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MX9301670A - Procedimiento de hidroconversion de fracciones pesadas, en fase liquida, en presencia de un catalizador disperso y de aditivos poliaromaticos. - Google Patents

Procedimiento de hidroconversion de fracciones pesadas, en fase liquida, en presencia de un catalizador disperso y de aditivos poliaromaticos.

Info

Publication number
MX9301670A
MX9301670A MX9301670A MX9301670A MX9301670A MX 9301670 A MX9301670 A MX 9301670A MX 9301670 A MX9301670 A MX 9301670A MX 9301670 A MX9301670 A MX 9301670A MX 9301670 A MX9301670 A MX 9301670A
Authority
MX
Mexico
Prior art keywords
catalyst
hydroconversion
polyaromatic
liquid phase
heavy fractions
Prior art date
Application number
MX9301670A
Other languages
English (en)
Inventor
Frederic Morel
Martin Boulinguiez
Bernard Fixari
Pierre Le Perchec
Jeanne Elmouchnino
Original Assignee
Inst Francais Du Petrole
Elf Antar France
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Inst Francais Du Petrole, Elf Antar France filed Critical Inst Francais Du Petrole
Publication of MX9301670A publication Critical patent/MX9301670A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/32—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions in the presence of hydrogen-generating compounds
    • C10G47/34—Organic compounds, e.g. hydrogenated hydrocarbons

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

Esta invención se refiere a un procedimiento para la hidroconversión en fase líquida de cargas hidrocarbonadas que contienen fracciones pesadas, y en forma más particular a su conversión profunda. Según la invención, la carga se pone en contacto con un catalizador disperso, en la presencia de un aditivo poliaromático. El catalizador está constituído por un sulfuro de un metal hidrogenante (tal como el molibdeno, níquel, cobalto) generado in situ a partir de un precursor, el aditivo lleva al menos 3 ciclos aromáticos, presenta un punto de ebullición superior a 300°C y se agrega a razón de 5 a 50 en peso de la carga. Una sinergia entre el catalizador y el aditivo, permite reducir la cantidad de catalizador y/o mejorar la conversión y la calidad de los productos.
MX9301670A 1992-03-26 1993-03-25 Procedimiento de hidroconversion de fracciones pesadas, en fase liquida, en presencia de un catalizador disperso y de aditivos poliaromaticos. MX9301670A (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9203660A FR2689137B1 (fr) 1992-03-26 1992-03-26 Procede d'hydro conversion de fractions lourds en phase liquide en presence d'un catalyseur disperse et d'additif polyaromatique.

Publications (1)

Publication Number Publication Date
MX9301670A true MX9301670A (es) 1994-05-31

Family

ID=9428109

Family Applications (1)

Application Number Title Priority Date Filing Date
MX9301670A MX9301670A (es) 1992-03-26 1993-03-25 Procedimiento de hidroconversion de fracciones pesadas, en fase liquida, en presencia de un catalizador disperso y de aditivos poliaromaticos.

Country Status (6)

Country Link
US (1) US5460714A (es)
CA (1) CA2092787C (es)
DE (1) DE4309669A1 (es)
FR (1) FR2689137B1 (es)
IT (1) IT1270973B (es)
MX (1) MX9301670A (es)

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US7645375B2 (en) * 2003-05-16 2010-01-12 Exxonmobil Research And Engineering Company Delayed coking process for producing free-flowing coke using low molecular weight aromatic additives
US7658838B2 (en) * 2003-05-16 2010-02-09 Exxonmobil Research And Engineering Company Delayed coking process for producing free-flowing coke using polymeric additives
US20050279673A1 (en) * 2003-05-16 2005-12-22 Eppig Christopher P Delayed coking process for producing free-flowing coke using an overbased metal detergent additive
US7306713B2 (en) * 2003-05-16 2007-12-11 Exxonmobil Research And Engineering Company Delayed coking process for producing free-flowing coke using a substantially metals-free additive
KR101227271B1 (ko) 2004-04-28 2013-01-28 헤드워터스 헤비 오일, 엘엘씨 콜로이드성 또는 분자상 촉매를 이용하여 중유를 개량하기위한 하이드로프로세싱 방법 및 시스템
US10941353B2 (en) 2004-04-28 2021-03-09 Hydrocarbon Technology & Innovation, Llc Methods and mixing systems for introducing catalyst precursor into heavy oil feedstock
ES2585891T3 (es) 2004-04-28 2016-10-10 Headwaters Heavy Oil, Llc Métodos y sistemas de hidroprocesamiento en lecho en ebullición
CN1950483A (zh) * 2004-04-28 2007-04-18 上游重油有限公司 固定床加氢处理法和系统，以及用来升级已有固定床系统的方法
EP1751253B1 (en) * 2004-05-14 2015-08-12 ExxonMobil Research and Engineering Company Delayed coking process for the production of substantially fre-flowing coke from a deeper cut of vacuum resid
BRPI0510522A (pt) * 2004-05-14 2007-10-30 Exxonmobil Res & Eng Co processo para produzir e remover coque, e, coque
EP1773967A1 (en) * 2004-05-14 2007-04-18 Exxonmobil Research And Engineering Company Viscoelastic upgrading of heavy oil by altering its elastic modulus
BRPI0511024A (pt) * 2004-05-14 2007-11-27 Exxonmobil Res & Eng Co processo de coqueificação retardada, e, coque
JP2007537345A (ja) * 2004-05-14 2007-12-20 エクソンモービル　リサーチ　アンド　エンジニアリング　カンパニー 油溶性多核芳香族化合物を用いたメソフェーズ抑制を介する、抑制剤により改善された熱による重油の品質向上
US7871510B2 (en) * 2007-08-28 2011-01-18 Exxonmobil Research & Engineering Co. Production of an enhanced resid coker feed using ultrafiltration
US8034232B2 (en) 2007-10-31 2011-10-11 Headwaters Technology Innovation, Llc Methods for increasing catalyst concentration in heavy oil and/or coal resid hydrocracker
US8142645B2 (en) 2008-01-03 2012-03-27 Headwaters Technology Innovation, Llc Process for increasing the mono-aromatic content of polynuclear-aromatic-containing feedstocks
US7794587B2 (en) * 2008-01-22 2010-09-14 Exxonmobil Research And Engineering Company Method to alter coke morphology using metal salts of aromatic sulfonic acids and/or polysulfonic acids
US7951747B1 (en) * 2009-04-03 2011-05-31 Sandia Corporation Single-layer transition metal sulfide catalysts
WO2012088025A2 (en) 2010-12-20 2012-06-28 Chevron U.S.A. Inc. Hydroprocessing catalysts and methods for making thereof
US9790440B2 (en) 2011-09-23 2017-10-17 Headwaters Technology Innovation Group, Inc. Methods for increasing catalyst concentration in heavy oil and/or coal resid hydrocracker
US9644157B2 (en) 2012-07-30 2017-05-09 Headwaters Heavy Oil, Llc Methods and systems for upgrading heavy oil using catalytic hydrocracking and thermal coking
JP6199973B2 (ja) 2012-08-24 2017-09-20 サウジ アラビアン オイル カンパニー 溶存水素を含有する原料のためのハイドロビスブレーキング方法
US11414607B2 (en) 2015-09-22 2022-08-16 Hydrocarbon Technology & Innovation, Llc Upgraded ebullated bed reactor with increased production rate of converted products
US11414608B2 (en) 2015-09-22 2022-08-16 Hydrocarbon Technology & Innovation, Llc Upgraded ebullated bed reactor used with opportunity feedstocks
US11421164B2 (en) 2016-06-08 2022-08-23 Hydrocarbon Technology & Innovation, Llc Dual catalyst system for ebullated bed upgrading to produce improved quality vacuum residue product
KR101988571B1 (ko) 2016-07-20 2019-06-12 한국에너지기술연구원 아로마틱 성분 및 레진 성분이 포함된 첨가제 및 이를 활용한 수첨전환 방법
US11732203B2 (en) 2017-03-02 2023-08-22 Hydrocarbon Technology & Innovation, Llc Ebullated bed reactor upgraded to produce sediment that causes less equipment fouling
JP7336831B2 (ja) 2017-03-02 2023-09-01 ハイドロカーボン テクノロジー アンド イノベーション、エルエルシー ファウリングが少ない堆積物を伴う改良された沸騰床リアクター
KR102433701B1 (ko) 2017-11-29 2022-08-18 한국에너지기술연구원 중질유분 전환 및 경질유분 수율 향상을 위한 수첨전환 방법
CA3057131C (en) 2018-10-17 2024-04-23 Hydrocarbon Technology And Innovation, Llc Upgraded ebullated bed reactor with no recycle buildup of asphaltenes in vacuum bottoms
US12497569B2 (en) 2022-05-26 2025-12-16 Hydrocarbon Technology & Innovation, Llc Method and system for mixing catalyst precursor into heavy oil using a high boiling hydrocarbon diluent

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US4485004A (en) * 1982-09-07 1984-11-27 Gulf Canada Limited Catalytic hydrocracking in the presence of hydrogen donor
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EP0396740A4 (en) * 1988-11-22 1991-04-17 Chevron Research Company Slurry catalysts for hydroprocessing heavy and refractory oils

Also Published As

Publication number Publication date
FR2689137A1 (fr) 1993-10-01
CA2092787C (fr) 2003-07-29
ITMI930573A0 (it) 1993-03-25
FR2689137B1 (fr) 1994-05-27
DE4309669A1 (de) 1993-09-30
US5460714A (en) 1995-10-24
CA2092787A1 (fr) 1993-09-27
IT1270973B (it) 1997-05-26
ITMI930573A1 (it) 1994-09-25

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