/GC0000284A/en active
- 2001-05-17 MY MYPI20012335 patent/MY126930A/en unknown
-
2002
- 2002-10-28 NO NO20025173A patent/NO328074B1/no not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| CZ303683B6 (cs) | 2013-03-06 |
| HK1058188A1 (en) | 2004-05-07 |
| CN1452606A (zh) | 2003-10-29 |
| ATE334112T1 (de) | 2006-08-15 |
| CN1241895C (zh) | 2006-02-15 |
| YU83802A (sh) | 2006-05-25 |
| CA2411000C (en) | 2006-11-14 |
| DE60029642T2 (de) | 2007-02-22 |
| EP1296925B1 (en) | 2006-07-26 |
| US6852877B1 (en) | 2005-02-08 |
| PL200233B1 (pl) | 2008-12-31 |
| AU2000250690B2 (en) | 2005-02-24 |
| GC0000284A (en) | 2006-11-01 |
| DE60029642D1 (de) | 2006-09-07 |
| EP1296925A1 (en) | 2003-04-02 |
| MY126930A (en) | 2006-10-31 |
| BR0015870B1 (pt) | 2011-03-22 |
| RU2239626C2 (ru) | 2004-11-10 |
| JP3884291B2 (ja) | 2007-02-21 |
| UA72617C2 (en) | 2005-03-15 |
| ES2265943T3 (es) | 2007-03-01 |
| RS50337B (sr) | 2009-11-10 |
| NO20025173L (no) | 2002-10-28 |
| PL358196A1 (en) | 2004-08-09 |
| JP2003534306A (ja) | 2003-11-18 |
| AU5069000A (en) | 2001-12-03 |
| CA2411000A1 (en) | 2001-11-29 |
| NZ522267A (en) | 2004-04-30 |
| BR0015870A (pt) | 2003-03-11 |
| NO328074B1 (no) | 2009-11-23 |
| NO20025173D0 (no) | 2002-10-28 |
| CZ20023735A3 (cs) | 2003-03-12 |
| WO2001090043A1 (en) | 2001-11-29 |
| AU2000250690A1 (en) | 2002-02-21 |
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