MX9302555A - Poliesterpolioles diluibles con agua, procedimiento para su obtencion y composiciones de aglutinantes, diluibles con agua, a base de los mismos. - Google Patents
Poliesterpolioles diluibles con agua, procedimiento para su obtencion y composiciones de aglutinantes, diluibles con agua, a base de los mismos.Info
- Publication number
- MX9302555A MX9302555A MX9302555A MX9302555A MX9302555A MX 9302555 A MX9302555 A MX 9302555A MX 9302555 A MX9302555 A MX 9302555A MX 9302555 A MX9302555 A MX 9302555A MX 9302555 A MX9302555 A MX 9302555A
- Authority
- MX
- Mexico
- Prior art keywords
- dilutable
- water
- weight
- polyester polyols
- obtaining
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/10—Materials in mouldable or extrudable form for sealing or packing joints or covers
- C09K3/1006—Materials in mouldable or extrudable form for sealing or packing joints or covers characterised by the chemical nature of one of its constituents
- C09K3/1021—Polyurethanes or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/91—Polymers modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
- C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
- C08G18/0823—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing carboxylate salt groups or groups forming them
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/44—Polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6633—Compounds of group C08G18/42
- C08G18/6659—Compounds of group C08G18/42 with compounds of group C08G18/34
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2190/00—Compositions for sealing or packing joints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2200/00—Chemical nature of materials in mouldable or extrudable form for sealing or packing joints or covers
- C09K2200/06—Macromolecular organic compounds, e.g. prepolymers
- C09K2200/0645—Macromolecular organic compounds, e.g. prepolymers obtained otherwise than by reactions involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2200/00—Chemical nature of materials in mouldable or extrudable form for sealing or packing joints or covers
- C09K2200/06—Macromolecular organic compounds, e.g. prepolymers
- C09K2200/0645—Macromolecular organic compounds, e.g. prepolymers obtained otherwise than by reactions involving carbon-to-carbon unsaturated bonds
- C09K2200/0655—Polyesters
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S528/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S528/904—Isocyanate polymer having stated hydrophilic or hydrophobic property
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- General Chemical & Material Sciences (AREA)
- Polyurethanes Or Polyureas (AREA)
- Paints Or Removers (AREA)
- Polyesters Or Polycarbonates (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Sealing Material Composition (AREA)
Abstract
Se presentan poliésterpolioles diluibles con agua, que presentan grupos uretano, que están neutralizados en un 25 a un 100 con bases, que presentan un índice de acidez de 6 a 45 mg de KOH/g correspondiente a los grupos ácidos, un índice de hidroxilo de 20 a 250 mg de KOH/g, un peso molecular Mw de 2.000 hasta 150.000, un contenido en grupos uretano de 2 hasta 16 en peso y un contenido en grupos carboxilo de 1 a 25 en peso, un procedimiento para la obtención de tales poliésterpolioles con empleo concomitante de cantidades de componentes que presentan segmentos de carbonato tales que se alcance el contenido en grupos carbonato citado, una combinación de agentes aglutinantes diluible con agua constituida por 30 a 98 en peso de tales poliésterpolioles y 2 a 70 en peso de una resina reticulante y el empleo de los poliésterpolioles a modo de componentes aglutinantes en agentes de recubrimiento o masas de sellado.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4216536A DE4216536A1 (de) | 1992-05-19 | 1992-05-19 | Wasserverdünnbare Polyesterpolyole und ihre Verwendung |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX9302555A true MX9302555A (es) | 1994-07-29 |
Family
ID=6459247
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX9302555A MX9302555A (es) | 1992-05-19 | 1993-04-30 | Poliesterpolioles diluibles con agua, procedimiento para su obtencion y composiciones de aglutinantes, diluibles con agua, a base de los mismos. |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US5349041A (es) |
| EP (1) | EP0578940B1 (es) |
| JP (1) | JP3169476B2 (es) |
| KR (1) | KR100254747B1 (es) |
| AT (1) | ATE164861T1 (es) |
| CA (1) | CA2096287C (es) |
| DE (2) | DE4216536A1 (es) |
| ES (1) | ES2114965T3 (es) |
| MX (1) | MX9302555A (es) |
Families Citing this family (58)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5756213A (en) * | 1995-10-06 | 1998-05-26 | Basf Corporation | Curable coating composition having carbonate-containing component |
| JP3989028B2 (ja) * | 1993-08-10 | 2007-10-10 | 日本ペイント株式会社 | 水性塗料組成物およびそれを用いる塗装方法 |
| DE4406159A1 (de) * | 1994-02-25 | 1995-08-31 | Bayer Ag | Wäßrige Polyester-Polyurethan-Dispersionen und ihre Verwendung in Beschichtungsmitteln |
| US5468802A (en) * | 1994-07-18 | 1995-11-21 | Ppg Industries, Inc. | Low volatile organic content automotive refinish coating composition |
| DE19500358A1 (de) | 1995-01-09 | 1996-07-11 | Bayer Ag | Polyesterpolyole und ihre Verwendung in Zweikomponenten-Polyurethanlacken |
| DE19538061C2 (de) * | 1995-10-13 | 2001-01-04 | Basf Coatings Ag | Wasserverdünnbarer Polyester |
| JP3361244B2 (ja) * | 1997-01-08 | 2003-01-07 | 大日精化工業株式会社 | 水性ウレタン樹脂接着剤組成物 |
| EP1004608B1 (en) * | 1998-11-11 | 2004-10-20 | Minnesota Mining And Manufacturing Company | Multi-layer sheet comprising a protective polyurethane layer |
| WO2000046265A1 (de) * | 1999-02-03 | 2000-08-10 | Basf Coatings Ag | Polyurethan und seine verwendung in der wässrigen kunststofflackierung |
| DE10004723A1 (de) * | 2000-02-03 | 2001-08-09 | Bayer Ag | Wässrige Sperrschicht auf Basis von Polyurethan-Disperionen |
| US6610779B1 (en) * | 1999-02-25 | 2003-08-26 | Bayer Aktiengesellschaft | Aqueous barrier layer based on polyurethane dispersions |
| WO2000055270A1 (en) * | 1999-03-17 | 2000-09-21 | E.I. Du Pont De Nemours And Company | High solids acid etch and mar resistant clear coating composition |
| DE10216896A1 (de) | 2002-04-17 | 2003-11-13 | Goldschmidt Ag Th | Wässrige Polysiloxan-Polyurethan-Dispersion, ihre Herstellung und Verwendung in Beschichtungsmitteln |
| DE10251797A1 (de) * | 2002-11-07 | 2004-05-19 | Bayer Ag | Polyurethanharz mit hohem Carbonatgruppengehalt |
| DE10345788A1 (de) * | 2003-10-02 | 2005-04-21 | Bayer Materialscience Ag | Wässrige Beschichtungsmittel für Can Coating |
| JP2006063259A (ja) * | 2004-08-30 | 2006-03-09 | Toyobo Co Ltd | 水系分散体と水系樹脂組成物 |
| DE102004054500A1 (de) * | 2004-11-11 | 2006-05-18 | Bayer Materialscience Ag | Polyester-Polyacrylat-Dispersionen mit Reaktivverdünner auf Basis von hydroxyfunktionellen Estern |
| DE102004054499A1 (de) * | 2004-11-11 | 2006-05-18 | Bayer Materialscience Ag | Polyester-Polyacrylat-Dispersionen mit Reaktivverdünnern auf Basis von lactongruppenhaltigen Verbindungen |
| JP5200317B2 (ja) * | 2005-03-30 | 2013-06-05 | 東洋紡株式会社 | 末端酸変性ハイパーブランチポリエステルの水分散体およびその製造方法 |
| DE102005029626A1 (de) * | 2005-06-23 | 2007-01-04 | Bayer Materialscience Ag | Polymermischung auf Basis von Polycarbonatpolyolen |
| DE102005056434A1 (de) * | 2005-11-26 | 2007-05-31 | Bayer Materialscience Ag | Wässrige, Urethangruppen enthaltende, hydroxyfunktionelle Polyester-Dispersionen |
| DE102006053741A1 (de) * | 2006-11-15 | 2008-05-21 | Bayer Materialscience Ag | Beschichtungsmittel |
| DE502008001947D1 (de) * | 2007-03-26 | 2011-01-13 | Basf Se | Wasseremulgierbare polyisocyanate |
| US20110040030A1 (en) * | 2008-05-14 | 2011-02-17 | Basf Se | Use of a cyclohexane diol mixture for manufacturing polymers |
| CN102333806B (zh) * | 2009-02-26 | 2014-06-04 | 宇部兴产株式会社 | 水性聚氨酯树脂分散体及其制造方法 |
| EP2239286A1 (de) | 2009-04-08 | 2010-10-13 | Bayer MaterialScience AG | Wässrige Bindemittel-Dispersion für Zweikomponenten-Lacke |
| US20110021694A1 (en) * | 2009-07-23 | 2011-01-27 | E.I. Du Pont De Nemours And Company | Polyesterurethane for coating compositions |
| KR101131888B1 (ko) * | 2009-11-27 | 2012-04-03 | 주식회사 노루비케미칼 | 플라스틱용 도료 조성물 및 이의 제조방법 |
| EP2348060A1 (de) * | 2010-01-21 | 2011-07-27 | Bayer MaterialScience AG | Urethanisierte Polyester |
| WO2012069414A1 (en) | 2010-11-25 | 2012-05-31 | Bayer Materialscience Ag | Polyurethane resin with high carbonate group content |
| AU2012244858A1 (en) | 2011-04-19 | 2013-11-07 | Bayer Intellectual Property Gmbh | Aqueous resin composition comprising a polyester-polyurethane resin and a dendritic polyol |
| US8354151B1 (en) | 2011-07-06 | 2013-01-15 | Bayer Materialscience Llc | Waterborne polyurethane coating compositions |
| US20130011590A1 (en) * | 2011-07-06 | 2013-01-10 | Bayer Materialscience Ag | Waterborne polyurethane coating compositions |
| US20140142244A1 (en) | 2011-07-15 | 2014-05-22 | Bayer Intellectual Property Gmbh | Aqueous resin composition comprising a polyester-polyurethane resin including a dendritic polyol |
| US20130034741A1 (en) * | 2011-08-04 | 2013-02-07 | Ppg Industries Ohio, Inc. | Branched polyester polymers comprising isophthalic acid and coatings comprising the same |
| KR20140101841A (ko) * | 2011-12-09 | 2014-08-20 | 바스프 에스이 | 수성 폴리우레탄 분산액의 복합 필름 라미네이션용 용도 |
| EP2900722B1 (en) | 2012-09-28 | 2016-10-19 | Basf Se | Water-dispersible polyisocyanates |
| WO2014067833A1 (de) * | 2012-11-02 | 2014-05-08 | Basf Se | Verwendung von wässrigen polyurethandispersionen zur kaschierung von formkörpern |
| WO2015185367A1 (de) * | 2014-06-06 | 2015-12-10 | Basf Coatings Gmbh | Selektiv abbeizbare beschichtungen für metall- und kunststoffuntergründe |
| KR101766013B1 (ko) * | 2015-06-16 | 2017-08-07 | 현대자동차주식회사 | 고탄성 수성 접착제 조성물 및 이를 이용한 성형품의 표면처리 방법 |
| EP3109269B1 (de) | 2015-06-25 | 2018-10-31 | Covestro Deutschland AG | Harnstofffreie polyurethan-dispersionen |
| WO2017058504A1 (en) * | 2015-10-02 | 2017-04-06 | Resinate Materials Group, Inc. | High performance coatings |
| WO2017097668A1 (en) | 2015-12-09 | 2017-06-15 | Basf Se | Water-dispersible polyisocyanates |
| WO2019068529A1 (en) | 2017-10-06 | 2019-04-11 | Basf Se | DISPERSIBLE POLYISOCYANATES IN WATER |
| CN111201275B (zh) | 2017-10-09 | 2022-07-01 | 欧文斯科宁知识产权资产有限公司 | 含水粘合剂组合物 |
| JP2020007419A (ja) * | 2018-07-04 | 2020-01-16 | Dic株式会社 | ポリエステルポリオールの中和物、樹脂組成物、およびポリエステルポリオールの中和物の製造方法 |
| EP3953536A4 (en) | 2019-04-09 | 2023-01-18 | Owens Corning Intellectual Capital, LLC | INSULATION PRODUCTS MOLDED WITH AQUEOUS BINDER COMPOSITIONS |
| KR102889829B1 (ko) * | 2019-04-09 | 2025-11-21 | 오웬스 코닝 인텔렉츄얼 캐피탈 엘엘씨 | 수성 결합제 조성물 |
| AU2020401048B2 (en) | 2019-12-09 | 2026-02-05 | Owens Corning Intellectual Capital, Llc | Fiberglass insulation product |
| US11813833B2 (en) | 2019-12-09 | 2023-11-14 | Owens Corning Intellectual Capital, Llc | Fiberglass insulation product |
| US20230095196A1 (en) | 2020-01-30 | 2023-03-30 | Basf Se | Color-stable curing agent compositions comprising water-dispersible polyisocyanates |
| CN115279851B (zh) * | 2020-02-20 | 2024-07-19 | 巴斯夫欧洲公司 | 适用于有机溶剂基双组分聚氨酯涂料组合物的超支化聚酯多元醇 |
| EP3875511A1 (de) * | 2020-03-05 | 2021-09-08 | Covestro Deutschland AG | Hochtemperatur-vernetzerdispersion |
| CA3197306A1 (en) | 2020-10-01 | 2022-04-07 | Owens Corning Intellectual Capital, Llc | B-stageable aqueous binder compositions |
| CN117597378A (zh) * | 2020-12-28 | 2024-02-23 | Ppg工业俄亥俄公司 | 聚酯聚合物 |
| JPWO2022158606A1 (es) * | 2021-01-25 | 2022-07-28 | ||
| US12428523B2 (en) | 2021-05-05 | 2025-09-30 | H.B. Fuller Company | Polyurethanes and moisture curable compositions including the same |
| JP7722549B1 (ja) * | 2024-12-26 | 2025-08-13 | artience株式会社 | 反応性接着剤、積層体及び包装体 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1022790B (de) * | 1955-10-17 | 1958-01-16 | Hudson Foam Plastics Corp | Verfahren zur Herstellung von Schaumstoffen |
| DE3836030A1 (de) * | 1988-10-22 | 1990-05-03 | Bayer Ag | Pur-dispersionen und loesemittel enthaltende beschichtungsmassen und deren verwendung zur herstellung von wasserdampfdurchlaessigen pur-beschichtungen |
| US5096992A (en) * | 1989-03-20 | 1992-03-17 | Reeves Brothers, Inc. | Use of modified diisocyanates for preparing linear thermoplastic polyurethane elastomers having improved properties |
| DE3936288A1 (de) * | 1989-11-01 | 1991-05-02 | Bayer Ag | In wasser dispergierbare bindemittelkombinationen, ein verfahren zur herstellung eines einbrennfuellers und dessen verwendung |
| DE3936794A1 (de) * | 1989-11-04 | 1991-05-08 | Bayer Ag | Waessriges ueberzugsmittel und die verwendung von in wasser dispergierbaren polyurethanpolyharnstoffen als bindemittel |
| DE4013710A1 (de) * | 1990-04-28 | 1991-10-31 | Bayer Ag | Verwendung von emulsionscopolymerisaten in klarlacken und ein waessriger klarlack |
-
1992
- 1992-05-19 DE DE4216536A patent/DE4216536A1/de not_active Withdrawn
-
1993
- 1993-04-30 MX MX9302555A patent/MX9302555A/es not_active IP Right Cessation
- 1993-05-07 EP EP93107452A patent/EP0578940B1/de not_active Expired - Lifetime
- 1993-05-07 DE DE59308370T patent/DE59308370D1/de not_active Expired - Lifetime
- 1993-05-07 AT AT93107452T patent/ATE164861T1/de active
- 1993-05-07 ES ES93107452T patent/ES2114965T3/es not_active Expired - Lifetime
- 1993-05-12 US US08/061,640 patent/US5349041A/en not_active Expired - Lifetime
- 1993-05-14 CA CA002096287A patent/CA2096287C/en not_active Expired - Fee Related
- 1993-05-17 JP JP13696493A patent/JP3169476B2/ja not_active Expired - Fee Related
- 1993-05-18 KR KR1019930008447A patent/KR100254747B1/ko not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CA2096287A1 (en) | 1993-11-20 |
| ES2114965T3 (es) | 1998-06-16 |
| DE59308370D1 (de) | 1998-05-14 |
| EP0578940A1 (de) | 1994-01-19 |
| CA2096287C (en) | 2003-04-15 |
| DE4216536A1 (de) | 1993-11-25 |
| US5349041A (en) | 1994-09-20 |
| EP0578940B1 (de) | 1998-04-08 |
| JPH0632883A (ja) | 1994-02-08 |
| KR100254747B1 (ko) | 2000-05-01 |
| ATE164861T1 (de) | 1998-04-15 |
| KR930023401A (ko) | 1993-12-18 |
| JP3169476B2 (ja) | 2001-05-28 |
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