[go: up one dir, main page]

MX2020003073A - Copolimeros lldpe de doble componente con impacto y resistencia a la rotura mejorados. - Google Patents

Copolimeros lldpe de doble componente con impacto y resistencia a la rotura mejorados.

Info

Publication number
MX2020003073A
MX2020003073A MX2020003073A MX2020003073A MX2020003073A MX 2020003073 A MX2020003073 A MX 2020003073A MX 2020003073 A MX2020003073 A MX 2020003073A MX 2020003073 A MX2020003073 A MX 2020003073A MX 2020003073 A MX2020003073 A MX 2020003073A
Authority
MX
Mexico
Prior art keywords
ethylene polymer
improved impact
breaking resistance
double component
lldpe copolymers
Prior art date
Application number
MX2020003073A
Other languages
English (en)
Inventor
Qing Yang
Ashish M Sukhadia
Chung Ching Tso
Yongwoo Inn
Jeremy Praetorius
John T Blagg
Original Assignee
Chevron Phillips Chemical Co Lp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chevron Phillips Chemical Co Lp filed Critical Chevron Phillips Chemical Co Lp
Publication of MX2020003073A publication Critical patent/MX2020003073A/es

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/08Copolymers of ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/08Copolymers of ethene
    • C08L23/0807Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
    • C08L23/0815Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04Homopolymers or copolymers of ethene
    • C08J2323/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04Homopolymers or copolymers of ethene
    • C08J2323/08Copolymers of ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/04Homopolymers or copolymers of ethene
    • C08J2423/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/04Homopolymers or copolymers of ethene
    • C08J2423/08Copolymers of ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/10Transparent films; Clear coatings; Transparent materials
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/16Applications used for films
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/062HDPE
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/066LDPE (radical process)

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Se describen composiciones de polímeros de etileno que contienen un primer componente de polímero de etileno ramificado homogéneamente y un segundo componente de polímero de etileno ramificado homogéneamente de mayor densidad que el primer componente de polímero de etileno. La composición de polímero de etileno se puede caracterizar por una densidad de 0.912 a 0.925 g/cm3, un índice de fusión inferior a 3.5 g/10 min y un parámetro CY-a a 190 °C de 0.25 a 0.65. Estas composiciones poliméricas tienen la excelente resistencia al impacto del dardo y las propiedades ópticas de un LLDPE catalizado con metaloceno, pero con una resistencia mejorada a la rotura en la dirección de la máquina, y se pueden usar en películas sopladas y otras aplicaciones de uso final.
MX2020003073A 2017-09-26 2018-09-19 Copolimeros lldpe de doble componente con impacto y resistencia a la rotura mejorados. MX2020003073A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US15/715,215 US10435527B2 (en) 2017-09-26 2017-09-26 Dual component LLDPE copolymers with improved impact and tear resistance
PCT/US2018/051614 WO2019067270A1 (en) 2017-09-26 2018-09-19 TWO-COMPONENT LLDPE COPOLYMERS HAVING ENHANCED RESISTANCE AND IMPACT RESISTANCE

Publications (1)

Publication Number Publication Date
MX2020003073A true MX2020003073A (es) 2020-07-28

Family

ID=63763031

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2020003073A MX2020003073A (es) 2017-09-26 2018-09-19 Copolimeros lldpe de doble componente con impacto y resistencia a la rotura mejorados.

Country Status (10)

Country Link
US (3) US10435527B2 (es)
EP (1) EP3688041B1 (es)
CN (1) CN111278867B (es)
BR (1) BR112020005069B1 (es)
CA (1) CA3077099C (es)
ES (1) ES3049332T3 (es)
MX (1) MX2020003073A (es)
MY (1) MY200243A (es)
RU (1) RU2744783C1 (es)
WO (1) WO2019067270A1 (es)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10435527B2 (en) 2017-09-26 2019-10-08 Chevron Phillips Chemical Company Lp Dual component LLDPE copolymers with improved impact and tear resistance
US11376575B2 (en) 2018-09-17 2022-07-05 Chevron Phillips Chemical Company Lp Modified supported chromium catalysts and ethylene-based polymers produced therefrom
US11427703B2 (en) * 2019-03-25 2022-08-30 Chevran Phillips Chemical Company LP Dual component LLDPE copolymers with improved impact and tear resistance, and methods of their preparation
US11028258B2 (en) 2019-08-19 2021-06-08 Chevron Phillips Chemical Company Lp Metallocene catalyst system for producing LLDPE copolymers with tear resistance and low haze
EP4031279A1 (en) 2019-09-16 2022-07-27 Chevron Phillips Chemical Company Lp Chromium-based catalysts and processes for converting alkanes into higher and lower aliphatic hydrocarbons
US11180435B2 (en) 2019-09-16 2021-11-23 Chevron Phillips Chemical Company, Lp Chromium-catalyzed production of alcohols from hydrocarbons
US11339279B2 (en) 2020-04-01 2022-05-24 Chevron Phillips Chemical Company Lp Dual catalyst system for producing LLDPE and MDPE copolymers with long chain branching for film applications
US11492429B2 (en) * 2020-06-05 2022-11-08 Formosa Plastics Corporation, U.S.A. Long-chain branched ethylene copolymer with novel composition distribution and films formed from the same
CN116490268B (zh) 2020-09-14 2026-01-13 切弗朗菲利浦化学公司 由烃通过过渡金属催化生产醇和羰基化合物
WO2023114773A1 (en) * 2021-12-16 2023-06-22 Chevron Phillips Chemical Company Lp Modifications of sulfated bentonites and uses thereof in metallocene catalyst systems for olefin polymerization
US12134591B2 (en) 2022-10-31 2024-11-05 Chevron Phillips Chemical Company Lp Methanol production from methane utilizing a supported chromium catalyst

Family Cites Families (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5382630A (en) 1988-09-30 1995-01-17 Exxon Chemical Patents Inc. Linear ethylene interpolymer blends of interpolymers having narrow molecular weight and composition distribution
US5972444A (en) * 1991-10-15 1999-10-26 The Dow Chemical Company Polyolefin compositions with balanced shrink properties
US5677383A (en) 1991-10-15 1997-10-14 The Dow Chemical Company Fabricated articles made from ethylene polymer blends
CZ283095A3 (en) 1993-04-28 1996-05-15 Dow Chemical Co Ethylene polymer compositions and articles produced from ethylene polymer mixtures
JPH09309926A (ja) * 1996-05-17 1997-12-02 Dow Chem Co:The エチレン共重合体の製造方法
EP0938521B1 (en) * 1996-11-13 2002-06-05 The Dow Chemical Company Shrink film having balanced properties or improved toughness and methods of making the same
EP0991715B1 (en) * 1997-06-20 2003-04-02 The Dow Chemical Company Ethylene polymer compositions and article fabricated from the same
BR9812478A (pt) 1997-09-19 2000-09-26 Dow Chemical Co "composição de interpolìmero de etileno composicionalmente otimizada, com uma distribuição estreita de peso molecular, processo de obtenção e artigos fabricados com a mesma"
US6242545B1 (en) 1997-12-08 2001-06-05 Univation Technologies Polymerization catalyst systems comprising substituted hafinocenes
US7135526B2 (en) 2001-06-22 2006-11-14 Univation Technologies, Llc Very low density polyethylene and high density polyethylene blends
JP4221363B2 (ja) 2001-07-19 2009-02-12 ユニベーション・テクノロジーズ・エルエルシー 物性が向上したポリエチレンフィルム
US6936675B2 (en) 2001-07-19 2005-08-30 Univation Technologies, Llc High tear films from hafnocene catalyzed polyethylenes
US7396881B2 (en) * 2002-10-01 2008-07-08 Exxonmobil Chemical Patents Inc. Polyethylene compositions for rotational molding
CA2411183C (en) 2002-11-05 2011-06-14 Nova Chemicals Corporation Heterogeneous/homogeneous copolymer
US6987695B2 (en) 2003-03-25 2006-01-17 Promos Technologies Inc. Writing data to nonvolatile memory
US7119153B2 (en) 2004-01-21 2006-10-10 Jensen Michael D Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength
AR053694A1 (es) * 2005-03-17 2007-05-16 Dow Global Technologies Inc Combinaciones polimericas de interpolimeros de etileno/alfa-olefina con compatibilidad mejorada
DE602007004315D1 (de) * 2006-04-07 2010-03-04 Dow Global Technologies Inc L und herstellungsverfahren dafür
RU2448991C2 (ru) 2007-06-13 2012-04-27 ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи Полиэтиленовые композиции, способы их получения и изделия, полученные из них
US7884163B2 (en) 2008-03-20 2011-02-08 Chevron Phillips Chemical Company Lp Silica-coated alumina activator-supports for metallocene catalyst compositions
US8114946B2 (en) 2008-12-18 2012-02-14 Chevron Phillips Chemical Company Lp Process for producing broader molecular weight distribution polymers with a reverse comonomer distribution and low levels of long chain branches
EP2558528A1 (en) * 2010-04-14 2013-02-20 Dow Global Technologies LLC Fuel containers made from polyethylene compositions with improved creep resistance
EP2541418B1 (en) * 2011-06-30 2019-01-23 Axis AB Method for increasing reliability in monitoring systems
US9115233B2 (en) * 2012-06-21 2015-08-25 Nova Chemicals (International) S.A. Ethylene copolymer compositions, film and polymerization processes
CA2798855C (en) 2012-06-21 2021-01-26 Nova Chemicals Corporation Ethylene copolymers having reverse comonomer incorporation
US8937139B2 (en) 2012-10-25 2015-01-20 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
CN104781319B (zh) 2012-11-07 2018-04-10 切弗朗菲利浦化学公司 低密度聚烯烃树脂以及从其制造的膜
CA2800056A1 (en) * 2012-12-24 2014-06-24 Nova Chemicals Corporation Polyethylene blend compositions
RU2654061C2 (ru) 2013-02-07 2018-05-16 ЮНИВЕЙШН ТЕКНОЛОДЖИЗ, ЭлЭлСи Получение полиолефина
US9181369B2 (en) 2013-03-11 2015-11-10 Chevron Phillips Chemical Company Lp Polymer films having improved heat sealing properties
JP6026385B2 (ja) 2013-10-25 2016-11-16 株式会社日立製作所 属性情報提供方法および属性情報提供システム
US9217049B2 (en) 2013-11-19 2015-12-22 Chevron Phillips Chemical Company Lp Dual catalyst systems for producing polymers with a broad molecular weight distribution and a uniform short chain branch distribution
US10000594B2 (en) 2016-11-08 2018-06-19 Chevron Phillips Chemical Company Lp Dual catalyst system for producing LLDPE copolymers with a narrow molecular weight distribution and improved processability
US10435527B2 (en) 2017-09-26 2019-10-08 Chevron Phillips Chemical Company Lp Dual component LLDPE copolymers with improved impact and tear resistance
US10358506B2 (en) 2017-10-03 2019-07-23 Chevron Phillips Chemical Company Lp Dual catalyst system for producing LLDPE copolymers with improved processability

Also Published As

Publication number Publication date
CA3077099A1 (en) 2019-04-04
BR112020005069B1 (pt) 2020-09-29
US10544273B2 (en) 2020-01-28
US11352471B2 (en) 2022-06-07
ES3049332T3 (en) 2025-12-16
RU2744783C1 (ru) 2021-03-15
US10435527B2 (en) 2019-10-08
US20200109246A1 (en) 2020-04-09
CN111278867B (zh) 2021-07-13
EP3688041C0 (en) 2025-08-20
EP3688041A1 (en) 2020-08-05
US20190322823A1 (en) 2019-10-24
WO2019067270A1 (en) 2019-04-04
MY200243A (en) 2023-12-15
EP3688041B1 (en) 2025-08-20
US20190092912A1 (en) 2019-03-28
CA3077099C (en) 2021-01-19
BR112020005069A2 (pt) 2020-05-19
CN111278867A (zh) 2020-06-12

Similar Documents

Publication Publication Date Title
MX2020003073A (es) Copolimeros lldpe de doble componente con impacto y resistencia a la rotura mejorados.
MX2024008885A (es) Polimeros de etileno y copolimeros de etileno para peliculas sopladas.
MY202454A (en) Dual component lldpe copolymers with improved impact and tear resistance, and methods of their preparation
BR112020006559A2 (pt) polímeros de etileno, seu artigos de fabricação e filme soprado ou fundido
RU2019110831A (ru) Высокотехнологичный мультимодальный сверхвысокомолекулярный полиэтилен
EA201800233A1 (ru) Композиции полипропилена для применения в автомобильной промышленности
RU2012134320A (ru) Толстые пленки, изготовленные экструзией с раздувкой
JP2012504684A5 (es)
MX2016016605A (es) Peliculas sopladas con tenacidad mejorada.
MX2016015839A (es) Composicion polimerica rellena con una mezcla de material de relleno inorganico.
MX2017007505A (es) Envasado de barrera auto reciclable.
BR112015022786A2 (pt) filmes de polímero tendo propriedades de selagem térmica melhoradas
MX2017001925A (es) Copolimeros de etileno producidos con un catalizador de un solo sitio.
MX364609B (es) Pelicula soluble en agua mejorada que tiene una mezcla de polimeros de pvoh, y envases realizados a partir de la misma.
IN2012DN06574A (es)
MY171423A (en) Ethylene-based polymers and articles made therefrom
MX2017015824A (es) Aislamiento de cable que comprende una mezcla de polietileno de baja densidad (ldpe) y polipropileno.
BR112017003303A2 (pt) polietileno de densidade muito baixa produzido com catalisador de sítio único
CL2021000188A1 (es) Formulaciones de polietileno para aplicaciones de moldeo por soplado de piezas grandes
MX2022012343A (es) Copolimero de polietileno lineal bimodal de baja densidad.
MY191855A (en) Bimodal polyethylene composition and pipe comprising the same
BR112017002569A2 (pt) composições adesivas compreendendo polímeros à base de olefina funcionalizados de baixo peso molecular
MX378573B (es) Resina autorreparante.
AR103018A1 (es) Composiciones poliméricas de polietileno con baja turbidez
MX377242B (es) Composicion de pelicula.