MX9308018A - Metodo para la preparacion continua de una mezcla de una cicloalcanona un cicloalcanol y un hidroperoxido de cicloalquilo. - Google Patents
Metodo para la preparacion continua de una mezcla de una cicloalcanona un cicloalcanol y un hidroperoxido de cicloalquilo.Info
- Publication number
- MX9308018A MX9308018A MX9308018A MX9308018A MX9308018A MX 9308018 A MX9308018 A MX 9308018A MX 9308018 A MX9308018 A MX 9308018A MX 9308018 A MX9308018 A MX 9308018A MX 9308018 A MX9308018 A MX 9308018A
- Authority
- MX
- Mexico
- Prior art keywords
- mixture
- continuous preparation
- cycloalcanol
- cycloalcanone
- cycloalkyl hydroperoxide
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 2
- 239000000203 mixture Substances 0.000 title abstract 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 title 1
- 150000001924 cycloalkanes Chemical class 0.000 abstract 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000010924 continuous production Methods 0.000 abstract 1
- -1 cycloalkyl hydroperoxide Chemical compound 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 150000002989 phenols Chemical class 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
- C07C29/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C407/00—Preparation of peroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C409/00—Peroxy compounds
- C07C409/02—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
- C07C409/14—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom belonging to a ring other than a six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/18—Systems containing only non-condensed rings with a ring being at least seven-membered
- C07C2601/20—Systems containing only non-condensed rings with a ring being at least seven-membered the ring being twelve-membered
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
La presente invención proporciona un método para la preparación continua de una mezcla de una cicloalcanona, un cicloalcanol y un hidroperóxido de cicloalquilo, de acuerdo con el cual se oxida el cicloalcano correspondiente en el que el alcano cíclico tiene entre 5 y 20 átomos de carbono, en un proceso continuo, con ayuda de un gas que contiene oxígeno, en ausencia de un catalizador metálico, a una temperatura entre 130 y 200º C, realizándose la oxidación al menos parcialmente en presencia entre 0,002 y 2 mmol de un compuesto fenólico por kg de mezcla de reacción (mmo1/kg).
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BE9201101A BE1006451A3 (nl) | 1992-12-16 | 1992-12-16 | Werkwijze voor de continue bereiding van een mengsel van een cycloalkanon, cycloalkanol en een cycloalkylhydroperoxide. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX9308018A true MX9308018A (es) | 1994-08-31 |
Family
ID=3886588
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX9308018A MX9308018A (es) | 1992-12-16 | 1993-12-15 | Metodo para la preparacion continua de una mezcla de una cicloalcanona un cicloalcanol y un hidroperoxido de cicloalquilo. |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US5406001A (es) |
| EP (1) | EP0674613B1 (es) |
| JP (1) | JPH08504437A (es) |
| KR (1) | KR100299587B1 (es) |
| CN (1) | CN1058478C (es) |
| AT (1) | ATE158271T1 (es) |
| BE (1) | BE1006451A3 (es) |
| BR (1) | BR9307663A (es) |
| DE (1) | DE69314054T2 (es) |
| ES (1) | ES2108968T3 (es) |
| MX (1) | MX9308018A (es) |
| PL (1) | PL174275B1 (es) |
| RU (1) | RU2116290C1 (es) |
| TW (1) | TW277055B (es) |
| UA (1) | UA35602C2 (es) |
| WO (1) | WO1994013613A1 (es) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2127248C1 (ru) * | 1997-08-05 | 1999-03-10 | Институт химии нефти СО РАН | Способ получения циклогексанола и циклогексанона |
| RU2402520C1 (ru) * | 2009-05-28 | 2010-10-27 | Институт Катализа Им. Г.К. Борескова Сибирского Отделения Российской Академии Наук | Способ получения смеси циклогексанола и циклогексанона |
| EP3050869B1 (de) * | 2015-01-30 | 2019-10-02 | Symrise AG | Verfahren zur Herstellung von substituierten Alkylcycloalkanonen |
| KR20200116139A (ko) * | 2018-01-30 | 2020-10-08 | 바스프 에스이 | 시클로알칸의 산화 방법 |
| RU2747484C1 (ru) * | 2020-10-27 | 2021-05-05 | Публичное акционерное общество "КуйбышевАзот" | Способ получения гидропероксида циклогексила |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU197555A1 (ru) * | 1965-06-16 | 1983-09-15 | Государственный Научно-Исследовательский Институт Органических Полупродуктов И Красителей | Способ получени альдегидов или кетонов |
| US3949004A (en) * | 1971-03-16 | 1976-04-06 | Atlantic Richfield Company | Hydroperoxide production |
| SU686329A1 (ru) * | 1977-12-15 | 1982-05-07 | Предприятие П/Я Р-6603 | Способ получени гидроперекиси циклододецила Б.Я.Ладыгина |
| SU799325A1 (ru) * | 1978-01-30 | 1982-05-07 | Предприятие П/Я Р-6603 | Способ получени гидроперекисей циклоалкилов Б.Я.Ладыгина |
| US5220075A (en) * | 1992-07-17 | 1993-06-15 | Abb Lummus Crest Inc. | Initiated peroxidation of secondary carbon in alkanes and cycloalkanes |
-
1992
- 1992-12-16 BE BE9201101A patent/BE1006451A3/nl not_active IP Right Cessation
-
1993
- 1993-11-29 TW TW082110062A patent/TW277055B/zh active
- 1993-12-02 EP EP94903137A patent/EP0674613B1/en not_active Expired - Lifetime
- 1993-12-02 JP JP6514007A patent/JPH08504437A/ja active Pending
- 1993-12-02 KR KR1019950702515A patent/KR100299587B1/ko not_active Expired - Fee Related
- 1993-12-02 RU RU95114380A patent/RU2116290C1/ru active
- 1993-12-02 PL PL93309345A patent/PL174275B1/pl unknown
- 1993-12-02 WO PCT/NL1993/000259 patent/WO1994013613A1/en not_active Ceased
- 1993-12-02 DE DE69314054T patent/DE69314054T2/de not_active Expired - Fee Related
- 1993-12-02 AT AT94903137T patent/ATE158271T1/de not_active IP Right Cessation
- 1993-12-02 ES ES94903137T patent/ES2108968T3/es not_active Expired - Lifetime
- 1993-12-02 BR BR9307663A patent/BR9307663A/pt not_active IP Right Cessation
- 1993-12-02 UA UA95062797A patent/UA35602C2/uk unknown
- 1993-12-15 US US08/166,344 patent/US5406001A/en not_active Expired - Fee Related
- 1993-12-15 CN CN93112701A patent/CN1058478C/zh not_active Expired - Fee Related
- 1993-12-15 MX MX9308018A patent/MX9308018A/es not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| KR950704223A (ko) | 1995-11-17 |
| CN1096026A (zh) | 1994-12-07 |
| ES2108968T3 (es) | 1998-01-01 |
| ATE158271T1 (de) | 1997-10-15 |
| RU95114380A (ru) | 1997-06-10 |
| WO1994013613A1 (en) | 1994-06-23 |
| PL309345A1 (en) | 1995-10-02 |
| DE69314054T2 (de) | 1998-04-02 |
| KR100299587B1 (ko) | 2001-11-22 |
| RU2116290C1 (ru) | 1998-07-27 |
| BR9307663A (pt) | 1999-06-29 |
| CN1058478C (zh) | 2000-11-15 |
| EP0674613A1 (en) | 1995-10-04 |
| TW277055B (es) | 1996-06-01 |
| US5406001A (en) | 1995-04-11 |
| UA35602C2 (uk) | 2001-04-16 |
| JPH08504437A (ja) | 1996-05-14 |
| PL174275B1 (pl) | 1998-07-31 |
| EP0674613B1 (en) | 1997-09-17 |
| DE69314054D1 (de) | 1997-10-23 |
| BE1006451A3 (nl) | 1994-08-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG | Grant or registration | ||
| MM | Annulment or lapse due to non-payment of fees |