MXPA97008773A - Resistant cosmetics that does not co - Google Patents
Resistant cosmetics that does not coInfo
- Publication number
- MXPA97008773A MXPA97008773A MXPA/A/1997/008773A MX9708773A MXPA97008773A MX PA97008773 A MXPA97008773 A MX PA97008773A MX 9708773 A MX9708773 A MX 9708773A MX PA97008773 A MXPA97008773 A MX PA97008773A
- Authority
- MX
- Mexico
- Prior art keywords
- cosmetic
- composition
- finish
- improves
- parts
- Prior art date
Links
- 239000002537 cosmetic Substances 0.000 title claims abstract description 194
- 239000000203 mixture Substances 0.000 claims abstract description 198
- 239000000049 pigment Substances 0.000 claims abstract description 57
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 29
- 238000009472 formulation Methods 0.000 claims abstract description 23
- 238000000034 method Methods 0.000 claims abstract description 23
- 150000001875 compounds Chemical class 0.000 claims abstract description 19
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000001856 Ethyl cellulose Substances 0.000 claims abstract description 14
- 235000019325 ethyl cellulose Nutrition 0.000 claims abstract description 14
- 229920001249 ethyl cellulose Polymers 0.000 claims abstract description 14
- 239000002904 solvent Substances 0.000 claims abstract description 8
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 5
- 239000004014 plasticizer Substances 0.000 claims abstract description 5
- 238000009825 accumulation Methods 0.000 claims abstract description 3
- 229960004667 ethyl cellulose Drugs 0.000 claims abstract 7
- 230000001681 protective effect Effects 0.000 claims abstract 2
- 239000000779 smoke Substances 0.000 claims abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 52
- 229920001577 copolymer Polymers 0.000 claims description 38
- 239000011347 resin Substances 0.000 claims description 32
- 229920005989 resin Polymers 0.000 claims description 32
- 235000019441 ethanol Nutrition 0.000 claims description 31
- 229920001296 polysiloxane Polymers 0.000 claims description 30
- 239000000975 dye Substances 0.000 claims description 24
- 239000004359 castor oil Substances 0.000 claims description 20
- 235000019438 castor oil Nutrition 0.000 claims description 20
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 20
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 claims description 19
- 229960005323 phenoxyethanol Drugs 0.000 claims description 19
- 239000001488 sodium phosphate Substances 0.000 claims description 19
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 19
- 235000019801 trisodium phosphate Nutrition 0.000 claims description 19
- 229910000406 trisodium phosphate Inorganic materials 0.000 claims description 19
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 16
- 239000000843 powder Substances 0.000 claims description 16
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 15
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 15
- 239000000126 substance Substances 0.000 claims description 15
- PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerol group Chemical group OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 14
- 239000003960 organic solvent Substances 0.000 claims description 14
- 229940008099 dimethicone Drugs 0.000 claims description 13
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 13
- 239000006185 dispersion Substances 0.000 claims description 13
- 239000000796 flavoring agent Substances 0.000 claims description 13
- -1 t-butyl-aminoethyl Chemical group 0.000 claims description 13
- 239000003349 gelling agent Substances 0.000 claims description 12
- CVHZOJJKTDOEJC-UHFFFAOYSA-N saccharin Chemical compound C1=CC=C2C(=O)NS(=O)(=O)C2=C1 CVHZOJJKTDOEJC-UHFFFAOYSA-N 0.000 claims description 11
- 239000000565 sealant Substances 0.000 claims description 11
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 10
- 239000003599 detergent Substances 0.000 claims description 10
- 239000000230 xanthan gum Substances 0.000 claims description 10
- 229920001285 xanthan gum Polymers 0.000 claims description 10
- 229940082509 xanthan gum Drugs 0.000 claims description 10
- 235000010493 xanthan gum Nutrition 0.000 claims description 10
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 9
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 9
- 239000011928 denatured alcohol Substances 0.000 claims description 8
- 235000013355 food flavoring agent Nutrition 0.000 claims description 8
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 8
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims description 8
- 239000003755 preservative agent Substances 0.000 claims description 8
- 230000002335 preservative effect Effects 0.000 claims description 8
- UKHVLWKBNNSRRR-TYYBGVCCSA-M quaternium-15 Chemical compound [Cl-].C1N(C2)CN3CN2C[N+]1(C/C=C/Cl)C3 UKHVLWKBNNSRRR-TYYBGVCCSA-M 0.000 claims description 8
- 229940096792 quaternium-15 Drugs 0.000 claims description 8
- WBZFUFAFFUEMEI-UHFFFAOYSA-M Acesulfame k Chemical compound [K+].CC1=CC(=O)[N-]S(=O)(=O)O1 WBZFUFAFFUEMEI-UHFFFAOYSA-M 0.000 claims description 7
- 239000000619 acesulfame-K Substances 0.000 claims description 7
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 7
- 235000010354 butylated hydroxytoluene Nutrition 0.000 claims description 7
- 239000002738 chelating agent Substances 0.000 claims description 7
- 235000011187 glycerol Nutrition 0.000 claims description 7
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 7
- 239000011118 polyvinyl acetate Substances 0.000 claims description 7
- ZKYCLDTVJCJYIB-UHFFFAOYSA-N 2-methylidenedecanamide Chemical group CCCCCCCCC(=C)C(N)=O ZKYCLDTVJCJYIB-UHFFFAOYSA-N 0.000 claims description 6
- 239000003906 humectant Substances 0.000 claims description 6
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 claims description 6
- 239000003921 oil Substances 0.000 claims description 6
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims description 6
- 235000010234 sodium benzoate Nutrition 0.000 claims description 6
- 239000004299 sodium benzoate Substances 0.000 claims description 6
- 239000000243 solution Substances 0.000 claims description 6
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 5
- 239000003963 antioxidant agent Substances 0.000 claims description 5
- 235000006708 antioxidants Nutrition 0.000 claims description 5
- 239000007864 aqueous solution Substances 0.000 claims description 5
- 235000019634 flavors Nutrition 0.000 claims description 5
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 5
- 239000011707 mineral Substances 0.000 claims description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 4
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 4
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 4
- 239000000194 fatty acid Substances 0.000 claims description 4
- 229930195729 fatty acid Natural products 0.000 claims description 4
- 150000004665 fatty acids Chemical class 0.000 claims description 4
- 235000013980 iron oxide Nutrition 0.000 claims description 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 4
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 claims description 4
- 239000010445 mica Substances 0.000 claims description 4
- 229910052618 mica group Inorganic materials 0.000 claims description 4
- 108090000623 proteins and genes Proteins 0.000 claims description 4
- 102000004169 proteins and genes Human genes 0.000 claims description 4
- 229920001897 terpolymer Polymers 0.000 claims description 4
- 239000002562 thickening agent Substances 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- GNSFRPWPOGYVLO-UHFFFAOYSA-N 3-hydroxypropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCO GNSFRPWPOGYVLO-UHFFFAOYSA-N 0.000 claims description 3
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 3
- 229920000178 Acrylic resin Polymers 0.000 claims description 3
- 239000004925 Acrylic resin Substances 0.000 claims description 3
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 3
- YBGZDTIWKVFICR-JLHYYAGUSA-N Octyl 4-methoxycinnamic acid Chemical compound CCCCC(CC)COC(=O)\C=C\C1=CC=C(OC)C=C1 YBGZDTIWKVFICR-JLHYYAGUSA-N 0.000 claims description 3
- 240000008042 Zea mays Species 0.000 claims description 3
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims description 3
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims description 3
- OFUHPGMOWVHNPN-QWZFGMNQSA-N [(2r)-2,5,7,8-tetramethyl-2-[(4r,8r)-4,8,12-trimethyltridecyl]-3,4-dihydrochromen-6-yl] (9z,12z)-octadeca-9,12-dienoate Chemical compound O1[C@](C)(CCC[C@H](C)CCC[C@H](C)CCCC(C)C)CCC2=C(C)C(OC(=O)CCCCCCC\C=C/C\C=C/CCCCC)=C(C)C(C)=C21 OFUHPGMOWVHNPN-QWZFGMNQSA-N 0.000 claims description 3
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 claims description 3
- 230000003078 antioxidant effect Effects 0.000 claims description 3
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- 230000003750 conditioning effect Effects 0.000 claims description 3
- 235000005822 corn Nutrition 0.000 claims description 3
- DLAHAXOYRFRPFQ-UHFFFAOYSA-N dodecyl benzoate Chemical compound CCCCCCCCCCCCOC(=O)C1=CC=CC=C1 DLAHAXOYRFRPFQ-UHFFFAOYSA-N 0.000 claims description 3
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- 235000010228 ethyl p-hydroxybenzoate Nutrition 0.000 claims description 3
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- 239000004744 fabric Substances 0.000 claims description 3
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- BWOROQSFKKODDR-UHFFFAOYSA-N oxobismuth;hydrochloride Chemical compound Cl.[Bi]=O BWOROQSFKKODDR-UHFFFAOYSA-N 0.000 claims description 3
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- 235000010339 sodium tetraborate Nutrition 0.000 claims description 3
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 claims description 3
- 239000000341 volatile oil Substances 0.000 claims description 3
- BEWCNXNIQCLWHP-UHFFFAOYSA-N 2-(tert-butylamino)ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCNC(C)(C)C BEWCNXNIQCLWHP-UHFFFAOYSA-N 0.000 claims description 2
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- 210000004761 scalp Anatomy 0.000 claims 4
- NMGPHUOPSWFUEB-UHFFFAOYSA-N 2-(butylamino)ethyl 2-methylprop-2-enoate Chemical class CCCCNCCOC(=O)C(C)=C NMGPHUOPSWFUEB-UHFFFAOYSA-N 0.000 claims 2
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- 150000001346 alkyl aryl ethers Chemical class 0.000 claims 1
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- 125000005909 ethyl alcohol group Chemical group 0.000 claims 1
- SYUXAJSOZXEFPP-UHFFFAOYSA-N glutin Natural products COc1c(O)cc2OC(=CC(=O)c2c1O)c3ccccc3OC4OC(CO)C(O)C(O)C4O SYUXAJSOZXEFPP-UHFFFAOYSA-N 0.000 claims 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
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Abstract
An improved cosmetic, which employs a color agent and a plasticizer in a volatile solvent, which includes a film-forming agent, which preferably has as components an Amphomer and ethyl-cellulose, as well as a cosmetic pigment. The resulting cosmetic is insoluble in water and has a longer staying power than that of a conventional lipstick. The novel cosmetic, once it dries, does not run or detach on the containers of drinks, on such or on human skin. The finish is so transparent that the cosmetic can be applied in at least three successive layers without accumulation of masses or crack formation. Once applied in this way, while allowing each layer to dry between each successive application, a person can take a shower, swim, smoke, kiss or drink without leaving cosmetic stains on cups of coffee, cheeks or necklaces. Compositions are also provided to increase the cosmetic finish. These compositions transform the cosmetic finish from a matte finish to a highly glossy finish. The compositions that improve the finish also wet and condition the lips, may include protective compounds. Also, compositions for improving the color of the cosmetic are provided. The present invention also relates to formulations for removing the above compositions from the lips. Likewise, kits or equipment that include the above compositions and methods for using these compositions are provided.
Description
RESISTANT COSMETIC THAT DOES NOT SUCCEED
BACKGROUND OF THE INVENTION Field of the Invention The present invention relates to kits, methods and compositions for improving the appearance of the lips. The invention contemplates cosmetic compositions for the application of color to the lips, compositions for improving the finish of the cosmetic, powders that improve the color and formulations for removing the color. Cases containing the above compositions are also considered. The present invention also relates to methods for using the foregoing compositions. Description of the Prior Art For many years, lipsticks have been used as a cosmetic preparation to highlight or alter the color of the lips. Conventional lipsticks are formed by a cosmetic dye in a wax carrier. Although these lipsticks have many disadvantages, there has not been an adequate alternative. Lipsticks, which until now have been available, have the marked disadvantage of transferring color easily from a person's lips to other objects. The color of these lipsticks is coursed and removed while swimming, smoking, kissing or other lip contact with items, such as coffee cups, tea cups, napkins and clothes. This leads to the loss of the application of the color of the lipstick when drinking drinks, when swimming and even without any of these activities, due simply to the licking of the lips. Thus, while the lipsticks are initially applied in a normal manner, in a relatively uniform application through the externally exposed areas of the lips, the application of the lipstick will easily dissipate and assume a non-uniform coverage. The greatest loss of lipstick application is typically near the portions of the lips closest to the person's mouth. As a consequence, it is necessary to frequently re-apply layers of the lipstick in order to maintain a uniform coverage of the application of the lipstick on the lips of a person. This frequent need for re-application aggravates a further disadvantage of conventional lipstick. The color of the lipstick has the additional disadvantage of being susceptible to the formation of cracks and mass accumulation. This disadvantage is particularly pronounced when several layers of lipstick have been applied, in an attempt to fill in the application of the lipstick that has been lost, due to the transfer to other articles. As a consequence, the frequent re-application of the lipstick results in the perceptible formation of cracks and masses of lipstick covering the lips of a person. This formation of cracks and masses of a lipstick application detracts from the natural appearance of the lips and is aesthetically inconvenient. Attempts have been made over the years to provide an alternative cosmetic, which does not lead to the disadvantages of lipstick. For example, U.S. Patent No. 2,230,063, discloses a liquid lipstick preparation, which employs a combination of ethyl cellulose and wax-free lacquer, as materials forming the film. However, the lacquer tends to form cracks. Thus, until now, an adequate alternative to lipstick has not been found. COMPENDIUM OF THE INVENTION The present invention is a novel alternative to lipsticks. The cosmetic of the present invention does not take the form of a viscous bar, but rather is a unique, waterproof and stain-proof liquid, which dries quickly to a smooth, extremely transparent finish, which feels remarkably like a skin not covered. The cosmetic of the present invention is both stain-proof and waterproof. It does not form ribbons, or run or remove when swimming or kissing. The use of the cosmetic of the present invention avoids the disadvantages of stains on coffee cups, cheeks and necklaces. The cosmetic of the present invention has twice as much power in its permanence than that of lipsticks that are said to be waterproof and kiss-proof. The cosmetic of the present invention has additional advantages that do not stick to dental work or braces. It can be used on hair or eyebrows, as well as to cover any bald area on the head. It can be used to cover scars or tattoos anywhere on the body. The present invention provides a perfect cosmetic for female business professionals. Its use in weddings, parties, on the beach, for its use while skiing and for its use during all active sports is highly advantageous. The cosmetic of the invention is extremely attractive and can be used on important banquet dates as well as during informal events. The user can still sleep or take a shower while using the cosmetic, since it does not discolor or run under such circumstances. The user can apply several layers of the cosmetic to achieve the desired appearance. The present invention also relates to compositions for improving the cosmetic finish. Such compositions, when applied to the cosmetic, transform the cosmetic finish from a matt finish to a high gloss finish. The compositions that improve the finish also keep the lips soft and moist and can be given a light massage on the lips, before the application of the cosmetic, to condition and moisten them. The compositions that improve the finish can be applied with an applicator rod. The user can apply multiple times the composition that improves the finish, when it is desired to moisten the lips or increase the finish of the cosmetic. The appearance of the lips can be further improved with the use of color-improving compositions, which comprise a coloring powder, which can be supplied in pressed or loose form. This coloring powder can be supplied in a compact form and can be moderately pressed in the cosmetic using a brush. The coloring powders can also be used as a base or they can be applied between the second and third layers of the cosmetic. The visual effect of the coloring powders can be moderate by applying the composition that improves the finish on the coloring powder. The present invention also relates to compositions for removing the cosmetic, for improving the finish and for improving the color. These compositions can be applied by brush on a fabric and applied to the lips when the user wishes to remove the previous compositions of the lips.
The present invention also relates to kits comprising the preceding compositions and methods for using these preceding compositions. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS In a broad aspect, the invention can be considered as a cosmetic comprising between about 0.1 and 20 parts of an alcohol-soluble and water-insoluble resin, between about 0.1 and 15 parts of ethyl cellulose, between about 0.1 and 15 parts of a cosmetic pigment and between about 50 and 99 parts of an organic solvent. All parts used here with percentage in weight. Preferably, the solvent is the denatured alcohol. In a preferred embodiment, the water-soluble and alcohol-insoluble resin is present between about 1 and 10 parts. In a more preferred embodiment, the ethyl cellulose is present between about 1 and 10 parts. In a more preferred embodiment, the cosmetic pigment is present between about 2 and 10 parts. In another broad aspect, the invention can be considered as an improvement in a cosmetic using a coloring agent and a plasticizer in a volatile solvent. The improvement is comprised of at least one film forming agent, present in an amount of at least about one percent, in which the agent forming the film is selected from the group consisting of: Amphomer, Lovocryl, Carboset, Joncryl , Quadamer, Gantrez and polyvinyl acetate copolymers. In yet another broad aspect, the invention can be considered as an improvement in a cosmetic that employs a pigment and a film forming agent in an organic solvent carrier. According to the improvement of the invention, the film-forming agent includes a soluble alcohol and a water insoluble substance, present in an amount of at least about one percent and is selected from the group consisting of Amphomer, Lovocryl, Carboset, Joncryl, Quadamer, Gantrez and polyvinyl acetate copolymers. The critical component of the invention is the resin soluble in alcohol and insoluble in water. A number of different queens of the type can be employed in formulating the cosmetic of the invention. The water-insoluble alcohol-soluble resin can be selected from the group consisting of octylacrylamides, acrylates, butylaminoethyl methacrylate copolymers and polyvinyl acetate copolymers. The alcohol-soluble resin, insoluble in water, or mixture of resins, serves as a vital component of the agent that forms the film. This agent forming the film can be selected from the group consisting of Amphomer, Lovocryl, Carboset, Joncryl, Quadamer, Gantrez and polyvinyl acetate copolymers. Five performance tests were performed on a variety of resins to determine their proper form for use in the present cosmetics. The suspension test was used to evaluate the ability of the test compound to be solubilized in a solution of 4.4% of the test resin, 3.5% ethylcellulose, 5% castor oil, 0.8% pigment D &C Red # 7 Calcium Lake and 90.7% ethyl alcohol. The rub test was designed to determine the ability of the resin to be retained on the skin. The composition used for the suspension test was applied on the skin and allowed to dry. Next, he rubbed the skin under cold water from the pipe until the composition began to separate and fall. A composition receives a "good" mark if it is capable of withstanding five minutes or more of rubbing. A composition receives a mark of adequate or poor if it resists less than a minute of rubbing. In the color test, the color of the resin-containing compositions used in the suspension test was applied to the lips and the color quality obtained was compared to that produced using a composition lacking the test resin. In the "Lip Sensitivity" test, the compositions used in the suspension test where the compounds were evaluated to determine if they produce a firm shrinking sensation, it forms cracks, dries on the lips or accumulates masses on the lips. The compounds that perform favorably in this test did not produce any of the preceding effects and were not noticed by the user. In the drying time test, the compositions used in the suspension were applied to the lips and the period of time the composition takes to dry was evaluated. Preferably, the compositions took about 20 seconds to dry. The above tests were performed on the following resins: (1) Resin 28-2930 (VA / crotonates / vinyl neodecanoate copolymer) available from National Starch Bridgeswater, NJ. (2) Amphomer LV-71 (octylacrylamide / acrylates / butylaminoethyl methacrylate copolymer), available from National Starch. (3) Water Lock G40-A180-D242 (corn starch / acrylamide / sodium acrylate copolymer), available from Grain Processing Corp., Muscatine, IA 52761. (4) Daihold (amp / acrylate copolymer), available from Sandoz Chemical Corp., Charlotte, NC. (5) Eastman AQ-385 and AQ-555 (diglycol copolymer / cyclohexanedimethanol / isophthalates / sulphyl-isophthalate-cough), available from Eastman Kodak, Rochester, NY.
(6) Ultra Hold 8 (acrylate / acrylamide copolymer), available from Base Corp., Clifton, NJ. (7) Omnirez 2000 (2-buteneic acid ester polymer with methoxyethene 2-monoethyl ester), available from ISP, Sherman Oaks, CA: (8) Gantrez Compounds, such as A-425, ES 425 and ES-435 ( which are butyl esters of PVM / MA copolymers), ES-335 (isopropyl ester of the PVM / MA copolymer) or ES-225 and SP-215 (ethyl esters of the PBM / MA copolymer), all of which are available from ISP, Sherman Oaks, CA: (9) H2old EP-1 Terpolymer (vinyl caprolactam / PVP / dimethylaminoethyl / methacrylate copolymer), available from ISP, Sherman Oaks, CA. (10) Amphomer Lovocryl-47 (octyl-acrylamide / acrylates / butylaminoethyl-methacrylate copolymer), available from National Starch, Bridge ater, NJ. (11) Amphomer 28-4910 (octylacrylamide / acrylates / butylaminoethyl methacrylate copolymer), available from National Starch, Bridgewater, NJ. (12) Advantage Plus Terpolymer (copolymer of
VA / butylmaleate / isobornyl-acrylate), available from ISP, Sherman Oaks, CA. (13) Copolymer 958 (PVP dimethyl-aminoethyl methacrylate copolymer) available from ISP, Sherman Oaks, CA.
(14) Jancryl (styrene / acrylate copolymer) available from SC Johnson Polymer, Racine, Wl. (15) Sentry Polyvinyl-12 acetate (polyvinyl acetate), available from Union Carbide Corp., Houston TX. (16) Carboset-525 (acrylate copolymer), available from B. F. Goodrich, Brecksville, OH. Table I summarizes the results of the performance tests. Resin 28-2930, Amphomer LV-71, Amphomer Lovlocryl-47 and Amphomer 28-4910, all received a "good" performance rating in previous performance tests. While any of the substances tested in the performance tests can be used in the formulation of the cosmetic of the invention, the water-soluble, alcohol-insoluble resin, which serves as the film-forming agent, preferably includes an Amphomer component. The most highly preferred Amphomer is the Amphomer LV-71. In the preferred formulation, the agent forming the film is preferably comprised of an Amphomer and ethyl cellulose. The Amphomer is a commercial brand, under which N-tert copolymers are sold. -octylacrylamide, methyl methacrylate, hydroxypropyl methacrylate, acrylic acid and t-butyl-aminoethyl methacrylate. Gantrez is a trademark under which vinyl methyl ether copolymers and mono-akyl ester esters of maleic anhydride are sold by GAF. Quadamer is a trademark under which the terpolymers of alkyl acrylamide, acrylamide or methacrylamide, N-vinyl pyrrolidone and acrylic or methacrylic acid are sold by American Cyanamid. The most preferred film forming agent is the commercially available Amphomer, sold as LV-71 by National Starch and Chemical Company, Specialty Polymers, which has the address of 10 Finderne Avenue, P. O. Box 6500, Bridgewater, New Jersey 08007-3300. Amphoteric acrylic resin, which forms commercially available chemicals such as Amphomer, has previously been used as an adjunct in hair spraying, as described, for example, in the U.S. Patent Nos. 4,192,861 and 4,315,910. However, the Applicant has discovered that this substance can also serve as the preferred form of the critical ingredient of a cosmetic, which forms a clear, colorless film on the lips, and which has a preservation power greater than that of pencils. conventional lipsticks The Amphomer used in the cosmetic of the invention functions as a transparent sealer. Joins and seals the cosmetic to the lips in a clear, transparent film, which does not form cracks or masses. The agent forming the film in the cosmetic composition is that which makes the product of prolonged duration. The Amphomer is an amphoteric acrylic resin. Its official designation of the product by the Cosmetic Toiletries and Fragrances Association (CTFA) is that of the octylacrylamide / acrylates / butylaminoethyl-methacrylate copolymer. The Amphomer is carboxylated at regular intervals along with its molecular chain. In its undissolved form, is a white, fine, free-flowing powder, has an intrinsic viscosity of 0.40 in ethanol at 25 ° C. It contains about 3% volatile substances and has an acidity of 2.05 me / gram. The cosmetic of the invention does not contain waxes or petroleum products. Waxes can stain while oil products can burn or dry lips. The cosmetic of the invention is so transparent that a wearer can form at least three different layers without any damage from which the product forms masses on the lips. In fact, the different layers of the cosmetic of the invention can be applied in different colors to achieve a unique aesthetic effect. Likewise, a different number of layers of the cosmetic can be applied to produce different aesthetic appearances. A single layer of the preferred embodiment of the cosmetic of the invention dries to a transparent finish. If a second layer of the cosmetic is applied on the first, a medium matte finish is achieved. Applying a third layer, the user achieves a matte finish of complete coverage. Even with the use of multiple layers, however, the cosmetic of the invention does not form masses or runs. The cosmetic of the invention can be formulated in any number of different colors by varying the color of the pigment used. The cosmetic of the invention is in a liquid form, when applied and the colors can be used individually or in a layered blend, to create an unlimited array of customized customer colors. Each layer takes about twenty seconds to dry from the time of application. In addition to its basic components, the cosmetic of the invention may include other substances to achieve certain effects. For example, the cosmetic can be formulated with at least about one part of a dimethicone component to achieve a gloss or satin effect. Although the cosmetic formulated in this way looks and feels viscous or sticky, it does not detach and remains on the lips despite extended wear and exposure to moisture. The cosmetic can also be formulated as a lip coater, using a higher concentration of cosmetic dyes or pigments in the formulation. When formulated in this way, the cosmetic can be used to delineate the lips in the same or a different color as the basic application. The cosmetic of the invention provides natural protection against the sun and protects the lips of cracks, both inside and outside, in cold and hot climates. It does not stick to teeth or dental braces. Unlike a current lipstick of the wearer, an individual using the cosmetic of the present invention can actually brush and apply the floss without running the cosmetic or reducing the thickness of its lining of the lips, and without having to return to Apply the lip cover. The cosmetic of the invention is organic and hypoallergenic. Unless a flavor or fragrance is added, it is also odor free and does not contain petroleum products. The cosmetic of the invention improves the beauty of the user without surgery or filling in the inner lips, where the conventional lipstick does not remain. The cosmetic of the invention is extremely transparent and is not sticky like conventional lipsticks. Even after applying three or more layers of the cosmetic of the invention, the lips feel uncovered and have a perfect matte finish.
The cosmetic of the invention is not entirely viscous and can still be emptied from a container. Its transparent consistency can be applied with a fine tip applicator, so that it can be applied with the precision of a makeup artist. The Amphomer used in the cosmetic of the invention functions as a transparent sealer. Joins and seals the cosmetic to the lips in a clear and transparent film, which does not form cracks or masses. The agent that forms the film in the cosmetic composition is that which makes the product of prolonged duration. The cosmetic of the invention is not peeled off with petroleum jelly or cleaning creams. Due to its permanence, care must be taken not to spill the cosmetic of the invention in liquid form on clothes or other fabrics. However, if the cosmetic accidentally spills on the carpet or clothes, it can be easily removed by applying water and then applying isopropyl alcohol or cosmetic-removing formulations, described below, on the condition that the cleaning is done promptly. In order to use the cosmetic of the invention it is recommended that the area of the lips be thoroughly cleaned with the cosmetic-removing compositions, described below. A cosmetic bottle containing small mixing spheres should be shaken for four or five times until the mixing spheres move freely inside the bottle. The cosmetic of the invention is then applied generously in the form of liquid to the dry and clean lips. It is recommended to apply three consecutive coats at one time for full coverage of a day. The cosmetic can be applied with a soft applicator of rabbit's foot or a brush applicator and must be applied through the lips in only one direction only. When the cosmetic is applied, the user should keep in mind that the freedom to create fuller lips, filling in the inner lips, where the regular lipstick does not remain. Approximately 20 seconds should be allowed to elapse between consecutive coatings, in order to allow the preceding coating to dry immediately. During this time, the lips should be separate and unstained. For best results, after the application of the cosmetic of the invention, the user should refrain from eating, drinking or smoking, for at least one minute. With the application of the cosmetic, the user's lips will initially feel itchy. This itching sensation will diminish or pass with repeated use, because the sealing effect of the product really helps to eliminate the sensation, but still presents the common cracks in most of the lips.
The itching sensation, which is sometimes present, can be avoided by first applying a thin layer of the cosmetic containing dimethicone. Subsequent layers of the same or different formulation of the cosmetic can be applied to achieve the desired degree of transparent or matte finish. The bottle containing the cosmetic of the invention must be kept closed after each use. With daily use, a 7,425 ml bottle should last for about two months. As previously noted, the solvent or organic carrier employed is preferably the denatured alcohol, sometimes named ethyl alcohol or ethanol. Other organic solvents that can be used in place of, or in addition to, denatured alcohol include stearyl alcohol, cetyl alcohol, cetaryl keto stearyl alcohol, SDA alcohol, methyl alcohol, isopropyl alcohol, isostearyl alcohol, lauryl alcohol, alcohol myristyl, behenyl alcohol, synthetic alcohol and C1840 alcohol. Other organic solvents that may be employed include higher fatty acids that are immiscible in water. They include lauric acid, myristic acid, stearic acid, palmitic acid, behenic acid and lanolin grade acid. Lanolin and triterpene can also be used in the organic solvent.
Depending on the concentration of the other components, the organic solvent, which is preferably the SDA 40B 190 denatured alcohol, is preferably present in the range between about 30 to 95 percent. Within this range, an organic solvent concentration of 80 to 95 percent will be used normally. The pigments that are used to supply the coloration of the cosmetic are normally provided as dispersions in castor oil. The pigment and castor oil are preferably present in the cosmetic of the invention in an aggregate amount between about 0.1 and 10 percent. Pigments of this type are normal in the cosmetics industry and are identified in that industry by the designations of FD &C, D &C designations, natural color designations that are compatible with alcohol solutions. Preferred pigments that are employed include the D &C Network No, 6, Barium Lake, D &C Network No. 7 Calcium Lake, D &C Orange No. 5, D &C Network No. 27, FD &C Yellow No 5, FD &C Blue No. 1, iron oxides and others. The D &C Lake colors are all made with iron, aluminum, calcium, barium, potassium, strontium or zirconium. Other pigments that can be used include those of dyes or coal tar origin and chemical compounds used as pigments. Inorganic colors, such as iron oxides can be used. The white pigments can be formed from titanium dioxide, zinc oxide, mica or beads. The pigments formed from nitro dyes can be used, if desired. These dyes contain a nitrogen atom and two oxygen atoms. However, only a few nitro dyes are certified by FD &C or D &C, because these nitro dyes can be absorbed through the skin and some are toxic. However, D &C Yellow No. 5 is an acceptable nitro dye, which can be used as a component of the pigment of the invention. Azo pigments can also be used. These pigments are characterized by the presence of the azo bond and the monoazo pigments include the largest number of pigments within this group. Another group of suitable pigments is the triphenylmethane group. FD &C Blue No. 1 is the most popular dye in this group and is widely used in the cosmetics industry. The xanthene pigments can also be used. This group of pigments include the Berrry Brilliant, which is widely used in lipstick colors, just like the D &C Orange. Certain of the quinoline dyes are also suitable for use as pigments. There are only two colors of certified cosmetics in this category, namely the D &C Yellow Nos. 10 and 11. These are bright greenish-yellow colors. Anthraquinone dyes are also suitable for use in the pigment formulation required by the compositions of the invention. These dyes are widely used in cosmetics, because they are not affected by light. D &C Violet No. 2 is an example of such a dye suitable for use in the invention. Anthraquinone dyes should not be used in the area of the lips, but can be used in other applications, such as nails. Indigo dyes are also suitable for use and have been used in cosmetics for many years. The D &C Blue No. 6 is an example of a suitable indigo dye. The pigments of vegetable, animal or mineral origin can also be used according to the invention. A suitable pigment of animal origin is cochineal extract. The natural colors and pigments of plant compounds that can be used include the ancusa of dyes, beans, carotene, chlorophyll, saffron and beetroot juice powder, crimson, ancusa root, carmel, grape skin extract and beta-carotene. The hydroxyacetone and indelible dyes can also be used in formulating the pigment in the cosmetic of the invention. Preferred embodiments of the cosmetic of the invention employ color pigments dispersed in castor oil. This dispersion is present in the range between one and ten percent of the formulation. The degree of concentration of the pigments in the castor oil determines the shade of the coloration. Usually, a concentration between 25 and 65 percent of pigments in castor oil, in the aggregate, is used in formulating the cosmetic. Castor oil acts as a plasticizer and also makes the film formed more flexible. Alternatively, the pigments may be soluble in alcohol, such as D & amp; amp; amp;; C Red 28 Lake, in this case a dispersion of castor oil is not necessary to solubilize the pigment in the present cosmetics. The pigments may contain 0.1 to 5% dye. Preferably the pigment contains 0.65 to 1.5% dye. The water insoluble, soluble and alcoholic resin, which is used, is the critical component that supplies the cosmetic of the invention with its numerous advantages over lipstick. While Amphomer is preferably used as the required alcohol-soluble, water-insoluble resin, other resins can be used, not only to add a color component, but also to serve as a sun screen. The cosmetic of the invention can also use vitamins, minerals, antioxidants, drugs, organic compounds, herbs, proteins, ordinary extracts, root extracts, enzymes, sorbitol, pectin and PCA to take advantage of its known properties of coloration, taste, wetting and adhesives, The invention can be illustrated by means of the following examples. EXAMPLE 1 The first step in formulating the cosmetic of the preferred embodiment of the invention is to create the sealant. This sealant is formed by mixing the agent that forms the film in the organic solvent. Specifically, 4.4 parts of Amphomer LV-71, obtained from the National Starch and Chemical Company, and 1.9 parts of Ethocel No. 22, obtained from Aqualon Corporation, were mixed at room temperature in 93.7 parts of denatured alcohol, especially graduated 190, sold as SDA 38B-190. Ethocel N-22 supplies ethyl cellulose that functions as a film former attached to the seal. This sealant is then placed aside momentarily. Five parts by weight of a dispersion of D &C Red
No. 7 Calcium Lake, in castor oil and 0.5 parts by weight of a dispersion of D &C Orange No. 5 in castor oil, were then selected for use as the pigment or color agent. Both the D &C Network No. 7 Calcium Lake and the D &C Orange No. 5 each comprise about 50 percent of the total weight of their respective dispersions. The remaining weight of the dispersions is attributable to castor oil. The pigments must be obtained in a milled form as fine as possible. The pigment dispersions are mixed together with another 0.5 parts by weight of castor oil. The mixture of pigment and castor oil is then mixed with the sealant, also at room temperature. The Amphomer, the Ethocel and the pigment ingredients are all easily soluble in the denatured alcohol. When mixed, the formulation is a somewhat cloudy solution. The ground pigment can be stirred into the sealant in any convenient manner. The resulting liquid mixture is a preferred embodiment of the cosmetic according to the invention. EXAMPLE 2 The formulation of Example 1 was repeated, but with the addition of two parts of methyl silicone to the sealant, before adding the pigments to this sealer. The use of dimethicone, such as methyl silicone, increases the brilliance of the cosmetic. EXAMPLE 3 The formulation of Example 1 was repeated, but with the addition of two parts by weight of glycerin as a humectant, when producing the sealant. The use of a moisturizer helps to moisten the lips. EXAMPLE 4 A sealant was first prepared by mixing 4.3 parts by weight of Amphomer LV-71 together with 3.2 parts by weight of Ethocell N-4 in 92.5 parts of especially denatured alcohol, SDA 40B-190. 8.25 parts of the pigment dispersion of D &C Red No. 7 in castor oil along with 0.25 parts of the pigment dispersion D &C Orange No. 5, in castor oil, then mixed with 0.5 additional parts of oil of castor and were introduced in the amount of sealer prepared previously. This sealant, therefore, constitutes 90.75 parts by weight of the total composition. The ground pigment and the additional castor oil were agitated in the sealant to produce the finished liquid cosmetic composition, according to the invention. All the cosmetic formulations of the previous examples will dry in a thin film, when applied to the lips. The cosmetic will not form cracks or masses, even with repeated applications. When any of the above formulations is applied to the wearer's lips in at least three layers, the coverage of the provided cosmetic will last a full day in a user with virtually any normal activity, without fading or peeling.
The above formulations can be used to apply color to the skin, nails, hair or to cover bald areas. In addition, the above compositions can be used as coatings to provide a definition. For use as a coating, darker pigments are preferred, although any pigment will work. Additionally, if used as a coating, the composition should be applied to the lips with a fine-tipped brush. Also, with slight modifications, the above formulations can be used to apply color around the eyes. For this application around the eyes, an aqueous solvent is used and the ethyl cellulose is omitted, and the aminomethyl-propanol Aminonathyl is added. A preferred composition for use around the eyes comprises between about 0.1 to 20 parts of a water-soluble resin, between about 0.1 and 15 parts of a cosmetic pigment, between about 0.5 and 4 parts of the amino-methyl-propanol , Aminonathyl. The present invention also considers compositions for improving the cosmetic finish. The composition can be applied on the cosmetic to increase the matt finish of the cosmetic, only in the high-gloss finish. In addition, the lips will remain soft and silky, while leaving in place the waterproof and slip proof cosmetic. The compositions that improve the finish can also be applied with a light massage on the lips, before the application of the cosmetic, to condition and moisten the lips. The composition improving the finish comprises a silicone. Preferably, the silicone is a silicone copolymer. In one version of this composition, the composition comprises about 100% silicone. Silicones work to provide the activity of a water barrier, brightness, extension and soaking. It can also include the ability to moisten and can function as a carrier for other active ingredients, such as sun screens or vitamins. Mixtures of different silicones can also be used to achieve the desired wetting, carrier or other beneficial effects. Virtually any of the silicones offered by GE Silicones will work in the present invention, including Cyclomethicone, Dimethicone, Cyclomethicone and Dimethicone blends, Dimethicone and Laureth-4 and Laureth-23, Dimethicone Copolyol, Cycomethicone and Dimeyhicone Copolyol, Trimethylsilylamodimethicone and other silicones supplied by GE Silicones for use in personal products. Preferably, the silicone is a silicone copolymer. Preferred silicones are the Dimethicones, available from GE Silicone, and the diethylsiloxane-methyl (polyoxyethylene) -siloxane copolymer, such as Dimethicone and
Triomethylsiloxysilicate, available from GE Silicones.
Representative dimethicones include the SF96® (5), SF96®
(20), SF96® (50-1000), Viscasil® 60M, SF1236 and SE30, available from GE Silicones. In another version of this embodiment, the composition improving the finish comprises a silicone, a lipophilic gelling agent and a condom. The silicones suitable for use in this embodiment are the same as those of the above composition. The lipophilic gelling agent acts as a carrier to introduce additional components into the composition. Additional suitable components are discussed below. In a highly preferred embodiment, the lipophilic gelling agent is Gilugel SL-5 (produced by Giulini Chemie, Germany, and available from Morse Chemical, Inc., San Gabriel, CA). A preferred preservative is phenoxyethanol. In a highly preferred version of the present invention, the finishing improving composition comprises about 1 to 99% silicone, about 0.1 to 50% of the lipophilic gelling agent and about 0.1 to 10% of the preservative. In a highly preferred version, the dimethyl-siloxane-methyl- (polyoxyethylene) -siloxane copolymer is present at a concentration of 88.40%. In a highly preferred version, the Gilugel SL-5 is present at 10%. Preferably, the preservative is phenoxyethanol or BHT (butylated hydroxytoluene). In a preferred embodiment, phenoxyethanol is present in 1.6%. In another preferred embodiment, BHT is present at 0.3%. Additional components may be added to the above composition, which include flavoring agents, skin conditioning agents, emollients, skin protectors, sun screens, UV light absorbers, anti-oxidants, humectants, essential oils, PABA minerals, heterocyclic compounds, oils, fats and fatty acids. Representative flavoring agents that can be used in the present compositions include cinnamon, mint extract, saccharin, Acesulfame K and other flavoring agents, such as those listed in the CTFA Cosmetic Ingredient Handbook 2nd Edition, published by the Cosmetic Association , Toiletry and Fragrance, 1101 17th St. NW Suite 3000, Washington, DC 20036 (1992). The amounts and identities of these flavoring agents can be adjusted to provide a desired flavor to the composition. Numerous skin conditioners can be selected for use in the present compositions, provided they are oil soluble. These include the moisturizing emollients, various agents and skin-conditioning occlusive agents listed in the CTFA Cosmetic Ingredient Handbook. The amounts and identities of the skin conditioning agents can be adjusted to give the desired results. A highly preferred humectant is glycerin. Many compounds that absorb UV are known and include those listed in the CTFA Cosmetic Ingredient Handbook. However, the preferred UV absorber is octylcrylene. Numerous skin screen agents are known to those skilled in the art, including those listed in the manual crFA Cosmetic Ingredient Handbook. However, a preferred skin screen is octyl-methoxy cinnamate. In a preferred version of this aspect, the antioxidant is a mixture of vitamin E linoleate from Seltzer Chemicals, Carlsbad, CA. Many skin protectors are known to those skilled in the art, including those listed in the CTFA Cosmetic Ingredient Handbook. Many essential oils, minerals, PABA, heterocyclic compounds, oils, fats and fatty acids, suitable for use in the present compositions are known to those skilled in the art. Representative compounds in each of these categories are listed in the CTFA Cosmetic Ingredient Handbook. Effective amounts of such compounds can be included in the present compositions to achieve the desired effect.
Preferred compositions improving the finish are listed in Examples 5 to 8. EXAMPLE 5
COMPOSITE AMOUNT (BY WEIGHT) 88. 40 Dimethylsiloxane-methyl (polyoxyethylene) siloxane copolymer 10. 00 Gilugel SL-5 1. 60 Phenoxyethanol
To formulate the previous composition, the Gilugel SL-5 was heated to melt. Then phenoxyethanol was added and the resulting mixture was added to the dimethyl siloxane-methyl (polyoxyethylene) -siloxane copolymer. EXAMPLE 6
COMPOUND AMOUNT (BY WEIGHT) 7. 00 Dimethylsiloxane-methyl (polyoxyethylene) siloxane copolymer 5. 50 Gilugel SL-5 0. 30 BHT (butylated hydroxytoluene) Phenoxyethanol 1.00 Phenoxyethanol 84. 10 Dimethicone 1. 00 Octylcrylene 1. 00 octyl-methoxy cinnamate 0. 10 mix of Vitamin E linoleate
The composition was prepared by heating the Gilugel to the melting point and adding octylcrylene, cinnamate. octyl-metxoi, vitamin E, phenoxyethanol and BHT. The two silicones were mixed separately and then the Gilugel mixture was added. EXAMPLE 7
COMPOUND AMOUNT (BY WEIGHT) 100.00 Dimethicone
EXAMPLE 8
COMPOUND AMOUNT (BY WEIGHT) 100, 00 Dimethylsiloxane-methyl (polyoxyethylene) siloxane
The present invention also contemplates compositions for removing the cosmetic. A version of the cosmetic remover is a solution that includes a mild detergent plus a preservative. Preferably, the mild detergent is present between about 0.5 to 10 parts and the condom is present between about 0.1 and 3 parts. A preferred moderate detergent is sodium lauryl sulfate and a preferred preservative is Quaternium 15 (Dowicil 2000, available from Dow Chemical). In a highly preferred embodiment of this composition, sodium lauryl sulfate is present in 0.5 part and the preservative is Quaternium 15 ((Dowicil 2000, available from Dow Chemical), at 0.1 part, with the rest of the composition Water being the alternative composition that removes the cosmetic from the lips may comprise a solution of alcohol and a chelating agent In a preferred embodiment of this embodiment, the alcohol is ethyl alcohol and the chelating agent is trisodium phosphate. Preferably, the trisodium phosphate is present in about 0.1 to 5 parts by weight In yet another embodiment, the cosmetic removing composition comprises an aqueous solution of a chelating agent, one or more mild detergents and a preservative. The water is distilled, preferably also the chelating agent is trisodium phosphate.
Preferred moderate detergents are the Empigen CDR 30
(cocoanfor acetate), available from Albright & Wilson,
Cumbria, United Kingdom) and the nonionic surfactant, polyoxyethylene-polyoxypropylene glycol (Pluronic® F127, Poloxamer 407). Preferred condoms are phenoxyethanol, sodium benzoate and Quaternium 15 (Dowacil 200, available from Dow Chemicals). In later aspects of this modality, one or more thicknesses are added. A preferred thickener is xanthan gum. This xanthan gum also functions to maintain the solubility of sodium lauryl sulfate and trisodium phosphate in alcohol-based formulations. In still other embodiments of the composition that removes the cosmetic, a flavoring agent may be added. Preferred flavoring agents are Acesulfame K (a Sunnett Brand Sweetener, available from Hoechst Celanes, 3340 W. Norfolk Rd., Portsmouth, VA 23703) and sodium saccharin. Preferably, the chelating agent is present between 0.5 and 5 parts, approximately. It is preferred that the detergents are present in about 5.05 to 20.5 parts. Preferably, the condom is present between 0.1 and 5 parts. Preferably also, the thickener is present between about 0.05 and 10 parts and the sweetener is present between about 0.05 and 5 parts. Moderate alkaline solutions can also be used to remove the cosmetic. A preferred aspect of this mode is 0.5 to 5 parts of sodium borate, with the remainder being water. In a highly preferred embodiment, sodium borate comprises 1.78 parts of the aqueous solution.
Examples 9 to 15 describe highly preferred embodiments of the formulations for removing the cosmetic. EXAMPLE 9
COMPOUND AMOUNT (BY WEIGHT) 90.29 Distilled water 1. 8 Trisodium phosphate 0.20 Polyoxyethylene-polyoxypropylene glycol (Poloxamer 407) 0. 13 Acesulfame K 1. 60 Phenoxyethanol 6. 00 Cocoanfor acetate (Empigen CDR 30). To formulate the above composition, the trisodium phosphate, Poloxamer, Acesulfame K are first added to the hot water. The cocoanfor acetate is then added to this aqueous composition, followed by the addition of phenoxyethanol. The above formulation can also be used to remove the applied coloration around the eyes. EXAMPLE 10 COMPOSITE AMOUNT (BY WEIGHT) 80. 67 Distilled water (DI) 16. 25 Ethanol (flavored denatured) 190 graduation 1. 25 Trisodium phosphate 0,. 25 Xanthan gum 0,. 20 Polyoxyethylene-polyoxypropylene glycol (Poloxamer 407) 0,. Sodium lauryl sulfate 0. 13 Sodium saccharin 1 • 0 Sodium benzoate To prepare the above formulation, trisodium phosphate, Poloxamer, sodium saccharin, sodium lauryl sulfate and sodium benzoate were added to the hot water. The xanthan gum was added separately to the alcohol. Next, the alcohol mixture was added to the aqueous mixture. Finally, the glycerin was added to the previous mixture. Alternatively, xanthan gum can be added to half the water at room temperature. Trisodium phosphate, Poloxamer, sodium saccharin, sodium lauryl sulfate and sodium benzoate can be added to hot water. The two aqueous mixtures can be combined with the alcohol. EXAMPLE 11
COMPOSITE AMOUNT (BY WEIGHT) 80. . 02 Distilled water 16,. 25 Ethanol (denatured with flavor) 190 1 graduation,. 25 Trisodium phosphate 0,. 25 Xanthan gum 0. . 20 Polyoxyethylene-polyoxypropylene glycol (Poloxamer 407) 0,. 30 Glycerin 0. . 13 Sodium saccharine 1-60 Phenoxyethanol
To formulate the above composition, trisodium phosphate, sodium saccharin, phenoxyethanol and Poloxamer were added to the hot water. The xanthan gum was mixed separately with the alcohol. The alcohol mixture was then combined with the aqueous mixture and the glycerin was added. Alternatively, xanthan gum can be added to half the water at room temperature. Trisodium phosphate, sodium saccharin, phenoxyethanol and Poloxamer were added to the hot water. The two aqueous mixtures can then be combined with the alcohol.
EXAMPLE 12
COMPOUND AMOUNT (BY WEIGHT) 90.30 Distilled water 1 - 78 Trisodium phosphate 0.20 Polyoxyethylene-polyoxypropylene glycol (Poloxamer 407) 6.00 Cocoanfor acetate (Empigen COR 30) 0. 12 Sodium saccharin 1. 60 Phenoxyethanol
To formulate the above composition, trisodium phosphate, sodium saccharin, phenoxyethanol and Poloxamer were added to the hot water. The xanthan gum was mixed separately with the alcohol. The alcohol mixture was then combined with the aqueous mixture and the glycerin was added. Finally, cocoanfor acetate was added. The above formulation can also be used to remove the applied color around the eyes. EXAMPLE 13
COMPOUND AMOUNT (BY WEIGHT) 91. 69 Distilled water 1 - 78 Trisodium phosphate 0.20 Polyoxyethylene-polyoxypropylene glycol (Poloxamer 407) 6 - 00 Cocoanfor acetate (Empigen CDR 30) 0.13 Acesulfame K 0.20 Quaternium 15
To formulate the above composition, Quaternium 15 was first added to water. Then, Poloxamer, trisodium phosphate and Acesulfame K were added. Finally, cocoanfor acetate was added. EXAMPLE 14
COMPOUND AMOUNT (BY WEIGHT) 0. 5 Sodium lauryl sulphate 90. 3 Distilled water 0.2 Quaternium 15
EXAMPLE 15
COMPOUND AMOUNT (BY WEIGHT) 1.78 Trisodium phosphate 98 .22 Ethyl alcohol
The compositions of Examples 12 and 13 are highly preferred. The present invention also relates to compositions to further increase the color of the cosmetic. These color-increasing compositions comprise colorants, such as mica, bismuth oxychloride, iron oxides, D &; C Lake, FD &C Lake dyes, D &C dyes, and FD &C dyes. Compositions that increase color are provided in pressed or loose form. If they are supplied in pressed form, the dyes are mixed with condoms. Preferred condoms are ethyl paraben, methyl paraben or poly paraben. Additionally, if they are supplied in the pressed form, a color-increasing composition also comprises a wax, such as the corn glutinous protein or a synthetic wax and the C12-C15 alkyl benzoate. A preferred formulation for increasing the color of the cosmetic is described in Example 16.
EXAMPLE 16
COMPOUND AMOUNT (BY WEIGHT) 4.24 Zinc stearate 3. 74 Bismuth oxychloride 66. 03 Colored mica powder 14. 95 C12-C15 alkyl benzoate 8. 72 blend of synthetic wax / corn glutinous protein, from Presperse, Inc., Hadley Rd., South Plainfield, NJ 07080 1 • 3 Ethyl-paraben 0. 65 Methyl-paraben 0. 15 Propyl-paraben To press the above composition , the loose powder was first mixed in an industrial blender. The resulting composition was then placed in a press.
Claims (79)
- CLAIMS 1. A cosmetic, which comprises approximately between 0.1 and 20 parts of an alcohol-soluble and water-insoluble resin, approximately between 0.1 and 15 parts of ethyl cellulose, approximately between 0.1 and 15 parts of a cosmetic pigment and approximately between 50 and 99 parts of an organic solvent.
- 2. A cosmetic, according to claim 1, wherein the water-soluble and water-insoluble resin is selected from the group consisting of: octylacrylamides, acrylates and butylaminoethyl methacrylates, copolymers of the above and polyvinyl acetate copolymers.
- 3. A cosmetic, according to claim 1, wherein the insoluble resin is an amphoteric acrylic resin.
- 4. A cosmetic, according to claim 1, further comprising at least about a part of a dimethicone component.
- 5. A cosmetic, according to claim 1, further comprising at least about a part of a humectant.
- 6. A cosmetic, according to claim 1, further comprising at least about a part of a UV light screen agent.
- 7. A cosmetic, according to claim 1, wherein the resin soluble in alcohol and insoluble in water is a transparent sealant.
- 8. A cosmetic, according to claim 1, in which the water-soluble and water-insoluble resin is a copolymer of N-tertiary, -octylacrylamide, methyl methacrylate, hydroxypropyl methacrylate, acrylic acid and / or methacrylate. t-butyl-aminoethyl, and the organic solvent is ethyl alcohol.
- 9. A cosmetic, according to the claim 1, which comprises approximately four to six parts of the copolymer, approximately three to four parts of ethyl cellulose, approximately seven to nine parts of a pigment dispersion in castor oil and approximately 80 to 95 parts of the solvent organic.
- 10. A cosmetic, according to claim 1, wherein the copolymer component is octylacrylamide / acrylate / butylaminoethyl methacrylate.
- 11. A cosmetic, according to the claim 1, in which the volatile solvent is comprised of denatured alcohol, present in the approximate range between 80 and 95 percent, the plasticizer is comprised of ethyl cellulose, present in the approximate range between three and four percent, and the color agent is comprised of a pigment dispersion in castor oil, present in the approximate range between 25 and 65 percent, and the resin is comprised of the copolymer present in the approximate range between four and six. percent.
- A cosmetic, according to claim 1, wherein the resin is in an organic solvent carrier, where this resin includes an alcohol-soluble and water-insoluble substance, present in an amount of at least about one percent and selected from the group consisting of: a copolymer of N-tert. -octylacrylamide, methyl methacrylate, hydroxypropyl methacrylate, acrylic acid and / or t-butyl-aminoethyl methacrylate, a copolymer of octylacrylamide, butaminoethyl acrylate and methacrylate, a copolymer of acrylates, a copolymer of styrene and acrylate, a terpolymer of alkyl acrylamide, acrylamide or methacrylamide, N-vinyl pyrrolidone and acrylic or methacrylic acid, a copolymer of vinylmethyl ether and monoalkyl ethers of maleic anhydride, and a copolymer of polyvinyl acetate.
- 13. A cosmetic, according to claim 1, wherein the resin is comprised of the copolymer, present in an amount between about one and ten percent.
- 14. A cosmetic, according to claim 1, wherein the pigment is provided as a dispersion in castor oil, and this pigment and castor oil are present in an aggregate amount between about 0.1 and 15 percent.
- 15. A cosmetic, according to claim 1, wherein the resin is present in the range between about 2 and 20 percent and the organic solvent carrier is comprised of the ethyl alcohol.
- 16. The use of the cosmetic, according to claim 1, as a cosmetic for the lips,
- 17. The use of the cosmetic, according to claim 1, to color the nails.
- 18. The use of the cosmetic, according to claim 1, to color the eye area.
- 19. The use of the cosmetic, according to claim 1, to color the scalp.
- 20. A composition that improves the finish of a cosmetic, which comprises silicone, a lipophilic gelling agent and a condom.
- The composition that improves the finish of a cosmetic, according to claim 20, in which this composition comprises about 1 to 99% silicone by weight, about 0.1 to 50% of the lipophilic gelling agent by weight and about 0.1 to 50% by weight. 10% of the condom by weight.
- 22. The composition that improves the finish of a cosmetic, according to claim 20, wherein the silicone is a copolymer of dimethicone.
- 23. The composition improving the finish of a cosmetic according to claim 22, wherein the dimethicone copolymer is selected from the group consisting of SF96® (5), SF96® (20), SF96® (50-100), Viscasil® 60M, SF1236 and SE30.
- 24. The composition that improves the finish of a cosmetic, according to claim 20, wherein the condom is selected from the group consisting of phenoxyethanol and BHT.
- 25. The composition that improves the finish of a cosmetic, according to claim 20, in which this composition improving the finish further includes a flavoring agent.
- 26. The composition that improves the finish of a cosmetic, according to claim 25, wherein the flavor agent is present between about 0.1 and 0.5 parts by weight.
- 27. The composition that improves the finish of a cosmetic, according to claim 20, wherein this composition improving the finish further comprises at least one skin conditioning agent.
- 28. The composition that improves the finish of a cosmetic, according to claim 20, in which this composition improving the finish further comprises at least one emollient.
- 29. The composition that improves the finish of a cosmetic, according to claim 20, in which this composition improving the finish further comprises at least one skin protector.
- 30. The composition that improves the finish of a cosmetic, according to claim 20, in which this composition improving the finish also comprises at least one screen for the sun.
- 31. The composition that improves the finish of a cosmetic, according to claim 30, in which the screen for the sun is octyl-methoxy cinnamate.
- 32. The composition that improves the finish of a cosmetic, according to claim 20, in which this composition improving the finish also comprises at least one agent that breaks UV light.
- 33. The composition that improves the finish of a cosmetic, according to claim 32, wherein the agent that absorbs UV light is octyl crylene.
- 34. The composition that improves the finish of a cosmetic, according to claim 20, in which this composition improving the finish also comprises at least one anti-oxidant.
- 35. The composition that improves the finish of a cosmetic, according to claim 34, wherein the anti-oxidant is a mixture of vitamin E linoleate.
- 36. The composition that improves the finish of a cosmetic, according to claim 20, in that this composition improving the finish also comprises at least one humectant.
- 37. The composition that improves the finish of a cosmetic, according to claim 36, wherein the humectant is glycerin.
- 38. The composition that improves the finish of a cosmetic, according to claim 20, in which this composition improving the finish also comprises essential oils.
- 39. The composition that improves the finish of a cosmetic, according to claim 20, in which this composition improving the finish further comprises minerals.
- 40. The composition that improves the finish of a cosmetic, according to claim 20, wherein this composition improving the finish further comprises oils.
- 41. The composition that improves the finish of a cosmetic, according to claim 20, in which this composition improving the finish further comprises fats.
- 42. The composition that improves the finish of a cosmetic, according to claim 20, in which this composition improving the finish further comprises fatty acids.
- 43. The composition that improves the finish of a cosmetic, according to claim 20, in which the lipophilic gelling agent is Gilugel SL-5.
- 44. A composition that removes the cosmetic, which comprises approximately 0.1 to 5 parts by weight of the trisodium phosphate in a solvent of ethyl alcohol.
- 45. A composition that removes the cosmetic, which comprises 0.5 to 5 parts by weight of the trisodium phosphate, at least one moderate detergent, and a condom in an aqueous solution.
- 46. The composition of claim 45, wherein this composition comprises between about 5.05 and 20.5 parts by weight of the mild detergent and between about 0.1 and 5 parts of the condom.
- 47. The composition of claim 45, wherein the moderate detergents are selected from the group consisting of polyoxyethylene-polyoxypropylene glycol, cocoanfor acetate and sodium lauryl sulfate.
- 48. The composition of claim 47, wherein the condom is selected from the group consisting of phenoxyethanol, sodium benzoate and Quaternium 15.
- 49. The composition of claim 45, further comprising a thickener.
- 50. The composition of claim 49, wherein the thickener is xanthan gum.
- 51. The composition of claim 45, further comprising at least one flavoring agent.
- 52. The composition of claim 51, wherein the flavor agent is selected from the group consisting of Acesulfame K and sodium saccharin.
- 53. A composition that improves the color of a cosmetic, which comprises at least one pressed dye, selected from the group consisting of mica, bismuth oxychloride, iron oxides, dyes D &; C Lake, FD &C Lake dyes, D &C dyes, and FD &C dyes, a wax selected from the group consisting of corn glutin protein and C12-C15 alkyl benzoate, and a condom, selected from the group consists of ethyl-paraben, methylparaben and poly-paraben.
- 54. A case to improve the appearance of the lips, this case comprises: (a) a cosmetic that includes approximately between 0.1 and 20 parts of an alcohol-soluble and water-insoluble resin, approximately between 0.1 and 15 parts of ethyl cellulose , approximately between 0.1 and 15 parts of a cosmetic pigment and approximately between 50 and 99 parts of an organic solvent; and (b) a composition that removes the cosmetic, which includes an aqueous solution between about 0.5 and 10 parts of a mild detergent, selected from the group consisting of sodium lauryl sulfate, polyoxyethylene-polyoxypropylene glycol and cocoanfor acetate. and approximately between 0.1 and 5 parts of a condom, selected from the group consisting of sodium benzoate, phenoxy-ethanol and Quaternium 15.
- 55. A case to improve the appearance of the lips, this case comprises: (a) a cosmetic, which includes approximately 0.1 to 20 parts of an alcohol-soluble and water-insoluble resin, approximately 0.1 to 15 parts of ethyl cellulose, approximately 0.1 to 15 parts of a cosmetic pigment and approximately 50 to 99 parts of a organic solvent; and (b) a composition that removes the cosmetic, according to claim 44.
- 56. The kit of claim 54, further comprising a composition that improves the cosmetic finish, including silicone, a lipophilic gelling agent and a preservative.
- 57. The kit of claim 55, further comprising a composition that improves the finish of a cosmetic, including silicone, a lipophilic gelling agent and a condom.
- 58. The kit of claim 54, further comprising a powder that enhances color.
- 59. The kit of claim 55, further comprising a powder that enhances color.
- 60. The kit of claim 55, wherein the color improving powder comprises at least one pressed dye, a wax and a condom.
- 61. The kit of claim 59, wherein the color improving powder comprises at least one pressed dye, a wax and a condom.
- 62. A method for improving the appearance of an area of the body, selected from the group consisting of the lips, nails, area of the eyes, or scalp, this method comprises applying the cosmetic of claim 1 to this area of the body .
- 63. A method, according to claim 62, further comprising applying a composition, which improves the finish of a cosmetic, which includes silicone, a lipophilic gelling agent and a condom, to the body area.
- 64. A method, according to claim 62, further comprising increasing the color of the body area by adding the composition that increases the color of the cosmetic to said area of the body.
- 65. The method of claim 63, wherein the area of the body is that of the lips, nails or area of the eye.
- 66. A method for increasing the appearance, comprising applying a color-increasing powder to an area of the body, having the composition of claim 1.
- 67. The method of claim 66, wherein the powder increases the color It comprises the composition of claim 53.
- 68. The method of claim 67, wherein the area of the body is that of the lips, nails or area of the eye.
- 69. A method for removing a cosmetic, according to claim 1, comprising applying an aqueous composition that includes approximately between 0.5 and 5 parts of sodium borate.
- 70. A method for removing a cosmetic, according to claim 1, comprising applying a composition comprised of a chelating agent,
- 71. The method of claim 70, wherein the chelating agent is in an aqueous solution or in an alcohol solution.
- 72. The method of claim 69, wherein the composition is applied to the area of the body selected from the group consisting of that of the lips, nails, scalp, or area of the eyes.
- 73. The method of claim 70, wherein the composition is applied to the body area selected from the group consisting of that of the lips, nails, scalp or area of the eyes.
- 74. The method according to claim 69, wherein the composition improving the cosmetic finish, comprising the silicone, a lipophilic gelling agent and a condom, is also removed.
- 75. The method according to claim 70, wherein the composition improving the finish of the cosmetic, comprising the silicone, a lipophilic gelling agent and a condom, is also removed.
- 76. The method according to claim 69, wherein the composition that improves the color of the cosmetic, comprising at least one pressed dye, a wax and a condom, is also removed.
- 77. The method according to claim 70, wherein the composition that improves the color of the cosmetic, comprising at least one pressed dye, a wax and a condom, is also removed.
- 78. A composition for applying color around the eyes, comprising approximately between 0.1 and 20 parts of a water-soluble resin, approximately between 0.1 and 15 parts of a cosmetic pigment and approximately between 0.5 and 4 parts of Aminonathyl, amino-methyl- propanol
- 79. A method for improving the appearance of the eyes, which comprises applying the composition of claim 74 to the area around the eyes. SUMMARY OF THE INVENTION An improved cosmetic, which employs a color agent and a plasticizer in a volatile solvent, which includes a film-forming agent, which preferably has as components an Amphomer and ethyl-cellulose, as well as a cosmetic pigment. The resulting cosmetic is insoluble in waand has a greastaying power than that of a conventional lipstick. The new cosmetic, once it dries, does not run or detach on beverage containers, on fabrics or on human skin. The finish is so transparent that the cosmetic can be applied in at least three successive layers without accumulation of masses or crack formation. Once applied in this way, while allowing each layer to dry between each successive application, a person can take a shower, swim, smoke, kiss or drink without leaving cosmetic stains on cups of coffee, cheeks or necklaces. Compositions are also provided to increase the cosmetic finish. These compositions transform the cosmetic finish from a matte finish to a highly glossy finish. The compositions that improve the finish also wet and condition the lips, and may include protective compounds. Also, compositions for improving the color of the cosmetic are provided. The present invention also relates to formulations for removing the above compositions from the lips. Also provided are kits or equipment that include the above compositions and methods for using these compositions.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/440,780 US5747017A (en) | 1995-05-15 | 1995-05-15 | Lip cosmetic |
| US08440780 | 1995-05-15 | ||
| PCT/US1996/006917 WO1996036310A1 (en) | 1995-05-15 | 1996-05-15 | Smear-resistant cosmetic |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MX9708773A MX9708773A (en) | 1998-03-31 |
| MXPA97008773A true MXPA97008773A (en) | 1998-10-15 |
Family
ID=
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