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MX2021013340A - Pieza moldeada que comprende un titanosilicato zeolitico tipo mfi y un aglutinante de silice, su proceso de preparacion y uso como catalizador. - Google Patents

Pieza moldeada que comprende un titanosilicato zeolitico tipo mfi y un aglutinante de silice, su proceso de preparacion y uso como catalizador.

Info

Publication number
MX2021013340A
MX2021013340A MX2021013340A MX2021013340A MX2021013340A MX 2021013340 A MX2021013340 A MX 2021013340A MX 2021013340 A MX2021013340 A MX 2021013340A MX 2021013340 A MX2021013340 A MX 2021013340A MX 2021013340 A MX2021013340 A MX 2021013340A
Authority
MX
Mexico
Prior art keywords
molded part
titanosilicate
catalyst
preparation process
type zeolite
Prior art date
Application number
MX2021013340A
Other languages
English (en)
Inventor
Markus Weber
Dominic Riedel
Ulrich Mueller
Joaquim Henrique Teles
Andrei - Nicolae PARVULESCU
Hans - Juergen LUETZEL
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Publication of MX2021013340A publication Critical patent/MX2021013340A/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/405—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/20—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state
    • B01J35/23—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state in a colloidal state
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/34—Mechanical properties
    • B01J35/37—Crush or impact strength
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/36—Steaming
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/05—Nuclear magnetic resonance [NMR]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Silicon Compounds (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Dispersion Chemistry (AREA)

Abstract

Una pieza moldeada química que comprende un material zeolítico que exhibe una isoterma de adsorción/desorción de nitrógeno de tipo I que se determina como se describe en el Ejemplo de referencia 1 y que tiene un tipo de marco MFI y una estructura de marco que comprende Si, O y Ti, en donde la pieza moldeada comprende además un aglutinante para dicho material zeolítico, en donde el aglutinante comprende Si y O, en donde la pieza moldeada exhibe un volumen de poro total de al menos 0.4 mL/g y una resistencia a la compresión de al menos 6 N.
MX2021013340A 2019-04-29 2020-04-27 Pieza moldeada que comprende un titanosilicato zeolitico tipo mfi y un aglutinante de silice, su proceso de preparacion y uso como catalizador. MX2021013340A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP19171503 2019-04-29
PCT/EP2020/061597 WO2020221683A1 (en) 2019-04-29 2020-04-27 Molding comprising a type mfi zeolitic titanosilicate and a silica binder, its preparation process and use as catalyst

Publications (1)

Publication Number Publication Date
MX2021013340A true MX2021013340A (es) 2021-11-17

Family

ID=66529750

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2021013340A MX2021013340A (es) 2019-04-29 2020-04-27 Pieza moldeada que comprende un titanosilicato zeolitico tipo mfi y un aglutinante de silice, su proceso de preparacion y uso como catalizador.

Country Status (8)

Country Link
US (1) US20220219154A1 (es)
EP (1) EP3962645A1 (es)
JP (1) JP7574216B2 (es)
KR (1) KR20220003063A (es)
CN (1) CN113784790A (es)
MX (1) MX2021013340A (es)
SG (1) SG11202110277RA (es)
WO (1) WO2020221683A1 (es)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113230705A (zh) * 2021-05-11 2021-08-10 李晟贤 一种滤料反洗方法
CN113230704A (zh) * 2021-05-11 2021-08-10 李晟贤 一种增强滤料过滤性能的方法
US20240326029A1 (en) 2021-11-22 2024-10-03 Basf Se Epoxidation catalyst and process for its preparation

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19859561A1 (de) 1998-12-22 2000-06-29 Basf Ag Verfahren zur Herstellung eines Formkörpers
ID26018A (id) 1998-04-08 2000-11-16 Basf Ag Produksi bodi yang terbentuk
DE10110139A1 (de) * 2001-03-02 2002-09-12 Basf Ag Formkörper und Verfahren zu dessen Herstellung
WO2007033934A2 (de) 2005-09-20 2007-03-29 Basf Se Verfahren zur ermittlung der tortuosität, katalysatorträger, katalysator und verfahren zur dehydrierung von kohlenwasserstoffen
US7825204B2 (en) * 2006-12-19 2010-11-02 Lyondell Chemical Technology, L.P. Inorganic oxide extrudates
EP2138554A4 (en) * 2007-03-20 2012-08-08 Mitsui Chemicals Inc METHOD FOR CONVERTING HYDROCARBONS WITH SHAPED ZEOLITE CATALYST
SG10201407829TA (en) * 2009-11-27 2015-01-29 Basf Se Process for the preparation of a titanium zeolite catalyst
MX2013006386A (es) * 2010-12-07 2013-10-25 Basf Se Proceso para la produccion de oxido de propileno.
EP3216520B1 (en) * 2012-02-07 2024-07-17 Basf Se Molding containing a zeolitic mww type material containing ti and zn and use thereof as a catalyst
FR2987046B1 (fr) * 2012-02-17 2014-03-21 Rhodia Operations Procede d'hydroxylation de composes aromatiques, catalyseur d'hydroxylation et son procede de preparation
EP2920112A4 (en) * 2012-11-13 2016-12-07 Basf Se PREPARATION AND USE OF A ZEOLITE MATERIAL IN A PROCESS FOR CONVERTING OXYGENATES IN OLEFINE
EP3016741B1 (en) * 2013-07-05 2020-07-01 Danmarks Tekniske Universitet Method for producing zeolites and zeotypes
BR112016007918B1 (pt) 2013-10-23 2020-12-29 Basf Se processo para a produção de um corpo de moldagem, corpo de moldagem e uso de um corpo de moldagem
US10995008B2 (en) * 2016-03-30 2021-05-04 Basf Se Process for the flash calcination of a zeolitic material
EP3464179B1 (en) * 2016-05-25 2022-04-13 The Regents of The University of California Zeolitic materials having encapsulated bimetallic clusters
EP4180396A3 (en) * 2018-08-27 2024-11-13 ExxonMobil Technology and Engineering Company Molecular sieves and a process for making molecular sieves

Also Published As

Publication number Publication date
KR20220003063A (ko) 2022-01-07
US20220219154A1 (en) 2022-07-14
JP7574216B2 (ja) 2024-10-28
SG11202110277RA (en) 2021-11-29
WO2020221683A1 (en) 2020-11-05
EP3962645A1 (en) 2022-03-09
JP2022530165A (ja) 2022-06-27
BR112021019270A2 (pt) 2022-01-04
CN113784790A (zh) 2021-12-10

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