MXPA98007941A - Composition of champu acondiciona - Google Patents

Abstract

The present invention relates to aqueous hair conditioning shampoo compositions comprising a specific surfactant component comprising an ethoxylated alkyl sulfate surfactant having from about 1 to about 8 moles of ethoxylation and one agent amphoteric surfactant in a shampoo with a conditioning agent, dispersed, insoluble, non-anionic silicone and a hair conditioning agent, of organic polymer, cationic, cellulose, soluble, selected

Description

COMPOSITION OF AIR CONDITIONER SHAMPOO FIELD OF THE INVENTION This invention relates to conditioning shampoo compositions containing a specific surfactant component comprising an ethoxylated alkyl sulfate surfactant having from about 1 to about 8 moles of ethoxylation and an amphoteric surfactant in a shampoo with a non-ionic, dispersed, insoluble conditioning agent, an organic, low viscosity conditioning oil, and a hair-conditioning agent, of organic polymer, cationic, cellulose, soluble, selected. The compositions provide improved performance of hair conditioning, including an improved feeling of wet hair. BACKGROUND OF THE INVENTION Human hair becomes dirty due to its contact with the surrounding atmosphere, and to a greater degree, the sebum secreted by the head. The accumulation of sebum causes the hair to have a disheveled feeling and an unattractive appearance. Hair fouling needs to be shampooed with frequent regularity. Shampooing the hair cleans the hair P683 remove excess dirt and sebum. However, the shampooing process has disadvantages since the hair is left in a wet, entangled and generally non-manageable state. Washing with shampoo can also result in hair becoming dry or "matted" and a loss of shine, due to the removal of natural oils or other materials that moisturize the hair. After washing with shampoo, the hair also suffers from a loss of "softness" perceptible by the user in drying. Hair can also suffer from increased levels of static drying after shampooing. This can interfere with the hairstyle and can result in a loose hair. A variety of approaches have been developed to mitigate problems after shampooing. These vary from the inclusion of hair conditioning aids in shampoos to the application after washing with shampoo and hair conditioners, ie, hair rinses. Hair rinses are generally liquid in nature and should be applied in a separate step after shampooing, leaving the hair for a period of time, and rinsing with fresh water. Of course, this is time consuming and not as convenient as shampoos that contain both hair conditioning and cleaning ingredients.

While a wide variety of shampoos containing conditioning aids have been described, they have not been entirely satisfactory for a variety of reasons. Cationic conditioning agents are highly desirable for use in hair conditioning because of their ability to control static, improve disentangling in number, in providing a feeling of damp, silky hair to the user. A problem that has been found in shampoos is related to compatibility problems between good anionic surfactants, cleaning agents, and most conventional cationic agents that have historically been used as conditioning agents. Efforts have been made to minimize the adverse interaction between the use of alternative surfactants and the improved cationic conditioning agents. Cationic surfactants that provide good complete conditioning in hair rinse products, in general, than when complexed with cleaning, anionic surfactants, and provide poor conditioning in a shampoo context. In particular, the use of the cationic, soluble surfactants, which form soluble ionic complexes, do not deposit well in the hair. Cationic surfactants, soluble, that form ionic, insoluble complexes are deposited in the hair, but they do not provide good hair conditioning benefits, and tend to cause the hair to have a dirty, coated feeling. The use of cationic, insoluble surfactants, for example, tricetyl-methyl-ammonium chloride, can provide excellent antistatic benefits, but can not otherwise provide good complete conditioning. Most cationic polymers tend to accumulate in the hair resulting in an undesirable "unclean" coated sensation. Therefore, cationic polymers, conventionally, are preferably used at limited levels to minimize this problem. However, this may limit the full benefits of conditioning that you have. Additionally, surfactant conditioning agents do not provide complete, optimal conditioning benefits, particularly in the "softness" area, especially when they are distributed as an ingredient in a shampoo composition. The materials that can provide increased softness are the non-ionic silicones. The silicones in the shampoo compositions have been described in a number of different publications. In the publications include US Patent No. 2,826,551, Geen, issued March 11, 1958; U.S. Patent No. 3,964,500, Drakoff, issued June 22, 1976; U.S. Patent No. 4,364,837, Pader, issued December 21, 1992, and British Patent No. 849,433, of oolston, issued September 28, 1960. While these patents describe compositions containing silicone, they also do not provide a totally satisfactory, since it was difficult to keep the silicone well dispersed and suspended from the product. Recently, insoluble silicone-containing hair conditioning shampoo compositions have been described in US Pat. No. 4,741,855, to Grote and Russel, issued May 3, 1988 and US Patent No. 4,788,066, to Bolich and William. , issued November 29, 1988. These shampoo compositions can distribute or provide excellent conditioning, complete, hair benefits while maintaining excellent cleaning performance, even with the use of anionic, detergent surfactants for a wide variety of applications. hair types. The Japanese Patent Application, disclosed, No. 56-72095, June 16, 1981, by Hirota et al. (Kao Soap Corp.) discloses a shampoo containing a cationic polymer and silicone conditioning agents. Still other combinations of patents relating to shampoos with cationic agents and silicone include EPO Application Publication No. 0 413 417, published February 20, 1991, by Hartnett et al. Another approach to providing hair conditioning benefits to shampoo compositions has been to use materials that are oily to the touch. These materials provide an improved taste and improved shine to the hair. Oily materials have also been combined with cationic materials in shampoo formulations. Japanese Patent Application, Showa 53-35902, disclosed, October 6, 1979 (Showa 545,129135), N. Uchino, (Lion Yushi Co.), discloses hair treatment compositions containing a cationic polymer, salt of fatty acid, and at least 10% of an oily component for use before or after shampooing. Suitable oil components are hydrocarbons, higher alcohols, fatty acid esters, glycerides and fatty acids. Japanese Patent Application 62 [1987] -327266, filed on December 25, 1987, published on July 4, 1989, disclosed, No. HEI 1 [1987] -168612, of Horie et al., Discloses detergent compositions containing a cationic surfactant and / or cationic polymer, anionic surfactant, and specific esters of the formula RCOOR ', wherein R and R' are straight or branched chain alkyls.

Despite these attempts to provide optimal combinations for hair cleaning and conditioning ability, it remains desirable to further provide improved shampoo conditioner compositions. For example, it remains desirable to improve the complete conditioning, and especially the illustrious gloss, wet and dry combing, and the dry hair feeling, of hair treated with shampoo containing silicone and cationic material. For shampoos containing oily materials in combination with cationic materials, it remains desirable to improve the overall conditioning, especially wet combing and detangling, dry styling, and the feeling of dry hair. However, the single increase in the level of one or both of the conditioning ingredients can result in adverse effects such as a greasy hair feeling and loss of fullness. It is desirable to provide conditioning without suffering from these disadvantages. An attempt to do this is described in the EPO Patent Publication No. 0 413 416, published on February 20, 1991, by Robbins et al., Which discloses a shampoo containing aminosilicone, anionic surfactant, cationic surfactant, and a hydrocarbon component. These types of formulations will normally be expected to result in an excessive accumulation of aminosilicone in the hair, and consequently a greasy hair feeling and loss of fullness, or a relatively limited degree of improvement due to the intentional use of very low levels of aminosilicone for avoid the adverse effects. The cationic surfactants would have limited ability to condition the hair due to the interaction with the anionic surfactant. The publication of the patent application EPO No. 0 413 417, published on February 20, 1991, discloses a shampoo containing an anionic surfactant and conditioning agents such as insoluble silicone (preferably, aminosilicone), cationic surfactant, polyethylenes, paraffins, microcrystalline waxes, fatty acids from 18 to 36 carbon atoms, or triglycerides, esters of higher fatty alcohols of higher fatty acids, and beeswaxes. Another patent document describing shampoo compositions and a variety of conditioning agents, in North American Patent No. 3,964.50, by Drakoff, issued June 22, 1976. This patent discloses a shampoo containing a silicone conditioner and a hair-incorporating agent selected from wood turpentine resins, shellac, sucrose acetate isobutyrate, and cationic aminocellulose. A recent approach to providing hair conditioning benefits to shampoo is described in U.S. Patent No. 5,085,857 (Reid et al.). The composition described combines a system of surfactant (selected from anionic, nonionic, amphoteric, or mixtures thereof), polymer derived from cationic guar and non-volatile silicone having a particle size of less than 2 microns. Without being bound by any theory, applicants have found that by using a selected cationic cellulose derivative polymer, instead of the cationic guar derivative polymer in a specific surfactant system, which optimizes the formed coacervate conditioner, the present invention results in a conditioning performance, significantly improved. Despite these approaches and attempts to provide optimal combinations of shampoos and hair conditioners, it remains desirable in providing improved shampoos and conditioners. It has now been found that complete conditioning can be achieved by combining a specific surfactant component comprising an ethoxylated alkyl sulfate surfactant having from about 1 to about 8 moles of ethoxylation and an amphoteric surfactant in a shampoo. with a non-ionic, dispersed, insoluble, conditioning agent, and a hair-conditioning agent, of organic, cationic, cellulose, soluble polymer. These compositions can provide improved conditioning, while reducing the level of undesirable side effects that result from increased level of conditioning in prior known conditioning systems. As discussed previously, a conditioning agent system that contains too much silicone can result in an accumulation of silicone in the hair during repeated uses and a loss of fullness of the hair. Too much oil results in an oily sensation and a loss of fullness of the hair. Too much cationic conditioning agent results in a messy, hair-coated sensation. It has now been found that the components of the present invention can provide complete, improved conditioning, while minimizing the adverse effects of the build-up of the conditioning agent, which may otherwise be incurred by increasing the levels of the individual components in the known conditioning systems, above. It is an object of this invention to provide shampoo compositions, which can provide excellent P683 cleaning performance and improved conditioning levels, while minimizing any of the aqueous side effects associated with accumulation due to the use of excess conditioning agent. It is also an object of this invention to provide a method for cleansing and conditioning the hair that can provide excellent cleansing in combination with improved conditioning, while benefiting the adverse side effects associated with the excess accumulation of the hair conditioning agent. These objects will become apparent from the description that follows, since many other objects will become apparent in a reading of this description.

SUMMARY OF THE INVENTION The present invention is directed to hair conditioning shampoo compositions, comprising: a) From about 5.0% to about 50% of a surfactant component, comprising: i) an alkyl sulfate surfactant, ethoxylated having from about 1 to about 8 moles of P683 ethoxylation, and ii) an amphoteric surfactant; b) from about 0.01% to about 3.0% of a cellulosic, cationic polymer, having a molecular weight of from about 400,000 to about 1,500,000 and a charge density of from about 0.6 to about 3 meq / gram; c) from about 0.005% to about 5% of a water-insoluble, non-volatile conditioning agent having an average particle size below about 4 microns; and d) an aqueous carrier wherein the composition comprises less than 5% of the ethoxylated alkyl sulfate surfactant having less than 1 mole of ethoxylation and wherein the content of the synthetic ester represents from 2.5% to 100% by weight of the total content of the liquid fatty ester of the composition. Shampoo compositions provide improved conditioning performance, including an improved feeling of damp hair P683 DETAILED DESCRIPTION OF THE INVENTION The shampoo compositions of the present invention may comprise, consist of, or consist essentially of the essential elements and limitations of the invention described herein, as well as of any additional or optional ingredients, components, or limitations described herein. All percentages, parts and ratios are based on the total weight of the shampoo compositions of the present invention, unless otherwise specified. All of these weights since they correspond to the ingredients listed are based on the active level and therefore do not include carriers or by-products that can be included in the commercially available materials, unless otherwise specified. As used herein, the term "soluble" refers to any material that is sufficiently soluble in water to form a substantially clear solution to the naked eye at a concentration of 0.1% by weight of the material in water at 25 ° C. Conversely, the term "insoluble" refers to all other materials that are therefore not sufficiently soluble in water to form a substantially clear solution to the naked eye at a concentration of 0.1% by weight of another material in water at 25 ° C. .

P683 As used herein, the term "liquid" refers to any visibly fluid fluid (by the naked eye) under ambient conditions (approximately one atmosphere of pressure at about 25 ° C). The shampoo compositions of the present invention, which include the essential and optional components thereof, are described in detail below.

Surfactant Agent Component Surfactant Agent Alkyl Ether The shampoo compositions of the present invention comprise from about 5.0% to about 50% of a surfactant, detergent component, comprising: i) an alkyl sulfate agent, ethoxylated, having from about 1 to about 8 moles of ethoxylation; and ii) an amphoteric surfactant component to provide a cleaning performance to the composition and wherein the resulting composition comprises less than about 5%, preferably less than about 3% and more preferably less than about 2% of the ethoxylated alkyl sulfate surfactant having less than 1 mole of ethoxylation. The component of surfactant, detergent, PG83 may optionally comprise additional surfactants. These surfactants must be physically and chemically compatible with the essential components described herein, or otherwise they should not undesirably prevent product stability, aesthetics or performance. The concentration of the surfactant component in the shampoo composition ranges from about 5% to about 50%, more preferably from about 8% to about 30%, more preferably from about 10% to about 25%, in the form even more preferred from about 12% to about 20%, the weight of the composition. The alkyl ether sulfates have the formula: RO (C2G40) xS03M, wherein R is alkyl or alkenyl from about 8 to about 24 carbon atoms, x is from 1 to 8, and M is a cation such as ammonium, alkanolamines, such as triethanolamine, monovalent metals, such as sodium and potassium, and polyvalent metal cations, such as magnesium and calcium. The cation M, of the detergent, anionic surfactant, must be chosen such that the surfactant component, detergent, is soluble in water. The solubility will depend on surfactants, detergents, anionics, P683, and the cations chosen. Preferably, R has from about 8 to about 18 carbon atoms, more preferably from about 10 to about 16 carbon atoms, more preferably from about 12 to about 14 carbon atoms, in both alkyl sulphates as of alkyl ether. Alkyl ether sulfates are typically made as condensation products of ethylene oxide and monohydric alcohols having from about 8 to about 24 carbon atoms. The alcohols can be derived from fatty acids, for example, coconut, palm or tallow oil, or can be synthetic. Lauryl alcohol or straight chain alcohols or derivatives of coconut or palm oil are preferred herein. These alcohols are reacted between about 1 and about 10, and especially about 3, molar proportions of ethylene oxide and the resulting mixture of the molecular species having, for example, an average of 3 moles of ethylene oxide per mole of alcohol , it sulfates and neutralizes. The highly preferred alkyl ether sulfates are those comprising a mixture of individual compounds, this mixture having an average alkyl chain length of about 10.

P683 up to about 16 carbon atoms and an intermediate degree of ethoxylation from about 1 to about 4 moles of ethylene oxide.

Amphoteric Surfactant The surfactant, amphoteric, suitable components for use in the shampoo composition herein include those that are known for use in shampoo or other personal care cleansing compositions, and that contain a group which is anionic to the pH of the shampoo composition. The concentration of these surfactant components in the shampoo composition preferably ranges from about 0.5% to about 20%, more preferably from about 1% to about 10%, more preferably from about 2% to about 5% in the composition. weight of the composition. Examples of amphoteric surfactants suitable for the use of a shampoo composition herein are described in US Pat. Nos. 5,104,646 (Bolich Jr et al.), US Pat. Nos. 5,106.09 (Bolich Jr, et al.) Descriptions. which are incorporated herein by reference. Examples of surfactants, detergents, amphoteric agents, which can be used P683 in the compositions of the present invention are those that are widely described as derivatives of secondary and tertiary amines, aliphatic in which the aliphatic radical can be straight or branched chain and wherein one of the aliphatic substituents contains from about 8 to about 18 carbon atoms and one contains a solubilization group in water, anionic, for example, carboxy, sulfonate, sulfate, phosphate or phosphonate. Examples of the compounds falling within this definition are sodium 3-dodecyl aminopropionate, sodium 3-dodecylamino propanes sulphonate, sodium lauryl sarcosinate, N-alkyl taurines such as that prepared by reacting dodecylamine with sodium isethionate. according to the teaching of U.S. Patent No. 2,658,072, N-higher alkyl aspartic acids such as those produced in accordance with the teaching of US Patent No. 2,658,072 N-higher alkyl aspartic acids such as those produced in accordance with US Pat. the teaching of US Patent No. 2,438,091 and the products sold under the trade name "MIRANOLMR" described in US Patent No. 2,528,378. Other amphoteric surfactants, sometimes classified as zwitterionic, such as betaines may also be useful herein P683 invention. These zwitterionics are considered to be amphoteric in the present invention, where the zwitterionic has a bound group and is anionic at the pH of the composition. Examples of betaines useful herein include higher alkyl betaines, such as dimethyl-carboxymethyl-betaine, cocoamidopropyl-betaine, cocobetaine, lauryl-amidopropyl-betaine, oleyl-betaine, lauryl-dimethyl-carboxymethyl-betaine, lauryl-dimethyl- alphacarboxyethyl-betaine, cetyl-dimethyl-carboxymethiol-betaine, lauryl-bis. (2-hydroxyethyl) carboxymethyl-betaine, stearyl-bis- (2-hydroxypropyl) carboxymethyl-betaine, oleyl-dimethyl-gamma-carboxypropyl-betaine, and lauryl-bis- (2-hydroxypropyl) alpha-carboxyethyl-betaine. The sulfobetaines can be represented by coco-dimethyl-sulfopropyl-betaine, stearyl-dimethyl-sulfopropyl-betaine, lauryl-dimethyl-sulfoethyl-betaine, lauryl-bis- (2-hydroxyethyl) -sulfopropyl-betaine and the like; amidobetaines and amidosulfobetaines, wherein the radical RCONH (CH2) 3 is bonded to the nitrogen atom of betaine, are also useful in this invention. Most preferred for use herein is cocoamidopropyl betaine. The shampoo compositions of the present invention may further comprise surfactants, detergents, further for use in combination with the surfactant, detergent, anionic component, P683 described hereinabove. Suitable optional surfactants include nonionic surfactants, cationic surfactants, and combinations thereof. Any surfactant known in the art for use in personal care products on the hair may be used, provided that the optional additional surfactant is also chemically and physically compatible with the essential components of the shampoo composition, or does not unduly damage the performance, aesthetics or stability of the product. The concentration of additional, optional, surfactants in the shampoo composition can vary with the desired cleaning or foam performance, the optional surfactant selected, the concentration of the desired product, the presence of other components in the composition, and other factors well known in the art. Preferred for use are the surfactants, detergents, anionics, optionals, which can be used in addition to the alkyl ether sulfates, are the water soluble salts of the organic sulfuric acid reaction products of the general formula [R ^ SOj-M] where RL is selected from the group consisting of a straight or branched chain, saturated, aliphatic hydrocarbon radical, having from about 8 P683 to about 24, preferably from about 10 to about 18, carbon atoms; and M is a cation, as previously described, subject to the same limitations with respect to the cations of polyvalent metals as discussed previously. Examples of these detergent surfactants are the salts of an organic sulfuric acid reaction product of a hydrocarbon of the methane series, including the iso-neo-, and n-paraffins having from about 8 to about 24 atoms carbon, preferably from about 12 to about 18 carbon atoms, and a sulfonating agent, for example, S03, H2SO4, contained according to the known sulfonation methods, including bleaching and hydrolysis. Preferred are n-paraffins of 10 to 18 carbon atoms, sulfonated alkali metals and ammonium. Still other suitable surfactants, detergents, anionics, are the reaction products of the fatty acids esterified with isethionic acid and neutralized with sodium hydroxide, where, for example, the fatty acids are derived from coconut oil or oil. palm; sodium or potassium salts of fatty acid amides of methyl tauride in which the fatty acids, for example, are derived from coconut oil P683 or palm oil. Other, anionic, similar surfactants are disclosed in U.S. Patent No. 2,486,921; U.S. Patent No. 2,486,922; and U.S. Patent No. 2,396,278, descriptions which are incorporated herein by reference. Other surfactants, detergents, anionics, suitable for use in shampoo compositions are succinates, examples of which include disodium N-octadecylsulphosuccinate, disodium lauryl sulfosuccinate; diammonium lauryl sulfosuccinate; N- (1,2-dicarboxyethyl) -N-octadecylsulfosuccinate tetrasodium; diamyl ether of sodium sulfosuccinic acid; dihexyl ester of sodium sulfosuccinic acid; dioctyl esters of sodium sulfosuccinic acid. Other suitable anionic detergent surfactants include olefin sulfonates having from about 10 to about 24 carbon atoms. The term "olefin sulfonates" is used herein to mean compounds that can be produced by the sulfonation of the alpha-olefins by means of sulfur trioxide, not rendered complex, followed by neutralization of the acidic reaction mixture in conditions such that any sulfone that has been formed in the reaction is hydrolyzed to give the hydroxy- P683 corresponding alkanesulfonates. Sulfur trioxide may be liquid or gaseous, and usually, but not necessarily, divided by inert ingredients, for example, by liquid S02, chlorinated hydrocarbons, etc., when used in the liquid form, or by air, nitrogen, S02 gaseous, etc., when used in the gaseous form. The alpha-olefins from which the olefin sulfonates are derived are the mono-olefins having from about 10 to about 24 carbon atoms, preferably from about 12 to about 16 carbon atoms. Preferably, they are the straight chain olefins. In addition to the true alkene sulfonates of a proportion of hydroxy alkane sulphonates, the olefin sulfonates may contain minor amounts of other materials, such as alkene disulfonates, depending on the reaction conditions, proportion of the reactants, the nature of the olefins. of start and impurities in the side and concentrated reactions of olefin, during the sulphonation process. A mixture of alpha-olefin sulfonate, specific, of the above type, is described more fully in U.S. Patent No. 3,332,880, which description is incorporated herein by reference.

P683 Another class of detergent, anionic surfactants suitable for use in shampoo compositions are the beta-alkyloxy alkane sulphonates. These compounds have the following formula: wherein R1 is a straight chain alkyl group having from about 6 to about 20 carbon atoms; R2 is a lower alkyl group having from about 1 (preferred) to about 3 carbon atoms, and M is a water-soluble cation as described hereinabove. Preferred additional, anionic, detergent surfactants for use in shampoo compositions include ammonium lauryl sulfate, ammonium laureth sulfate, triethylamine lauryl sulfate, triethylamine laureth sulfate, triethanolamine lauryl sulfate, and laureth. triethanolamine sulfate, monoethanolamine lauryl sulfate, monoethanolamine laureth sulfate, diethanolamine lauryl sulfate, diethanolamine laureth sulfate, lauric monoglyceride sodium sulfate, sodium lauryl sulfate, sodium laureth sulfate, lauryl sulfate potassium, potassium laureth sulfate, sodium lauryl sarcocinate, P683 sodium lauroyl sarcocinate, lauryl sarcocin, cocoyl-sarcosine, ammonium cocoyl sulfate, ammonium lauroyl sulfate, sodium cocoyl sulfate, sodium lauroyl sulfate, potassium cocoyl sulfate, potassium lauryl sulfate, lauryl potassium sulfate, triethanolamine lauryl sulfate, triethanolamine lauryl sulfate, triethanolamine lauryl sulfate, monoethanolamine cocoyl sulfate, monoethanolamine lauryl sulfate, sodium tridecylbenzenesulfonate, sodium dodecylbenzenesulfonate , and combinations thereof.

Polymer Hair Conditioner, Cationic Polymeric, cellulose, cationic polymer materials, suitable for use herein, include those of the formula: Rl A-O (-fc-N + R3X *) wherein: A is a cellulose glucose anhydride residue; R is an alkylene, opxyalkylene, polyoxyalkylene, or hydroxyalkylene group, or combinations of P683 the same, R1, R2 and R3 are independently alkyl, aryl, alkylaryl, arylalkyl, alkoxyalkyl or alkoxyaryl groups, each group containing up to about 18 carbon atoms, and the total number of carbon atoms for each cationic portion (is say, the sum of carbon atoms in R1, R2 and R3) which is preferably close to 20 or less, and X is an anionic counterion, as previously described. The cellulosic, cationic polymer has a molecular weight ranging from about 400,000 to about 1,500,000, preferably from about 500,000 to about 1,500,000, and more preferably from about 800,000 to about 1,200,000, and a loading speed from about 0.6 to about about 3 meq / gram, preferably from about 0.7 to about 2.0 meq / gram, more preferably from about 0.9 to about 1.5 meq / gram. Cationic cellulose is available from Amerchol Corp. (Edison, NJ, USA) in its Polymer JR and LR series of polymers, as salts of hydroxyethylcellulose reacted with trimethylammonium substituted epoxide, referred to in the industry (CTFA) as Polyquaternium 10 .

P683 The cationic, water soluble, described herein, are either soluble in the shampoo composition, or are preferably soluble in a complex coacervate phase in the shampoo composition formed by the cationic polymer and the anionic surfactant described above. at the moment. Complex coacervates of the cationic polymer can also be formed with other optional anionic components of the shampoo composition. The formation of the coacervate is dependent on a variety of criteria - such as molecular weight, concentration of the components, and ratio of the ionic interacting components, ion concentration (including modification of the ionic concentration, for example, by the addition of salts) , charge density of the cationic and anionic components, pH and temperature. Coacervate systems and the effects of these parameters have been described, for example, by J. Caelles et al., "Anionic and Cationic Compounds in Mixed Systems", Cosmetics & Toiletries, Vol. 106, April 1991, pages 49-54, C. J. Van Oss, "Coacervation, complex-Coacervation and Flocculation"; J. Dispersion Science and Technology, Vol. 9 (5,6), 1988-89, pages 561-573, and DJ Burgess, "Practical Analysis of Complex Coacervate Systems", J. Of Colloid and Interface Science, Vol. 140, No. 1, November P683 1990, pages 227-238, descriptions which are incorporated herein by reference. It is believed to be particularly advantageous for the cationic polymer to be present in the shampoo composition in a coacervate phase or to form a coacervate phase in application or rinse of the shampoo to hair, or hair. Complex coacervates are thought to settle more easily on the hair. Thus, in general, it is preferred that the cationic polymer exists in the shampoo composition as a coacervate form or forms a coacervate phase in the dilution. If there is no coacervate in the shampoo composition, the cationic polymer will preferably exist in a complex coacervate form in the shampoo in the direction with the water. Techniques for the analysis of complex coacervate formation are known in the art. For example, microscopic analyzes of the shampoo compositions, at any chosen dilution stage, can be used to identify whether a coacervate phase has been formed. This coacervate phase can be identified as an additional emulsified phase in the composition. The use of dyes can help in the distinction of the coacervate phase from other insoluble phases, dispersed in the shampoo composition.

P683 Insoluble Hair Conditioner The shampoo compositions of the present invention further comprise an insoluble hair conditioning agent at concentrations effective to provide hair conditioning benefits. These concentrations generally range from about 0.005% to about 5%, preferably from about 0.05% to about 4%, more preferably from about 0.1% to about 3.5%, more preferably from about 0.2% to about 3 %, the weight of the shampoo compositions. The insoluble hair conditioning particles useful in the present invention have a particle size range below about 4 microns, preferably below about 1 micron, more preferably below about 0.5 microns. Useful conditioning agents include silicone and petrolatum.

Hair Conditioning Agent, Silicone More volatile, silicone conditioning agents are more preferred for use herein. Typically, they will be intermixed in the shampoo composition to be in the form of a discontinuous phase, P683 separated, of insoluble, dispersed particles, also referred to as drops. These drops can be dispersed with a dispersion source described hereinafter. The silicone hair conditioning agent phase will comprise a hair conditioning, of silicone fluid, such as a silicone fluid and may also comprise other ingredients such as a silicone resin to improve the efficiency of deposition of the silicone fluid or improving hair shine (especially when using silicone conditioning agents (e.g., highly phenylated silicones), of high refractive index (e.g., above about 1.46.) As used herein, "non-volatile" "refers to silicone material with little or no significant vapor pressure under ambient conditions, as understood by those skilled in the art.The boiling point under one atmosphere (atm) will preferably be at least about 25 ° C, in the form more preferably at least about 275 ° C, more preferably at least about 300 ° C. The vapor pressure is preferably and about 0.2 mm HG at 25 ° C or less, preferably about 0.1 mm HG at 25 ° C or less. The conditioning phase of the silicone hair should comprise volatile silicone, silicone not P683 volatile, or mixtures thereof. Typically, if volatile silicones are present, they will be incidental to their use as a solvent or carrier for commercially available forms of ingredients of non-volatile silicone materials, such as gums and silicone resins. Silicone hair conditioning agents for use in shampoo compositions preferably have a viscosity of from about 20 to about 2,000,000 centistokes, more preferably from about 1,000 to about 1,800,000 centistokes, even more preferably from about 10,000 to about 1,500,000 centistokes, more preferably from about 30,000 to about 1,000,000 centistokes, at 25 ° C. The viscosity can be measured by means of a glass capillary viscometer as set forth in test method CTM0004 of Dow Corning Corporate, July 20, 1970. Optional silicone fluid for use in shampoo compositions includes silicone which are fluid silicone materials with a viscosity of less than 1,000,000 centistokes, preferably between about 5 and 1,000,000 centistokes, more preferably between about 10 and about 600,000 centistokes, most preferably between P683 approximately 10 and approximately 500, 100,000 centistokes, more preferably between 10 and 300,000 centistokes at 25 ° C. Suitable silicone oils include polyethylsiloxanes, polyarylsiloxanes, polyalkyl aryl siloxanes, polyether siloxane copolymers, and mixtures thereof. Other non-volatile, insoluble silicone fluids having hair conditioning properties can also be used. Optional silicone oils for use in the composition include polyalkyl or polyaryl-siloxanes that conform to the following formula: where R is preferably aliphatic alkyl or alkenyl, or aryl, R may be substituted or unsubstituted, and x is an integer of 1 to about 8,000. Suitable unsubstituted R groups include alkoxy, aryloxy, alkaryl, arylalkyl, arylalkenyl, alkanamino, and aryl and aliphatic groups, substituted with halogen and substituted with hydroxyl, substituted with ether. Suitable R groups also include cationic amines and quaternary ammonium groups.

P683 Aliphatic or substituted aryl groups in the siloxane chain can have any structure so long as the resulting silicones remain fluid at room temperature, are hydrophobic, non-irritant, toxic or otherwise dangerous when applied to hair, are compatible with the other components of the shampoo compositions, are chemically stable under normal use and storage conditions, are insoluble in the shampoo compositions, and are capable of being deposited on, and conditioned, the hair. The two R groups on the silicon atom of each monomeric silicone unit can represent the same group or different groups, preferably the two L groups represent the same group. Preferred alkyl and alkenyl substituents are alkyls and alkenyls of 1 to 5 carbon atoms, more preferably 1 to 4 carbon atoms, more preferably 1 to 2 carbon atoms. The aliphatic portions of the groups containing alkyl, alkenyl or alkynyl (such as alkoxy, alkaryl and alkanamino) can be straight or branched chains and preferably have from one to five carbon atoms, more preferably from one to four carbon atoms , even more preferably from one to three P683 carbon atoms, more preferably from one to two carbon atoms. As discussed above, the R substituents herein may contain amino functionalities, for example, alkamino groups, which may be primary, secondary or tertiary amines or quaternary ammonium. These include mono-, di- and tri-alkylamino and alkoxyamino groups, wherein the chain length of the aliphatic portion is preferably as described above. The substituents R may also be substituted with other groups, for example, halogens (for example, chloride, fluoride and bromide), aliphatic or aryl groups, halogenated, and hydroxy (for example, aliphatic groups substituted with hydroxy.) The appropriate halogenated R groups they may include, for example, tri-halogenated alkyl groups (preferably fluorine) such as -R1-C (F) 3, wherein R1 is alkyl of 1 to 3 carbon atoms Examples of these polysiloxanes include poly-3, 3 3-trifluoropropylsiloxane Suitable R groups include methyl, ethyl, propyl, phenyl, methylphenyl and phenylmethyl Preferred silicones are polydimethylsiloxane, polydiethylsiloxane and polymethylphenylsiloxane Polydimethylsiloxane is especially preferred Other suitable R groups include methyl, methoxy, ethoxy , propoxy and aryloxy.The three R groups in the end caps of the silicone can P683 also represent the same or different groups. Non-volatile polyalkylsiloxane fluids which may be used include, for example, polydimethylsiloxanes. These siloxanes are available, for example, from General Electric Company in their Viscasil R and SF 96 series, and from Dow Corning and their Dow Corning 200 series. The polyalkyl aryl siloxane fluids, which can be used, also include, for example , polymethylphenylsiloxanes. These siloxanes are available, for example, from the General Electric Company as the SF 1075 methyl phenyl fluid or from Dow Corning as the cosmetic grade fluid 556. The polyether siloxane copolymers, which can be used, include, for example, a polydimethylsiloxane modified with polypropylene oxide (for example, Dow Corning DC-1248) although ethylene oxide or mixtures of ethylene oxide and propylene oxide can also be used. The level of ethylene oxide and polypropylene oxide should be sufficiently low to prevent solubility in water and the composition herein. Suitable substituted alkylamino silicones include those that conform to the following formula: P683 where x and y are integers. This polymer is also known as "amodimethicone". Suitable silicone, cationic fluids include those that conform to the formula described hereinabove, wherein (Rx) aG3_a-Si (-OSiG2) n - (- OSiGb (Rx) 2-b) m-0 -SiG3-a (R?) A in which G is chosen from the group consisting of hydrogen, phenyl, OH, alkyl of 1 to 8 carbon atoms, and preferably methyl; a denotes an integer from 1 to 3, and preferably equal to 0; b denotes = o 1 and preferably equal to l; the sum n + m is a number from 1 to 2,000, and preferably from 50 to 150, n which is capable of denoting a number from 0 to 1999 and preferably from 49 to 149 and m which is capable of denoting an integer of 1 to 2000, and preferably from 1 to 10; Rl is a monovalent radical of the formula CqH2qL in which q is an integer from 2 to 8, and L is chosen from the groups.

P683 -N (R2) CH2-CH2-N (R2) 2 -N (R2) 2 -N (R2) 3A- -N (R2) CH2-CH2-NR2H2A- in which R2 is selected from the group it consists of hydrogen, phenyl, benzyl, a saturated hydrocarbon radical, preferably an alkyl radical containing from 1 to 20 carbon atoms, and A- denotes a halide ion. A silicone, cationic, especially preferred, which corresponds to the previous formula is the polymer known as "trimethylsilylamodimethicone", which conforms to the following formula: m Other cationic, silicone polymers that can be used in shampoo compositions are those that conform to the following formula: P683 where R3 denotes a monovalent hydrocarbon radical, having from 1 to 18 carbon atoms, preferably an alkyl or alkenyl radical such as methyl; R4 denotes a hydrocarbon radical, preferably an alkylene radical of 1 to 18 carbon atoms or alkyleneoxy, of 1 to 18 carbon atoms, and preferably 1 to 8 carbon atoms; Q- is a halide ion, preferably chloride; r denotes an average statistical value of 2 to 20, preferably 2 to 8; s denotes an average statistical value of 20 to 200, and preferably 20 to 50. A preferred polymer of this class is available from Union Carbide under the name "UCAR SILICONE ALE 56." Other silicone fluids, suitable for use in silicone conditioning agents, are insoluble silicone gums. These gums are polyorganosiloxane materials that have a viscosity 25 ° C of more than or equal to 1,000,000 centistokes. Silicone gums are described in U.S. Patent No. 4,152,416; by Noli y Walter, Chemistry and Technology of Silicones, New P683 York: Academis Press 1968; and in General Electric Silicone Rubber Product Data Sheets SE 30, SE 33, SE 54 and SE 76, all of which are incorporated herein by reference. Silicone gums will typically have a mass molecular weight in excess of 200,000, generally between about 200,000 and about 1,000,000, specific examples of which include polydimethylsiloxane, (polydimethylsiloxane) copolymer (methylvinylsiloxane), poly (dimethylsiloxane) copolymer ( diphenyl siloxane) (methylvinylsiloxane), and mixtures thereof. The silicone hair conditioning agent may also comprise a mixture of polydimethylsiloxane gum (viscosity greater than 1,000,000 centistokes) and polydimethylsiloxane oil (viscosity of about 10 to about 100,000 centistokes), wherein the ratio of the gum to the fluid is from about 30:70 to about 70:30, preferably from about 40:60 to about 60:40. Another category of insoluble, non-volatile, silicone fluid conditioning agents are high refractive index silicones, which have a refractive index of at least about 1.46, preferably at least about 1.48, more preferably Preferred P683 at least about 1.52, more preferably at least about 1.55. Although not intended to be necessarily limited, the refractive index of the polysiloxane fluid will generally be less than about 1.70, typically less than about 1.60. The "fluid" of polysiloxane includes oils as well as gums. The high refractive index polysiloxane fluid, suitable for the purposes herein, includes those that conform to the formula described hereinbefore, as well as the cyclic polysiloxanes such as those that conform to the following formula: wherein R is as defined above, n is from about 3 to about 7, preferably from 3 to 5. The high refractive index polysiloxane fluids contain a sufficient amount of substituents of R containing aryl, to increase the refractive index to the desired level, which is described P683 above. In addition, R and n must be selected so that the material is not volatile, as defined above. The substituents containing aryl contain 5 and 6 membered aryl rings, alicyclic and heterocyclic, and substituents containing 5 or 6 membered rings, fused. The aryl rings themselves can be substituted or unsubstituted. Substituents include substituents include aliphatic substituents, and may also include alkoxy substituents, acyl substituents, ketones, allogens (e.g., Cl and Br), amines, etc. Aryl-containing groups, for example, include substituted and unsubstituted lows, such as phenyl, and phenyl derivatives such as phenyls with alkyl or alkenyl substituents of 1 to 5 carbon atoms, for example, allylphenyl, methylphenyl and ethylphenyl, vinylphenyls, such as styrenyl, and phenyldolalkynes (for example, phenyl C2-C4 alkyne). Heterocyclic aryl groups include substituents derived from furan, imidazole, pyrol, pyridine, etc. Substituents of the fused aryl ring include, for example, naphthalene, comarin and purine. In general, polysiloxane fluids of high refractive index will have a degree of substituents containing aryl of at least about 15%, in the form P683 preferably at least about 20%, more preferably at least about 25%, even more preferably at least 35%, more preferably at least about 50%. Although it is not proposed to necessarily limit the invention, the degree of aryl substitution will be less than about 90%, more generally less than about 85%, preferably from about 55% to about 80%. Polysiloxane fluids are also characterized by relatively high surface tensions, as a result of aryl substitution. In general, the polysiloxane fluids herein will have a surface tension of at least about 24 dynes / cm2 typically at least about 27 dynes / cm2. The surface tension for the purpose of this is measured by a Nouy ring tensiometer according to test method CTM 0461, Dow Corning Corporate, November 23, 1971. Changes in surface tension can be measured in accordance with the previous test method or according to the ASTM 1331 method. Preferred high refractive index polysiloxane fluids have a combination of substituents derived from phenyl, or phenyl (preferably phenyl), with alkyl substituents, preferably alkyl of 1 to 4 carbon atoms (in P683 more preferably methyl), hydroxy, alkylamino of 1 to 4 carbon atoms (especially -R1NHR2NH2 where each R1 and R2 independently is alkyl of 1 to 3 carbon atoms, alkenyl and / or alkoxy) Polysiloxanes of high refractive index are available from Dow Corning Corporation (Midland, Michigan, USA) Huís America (Piscatciway, New Jersey, USA), and General Electric Silicones (Waterford, New York, USA.): It is preferred to use high refractive index silicones in solution with a propagation agent, such as a silicone resin or a surfactant, to reduce the surface tension by an amount sufficient to improve the spread and thereby improve the gloss (subsequent to drying) of the hair treated with the composition. , a sufficient amount of the propagation agent to reduce the surface tension of the high refractive index polysiloxane fluid by at least about 15%, preferably at least about 10%, more preferably at least about 15%, even more preferably at least about 20%, more preferably at least about 25%. Reductions in the surface tension of the polysiloxane fluid / spreading agent mixture can provide an improvement in hair shine.

P683 Also, the propagation agent will preferably reduce the surface tension by at least about 2 dynes / cm 2, preferably at least about 3 dynes / cm 2, even more preferably 4 dynes / cm 2, more preferably at least about 5 dynes / cm 2, more preferably at least about 5 dynes / cm 2, more preferably at least about 5 dynes / cm 2, more preferably at least about 5 dynes / cm 2, more preferably at least about 5 dynes / cm 2. dynes / cm2. The surface tension of the mixture of the polysiloxane fluid and the propagation agent, in the proportions presented in the final product, is preferably 30 dynes / cm 2 or less, more preferably at least about 28 dynes / cm 2 or less in more preferred at approximately 25 dynes / cm2 or less. Typically, the surface tension will be in the range of from about 15 to about 30, more typically from about 18 to about 28, and more generally from about 20 to about 25 dynes / cm2. The weight ratio of the highly arylated polysiloxane fluid to the propagation people will generally be between about 1000: 1 and about 1: 1, preferably between about 100: 1 to about 2: 1, more preferably between about 50. : 1 and about 2: 1, more preferably from about 25: 1 to about 2: 1. When fluorinated surfactants are used, P683 particularly high polysiloxane: propagation agent ratios can be effective due to the efficiency of their surfactants. In this way, it is contemplated that ratios can be used significantly above 1000: 1. References that describe the examples of some silicone fluids as suitable for use in shampoo compositions include U.S. Patent No. 2,826,551, U.S. Patent No. 3,964,500, U.S. Patent No. 4,364,837, U.S. Patent No. 849,433, and Silicon Compounds, Petrarch Systems, Ine (1984), all of which are incorporated herein by reference. The silicone resins can be included in the silicone conditioning agent. These resins are siloxane, polymeric, highly crosslinked systems. Crosslinking is introduced through the incorporation of trifunctional and tetrafunctional silanes with monofunctional or difunctional silanes, or both, during the manufacture of the silicone resin. As is well understood in the art, the degree of crosslinking that is required in order to result in a silicone resin will vary according to the specific silane units incorporated in the silicone resin. In general, silicone materials that have a sufficient level of P683 units of trifunctional and tetrafunctional siloxane monomer (and therefore, a sufficient level of crosslinking) such that they dry to a film, rigid or hard, are considered to be silicone resins. The ratio of oxygen atoms to silicon atoms is indicative of the level of crosslinking in a particular silicone material. The silicone materials having at least about 1.1 oxygen atoms per silicon atoms will generally be silicone resins herein. Preferably, the ratio of oxygen: silicon atoms is at least about 1.2: 1.0. The silanes used in the manufacture of silicone resins include monomethyl-, dimethyl-, trimethyl-, monophenyl-, diphenyl-, methylphenyl-, monovinyl-, and methylvinyl-chlorosilanes, and tetrachlorosilane, with the methyl-substituted silanes which are the most commonly used. Preferred resins are offered by General Electric as GE SS4230 and SS4267. Commercially available silicone resins will generally be supplied in a form dissolved in a silicone fluid, nonvolatile, or volatile, low viscosity. The silicone resins for use herein should be supplied and incorporated into the present compositions in the dissolved form, as will be readily apparent to those skilled in the art. The background material in the silicones that P683 include sections covering silicone fluids, gums and resins, as well as the manufacture of silicones, can be found in Encyclopedia of Polymer Science and Engineering, Volume 15, Second Edition, pp 204-308, John Wiley & Sons, Inc., 1989, incorporated herein by reference. The silicone materials and silicone resins in particular, can be conveniently identified according to a shorthand nomenclature system well known to those skilled in the art as the "MDTQ" nomenclature. Under this system, the silicone is described according to the presence of several siloxane monomer units, which constitute the silicone. Briefly, the symbol M denotes the monofunctional unit (CH3) 3Si0.5; D denotes the difunctional unit (CH3) 2SiO; T denotes the trifunctional unit (CH3) Si01 > 5; Q denotes the quatri or tetra-functional unit Si02. The cousins of the unit symbols, for example, M ', D', T 'and Q' denote different methyl substituents, and must be defined specifically for each occurrence. Typical alternative substituents include groups such as vinyl, phenyl, amines, hydroxyls, etc. The molar ratio of the various units, either in terms of the subscripts to the symbols indicating a total number of each type of unit in the silicone (or an average thereof) or as P683 relations specifically indicated in combination with the full molecular weight of the description of the silicone material under the MDTQ system. The relative, higher molar amounts of T, Q, T 'and / or Q' to D, D 'M and / or M' in a silicone resin is indicative of high levels of crosslinking. As discussed above, however, the total level of crosslinking can also be indicated by the oxygen to silicon ratio. The silicone resins for use herein that are preferred are MQ, MT, MTQ, MDT and MDTQ resins. In this way, the preferred silicone substituent is methyl. Especially preferred are MQ resins wherein the M: Q ratio is from about 0.5: 1.0 to about 1.5: 1.0 and the average molecular weight of the resin is from about 1000 to about 10,000. The weight ratio of the non-volatile silicone fluid, having a refractive index below 1.46, to the silicone resin component, when used, is preferably from about 4: 1 to about 400: 1, preferably this ratio is from about 9: 1 to about 200: 1, more preferably from about 19: 1 to about 100: 1, particularly, when the silicone fluid component is a P683 polydimethylsiloxane or a mixture of polydimethylsiloxane fluid and polydimethylsiloxane gum as described above. As for the silicone resin forms a part of the same phase in the compositions herein as the silicone fluid, i.e., the conditioning active, the sum of the fluid and resin should be included in the determination of the level of the agent silicone conditioner in the composition. The composition of the shampoo of the present invention may further comprise a dispersing or suspending agent for the conditioning agent, insoluble, these suspending agents are well known in the shampooing and conditioning art. Examples of some suitable suspending agents are described in U.S. Patent No. 4,741,855, U.S. Patent No. 4,788,006, U.S. Patent 4,702,272, U.S. Patent No. 2,798,053, which disclosures are incorporated herein by reference. Suitable suspending agents for use in combination with the insoluble conditioning agent include acyl derivatives, long chain amine oxides, xanthan gum, and carboxyvinyl polymers. Other suitable suspending agents include primary amines having a fatty alkyl position having at least about 16 carbon atoms, P683 secondary amines having two fatty alkyl portions, each having at least about 12 carbon atoms, di (hydrogenated tallow) phthalic acid amide, and cross-linked maleic vinyl ether-maleic anhydride copolymer. Other suspending agents, suitable for use in combination with the insoluble conditioning agent include those which can impart a gel-like viscosity to the composition, such as water-soluble or colloidally water-soluble polymers such as cellulose ethers (e.g. , methyl cellulose, hydroxybutyl methyl cellulose, hydroxypropyl cellulose, hydroxypropyl methyl cellulose, hydroxyethyl ethyl cellulose, and hydroxyethyl cellulose), guar gum, polyvinyl alcohol, polyvinyl pyrrolidone, hydroxypropyl guar gum, starch and starch derivatives, and other thickeners, modifiers of viscosity, gelation agents, and so on.

Water The shampoo compositions of the present invention comprise from about 20% to about 94%, preferably from about 50% to about 94%, more preferably from about 60% to about 85% by weight of water.

P683 Other Optional Components The shampoo compositions of the present invention may further comprise one or more optional components known for use in shampoo-conditioner compositions, provided that the optional components are physically and chemically compatible with the essential component described in present, or not otherwise wrongly damaging the stability, aesthetics or performance of the product. The concentrations of these optional components typically vary from about 0.001% to about 10% by weight of the shampoo compositions. Optional components include antistatic agents, dyes, organic solvents or diluents, pearlescent aids, foam boosters, additional surfactants or surfactant coagents (non-ionic, cationic, zwitterionic), pediculocides, pH adjusting agents, perfume, preservatives, proteins, active agents in the skin, dispersing agents, styling polymers, sunscreens, thickeners, vitamins and viscosity adjusting agents. This list of optional components does not mean that it is exclusive, and other optional components can be used.

P683 Manufacturing Method The shampoo compositions of the present invention can be prepared by using various formulation and mixing techniques or methods known in the art for preparing surfactant or conditioning compositions, or other similar compositions.

Method of Use The shampoo compositions of the present invention are used in a conventional manner to clean and condition the hair or skin. An effective amount of the composition is applied to clean and condition the hair or skin to the hair or skin, which has been preferably wetted with water, and then thoroughly rinsed. These effective amounts vary in general from about 1 g to about 50 g, preferably from about 1 g to about 20 g. Application to the hair typically includes the work of the composition through the hair such that most or all of the hair is brought into contact with the composition. This method for cleaning and conditioning the hair comprises the steps of: a) wetting the hair with water b) applying an effective amount of the shampoo composition to the hair and c) P683 rinse the hair shampoo composition using water. These steps can be repeated as many times as desired to achieve the desired benefit of cleaning and conditioning.

EXAMPLES The shampoo compositions illustrated in Examples I-XV illustrate specific embodiments of the shampoo compositions of the present invention, but are not intended to limit the same Other modifications may be understood by those skilled in the art without departing from the spirit and scope of this invention. These exemplary embodiments of the shampoo compositions of the present invention provide for hair cleansing and improved hair conditioning performance. All the exemplified compositions can be prepared by conventional formulation and mixing techniques. The amounts of the components are listed as hundreds by weight and exclude minor materials such as diluents, filling agent, and so on. Therefore, the formulations listed, comprise the listed components and any minor material associated with these components P683 Component Example Number I II III IV V Laureth-3 Ammonium sulphate 14.00 14.00 14.00 14.00 14.00 Cocamidopropylbetaine 2.70 2.70 2.70 2.70 2.70 Polyquaternium-10 (3) 0.15 0.15 0.05 0.30 0.15 Cocamide MEA 0.80 0.80 0.80 0.80 0.80 Cetyl Alcohol 0.42 0.42 0.42 0.42 0.42 0.42 0.42 0.50 0.50 0.37 0.37 0.70 0.70 0.70 0.70 0.70 0.70 0.70 0.70 0.70 0.70 0.70 0.70 0.70 0.70 0.70 0.70 0.70 0.75 0.37 0.37 0.37 0.37 (ppm) 64 64 64 64 64 Water and minors r, _ ~-1 nn a- P683 Component Number of Example I II III IV V Laureth-3 Ammonium sulphate 14.00 11.75 12.50 14.85 12.50 Cocamidopropyl betaine 2.70 2.25 4.20 1.85 4.20 Polyquaternium-10 (3) 0.15 0.13 0.15 0.15 0.15 Cocamicla MEA 0.80 0.80 0.80 0.80 0 Cetyl Alcohol 0 0.42 0.42 0.42 0.42 Stearyl Alcohol 0 0.18 0.18 0.18 0.18 Ethylene glycol distearate 1.50 1.50 1.50 1.50 1.50 Dimethicone (1) 1.00 3.00 1.00 1.00 1.00 Perfume solution 0.70 0.70 0.70 0.70 0.70 DMDM hydantoin 0.37 0.37 0.37 0.37 0.37 Color Solution (ppm) 64 64 64 64 64 Water and minors c.s for 100% P683 Component Example Number I II III IV V Laureth-3 Ammonium sulphate 14.00 14.00 14.00 10.00 10.00 Cocamidopropylbetaine 2.70 2.70 2.70 2.00 2.00 Polyquaternium-10 (3) 0.15 0.15 0.15 0.10 0.10 Cocamide MEA 0.80 0.80 0.80 0.60 Cetyl Alcohol 0 0.42 0 0.42 0 Stearyl alcohol 0 0.18 0 0.18 0 Ethylene glycol distearate 0 0 0 1.50 1.50 Carbopol 981 (2) 0.50 0.50 0.50 0 0 Dimethicone (1) 1.00 1.00 1.00 1.00 0.50 Perfume solution 0.70 0.70 0.70 0.70 0.70 DMDM hydantoin 0.37 0.37 0.37 0.37 0.37 Color Solution (ppm) 64 64 64 64 64 Water and minors _ ~ _ 1 a- (1) Dimethicone is a 60,000 csk polydimethylsiloxane solution with particle size of about 300 in nm available from Dow Corning (DC 1664). (2) Carbopol 981 is a crosslinked polyacrylate available from B.F. Goodrich. (3) Polyquaternium-10 JR30M is a polymer derived from cationic cellulose commercially available from Amerchol.

P683

Claims (15)

1. CLAIMS: 1. An aqueous shampoo composition, comprising: a) from about 5.0% to about 50% of a surfactant component, comprising: i) an ethoxylated alkyl sulfate surfactant, having from about 1 to about 8 moles of ethoxylation; and ii) an amphoteric surfactant; b) from about 0.01% to about 3.0% of a cellulosic, cationic polymer, having a molecular weight of from about 400,000 to about 1,500,000 and a charge density of from about 0.6 to about 3 meq / gram; c) from about 0.005% to about 5% of a water-insoluble, non-volatile silicone conditioning agent having an average particle size below about 4 microns; and d) an aqueous carrier wherein the composition comprises less than about 5% of the ethoxylated alkyl sulfate surfactant having less than 1 mole of ethoxylation. P683 2. An aqueous shampoo composition according to claim 1, comprising from about 8.0% to about 30% of the surfactant component, and wherein the composition comprises less than about 3% ethoxylated surfactant having less than 1 mole of ethoxylation and wherein the amphoteric surfactant is cocoamidopropyl betaine and wherein the non-volatile conditioning agent is a silicone. 3. An aqueous shampoo composition according to claim 2, wherein the non-volatile silicone conditioning agent is selected from the group consisting of polyaryl siloxanes, polyalkyl siloxanes, polyalkylaryl siloxanes, derivatives thereof, and mixtures thereof. 4. An aqueous shampoo composition according to claim 1, wherein the non-volatile silicone conditioning agent has an average particle size of less than less than about 1 miera. 5. An aqueous shampoo composition according to claim 4, wherein the non-volatile silicone conditioning agent has an average particle size of less than about 0.5 microns. 6. An aqueous shampoo composition according to claim 3, wherein the conditioning agent of P683 silicone, non-volatile, is polydimethylsiloxane. 7. An aqueous shampoo composition according to claim 1, wherein the cationic polymer hair conditioning agent has a cationic charge density from about 0.7 meq / gram to about 2.0 meq / gram. 8. An aqueous shampoo composition according to claim 2, wherein the composition comprises an additional, anionic surfactant, wherein the composition comprises less than about 2% of the ethoxylated surfactant having less than 1 mole of ethoxylation. 9. An aqueous shampoo composition according to claim 7, wherein the hair conditioning agent of cellulosic polymer, cationic, is polyquaternium-10. 10. An aqueous shampoo composition according to claim 7, wherein cationic cellulosic polymer conditioning agent has a cationic charge density from about 0.9 meq / gram to about meq / gram. 11. An aqueous shampoo composition according to claim 2, wherein the amphoteric surfactant is cocoamidopropyl betaine and comprises from about 1% to about 10% of the P683 composition. 12. An aqueous shampoo composition according to claim 11, wherein the amphoteric surfactant is cocoamidopropyl betaine and comprises from about 2% to about 5% of the composition. 13. An aqueous shampoo composition according to claim 1, wherein the non-volatile silicone conditioning agent comprises from about 0.05% to about 4% of the composition. 14. An aqueous shampoo composition according to claim 1, wherein the non-volatile silicone conditioning agent comprises from about 0.2% to about 3% of the composition. 15. An aqueous shampoo composition according to claim 14, wherein the hair conditioning agent, cationic polymer, has a molecular weight from about 800.00 to about 120000,000. P683