MXPA99005948A - Lipophilic adhesive for secure topical attachment to the skin and comfortable removal - Google Patents

Abstract

The present invention relates to lipophilic topical adhesives for attachment to the skin. In particular the present invention relates to such topical adhesives which can be preferably employed for attachment to the skin in the area were absorption of bodily liquids is desired. The lipophilic topical adhesive provides secure attachment and is pleasing to the skin upon application, yet causes no discomfort upon removal. This is achieved by selecting the chemical composition and rheological characteristics of the topical adhesives.

Description

LIPOFILIC ADHESIVE FOR RELEVANT TO TOP OF THE SKIN AND PROPER REMOVAL FIELD OF THE INVENTION The present invention relates to lipophilic topical adhesives for attachment to the skin. In particular, the present invention relates to these topical adhesives which can be used for fixing to the skin in the area where the absorption of body fluids is desired, particularly for the adhesion of sanitary napkins, pantiliners, adult incontinence products. or pads for oozing. The lipophilic topical adhesive of the present invention can also be used to attach to the skin other articles such as protective articles, garments, prostheses, hot linings, cold linings, hearing aids, face masks, ornamental articles, or eyeglasses. , or also functional articles such as cosmetic or pharmaceutical supply articles that provide a substance to the skin. In addition, the iiphophilic topical adhesive of the present invention can be used in functional articles that are not fixed to the skin, but as a component in articles that require a high residence time on the skin such as cosmetic or decorative cosmetics. . The topical adhesive provides secure fixation or increased residence time and is suitable for the skin upon application, yet does not cause discomfort when removed. This is achieved by selecting the chemical composition and the rheological characteristics of topical adhesives.

BACKGROUND OF THE INVENTION The general prior art in the field of topical adhesives for fixation to the skin, was developed particularly in the field of relief bandages, plastids and bandages. However, these articles are typically applied in an emergency situation, where, for example, a wound has occurred on the wearer's skin and absorption of body fluids emanating from the wound is desired. In this context, aspects of the performance of the absorbent article such as the use and easy application and easy removal without pain, discretion are subordinated to criteria such as sterility, healing protection, mechanical protection of the wound. Also the absorbent articles that protect the wound are mainly adhered to the areas of the skin where the body hair can be removed before the application of the article or where little or no hair grows. The present invention relates to topical adhesives that are particularly useful for absorbent articles for the absorption of body fluids, which naturally emanate from the body without a wound. For example, to fix sanitary pads or pantiliners in the genitourinary region. Also, devices that are used, for example, in the genital region or the sweat pads that are used within the region of a person's armpit, can suitably employ the adhesive of the present invention. The present invention relates to topical adhesives that are particularly useful for protective articles, such as protectors or bandages of the genital organs of the knees or elbows; garments such as brassieres, surgical gowns or garment parts during the cutting of a tailor; in nasal plastids, prostheses such as breast replacements or wigs; thermal wrappings for example, to relieve menstrual cramps, arthritis pain, back pain, the pain of bruises during sports or work or simply to provide heat, ice wraps; for example to provide pain relief caused by contusions and to reduce swelling; hearing aids, protective masks of the face; ornamental items such as jewelry, earrings, capes, tattoos; glasses or other glasses. These items are not used for the absorption of body fluids. For example, the attachment of a wig to the skin, over the skull or knee or elbow protectors, to these body surfaces that undergo substantial wrinkling and extension can be adequately done by the adhesive of the present invention. The present invention may further relate to topical adhesives that are particularly useful for functional articles such as cosmetics or pharmaceutical products that provide a substance such as skin treatment substances, creams, lotions, hormones, vitamins, deodorants or drugs. Cosmetic or pharmaceutical supply articles alternatively can also provide a substance that emanates far from the skin. as insecticides, inhalation drugs or perfumes; in addition the lipophilic adhesive of the present invention can also be used in functional articles that do not adhere to the skin but as a component in articles that require a long residence time on the skin such as decorative cosmetics (lipstick, eye shadows) , theater makeup), or cleaning items (hand cleaner, face mask, hygienic cleaner especially for pores). These items are not used for the absorption of body fluids. For example, the attachment of a vitamin poultice to the skin or of a drug-releasing article for inhalation to the breast can be suitably made by the adhesive of the present invention. The inclusion of the adhesive in decorative cosmetics allows to increase its resistance of dissipation or disappearance while it does not create a problem to remove it. Topical adhesives that are used for absorbent articles such as sanitary napkins or pantiliners have generally been disclosed in the inventorial register established by United States law H1602 or WO 96/33683. Some additional details of the adhesive have been disclosed in PCT publication WO 95/16424.

In this document sanitary napkins having a topical adhesive that is applied on the side facing the user of a sanitary napkin along the entire periphery is disclosed. The problem underlying this document is mainly the secure attachment to the skin but it also mentions the problems of disunion of these items after being used without causing undue pain to a user. The disclosure of the international publication WO 95/16424 includes a detailed analysis of the criteria for the topical adhesive with respect to the rheological criteria. However, this document has little respect for the problem of painless removal of these articles since the rheological criteria taught include depilatory compositions, that is, for the removal of the hair, which are commercially available as STREP MIELE ™ sold in Italy by Laboratori Vaj- SpA The adhesives for topical fixation mentioned in WO 95/16424 also include the current pressure sensitive adhesives which are used to attach sanitary napkins to undergarments. In addition, this document only identifies the static rheological characteristics but is reserved for the dynamic rheological behavior of a topical adhesive. In WO 96/13238 a frequency model of the topical dependent adhesive is disclosed. However, all measurements reported, for example, on page 9 were made at temperatures between less than 60 ° C and 120 ° C and the actual frequency is 0.1 to 100 rad / s. In order to obtain the necessary data at the application temperature (at approximately 20 ° C, typical bath, ie storage temperature) the Williams-Landel-Ferry equation (hereinafter WLF) was used. This WLF equation is empirical and only valid within certain limits, for example, it can not be used to extrapolate temperatures below the glass transition temperature of a polymeric adhesive, also the WLF can not be used on the basis of values obtained below the glass transition temperature. Details about the WLF equation and its applicability in "Principles of Polymer Processing" can be found by Z. Tadmor and C.G. Gogos, published by John Wiley & Sons or in "Viscoelastic Properties of Polymers", by J.D. Ferry also published by John Wiley & They are. Since this is missing from WO 96/13238 the applicability of the disclosed data can not be achieved. European patent application EP-638 303 discloses the use of a topical adhesive on the lateral folds of sanitary napkins, in order to keep the folds in an upright position. The Swiss publication discloses the use of a very long sanitary napkin having beveled outer edges with a topical adhesive on the four corners of the extreme edges in order to provide an area of external topical adhesive of the pubic hair growth region. Both requests are reserved as to the adhesive composition. Based on the prior art, it is an object of the present invention to provide a lipophilic topical adhesive for secure fixation and painless removal of the skin. It is another object of the present invention to ensure that when removing, no residual adhesive will remain on the skin or on the hair. It is still a further object of the present invention that the lipophilic adhesive for topical fixation does not cause a cold or otherwise unacceptable temperature sensation upon application occurrence despite a temperature difference of the adhesive with respect to the temperature of the skin. .

In addition to the above objects of the present invention, it is also desirable that topical adhesives provide adhesives with additional benefits such as supplies / dispersion of a compound or composition that is beneficial to the skin or the general body or also physical protection. In addition, topical adhesives that do not affect the natural condition of the skin for example, being breathable or transmitters of water vapor or water vapor / sweat absorbers are preferred.

BRIEF DESCRIPTION OF THE INVENTION Although the present invention will be described herein in its use in disposable absorbent articles for the attachment of the topical adhesive to a user of these articles, further alternating uses of the present invention are possible. The present invention is also useful for fastening to the skin or protective articles of use such as guards or bandages of genitals, knees or elbows, garments such as brassieres, surgical gowns, or parts of garments during the making of a tailor, in nasal plastids; prostheses such as breast replacements or wigs; thermal wrappings for example to relieve menstrual cramps, arthritis pain, back pain, the pain of bruises during sports or work or simply to provide heat, ice wrappings, for example, to provide pain relief of contusions and / or to reduce swelling; headphones; protective masks for the face; ornamental items such as jewelry, earrings, caps, tattoos, glasses or other glasses. These items are non-absorbent of body fluids. In addition, the present invention may be useful for attaching functional articles to the skin or improving the function of these articles when worn on the skin. Functional articles are cosmetic or pharmaceutical supply articles that provide a substance to the skin such as skin treatment substances, creams, lotions, hormones, vitamins, deodorants or drugs, alternatively cosmetic or pharmaceutical articles for delivery or delivery they can also provide a substance that emanates away from the skin such as insecticides, inhalation drugs or perfumes; in addition the adhesive of the present invention can also be used in functional articles that are not fixed to the skin but as a component in articles that require a long residence time on the skin such as decorative cosmetics (lipstick, eye shadow, makeup theater), or cleaning items (hand cleaner, face mask, hygienic cleaners, mainly for pores). These items are also non-absorbent of body fluids. The topical adhesive allows secure attachment of an article to the user's skin and maintains the functionality of these articles. The term "functional" in this context means that the article after being placed on the skin fulfills an additional function that is maintained or improved by the topical adhesives according to the present invention. The articles typically have a surface facing the user and an external surface. In its use in disposable absorbent articles, the topical adhesive of the present invention is intended for topical adhesive bonding to a user of these articles. Disposable absorbent articles, such as sanitary napkins, pantiliners, incontinence articles and armpit sweat pads, typically have a surface facing the user and an external surface. The article comprises an absorbent core structure between the surface facing the user and the external surface to absorb the fluids emanating from a user, such as urine, feces, menstruation, sweat and vaginal discharge. The topical adhesive allows to fix an article to the skin of the user. The detailed analysis of the sequence of common situations that occur from the application of these articles until the moment of removal has shown the specific characteristics of the adhesive needed to be fulfilled in order to achieve the desired performance objectives, in particular, safe initial fixation, secure fixation during use and removal at the end without pain. The characteristics that have been considered in this context are the elastic module that describes the elastic behavior of the material, and the viscous module that describes the viscous behavior of the adhesive material. The viscous behavior of the adhesive can be interpreted to represent an indication of the adhesive's ability to quickly bond and adhere safely. The elastic behavior can be interpreted as a sign or signal of the "firmness" behavior of the adhesive. Its value is also critical for good initial fixation. It is believed that their combination is an indicator of the force required when the removal occurs. The relationship between the elastic modulus and the viscous modulus is considered to be an indication over which the fraction of the removal energy within the adhesive will be dissipated and over which the fraction is available to cause actual removal. In order to provide topical adhesives for initial and prolonged secure fixation and easy / painless removal, the relationship between the elastic modulus and the viscous modulus as well as its dynamic behavior is of key importance. The topical adhesive has an elastic modulus at a temperature of 37 ° C (100 ° Fahrenheit), abbreviated G'37 and a viscous modulus at a temperature of 37 ° C (100 ° Fahrenheti) of G "37. elastic dynamic behavior defined as? G'37 which is the difference of G'37 at a frequency of 100 fad7sec and G'37 at a frequency of 1 rad / sec and a viscous dynamic behavior? g "37 that the difference of G '3T at a frequency of 100 rad / sec and 6"37 at a frequency of 1 rad / sec.The topical adhesive according to the present invention satisfies the following conditions.

• G'37 (1 rad / sec) is on the scale from 1500 Pa to 20000 Pa, preferably 1500 Pa to 15000 Pa, more preferably 3000 Pa to 10000 Pa. • G "(1 rad / sec) is on the scale of 100 Pa to 15000 Pa, preferably 100 Pa to 10000 Pa, more preferably 3000 Pa to 5000 Pa. • the proportion of G'37 (1 rad7seg) / G "37 (1 rad7seg) is on the scale of 3 to 30. • the G 'ratio (100 rad / sec) -G "(100 rad / seq) G' ^ (1 rad / sec) - G" 37 (1 rad / sec) is not less than 0.5, preferably on the scale of 0.7 to 3, most preferably on the scale of 1 to 1.8 • any of the ratio of? G'37 / G37 (1 rad / sec) is not greater than 1.5, preferably not greater than unity and most preferably not greater than 0.8, or G'37 is not greater than 10000 Pa, preferably less than 5000 Pa, more preferably less than 2000 Pa, less. • the value of the ratio G'37 / G "37 at least for the frequency scale of about 1 rad / sec to 100 rad / sec, should preferably be 3.3 or higher, more preferably 5 higher, more preferably 10 or higher , while not exceeding about 30, preferably 20, anywhere in the frequency range. • the rheological behavior can also be related to the values of the vitreous transition temperature Tg. For topical adhesives according to the present invention, it should preferably be less than 15 ° C, more preferably less than 20 ° C, and most preferably less than -25 ° C. • The behavior and rheological acceptance of a topical adhesive can also be related to the specific heat capacity. Preferably, the specific heat capacity of the topical adhesive is less than 4 J / gK, more preferably less than 3 J / gK and most preferably less than 2 J / gK. • The behavior and rheological acceptance of a topical adhesive can also be related to the specific heat conductivity of the adhesive. Preferably, the conductivity of the specific heat is as low as possible, preferably between 1 and 0.1 W / m / K, more preferably between 0.6 and 0.1 W / m / K. Provided that the above rheological conditions are satisfied, the adhesives will also satisfy conditions such as sufficient adhesion (to avoid adhesive residue on the skin), which are critical to the commercial use of these adhesives and apparent to those skilled in the art. Adhesive compositions that meet the above criteria can be used as topical adhesives for the articles mentioned above, or as components in the formulation of functional articles, and particularly for disposable absorbent articles as long as they also meet the common requirements of being safe from to be used on human skin or animals during use and generally after disposal of the article. Often the criteria of hygienic appearance and comfortable feeling when in contact are important, such that adhesive compositions that will be transparent or white are preferred, and which avoid an uncomfortable, cold feeling when applied. The above rheological criteria and other considerations can be satisfied by the compositions of the particularly preferred adhesive of the present invention, wherein the composition comprises from 3% to 15%, preferably from 5% to 10%, by weight of a first polystyrene copolymer -block-poly (ethylene-ran-butylene) - of polystyrene block having a content of three upper block of 70%, a higher styrene content of 25% by weight, and a higher molecular weight of 60,000; from 0% to 9%, preferably from 0% to 6%, by weight of a second polystyrene (polyethylene-ran-butylene) -block polystyrene copolymer having a content of three blocks of less than 70% , a styrene content of less than 20% by weight, and a molecular weight of less than 60,000; from 20% to 95%, preferably from 30% to 60%, by weight of an oil having a paraffinic fraction greater than 50% by weight and a lower aromatic fraction of the % by weight, as a plasticizer compound; from 0% to 50%, preferably from 30% to 50%, by weight of a hydrogenated cycloaliphatic adhesive modifier resin; and of 0% to 10% of additives such as antioxidants or gel stabilizing substances, preferably the antioxidant substances are comprised in an amount of 0.3% to 1% by weight, and the gel stabilizing substances are comprised in an amount of 0% to 1 % in weigh. The first and second block polystyrene copolymers of polystyrene-ran-butylene of polystyrene block are preferably selected from the group consisting of styrene-butadiene-styrene-isoprene-styrene-styrene block copolymers, styrene-ethylene-butylene-styrene, styrene-ethylene-propylene-styrene. The oil is preferably selected from the group consisting of natural or synthetic oils such as vegetable oils, mineral oils or combinations thereof.

DETAILED DESCRIPTION OF THE INVENTION Adhesive for Topical Fixation The topical adhesive according to the present invention is applied directly to the skin. In a particular application, the adhesive can be used in sanitary napkins which are applied to the genital region of a typically female user around the discharge area of the liquid. The word "skin" according to the present invention is not only related to the specific dermis of the user but includes the mucosal tissue also as the hair that is typically found in the genital region of the users of the sanitary napkins. In order to provide fixation of an article according to the present invention to the skin, it is necessary to provide a certain area on the side of the article that is facing the skin with the topical adhesive. For the various designs of sanitary napkins it is contemplated, but preferably the topical adhesive is provided adjacent to the peripheral edge of the topsheet such that a central area of the article is left without adhesive. This will more appropriately facilitate the placement of the towel in such a way that the region of the liquid-permeable upper sheet is placed adjacent to the hole where the body fluid emanates, such that the liquid emanating is transported immediately towards the absorbent structure of the absorbent article without the possibility of leakage or spillage.

Characteristics. Physical, Rheological and Adhesive of a Topical Adhesive Even when topical adhesives similar to pressure sensitive adhesives are used in the hair of human skin and in mucosal tissues, it is understood that topical adhesive compositions can only with difficulty be considered typical pressure sensitive adhesives (referred to as PSA hereinafter) on the basis of the most characteristic rheological behaviors that identify these materials. In fact, as the person skilled in the art of adhesives knows, the most characteristic aspect that distinguishes a PSA from other substances that can temporarily stick things (as can, for example, water between two glass plates), is the fact that its rheological parameters and especially the elastic modulus G 'vary greatly with the frequency of the applied stresses. More particularly the G 'of the PSA may increase over some types of magnitude while the frequency of the applied voltages varies from the typical binding frequency to the typical disbudding frequency, i.e. from 1 rad / sec to 100 rad / sec as is indicated below. As a first consequence, it is inadmissible to define materials destined to be used as "topical adhesives", giving values of the rheological parameters and especially of G 'at a fixed frequency value. This can be misleading because in the absence of other features it will include materials that do not have practical values. It is consequently necessary that the rheological characterization should be based on dynamic considerations. This applies not only to the elastic modulus G 'but also to the viscous modulus G "and consequently also to (d) = G7G' It is well known that the typical PSA does not have only a high variation of G 'through the frequencies considered, but there is also a variation of G "even higher that may be close to or even higher than the value of G ', that is (d) becomes approximately or even higher than 1, particularly in the frequencies that They are typical of disunity, without wishing to be bound by theory, this can be interpreted as meaning that a high fraction of the energy applied for disunion dissipates within the adhesive (so that it is not effective at causing disunity) , while this fact macroscopically causes the recording of a very high level of adhesive strength As indicated above, the materials useful as topical adhesives according to the present invention have rheological characteristics which are measured at a reference temperature of 37 ° C. ° C (as the normal body temperature of humans), and within a frequency scale.It has been found that when applying an article such as a sanitary napkin, as a topical adhesive, adhesive contact is formed at a low frequency, while disbonding occurs at the rate of removal of the article. This speed is expressed as a frequency of 100 rad / sec whereas it has been found that the low frequency of forming the adhesive bond is in the order of 1 rad / sec. Therefore, the range of frequencies to be used in agreement is between 1 and 100 rad / sec. It is believed that the characteristics of the adhesive bond are selected most appropriately at the temperature of the human body. Since the topical adhesive according to the present invention is used directly on the skin and the person skilled in the art is directed to select the composition of the adhesive to have a small specific heat capacity (eg, preferably less than 4 J / g / K), the actual temperature of the topical adhesive will reach 37 ° C very quickly or will still be heated by a human before application. In order to provide good bonding conditions, ie at a frequency of about 1 rad / sec, the absolute values of the elastic modulus should not be too high, otherwise the adhesive is too hard and is not able to bond intimately or molding to the surface to which it is expected to adhere.

It is also important to have an absolute value of G "low in order to have a good cohesion that is particularly valuable to be used in the field of sanitary napkins, and to generate when articles are used that are frequently removed and adhered again or replaced, While the material remains soft, and is able to adhere gently to the skin, the ratio of G'37 (1 rad / sec) to G "37 (1 rad / sec) is important to ensure that these two values are balanced when occurring adhesion to the skin. At the same time, the absolute changes of G'37 need to be limited within the range of frequencies considered. Consequently, a low value must be maintained for the ratio of? G'37 (ie, G'37 (100 rad / sec) -G'37 (1 rad / sec)), above G'37 ( 1 rad7sec) in order to maintain the secure fixation of the topical adhesive without causing discomfort during the time or in the removal / lamination. This can also be expressed in absolute terms by keeping the? G'37 below certain values. Importantly, the ratio of G '(100 rad / eq) - G "^ (100 rad / sec) G'37 (1 rad / sec) -G" 37 (1 rad / sec) needs to be sufficiently large for ensure that the dynamic behavior of both the elastic modulus and the viscous modulus are maintained in a relationship that provides safe adhesion and painless and easy removal. Finally, the person skilled in the art will also recognize that the vitreous transition temperature Tg of the adhesive composition, the specific heat capacity, and the specific heat conductivity are parameters that are useful to more fully define the group of topical adhesives tools. The following set of characteristics must be satisfied: • G'37 (1 rad / sec) is on the scale from 1500 Pa to 20000 Pa, preferably 1500 Pa to 15000 Pa, more preferably 3000 Pa to 10000 Pa. • G "(1 rad / sec) is on the scale of 100 Pa to 15000 Pa, preferably 100 Pa to 10000 Pa, more preferably 3000 Pa to 5000 Pa. • the proportion of G'37 (1 rad7sec) / G "37 (1 rad7sec) is in the scale from 3 to 30. • the ratio G '^ (100 rad / sec) -G% 7 (100 rad / sec) G'37 (1 rad / sec) - G "37 (1 rad / sec) is not less than 0.5, preferably on the scale of 0.7 to 3, most preferably on the scale of 1 to 1.8 • any of the proportion of? G'37 / G37 (1 rad / sec) is not greater than 1.5, preferably not greater than the unit and most preferably not greater than 0.8, or "G'37 is not greater than 10000 Pa, preferably less than 5000 Pa, more preferably less than 2000 Pa, less. • the value of the G'37 / G ratio" 37 at least for the approximate frequency scale 1 rad / sec to 100 rad / sec, should preferably be 3.3 or higher, more preferably 5 higher, more preferably 10 or higher, while not exceeding about 30, preferably 20, anywhere in the frequency range. • the rheological behavior can also be related to the values of the vitreous transition temperature Tg. For topical adhesives according to the present invention, it should preferably be less than 15 ° C, more preferably less than 20 ° C, and most preferably less than -25 ° C. • The behavior and rheological acceptance of a topical adhesive can also be related to the specific heat capacity. Preferably, the specific heat capacity of the topical adhesive is less than 4 J / gK, more preferably less than 3 J / gK and most preferably less than 2 J / gK. • The behavior and rheological acceptance of a topical adhesive can also be related to the specific heat conductivity of the adhesive. Preferably, the conductivity of the specific heat is as low as possible, preferably between 1 and 0.1 W / m / K, more preferably between 0.6 and 0.1 W / m / K.

Chemical Characteristics and Composition of a Topical Adhesive In order to provide topical adhesive that meets the requirements of the rheological and physical characteristics of a topical adhesive above, the following formulation criteria must be used. It should be noted that most of the compositions useful as the topical adhesive have a substantially gel-like structure and are preferably gels. This derives from the fact that: the predominant component is the plasticizer which is a liquid material at room temperature a macromolecular or polymeric component is present in minor amounts against the plasticizer. This form, in the preferred modalities, a three-dimensional network made by the physical and chemical bonds between the molecules. Particularly useful physical links are the bonds present in systems containing block thermoplastic elastomers. Typical compositions for topical adhesives can be divided into three families according to the nature of their main component, ie, normally the plasticizer or liquid plasticizers (s): 1) The hydrophobic (lipophilic) compositions in which the plasticizer is typically an oil or mixtures of oils of vegetable and mineral origin and the polymer is usually a synthetic polymer, preferably an elastomer, soluble, or capable of swelling the oil or oils. 2) Mixed phase compositions in which both hydrophobic and hydrophilic components, possibly both plasticizers and polymers, form two or more separate phases. In these cases, an emulsifier / surfactant is preferably present at an adequate level to form stable emulsions between incompatible phases. For topical adhesives according to the present invention, it is preferable that the hydrophobic components are predominant against the hydrophilic components. 3) The hydrophilic compositions in which typically the plasticizer is water / glycerol / glycols and the like and / or mixtures thereof and the polymer phase is of synthetic (for example polyacrylics), or natural (for example natural gums) or mixtures thereof. It is important that, unlike the medical field and prior art cited, hydrophilic compositions are not preferred, although hydrophobic and mixed phase compositions 1) and 2) are preferred in the applications of the present invention. This partly depends on technical reasons in the sense that many of the hydrophilic compositions used in the medical field show elasticity and cohesion too low to be useful in the present application. The other reason for preferring the hydrophobic or easily mixed compositions is that the application of the present invention, particularly in the field of sanitary napkins, will include a likelihood of contacting the topical adhesive with the liquid being absorbed. Since the liquids are, all of a general aqueous type, in contact with a topical hydrophilic adhesive, it would result in a certain absorption of the body fluids in the topical adhesives. This would then have the result of changing the rheological characteristics and therefore the functionality of the topical adhesive and cause an unhygienic appearance. In addition, the hydrophilic topical adhesive also tends to be perceived as cold and wet which upon application to a human skin is not in line with the typical expectation. Additional problems result from the fact that particular topical adhesives comprising water as the plasticizer have a tendency to dry unless sealed in a waterproof package. It has been found that the particularly preferred compositions belonging to the first family of the hydrophobic compositions are those comprising: from 3% to 15%, preferably from 5% to 10%, by weight of a first poly block copolymer of polystyrene (ethylene-ran-butylene) - of polystyrene block having a content of 3 upper blocks of 70%, a styrene content greater than 25% by weight, and a molecular weight higher than 60,000; - from 0% to 98%, preferably from 0% to 6%, by weight, of a second block polystyrene copolymer of polystyrene (polyethylene-ran-butylene) -of styrene block having a content of three blocks of less than 70 %, a styrene content less than % by weight, and a molecular weight of less than 60,000. Both the first and the second polystyrene block polystyrene copolymers of polystyrene block are preferably selected from the block consisting of styrene block copolymers of the styrene-butadiene-styrene, styrene-type. isoprene-styrene-styrene-butylene-styrene, styrene-ethylene-propylene-styrene. from 20% to 95%, preferably from 30% b to 60% by weight of an oil having a paraffinic fraction greater than 50% by weight, and an aromatic fraction of less than 5% by weight, as a plasticizer compound. The oil may be selected from natural or synthetic oils, such as vegetable oils, mineral oils, or combinations thereof. from 0% to 50%, preferably from 30% to 50%, by weight of a hydrogenated, cycloaliphatic, tack-modifying resin. The resin has the main scope of adapting the Tg of the systems based on synthetic polymers, and must be compatible with the rubber consistency blocks of the styrenic polymers. from 0% to 10% by weight of additives, these additives can be substances that facilitate and stabilize the gel and the gel formation processes of hydrophobic liquid plasticizers. These may be, for example, fatty acids of C8 to C22, its metal salts and its polyoxyl derivatives derived from lanolin, silica; bentonite, muroionite and its derivatives; polyamides, waxes or mixtures thereof. Common additives known in the art such as preservatives, antioxidants, anti-ultraviolet agents, pigments, mineral fillers, rheology modifiers, etc., may also be included. The substances preferably antioxidants are comprised in an amount of 0.3% to 1% by weight, and the gel stabilizing substances are comprised in an amount of 0% to 1% by weight.

Application of the Topical Adhesive Absorbent articles in which the topical adhesive may be used in accordance with a preferred embodiment of the present invention, may be made by any of the ordinary manners of the art. The application of the adhesive to the topsheet, or, more generally, to the side facing the skin of these articles, should not cause greater problems for those skilled in the art since it can be provided by any of the commonly known techniques. used for other adhesives. The total area of the skin or the surface that faces the user of an article that is covered by the lipophilic topical adhesive, depends on its intended use. For the preservation of the adhesive, it should not be greater than 80%, preferably from 30% b to 60% of the surface it gives to the user. In the preferred embodiment of an absorbent article, the total area of the surface facing the skin that is covered by the topical adhesive should not be greater than 20%, preferably not greater than 10%. Preferably, the adhesive is near the periphery of the absorbent article and in the case of the upper sheets of film (or when the backsheet is folded over the upper sheet), the adhesive is preferably on a part of the film that is not permeable to liquids. If possible, the article also provides breathability by being at least permeable to water vapor, preferably permeable to air to prevent it from being poorly ventilated. The breathability, if not supported or maintained by the topical adhesive as such, may be limited to the area of the article where no adhesive is applied. The topical adhesive in an article is preferably protected before use. This protection can be provided by a release liner such as a paper treated with silicone or surfactant, providing easy detachment of the selected topical adhesive. In a preferred embodiment, this invention can be used beneficially in disposable absorbent articles that are applied directly to the skin of a wearer. The article normally exhibits absorbency of bodily fluids, the protection of the user's garments against staining is comfortable to use, and is easy to produce and pack. The disposable absorbent article is described below with reference to a sanitary napkin or catamenial product, however, pantiprotectors, adult incontinence articles or sweat pads are also included under the term "disposable absorbent articles". The term "sanitary napkin" as used herein, refers to an article that is worn by women adjacent to the pudendal region and which is intended to absorb and contain the various body fluids that are discharged from the body (e.g. vaginal, menstrual and / or urine), and which are intended to be discarded after a single use. A disposable absorbent article is preferably thin, more preferably between 1 and 5mm thick and, either, substantially planar before use or in a preconfigured form. The terms "attached" or "fixed", as used herein, encompass configurations by which a first member is directly connected to a second member and configurations by which a first member is indirectly connected to a second member by connecting the first member to intermediate members who in turn are connected to the second member. In a preferred embodiment, a sanitary napkin of the present invention comprises a liquid permeable upper sheet, a liquid impermeable back sheet attached to the upper sheet, and an intermediate absorbent core to the upper sheet and the back sheet. The sanitary napkin has two main surfaces, a surface that is in contact with the body or that faces the user on which the topical adhesive is applied and a surface that faces the garment or that is in contact with the garment. The upper sheet is docile, soft feeling, and non-irritating to the user's skin, the upper sheet may also have elastic characteristics that allow it to be stretched in one or two directions, in parts of the upper sheet, or in all its extension.

In addition, the topsheet is permeable to fluid, allowing fluids (eg, menses and / or urine) to easily penetrate through its thickness. The preferred top sheets for use in the present invention are typically selected from the upper nonwoven sheets with raised upper region and upper sheets of film formed with openings. Films formed with openings are especially preferred for the upper sheets because they are permeable to body exudates and not yet absorbent, and have a reduced tendency to allow the fluids to pass back through and rewet the user's skin . In this way, the surface of the formed film that is in contact with the user remains dry, thus reducing the staining of the body and creating a more comfortable feeling for the wearer. Suitable formed films are described in U.S. Patent No. 3,929,135, U.S. Patent No. 4,324,246; U.S. Patent No. 4,342,314; U.S. Patent No. 4,463,045; and United States Patent No. 5,006,394. Top sheets of film formed with particularly preferred micro apertures are disclosed in the United States Patent No. 4,609,518 and in United States Patent No. 4,629,643. A preferred top sheet for the present invention comprises the formed film described in one or more of the above patents and sanitary napkins are marketed by The Procter & Gamble Company of Cincinnati, Ohio as "DRI-WEAVE". Topical adhesives are very well used on top sheets that do not have a homogeneous liquid passages distribution but only a part of the top sheet that comprises the liquid passages oriented in such a way that they result in a centrally permeable and peripherally permeable upper sheet to liquids. Another alternative is the so-called hybrid top sheets, which incorporate structures in fibrous and film form, particularly useful embodiments of these hybrid top sheets are disclosed in PCT Publication Nos. WO 93/09744; WO 93/11725 or WO 93/11726. When we refer to the top sheet, a multi-layered structure or a single layer structure is contemplated. The hybrid top sheet mentioned above, is this multi-layered design, but other multi-layered top sheets such as the primary and secondary top sheet designs are also considered. The absorbent core can also comprise multiple layers and provides the function of fluid storage and distribution. Placed in fluid communication with, and typically underlying, the top sheet, is the absorbent core. The core may comprise any normal absorbent material or combinations thereof. This preferably comprises gelling absorbent materials, generally referred to as "hydrogel", "superabsorbent", "hydrocolloid" materials in combination with suitable carriers. The gelling absorbent materials suitable for use herein will often comprise a partially neutralized, lightly crosslinked polymeric gelling material, substantially insoluble in water. This material forms a hydrogel upon contact with water. These polymer materials can be prepared from acid-containing, unsaturated, polymerizable monomers, such as acrylic acid, which are well known in the art. Suitable carriers include materials that are conventionally used in absorbent structures such as natural, modified or synthetic fibers, particularly modified or unmodified cellulose fibers in the form of fluff and / or tissue. Suitable carriers can be used together with the gelling absorbent material, however, they can also be used alone or in combinations. Tissue and tissue laminates are very preferred, in the context of sanitary napkins / liners. The absorbent core can also comprise multiple layers and provide the function of fluid storage and distribution. One embodiment of the core, particularly useful in the application of the present invention, comprises a laminate of double-layer tissue formed by folding the tissue over itself. These layers can be joined together. The gelling absorbent material or other optional material can be comprised between the layers. The absorbent core may include optional components normally present in the absorbent webs such as odor control agents, in particular suitable zeolites. The backsheet primarily prevents the exudates absorbed and contained within the absorbent core from wetting articles that come into contact with the absorbent product such as underpants, briefs, pajamas, and undergarments. The backsheet is preferably impervious to liquids (eg, menses and / or urine and is normally manufactured from a thin plastic film.) The backsheet typically extends throughout the entire absorbent core and can extend over and form a part. of the top sheet, bending around the absorbent core In this way a preferred configuration of the top sheet as disclosed in U.S. Patent No. 4,342,314, column 16, lines 47 to 62, can be achieved without the requirement of Selectively perforating the top sheet Preferably, the backsheet also provides breathability to the absorbent article by being at least permeable to water vapor, preferably permeable to air The backsheet can be a laminate, for example, a combination of microporous film, and / or a non-woven material, and / or film formed with openings. You wish, it can be limited to the periphery or the center of the back sheet, or this can be through the whole of the back sheet.

EXAMPLE 1 An oil-based composition useful in sanitary napkins according to the present invention was prepared using 10% by weight of Krato G-1651, a styrene / ethylene / butylene / styrene block copolymer containing 33% styrene enp and available from Shell Co., and 49% by weight of Kaydol, a paraffinic mineral oil available from Witco Co. Moreover, the composition contains 40% by weight of the tackifying resin. The tackifying modifier resin was Exorez 5300, a hydrogenated resin available from Exxon Co. Magnesium stearate, available from Cerlo Erba, S.p.A. as a co-gelling agent for the oil at a level of 0.7% by weight. Irganox 1010, an antioxidant available from Ciba Geigy, was added at a level of 0.3% by weight. Finally, the formulation had the following percentage composition: Kraton G-1651 10.0% by weight Kaydol 49.0% by weight Escorex 5300 40.0% by weight Magnesium stearate 0.7% by weight Irganox 1010 0.3% by weight The composition shown has the following properties Rheological 37 ° C. a) Elastic modulus at 1 rad / sec G'37 = 7038 Pa b) Viscous module at 1 rad / sec G "37 = 487 Pa c) Proportion of Elastic and Viscous Modules at 1 rad / sec, G'37 / G "37 = 14.45 d) Proportion of G '^ dOO rad / sec) - G (100 rad / sec) G'37 (1 rad / sec) - G "37 (1 rad / eg) = 1.11 e) The proportion of? G'37 on G'37 (1 rad / sec) it was 0.291, with? G'37 = 20501 Pa. The previous formulation was tested on a sanitary pad and was judged as comfortable for the initial application and the removal of the hairy, sensitive skin.

Comparative Example A composition based on oil of componotine was mixed, using 7. 1% by weight of Kraton G-1651, a styrene / ethylene / butylene / styrene block copolymer, containing 33% by weight of styrene and available from Shell Co., and 41.9% by weight of Kaydol, an oil paraffinic mineral available from Witco Co.

Moreover, the composition with tube 704 part of tackifying resin resin per 100 parts of Kraton polymer. The tackifier resin was Regalrez 3102, a hydrocarbon resin available from Hercules Co. Magnesium stearate, available from Cario Erba, S.p.A., was used as a co-gelling agent for the oil at a level of 0.7% by weight. Irganox 1010, an antioxidant available from Ciba-Geigy, was added at a level of 0.3% by weight. Finally, the formulation had the following percentage composition: Kraton G-1651 7.1% by weight Kaydol 41.9% by weight Regalrez 3102 50.0% by weight Magnesium stearate 0.7% by weight Irganox 1010 0.3% by weight The composition showed the rheological properties of 37 ° C following: a) Elastic modulus at 1 rad / sec G'37 = 3059 Pa b) Viscous module at 1 rad / sec G "37 = 1208 Pa c) Proportion of Elastic and Viscous Modules at 1 rad / sec, G'37 / G "37 = 2.53 d) Proportion of G '^ dOO rad / sec) - G "^ (100 rad / sec) G'37 (1 rad / sec) - G" 37 (1 rad / eg) = 2.87 e) The proportion of? G '37 over G'37 (1 rad / sec) was 3,944 with? G'37 = 12064.7 Pa. The above formulation was judged to be highly uncomfortable for the delamination of the forearm skin. The application to sensitive hairy skin was unacceptable.

Claims (5)

1. A lipophilic topical adhesive for securing an article to the skin, said topical adhesive comprising: "from 3% to 15%, preferably from 5% to 10% by weight of a first polystyrene block copolymer of poly (euthno-ran-butylene) ) of polystyrene block having a content of three blocks greater than 70%, a styrene content greater than 25% by weight, and a molecular weight greater than 60,000. "From 0% to 9%, preferably from 0% to 6% by weight, of a block polystyrene copolymer of (polyethylene-ran-butylene), of polystyrene block having a content of 3 blocks of less than 70%, a styrene content of less than 20% by weight, and a molecular weight of less than 60,000; • 20% > to 95%, preferably from 30% to 60% by weight, of an oil having a paraffinic fraction greater than 50% by weight, and an aromatic fraction of less than 5% by weight, as a plystifying compound; • from 0% to 50%), preferably from 30% to 50%, by weight of a hydrogenated cycloaliphatic resin that modifies the tackiness; • from 0% to 10% by weight of additives such as antioxidants, or gel stabilizing substances, preferably from 0.3% to 1% by weight of antioxidants and from 0% to 1% by weight of the gel stabilizing substances.

2. A lipophilic topical adhesive according to claim 1, wherein: • each of said first and second block polystyrene polystyrene (polystyrene-ran-butylene) -polystyrene block copolymers is selected from the following group: styrene block copolymers of the styrene-butadiene-styrene, styrene, isoprene, styrene-styrene-isoprene-styrene-styrene-ethylene-butylene-styrene, styrene-ethylene-propylene-styrene type; and • said agent is selected from the following group: natural and synthetic oils such as vegetable oils, mineral oils or combinations thereof; • said additives are selected from the following group: C8 to C22 fatty acids, their metal salts and their polyoxie derivatives; lanolin derivatives; silica, bentonite; monmorillonite and its derivatives; polyamides; waxes or mixtures thereof.

3. A lipophilic topical adhesive according to any of the preceding claims, wherein the adhesive has a glass transition temperature of less than -15 ° C, preferably less than -20 ° C, more preferably -25 ° C.

4. A lipophilic topical adhesive according to any of the preceding claims, wherein said article is a disposable absorbent article.

5. The use of a lipophilic topical adhesive according to any of the preceding claims in a sanitary napkin or in a pantyhose.