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MX9710097A - Conducto de luz acrilico flexible, y de estabilidad foto-termal mejorada. - Google Patents

Conducto de luz acrilico flexible, y de estabilidad foto-termal mejorada.

Info

Publication number
MX9710097A
MX9710097A MX9710097A MX9710097A MX9710097A MX 9710097 A MX9710097 A MX 9710097A MX 9710097 A MX9710097 A MX 9710097A MX 9710097 A MX9710097 A MX 9710097A MX 9710097 A MX9710097 A MX 9710097A
Authority
MX
Mexico
Prior art keywords
conditions
thermal
combination
thermal stability
photo
Prior art date
Application number
MX9710097A
Other languages
English (en)
Other versions
MXPA97010097A (es
Inventor
Casmir Stanislaus Ilenda
Phelps Brian Johnson
Michael Paul Hallden-Abberton
Original Assignee
Rohm & Haas
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rohm & Haas filed Critical Rohm & Haas
Publication of MX9710097A publication Critical patent/MX9710097A/es
Publication of MXPA97010097A publication Critical patent/MXPA97010097A/es

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/0008Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/005Stabilisers against oxidation, heat, light, ozone
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/10Esters; Ether-esters
    • C08K5/101Esters; Ether-esters of monocarboxylic acids
    • C08K5/105Esters; Ether-esters of monocarboxylic acids with phenols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/49Phosphorus-containing compounds
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/04Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
    • G02B1/045Light guides
    • G02B1/046Light guides characterised by the core material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/09Articles with cross-sections having partially or fully enclosed cavities, e.g. pipes or channels
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/02Optical fibres with cladding with or without a coating
    • G02B6/02033Core or cladding made from organic material, e.g. polymeric material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913Rod, strand, filament or fiber
    • Y10T428/2933Coated or with bond, impregnation or core

Landscapes

  • Chemical & Material Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • General Physics & Mathematics (AREA)
  • Optical Fibers, Optical Fiber Cores, And Optical Fiber Bundles (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Un conducto de luz acrílico tiene una estabilidad termal y fototermal para muchos propositos, pero es deficiente al mantener la claridad, color y buenas propiedades opticas bajo condiciones de exposicion a temperaturas altas, especialmente en combinacion con la exposicion durante periodos largos al paso de luz. La estabilidad termal mejorada, como se refleja en la formacion de color reducida, puede impartirse ajustando las condiciones de polimerizacion para producir el polímero de nucleo no curado de la construccion de nucleo/revestimiento con un contenido de vinilo terminal muy reducido, de preferencia por debajo de 0.5 grupos de vinilo/1000 unidades de monomero. Esta mejora de proceso, en combinacion con la adicion seleccionada de una combinacion de ciertos fenoles impedidos y fosfitos orgánicos hidrolíticamente estables, produce una mejora substancial en la resistencia a la decoloracion bajo condiciones fototermales, mientras se mantiene la resistencia a la decoloracion bajo condiciones termales. Las condiciones del proceso conocido, que no producen un contenido vinilo terminal más bajo, en combinacion con los aditivos seleccionados, también producen conductos acrílicos de luz con una estabilidad fototermal mucho muy mejorada.
MXPA/A/1997/010097A 1996-12-17 1997-12-11 Conducto de luz acrilico flexible, y de estabilidad foto-termal mejorada MXPA97010097A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US3302496P 1996-12-17 1996-12-17
US033024 1996-12-17

Publications (2)

Publication Number Publication Date
MX9710097A true MX9710097A (es) 1998-06-28
MXPA97010097A MXPA97010097A (es) 1998-10-30

Family

ID=

Also Published As

Publication number Publication date
JPH10186147A (ja) 1998-07-14
TW349957B (en) 1999-01-11
SK171497A3 (en) 2000-04-10
EP0849315B1 (en) 2000-06-28
BR9706370A (pt) 1999-06-08
EP0849315A1 (en) 1998-06-24
DE69702379D1 (de) 2000-08-03
US6207747B1 (en) 2001-03-27
CZ401297A3 (cs) 1998-09-16
DE69702379T2 (de) 2001-03-22
KR19980064284A (ko) 1998-10-07
CA2223380A1 (en) 1998-06-17

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