MX9708641A - Adhesivos sensibles a la presion, en base a acrilico, pigmentados, curados con radiacion ultravioleta, y metodo para la fabricacion de los mismos. - Google Patents
Adhesivos sensibles a la presion, en base a acrilico, pigmentados, curados con radiacion ultravioleta, y metodo para la fabricacion de los mismos.Info
- Publication number
- MX9708641A MX9708641A MX9708641A MX9708641A MX9708641A MX 9708641 A MX9708641 A MX 9708641A MX 9708641 A MX9708641 A MX 9708641A MX 9708641 A MX9708641 A MX 9708641A MX 9708641 A MX9708641 A MX 9708641A
- Authority
- MX
- Mexico
- Prior art keywords
- adhesives
- cured
- pressure sensitive
- sensitive adhesives
- hydrogen
- Prior art date
Links
- 239000004820 Pressure-sensitive adhesive Substances 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 title 1
- 239000000178 monomer Substances 0.000 abstract 4
- 239000000853 adhesive Substances 0.000 abstract 3
- 230000001070 adhesive effect Effects 0.000 abstract 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 2
- 229920006243 acrylic copolymer Polymers 0.000 abstract 2
- 239000000049 pigment Substances 0.000 abstract 2
- 150000003512 tertiary amines Chemical class 0.000 abstract 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 abstract 1
- GDFCSMCGLZFNFY-UHFFFAOYSA-N Dimethylaminopropyl Methacrylamide Chemical compound CN(C)CCCNC(=O)C(C)=C GDFCSMCGLZFNFY-UHFFFAOYSA-N 0.000 abstract 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 abstract 1
- 125000005250 alkyl acrylate group Chemical group 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 238000004132 cross linking Methods 0.000 abstract 1
- 150000001991 dicarboxylic acids Chemical class 0.000 abstract 1
- 150000005690 diesters Chemical class 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 150000003254 radicals Chemical class 0.000 abstract 1
- 230000002195 synergetic effect Effects 0.000 abstract 1
- 239000004408 titanium dioxide Substances 0.000 abstract 1
- 125000002348 vinylic group Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/28—Non-macromolecular organic substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/54—Inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
- C09J2301/302—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
En la presente invencion de proporcionan adhesivos sensibles a la presion que curan para proporcionar una gran fuerza cohesiva, a temperatura ambiente y a temperaturas elevadas, y a un método para fabricar esos adhesivos. Los adhesivos comprenden un copolímero acrílico preparado o mezclado con un pigmento y un fotoiniciador que extrae o capta hidrogeno. También se puede adicionar un agente que proporcione adhesividad y/o un acrilato o metacrilato multifuncional. EL copolímero acrílico se prepara a partir de una mezcla monomérica substancialmente libre de ácido, de al menos un acrilato de alquilo y de un monomero que contenga amina terciaria, tal como la DMAPMA. También se incluyen, preferentemente, otros monomeros que incluyen monomeros vinílicos, polares y diésteres de ácidos dicarboxílicos atilénicamente insaturados. A pesar de la presencia de dioxido de titanio u otros pigmentos, los copolímeros preparados o mezclados, se curan mediante radiacion ultravioleta para proporcionar una gran fuerza cohesiva, a través de la combinacion de grupos funcionales de amina terciaria y fotoiniciadores que extraen o captan hidrogeno, que forman un efecto sinergístico cuando se irradian, conduciendo a la formacion de radiaciones libres y a la reticulacion del polímero. También se proporcionan adhesivos no pigmentados.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US43851795A | 1995-05-10 | 1995-05-10 | |
| US438517 | 1995-05-10 | ||
| PCT/US1996/006132 WO1996035725A1 (en) | 1995-05-10 | 1996-05-01 | Pigmented, uv-cured, acrylic-based, pressure sensitive adhesives, and method for making same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MXPA97008641A MXPA97008641A (es) | 1998-02-01 |
| MX9708641A true MX9708641A (es) | 1998-02-28 |
Family
ID=23740937
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX9708641A MX9708641A (es) | 1995-05-10 | 1996-05-01 | Adhesivos sensibles a la presion, en base a acrilico, pigmentados, curados con radiacion ultravioleta, y metodo para la fabricacion de los mismos. |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US5686504A (es) |
| EP (1) | EP0824551A4 (es) |
| AU (1) | AU5635796A (es) |
| CA (1) | CA2220409C (es) |
| MX (1) | MX9708641A (es) |
| WO (1) | WO1996035725A1 (es) |
Families Citing this family (52)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6277229B1 (en) | 1995-08-25 | 2001-08-21 | Avery Dennison Corporation | Image transfer sheets and a method of manufacturing the same |
| US6080261A (en) * | 1995-08-25 | 2000-06-27 | Popat; Ghanshyam H. | Adhesive image transfer technique |
| US6824839B1 (en) | 1995-08-25 | 2004-11-30 | Avery Dennison Corporation | Water-activated polymers and adhesive image transfer technique |
| US20030108730A1 (en) * | 2000-02-14 | 2003-06-12 | John Francis | Opaque polyester film as substrate with white coatings on both sides |
| US6174578B1 (en) * | 1997-10-24 | 2001-01-16 | Rexam Industries Corp. | Radiation deactivatable adhesive tape |
| US6544634B1 (en) * | 1999-03-19 | 2003-04-08 | Pinnacle Products Group, Ltd. | Graphic image fusion |
| US7927688B2 (en) * | 1999-03-19 | 2011-04-19 | Standard Register Company | Security information and graphic image fusion |
| US7369048B2 (en) * | 1999-03-19 | 2008-05-06 | Fusion Graphics, Inc. | RFID systems and graphic image fusion |
| US6429235B1 (en) | 1999-08-27 | 2002-08-06 | Cognis Corporation | Energy-curable composition for making a pressure sensitive adhesive |
| US11768321B2 (en) | 2000-01-21 | 2023-09-26 | Viavi Solutions Inc. | Optically variable security devices |
| DE10008840A1 (de) | 2000-02-25 | 2001-09-06 | Beiersdorf Ag | Strukturierte UV-vernetzte Acrylathaftklebemassen |
| DE10008842C1 (de) | 2000-02-25 | 2001-06-28 | Beiersdorf Ag | Polymerblends |
| DE10008843A1 (de) | 2000-02-25 | 2001-09-06 | Beiersdorf Ag | Polare Acrylathaftklebemassen |
| JP2001240842A (ja) * | 2000-02-28 | 2001-09-04 | Nitto Denko Corp | 紫外線硬化型粘着剤組成物とその粘着シ―ト類 |
| US6565968B1 (en) | 2000-04-12 | 2003-05-20 | Avery Dennison Corporation | UV-curable pressure-sensitive adhesives and protective coatings |
| DE10049669A1 (de) | 2000-10-06 | 2002-04-11 | Tesa Ag | Verfahren zur Herstellung von vernetzten Acrylatschmelzhaftklebemassen |
| EP1245656A1 (en) * | 2001-03-30 | 2002-10-02 | 3M Innovative Properties Company | Transparent pressure-sensitive adhesive layer |
| US20040137222A1 (en) * | 2001-03-30 | 2004-07-15 | Welke Siegfried K. | Transparent pressure-sensitive adhesive layer |
| DE10129608A1 (de) | 2001-06-20 | 2003-05-28 | Tesa Ag | Stripfähige Systeme auf Basis von Acrylatblockcopolymeren |
| US6908586B2 (en) * | 2001-06-27 | 2005-06-21 | Fusion Uv Systems, Inc. | Free radical polymerization method having reduced premature termination, apparatus for performing the method and product formed thereby |
| JP2004262957A (ja) * | 2003-01-30 | 2004-09-24 | Mitsubishi Plastics Ind Ltd | ホットメルト型紫外線架橋透明粘着剤、透明粘着シート及び積層体 |
| US20040180169A1 (en) * | 2003-02-18 | 2004-09-16 | Jennifer Slabe | Pressure sensitive adhesive constructions of light weight paper and methods of making the same |
| DE50309603D1 (de) * | 2003-05-30 | 2008-05-21 | Tesa Ag | Polyacrylathaltige haftklebemasse und -artikel sowie zugehöriges hotmelt-verarbeitungsverfahren |
| US7262242B2 (en) | 2004-02-18 | 2007-08-28 | Eastman Chemical Company | Aromatic/acrylate tackifier resin and acrylic polymer blends |
| US7332540B2 (en) | 2004-02-18 | 2008-02-19 | Eastman Chemical Company | Aromatic-acrylate tackifier resins |
| US7238732B2 (en) | 2004-02-18 | 2007-07-03 | Eastman Chemical Company | Radiation-curable adhesive compositions |
| DE102004044085A1 (de) * | 2004-09-09 | 2006-03-16 | Tesa Ag | Haftklebemasse mit dualem Vernetzungsmechanismus |
| US20060177649A1 (en) * | 2005-02-07 | 2006-08-10 | Clark Mark D | Methods of blocking stains on a substrate to be painted, and composites suitable for use in such methods |
| TW200636032A (en) * | 2005-04-13 | 2006-10-16 | Lg Chemical Ltd | Acrylic adhesive composition having excellent impact resistance, optical film using the adhesive composition, and liquid crystal display comprising the optical film |
| US12204120B2 (en) | 2006-03-06 | 2025-01-21 | Viavi Solutions Inc. | Optically variable security devices |
| EP1832439B1 (en) * | 2006-03-06 | 2014-04-23 | JDS Uniphase Corporation | Article having an optical effect |
| US20080302487A1 (en) | 2007-06-07 | 2008-12-11 | Closure Medical Corporation | Mesh dispenser |
| US8765217B2 (en) | 2008-11-04 | 2014-07-01 | Entrotech, Inc. | Method for continuous production of (meth)acrylate syrup and adhesives therefrom |
| US8329079B2 (en) | 2009-04-20 | 2012-12-11 | Entrochem, Inc. | Method and apparatus for continuous production of partially polymerized compositions and polymers therefrom |
| US10083634B2 (en) | 2010-11-15 | 2018-09-25 | Taylor Communications, Inc. | In-mold labeled article and method |
| JP6014265B2 (ja) * | 2012-08-31 | 2016-10-25 | アームストロング ワールド インダストリーズ インコーポレーテッド | 耐久性のあるuv硬化性コーティング |
| EP2733186A1 (en) * | 2012-11-19 | 2014-05-21 | 3M Innovative Properties Company | Highly tackified acrylate pressure sensitive adhesives |
| JP6199487B2 (ja) * | 2013-06-19 | 2017-09-20 | エルジー・ケム・リミテッド | 粘着剤組成物 |
| TWI593153B (zh) * | 2013-09-30 | 2017-07-21 | 樂金顯示科技股份有限公司 | 有機電子裝置及其應用 |
| JP6571667B2 (ja) * | 2014-08-29 | 2019-09-04 | スリーエム イノベイティブ プロパティズ カンパニー | 感圧接着剤組成物、マーキングフィルム及び再帰性反射シート |
| SG11201705084QA (en) * | 2014-12-22 | 2017-07-28 | 3M Innovative Properties Co | Tackified acrylate pressure sensitive adhesives with low acid content |
| EP3237541B1 (en) | 2014-12-22 | 2024-07-10 | 3M Innovative Properties Company | Compositions and films comprising polylactic acid polymer, polyvinyl acetate polymer and plasticizer |
| TWI586780B (zh) | 2015-03-23 | 2017-06-11 | 阿科瑪法國公司 | 壓敏性黏合劑 |
| DE102015217131A1 (de) | 2015-09-08 | 2017-03-09 | Tesa Se | Klebharz-modifizierte Haftklebemasse |
| WO2017200756A1 (en) | 2016-05-20 | 2017-11-23 | 3M Innovative Properties Company | Oriented polylactic acid polymer based film |
| WO2017222824A1 (en) | 2016-06-21 | 2017-12-28 | 3M Innovative Properties Company | Graphic articles comprising semicrystalline polylactic acid based film |
| WO2018005585A1 (en) | 2016-06-29 | 2018-01-04 | 3M Innovative Properties Company | Ionizing radiation crosslinkable tackifed (meth)acrylate (co)polymer pressure sensitive adhesives with low acid content |
| CN108300332B (zh) * | 2017-10-23 | 2021-01-26 | 广东工业大学 | 一种光固化压敏胶、其制备方法及压敏胶带 |
| DE102018222213A1 (de) * | 2018-12-18 | 2020-06-18 | Beiersdorf Ag | Klebmasse zur Verklebung auf der Haut |
| KR20240060706A (ko) | 2018-12-28 | 2024-05-08 | 생-고뱅 퍼포먼스 플라스틱스 코포레이션 | 접착제 조성물 및 이의 형성 방법 |
| WO2020139673A1 (en) | 2018-12-28 | 2020-07-02 | Saint-Gobain Performance Plastics Corporation | Adhesive composition and methods of forming the same |
| DE102021006273B4 (de) | 2021-12-21 | 2024-06-13 | Lohmann Gmbh & Co. Kg | Indikatormischung |
Family Cites Families (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2956904A (en) * | 1954-11-04 | 1960-10-18 | Minnesota Mining & Mfg | Pressure-sensitive adhesive tapes |
| US3328194A (en) * | 1962-12-28 | 1967-06-27 | Kendall & Co | Irradiation of pressure-sensitive adhesive tape in an oxygen-free state |
| DE1720604A1 (de) * | 1967-01-18 | 1971-08-05 | Hoechst Ag | Verfahren zur Herstellung vernetzter Copolymerisate |
| US3759807A (en) * | 1969-01-28 | 1973-09-18 | Union Carbide Corp | Photopolymerization process using combination of organic carbonyls and amines |
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| CA1065085A (en) * | 1974-05-20 | 1979-10-23 | John P. Guarino | Radiation curable coating |
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| US4038164A (en) * | 1975-09-18 | 1977-07-26 | Stauffer Chemical Company | Photopolymerizable aryl and heterocyclic glyoxylate compositions and process |
| US4077859A (en) * | 1976-10-04 | 1978-03-07 | Celanese Corporation | Polyunsaturated halogenated monomers for use in ultraviolet coating systems |
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| US4234674A (en) * | 1979-08-08 | 1980-11-18 | Monsanto Company | Amino-functional photopolymer compositions and photo-oxidation imaging processes employing same |
| US4281152A (en) * | 1980-06-20 | 1981-07-28 | Gulf Oil Corporation | Acrylate monomers and photopolymerizable compositions containing same |
| US4364972A (en) * | 1981-01-16 | 1982-12-21 | Minnesota Mining And Manufacturing Company | Pressure-sensitive adhesive copolymers of acrylic acid ester and N-vinyl pyrrolidone |
| US4379201A (en) * | 1981-03-30 | 1983-04-05 | Minnesota Mining And Manufacturing Company | Multiacrylate cross-linking agents in pressure-sensitive photoadhesives |
| US4354008A (en) * | 1981-05-06 | 1982-10-12 | National Starch And Chemical Corporation | Pressure sensitive, hot melt adhesives |
| DE3234045A1 (de) * | 1981-09-17 | 1983-03-24 | Daicel Chemical Industries, Ltd., Sakai, Osaka | 2-methylpropylenglycol-monoacrylat oder -diacrylat und das diacrylat enthaltende lichtempfindliche zusammensetzung |
| US4574130A (en) * | 1982-07-03 | 1986-03-04 | Smith & Nephew Associated Companies P.L.C. | Polymerizable compounds |
| IT1176018B (it) * | 1984-04-12 | 1987-08-12 | Lamberti Flli Spa | Chetoni aromatico alifatici polimerici o polimerizzabili adatti all'impiego come fotoiniziatori di polimerizzazione |
| DE3512179A1 (de) * | 1985-04-03 | 1986-12-04 | Merck Patent Gmbh, 6100 Darmstadt | Fotoinitiatoren fuer die fotopolymerisation in waessrigen systemen |
| DE3534645A1 (de) * | 1985-09-28 | 1987-04-02 | Merck Patent Gmbh | Copolymerisierbare fotoinitiatoren |
| US4714655A (en) * | 1985-10-04 | 1987-12-22 | Avery International Corporation | Pressure-sensitive adhesive containing heat-sensitive materials, and method of making the same |
| US4737559A (en) * | 1986-05-19 | 1988-04-12 | Minnesota Mining And Manufacturing Co. | Pressure-sensitive adhesive crosslinked by copolymerizable aromatic ketone monomers |
| EP0258719A3 (de) * | 1986-08-30 | 1989-07-05 | Ciba-Geigy Ag | Zweischichtensystem |
| US4814215A (en) * | 1986-11-07 | 1989-03-21 | The B. F. Goodrich Company | Adhesive composition, process, and product |
| US5028484A (en) * | 1987-08-14 | 1991-07-02 | Minnesota Mining And Manufacturing Company | Pressure-sensitive adhesive |
| US5264533A (en) * | 1988-06-16 | 1993-11-23 | Basf Aktiengesellschaft | Benzophenone derivatives and their preparation |
| JP2604453B2 (ja) * | 1988-12-14 | 1997-04-30 | 積水化学工業株式会社 | アクリル系粘着テープ |
| DE3844445A1 (de) * | 1988-12-31 | 1990-07-19 | Basf Ag | Uv-vernetzbare massen auf basis von (meth)-acrylesterpolymerisaten |
| DE3914375A1 (de) * | 1989-04-29 | 1990-11-15 | Basf Ag | Durch ultraviolette strahlung haertbares mittel |
| US5278271A (en) * | 1989-05-02 | 1994-01-11 | Saiden Chemical Industry Co., Ltd. | Pressure sensitive adhesive composition and a pressure sensitive adhesive sheet, a label and a laminate utilizing it |
| DE3942232A1 (de) * | 1989-12-21 | 1991-06-27 | Beiersdorf Ag | Schmelzhaftkleber auf acrylatbasis |
-
1996
- 1996-05-01 WO PCT/US1996/006132 patent/WO1996035725A1/en not_active Ceased
- 1996-05-01 AU AU56357/96A patent/AU5635796A/en not_active Abandoned
- 1996-05-01 CA CA002220409A patent/CA2220409C/en not_active Expired - Fee Related
- 1996-05-01 EP EP96913312A patent/EP0824551A4/en not_active Withdrawn
- 1996-05-01 MX MX9708641A patent/MX9708641A/es not_active IP Right Cessation
- 1996-11-19 US US08/752,432 patent/US5686504A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| WO1996035725A1 (en) | 1996-11-14 |
| CA2220409C (en) | 2002-07-16 |
| CA2220409A1 (en) | 1996-11-14 |
| EP0824551A1 (en) | 1998-02-25 |
| US5686504A (en) | 1997-11-11 |
| AU5635796A (en) | 1996-11-29 |
| EP0824551A4 (en) | 1999-04-28 |
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