MX2021000699A - Compuesto de multi-aziridina. - Google Patents
Compuesto de multi-aziridina.Info
- Publication number
- MX2021000699A MX2021000699A MX2021000699A MX2021000699A MX2021000699A MX 2021000699 A MX2021000699 A MX 2021000699A MX 2021000699 A MX2021000699 A MX 2021000699A MX 2021000699 A MX2021000699 A MX 2021000699A MX 2021000699 A MX2021000699 A MX 2021000699A
- Authority
- MX
- Mexico
- Prior art keywords
- sub
- aziridine compound
- daltons
- structural units
- linking chains
- Prior art date
Links
- 239000012736 aqueous medium Substances 0.000 abstract 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 1
- 238000004132 cross linking Methods 0.000 abstract 1
- 229920001002 functional polymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D403/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00
- C07D403/14—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing three or more hetero rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/2805—Compounds having only one group containing active hydrogen
- C08G18/285—Nitrogen containing compounds
- C08G18/2875—Monohydroxy compounds containing tertiary amino groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/22—Catalysts containing metal compounds
- C08G18/227—Catalysts containing metal compounds of antimony, bismuth or arsenic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/2805—Compounds having only one group containing active hydrogen
- C08G18/2815—Monohydroxy compounds
- C08G18/283—Compounds containing ether groups, e.g. oxyalkylated monohydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
- C08G18/758—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing two or more cycloaliphatic rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7614—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring
- C08G18/7628—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring containing at least one isocyanate or isothiocyanate group linked to the aromatic ring by means of an aliphatic group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
- C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3432—Six-membered rings
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/10—Homopolymers or copolymers of methacrylic acid esters
- C09D133/12—Homopolymers or copolymers of methyl methacrylate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/73—Polyisocyanates or polyisothiocyanates acyclic
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Plural Heterocyclic Compounds (AREA)
- Paints Or Removers (AREA)
- Polyurethanes Or Polyureas (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
Abstract
La presente invención se refiere a un compuesto de multi-aziridina que tiene: a) de 2 a 6 de las siguientes unidades estructurales (A): (ver Fórmula) por lo que R', R'', R1, R2, R3 y R4 son como se definen en la presente m es un número entero de 1 a 6; b) una o más cadenas de ligación en donde cada una de estas cadenas de ligación ligan dos de las unidades estructurales A; y c) un peso molecular en el intervalo de 600 Daltons a 5000 Daltons. El compuesto de multi-aziridina se puede utilizar por ejemplo para reticulación de por ejemplo polímeros funcionales de ácido carboxílico disueltos y/o dispersados en un medio acuoso.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP18184969 | 2018-07-23 | ||
| PCT/EP2019/069198 WO2020020714A1 (en) | 2018-07-23 | 2019-07-17 | Multi-aziridine compound |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX2021000699A true MX2021000699A (es) | 2021-03-25 |
Family
ID=63035916
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2021000699A MX2021000699A (es) | 2018-07-23 | 2019-07-17 | Compuesto de multi-aziridina. |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US11878969B2 (es) |
| EP (1) | EP3827042B1 (es) |
| JP (1) | JP7271825B2 (es) |
| CN (1) | CN112469755B (es) |
| AU (2) | AU2019308863B2 (es) |
| ES (1) | ES2982030T3 (es) |
| MX (1) | MX2021000699A (es) |
| PL (1) | PL3827042T3 (es) |
| WO (1) | WO2020020714A1 (es) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112469755B (zh) | 2018-07-23 | 2022-12-02 | 科思创(荷兰)有限公司 | 多氮丙啶化合物 |
| WO2021148564A1 (en) | 2020-01-22 | 2021-07-29 | Dsm Ip Assets B.V. | Method of cross-linking biomaterial with a polyfunctional aziridine compound and products obtained therewith |
| WO2021148570A1 (en) | 2020-01-22 | 2021-07-29 | Covestro (Netherlands) B.V. | Multi-aziridine compound |
| IT202000017317A1 (it) * | 2020-07-16 | 2022-01-16 | Italkem Srl | Composti di tipo macromolecolare e suo uso in composizioni |
| IT202000001486A1 (it) * | 2020-01-27 | 2021-07-27 | Italkem Srl | Composti di tipo macromolecolare e suo uso in composizioni |
| CN115335424A (zh) * | 2020-01-27 | 2022-11-11 | 意大利亿达化料有限公司 | 大分子化合物以及其在组合物中的用途 |
| DE102021202598A1 (de) | 2021-03-17 | 2022-09-22 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung eingetragener Verein | Stabilisator-Zusammensetzung, Verwendung der Stabilisator-Zusammensetzung, Verfahren zur Stabilisierung von Kondensationspolymeren gegen hydrolytischen Abbau sowie hydrolysestabilisierte Zusammensetzung und Formkörper oder Formteil hieraus |
| EP4122592A1 (en) | 2021-07-23 | 2023-01-25 | Follmann GmbH & Co. KG | Environmentally friendly microcapsules and a method for the production thereof |
| NL2028984B1 (en) | 2021-08-18 | 2023-02-24 | Stahl Int B V | Process for the preparation of polycarbodiimides with aziridine functions, which may be used as crosslinking agent. |
| US20240392150A1 (en) | 2021-11-30 | 2024-11-28 | Agfa Nv | Resin Particle Dispersion for Inkjet Printing |
| EP4441154A1 (en) | 2021-12-02 | 2024-10-09 | Agfa Nv | Resin particle dispersion for inkjet printing |
| DE102022206467A1 (de) | 2022-06-27 | 2023-12-28 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung eingetragener Verein | Stabilisator-Zusammensetzung, Verwendung der Stabilisator-Zusammensetzung, Verfahren zur Stabilisierung von Kondensationspolymeren gegen hydrolytischen Abbau sowie hydrolysestabilisierte Zusammensetzung und Formkörper oder Formteil hieraus |
| DE102022122740A1 (de) * | 2022-09-07 | 2024-03-07 | Tesa Se | Acrylathaftklebstoff sowie mit dem Acrylathaftklebstoff ausgerüstetes Klebeband |
| CN120390778A (zh) | 2022-12-19 | 2025-07-29 | 爱克发有限公司 | 用于喷墨印刷的含有树脂的预处理液体和记录方法 |
| CN115894910B (zh) * | 2022-12-27 | 2024-08-13 | 湖南科之杰新材料有限公司 | 一种掺敏单体及其制备方法和应用 |
| KR20250172623A (ko) | 2023-04-10 | 2025-12-09 | 피피지 인더스트리즈 오하이오 인코포레이티드 | 코팅된 기재의 제조 방법 및 이에 사용되는 비수성 경화성 필름 형성 조성물 |
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| US3329674A (en) | 1963-11-01 | 1967-07-04 | Thiokol Chemical Corp | Aziridinyl derivatives of polyfunctional epoxides |
| US3337533A (en) * | 1963-11-26 | 1967-08-22 | Dow Chemical Co | Aziridinyl carbamates |
| CH1199066D (es) | 1965-08-19 | |||
| US3763132A (en) * | 1965-09-09 | 1973-10-02 | Thiokol Chemical Corp | Composition comprising carboxyl terminated polymers and aziridines |
| JPS4727971Y1 (es) | 1967-01-18 | 1972-08-24 | ||
| DE1694134A1 (de) | 1967-02-28 | 1971-07-15 | Bayer Ag | Verfahren zur Herstellung von Schaumstoffen auf Isocyanatbasis |
| US3583977A (en) | 1968-06-18 | 1971-06-08 | Gen Tire & Rubber Co | Hydroxy aziridinyl compounds |
| AU2698771A (en) | 1970-04-20 | 1972-09-28 | The Dow Chemical Company | Water dispersible coating compositions |
| JPS4727971U (es) | 1971-04-19 | 1972-11-29 | ||
| US3933936A (en) * | 1973-02-20 | 1976-01-20 | The Dow Chemical Company | Rapid setting adhesive compounds |
| DE2521859C3 (de) * | 1975-05-16 | 1981-11-05 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Herstellung von Aziridincarbonsäureestern |
| JPS59128291A (ja) | 1983-01-06 | 1984-07-24 | 日産自動車株式会社 | ポリジエン系コンポジツト推進薬の粘結剤 |
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| NL9100578A (nl) | 1991-04-03 | 1992-11-02 | Stahl Holland Bv | Multifunctionele waterdispergeerbare verknopingsmiddelen. |
| AU1891492A (en) | 1991-04-29 | 1992-12-21 | Ppg Industries, Inc. | A stable, one-package, non-gelled coating composition curable under ambient conditions |
| US5741543A (en) | 1995-02-10 | 1998-04-21 | Minnesota Mining And Manufacturing Company | Process for the production of an article coated with a crosslinked pressure sensitive adhesive |
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| CN112469755B (zh) | 2018-07-23 | 2022-12-02 | 科思创(荷兰)有限公司 | 多氮丙啶化合物 |
-
2019
- 2019-07-17 CN CN201980048944.7A patent/CN112469755B/zh active Active
- 2019-07-17 US US17/261,282 patent/US11878969B2/en active Active
- 2019-07-17 EP EP19739997.5A patent/EP3827042B1/en active Active
- 2019-07-17 AU AU2019308863A patent/AU2019308863B2/en active Active
- 2019-07-17 JP JP2020568563A patent/JP7271825B2/ja active Active
- 2019-07-17 PL PL19739997.5T patent/PL3827042T3/pl unknown
- 2019-07-17 WO PCT/EP2019/069198 patent/WO2020020714A1/en not_active Ceased
- 2019-07-17 MX MX2021000699A patent/MX2021000699A/es unknown
- 2019-07-17 ES ES19739997T patent/ES2982030T3/es active Active
-
2022
- 2022-03-01 AU AU2022201385A patent/AU2022201385B2/en active Active
-
2023
- 2023-12-01 US US18/526,220 patent/US12180194B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| US12180194B2 (en) | 2024-12-31 |
| US11878969B2 (en) | 2024-01-23 |
| AU2022201385A1 (en) | 2022-03-24 |
| AU2022201385B2 (en) | 2024-01-11 |
| WO2020020714A1 (en) | 2020-01-30 |
| CN112469755A (zh) | 2021-03-09 |
| US20240166634A1 (en) | 2024-05-23 |
| US20210332031A1 (en) | 2021-10-28 |
| EP3827042A1 (en) | 2021-06-02 |
| EP3827042B1 (en) | 2024-04-10 |
| CN112469755B (zh) | 2022-12-02 |
| JP2021531242A (ja) | 2021-11-18 |
| AU2019308863A1 (en) | 2021-01-07 |
| JP7271825B2 (ja) | 2023-05-12 |
| AU2019308863B2 (en) | 2021-12-02 |
| PL3827042T3 (pl) | 2024-08-12 |
| ES2982030T3 (es) | 2024-10-14 |
| BR112021001004A2 (pt) | 2021-04-20 |
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