MX344812B - Deshidrohalogenacion selectiva de hidrocarburos halogenados terciarios y eliminacion de impurezas de hidrocarburos halogenados terciarios. - Google Patents
Deshidrohalogenacion selectiva de hidrocarburos halogenados terciarios y eliminacion de impurezas de hidrocarburos halogenados terciarios.Info
- Publication number
- MX344812B MX344812B MX2014000899A MX2014000899A MX344812B MX 344812 B MX344812 B MX 344812B MX 2014000899 A MX2014000899 A MX 2014000899A MX 2014000899 A MX2014000899 A MX 2014000899A MX 344812 B MX344812 B MX 344812B
- Authority
- MX
- Mexico
- Prior art keywords
- tertiary
- dichloro
- propene
- tertiary halogenated
- hydrocarbon
- Prior art date
Links
- 150000008282 halocarbons Chemical group 0.000 title abstract 5
- 239000012535 impurity Substances 0.000 title abstract 4
- 238000006704 dehydrohalogenation reaction Methods 0.000 title abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 4
- UOORRWUZONOOLO-UHFFFAOYSA-N 1,3-dichloropropene Chemical compound ClCC=CCl UOORRWUZONOOLO-UHFFFAOYSA-N 0.000 abstract 3
- 150000008280 chlorinated hydrocarbons Chemical group 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- 229930195735 unsaturated hydrocarbon Natural products 0.000 abstract 2
- UOORRWUZONOOLO-OWOJBTEDSA-N (E)-1,3-dichloropropene Chemical compound ClC\C=C\Cl UOORRWUZONOOLO-OWOJBTEDSA-N 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 238000007033 dehydrochlorination reaction Methods 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 abstract 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 abstract 1
- 229910000039 hydrogen halide Inorganic materials 0.000 abstract 1
- 239000012433 hydrogen halide Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
- 239000012808 vapor phase Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/38—Separation; Purification; Stabilisation; Use of additives
- C07C17/395—Separation; Purification; Stabilisation; Use of additives by treatment giving rise to a chemical modification of at least one compound
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/009—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping in combination with chemical reactions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/34—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping with one or more auxiliary substances
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/38—Separation; Purification; Stabilisation; Use of additives
- C07C17/383—Separation; Purification; Stabilisation; Use of additives by distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B2200/00—Indexing scheme relating to specific properties of organic compounds
- C07B2200/09—Geometrical isomers
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
Se describe un proceso para convertir hidrocarburos halogenados terciarios en una corriente que contiene hidrocarburo halogenado terciario a un producto de hidrocarburo insaturado menos halogenado o no halogenado correspondiente con la liberación de haluro de hidrógeno que involucra poner en contacto el hidrocarburo halogenado terciario con un catalizador de deshidrohalogenación tipo adsorbente en una zona de reacción y opcionalmente pasar un gas de desorción a través de la zona de reacción para eliminar los productos de reacción de fase de vapor desde la zona de reacción. Un proceso para eliminar una impureza de hidrocarburo dorado terciario del 1 ,3-dicloro-1-propeno involucra poner en contacto una mezcla que contiene el 1 3-dicloro-1-propeno y la impureza de hidrocarburo dorado terciario con un catalizador de deshidrogenación efectivo para catalizar una conversión de la impureza de hidrocarburo dorado terciario a un hidrocarburo insaturado no dorado o menos dorado correspondiente y cloruro de hidrógeno y destilar el 1 ,3-dicloro-1-propeno para producir una fracción de cis-1 ,3-dicloro-1-propeno purificado y una fracción de trans-1 ,3-dicloro-1-propano purificado.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US26959409P | 2009-06-26 | 2009-06-26 | |
| PCT/US2010/001841 WO2010151342A1 (en) | 2009-06-26 | 2010-06-24 | Selective dehydrohalogenation of tertiary halogenated hydrocarbons and removal of tertiary halogenated hydrocarbon impurities |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX344812B true MX344812B (es) | 2017-01-09 |
Family
ID=43386827
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2011013796A MX2011013796A (es) | 2009-06-26 | 2010-06-24 | Deshidrohalogenacion selectiva de hidrocarburos halogenados terciarios y eliminacion de impurezas de hidrocarburos halogenados terciarios. |
| MX2014000899A MX344812B (es) | 2009-06-26 | 2010-06-24 | Deshidrohalogenacion selectiva de hidrocarburos halogenados terciarios y eliminacion de impurezas de hidrocarburos halogenados terciarios. |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2011013796A MX2011013796A (es) | 2009-06-26 | 2010-06-24 | Deshidrohalogenacion selectiva de hidrocarburos halogenados terciarios y eliminacion de impurezas de hidrocarburos halogenados terciarios. |
Country Status (14)
| Country | Link |
|---|---|
| US (4) | US8449729B2 (es) |
| EP (2) | EP2789599B1 (es) |
| JP (1) | JP5800805B2 (es) |
| CN (2) | CN102712553B (es) |
| AR (1) | AR078130A1 (es) |
| AU (1) | AU2010263184B2 (es) |
| CA (1) | CA2764278C (es) |
| CO (1) | CO6480952A2 (es) |
| ES (2) | ES2644765T3 (es) |
| IL (1) | IL217106A (es) |
| MX (2) | MX2011013796A (es) |
| PL (1) | PL2789599T3 (es) |
| TW (1) | TWI472506B (es) |
| WO (1) | WO2010151342A1 (es) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MX2011013796A (es) | 2009-06-26 | 2012-02-08 | Dow Agrosciences Llc | Deshidrohalogenacion selectiva de hidrocarburos halogenados terciarios y eliminacion de impurezas de hidrocarburos halogenados terciarios. |
| US8653309B2 (en) | 2011-04-20 | 2014-02-18 | Honeywell International Inc. | Process for producing trans-1233zd |
| BR112014026614A2 (pt) * | 2012-04-30 | 2017-06-27 | Dow Agrosciences Llc | veículos de administração de composições pesticidas |
| BR112015030909B1 (pt) | 2013-06-28 | 2021-10-26 | Dow Global Technologies Llc | Sistema resistente à incrustação para a preparação de um composto e processo resistente à incrustação para a preparação de um composto |
| CN110092707B (zh) * | 2018-01-30 | 2020-08-11 | 中昊晨光化工研究院有限公司 | 一种四氟乙烯生产过程中去除氟化氢的方法 |
| CN110396036B (zh) * | 2019-08-12 | 2021-10-22 | 江苏扬农化工集团有限公司 | 一种分离氯丙烯和氯丙烷的方法 |
| CN111939968B (zh) * | 2020-05-31 | 2024-02-09 | 南京克米斯璀新能源科技有限公司 | 一种用于六氯苯脱氯的催化剂 |
| CN111847382B (zh) * | 2020-08-03 | 2023-05-30 | 江苏三美化工有限公司 | 一种去除氯化氢中氟化氢的反应系统 |
| CN114887345B (zh) * | 2022-06-10 | 2025-01-28 | 拓烯科技(衢州)有限公司 | 一种4-甲基-1-戊烯分离装置和工艺 |
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| US2899473A (en) * | 1959-08-11 | Process for the manufacture of olefinic compounds | ||
| US2322258A (en) * | 1938-12-24 | 1943-06-22 | Dow Chemical Co | Dehydrohalogenation of halogenated orgeanic compounds |
| US2389230A (en) * | 1941-11-25 | 1945-11-20 | Phillips Petroleum Co | Process for treating hydrocarbons |
| US2490973A (en) * | 1946-10-10 | 1949-12-13 | Standard Oil Co | Dehydrohalogenation |
| US2920122A (en) * | 1956-03-07 | 1960-01-05 | Union Carbide Corp | Dehydrohalogenation of halo-substituted hydrocarbon |
| US3240834A (en) * | 1962-07-02 | 1966-03-15 | Phillips Petroleum Co | Dehydrohalogenation of hydrocarbon halides |
| US3257472A (en) * | 1962-09-10 | 1966-06-21 | Phillips Petroleum Co | Dehydrohalogenation |
| US3277204A (en) * | 1963-12-02 | 1966-10-04 | Chevron Res | Halogenation and dehydrochlorination of straight chain alkanes using an aromatic diluent |
| US3277205A (en) * | 1964-01-06 | 1966-10-04 | Chevron Res | Enhancement of conversion of catalytic dehydrochlorination by dilution with an inert gas |
| US3274273A (en) * | 1964-03-16 | 1966-09-20 | Universal Oil Prod Co | Dehydrohalogenation process |
| US3372207A (en) * | 1964-07-10 | 1968-03-05 | Phillips Petroleum Co | Alkylation process |
| US3247277A (en) * | 1965-02-15 | 1966-04-19 | Phillips Petroleum Co | Production of 2, 3-dimethylbutenes |
| US3329730A (en) * | 1965-03-16 | 1967-07-04 | Phillips Petroleum Co | Dehydrohalogenation of halogenated saturated hydrocarbons |
| US3363022A (en) * | 1965-06-10 | 1968-01-09 | Chevron Res | Catalytic dehydrochlorination of chloroparaffins |
| US3401211A (en) * | 1966-04-25 | 1968-09-10 | Phillips Petroleum Co | 1-olefin production |
| JPS428849Y1 (es) | 1966-06-15 | 1967-05-11 | ||
| US3445538A (en) * | 1966-09-21 | 1969-05-20 | Universal Oil Prod Co | Preparation of olefins |
| US3523982A (en) * | 1968-02-29 | 1970-08-11 | Phillips Petroleum Co | Dehydrohalogenation process |
| US3576900A (en) * | 1969-02-27 | 1971-04-27 | Goodyear Tire & Rubber | Preparation of diolefins from tertiary and secondary alkyl halides |
| BE757565A (fr) * | 1969-10-17 | 1971-03-16 | Goodyear Tire & Rubber | Procede de preparation de diolefines |
| BE791904A (fr) * | 1972-11-10 | 1973-05-24 | Ici Ltd | Procede de deshydrochloration |
| US3908009A (en) * | 1974-04-29 | 1975-09-23 | Dow Chemical Co | Inhibiting discoloration of aqueous compositions containing hexamethylenetetramine 1,3-dichloropropene salts |
| JPS5233605A (en) * | 1975-09-10 | 1977-03-14 | Dow Chemical Co | Method of pemoval of 1*33dichllropropene from bottom oil of allylchloride column |
| US4319062A (en) * | 1976-08-02 | 1982-03-09 | The Dow Chemical Company | Allyl chloride process |
| US4384159A (en) * | 1982-03-12 | 1983-05-17 | The Dow Chemical Company | Catalytic dehydrohalogenation process |
| DE3725196A1 (de) * | 1987-07-30 | 1989-02-09 | Bayer Ag | Verfahren zur herstellung von 1,2-dichlorbenzol |
| DE3808951A1 (de) | 1988-03-17 | 1989-10-05 | Basf Ag | Photopolymerisierbare, zur herstellung von druckformen geeignete druckplatte |
| US5107061A (en) * | 1990-04-06 | 1992-04-21 | Exxon Chemical Patents Inc. | Removal of organochlorides from hydrocarbon feed streams |
| JP3304999B2 (ja) | 1992-02-24 | 2002-07-22 | キヤノン株式会社 | 辞書管理方法及びその装置 |
| WO1997003035A1 (en) | 1995-07-07 | 1997-01-30 | The Dow Chemical Company | Integrated process for handling saturated and unsaturated chlorinated hydrocarbonaceous waste and by-products from allyl chloride and propylene oxide processes |
| US5763711A (en) * | 1996-08-07 | 1998-06-09 | The Dow Chemical Company | Catalyst for the rearrangement of allylic geminal dihalogen compounds |
| JP4650968B2 (ja) * | 2000-09-27 | 2011-03-16 | 鹿島ケミカル株式会社 | 高純度で着色の少ないトランス−1,3−ジクロロプロペンの製造方法 |
| MX2011013796A (es) | 2009-06-26 | 2012-02-08 | Dow Agrosciences Llc | Deshidrohalogenacion selectiva de hidrocarburos halogenados terciarios y eliminacion de impurezas de hidrocarburos halogenados terciarios. |
-
2010
- 2010-06-24 MX MX2011013796A patent/MX2011013796A/es active IP Right Grant
- 2010-06-24 CA CA2764278A patent/CA2764278C/en not_active Expired - Fee Related
- 2010-06-24 AU AU2010263184A patent/AU2010263184B2/en not_active Ceased
- 2010-06-24 WO PCT/US2010/001841 patent/WO2010151342A1/en not_active Ceased
- 2010-06-24 US US12/803,345 patent/US8449729B2/en not_active Expired - Fee Related
- 2010-06-24 EP EP14173170.3A patent/EP2789599B1/en not_active Not-in-force
- 2010-06-24 CN CN201080028223.9A patent/CN102712553B/zh not_active Expired - Fee Related
- 2010-06-24 MX MX2014000899A patent/MX344812B/es unknown
- 2010-06-24 PL PL14173170T patent/PL2789599T3/pl unknown
- 2010-06-24 ES ES14173170.3T patent/ES2644765T3/es active Active
- 2010-06-24 CN CN201510586968.1A patent/CN105294388B/zh not_active Expired - Fee Related
- 2010-06-24 JP JP2012517497A patent/JP5800805B2/ja not_active Expired - Fee Related
- 2010-06-24 EP EP10792464.9A patent/EP2445854B1/en not_active Not-in-force
- 2010-06-24 ES ES10792464.9T patent/ES2602027T3/es active Active
- 2010-06-25 TW TW99120798A patent/TWI472506B/zh not_active IP Right Cessation
- 2010-06-25 AR ARP100102274 patent/AR078130A1/es active IP Right Grant
-
2011
- 2011-12-20 IL IL21710611A patent/IL217106A/en active IP Right Grant
- 2011-12-26 CO CO11178638A patent/CO6480952A2/es active IP Right Grant
-
2013
- 2013-03-15 US US13/837,276 patent/US9126886B2/en not_active Expired - Fee Related
- 2013-03-15 US US13/835,951 patent/US9139500B2/en not_active Expired - Fee Related
-
2015
- 2015-07-28 US US14/811,244 patent/US9745233B2/en not_active Expired - Fee Related
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