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MX2020001449A - Proceso de varias etapas para convertir alquilenoureas ciclicas en sus correspondientes alquilenaminas. - Google Patents

Proceso de varias etapas para convertir alquilenoureas ciclicas en sus correspondientes alquilenaminas.

Info

Publication number
MX2020001449A
MX2020001449A MX2020001449A MX2020001449A MX2020001449A MX 2020001449 A MX2020001449 A MX 2020001449A MX 2020001449 A MX2020001449 A MX 2020001449A MX 2020001449 A MX2020001449 A MX 2020001449A MX 2020001449 A MX2020001449 A MX 2020001449A
Authority
MX
Mexico
Prior art keywords
alkyleneamines
alkyleneureas
removal step
cyclic alkyleneureas
step process
Prior art date
Application number
MX2020001449A
Other languages
English (en)
Inventor
Jacob Berend Ten Kate Antoon
Krister Edvinsson Rolf
Fredrik LAKE Karl
Ehlers Ina
Nicolas Kantzer Eike
Van Dam Hendrik
Veneman Rens
Jozef Thomas Raaijmakers Michiel
Jovic Slavisa
Original Assignee
Nouryon Chemicals Int Bv
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nouryon Chemicals Int Bv filed Critical Nouryon Chemicals Int Bv
Publication of MX2020001449A publication Critical patent/MX2020001449A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/62—Preparation of compounds containing amino groups bound to a carbon skeleton by cleaving carbon-to-nitrogen, sulfur-to-nitrogen, or phosphorus-to-nitrogen bonds, e.g. hydrolysis of amides, N-dealkylation of amines or quaternary ammonium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456—Removing acid components
    • B01D53/1475—Removing carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1493—Selection of liquid materials for use as absorbents
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/82—Purification; Separation; Stabilisation; Use of additives
    • C07C209/86—Separation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C211/00—Compounds containing amino groups bound to a carbon skeleton
    • C07C211/01—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms
    • C07C211/02—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
    • C07C211/14—Amines containing amino groups bound to at least two aminoalkyl groups, e.g. diethylenetriamines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C213/00—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/202—Alcohols or their derivatives
    • B01D2252/2021—Methanol
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20436—Cyclic amines
    • B01D2252/20447—Cyclic amines containing a piperazine-ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/504—Carbon dioxide
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

La invención se refiere a un proceso para convertir una materia prima que comprende alquilenoureas cíclicas en sus correspondientes alquilenoaminas, que comprende - una etapa de eliminación del CO2 en la que las alquilenoureas cíclicas se convierten en sus correspondientes alquilenoaminas mediante la reacción de alquilenoureas cíclicas en la fase líquida, con agua, habiendo eliminación del CO2, - una etapa de eliminación de aminas en la que las alquilenoureas cíclicas se convierten en un proceso de separación reactiva en sus correspondientes alquilenoaminas mediante reacción con un compuesto de amina seleccionado a partir del grupo de aminas primarias o aminas secundarias que tienen una temperatura de ebullición más elevada que las alquilenoaminas formadas durante el proceso. Se ha descubierto que la combinación de una etapa de eliminación de CO2 y una etapa de eliminación de aminas permite convertir alquilenureas en las aminas correspondientes de manera eficiente en una elevada velocidad de reacción.
MX2020001449A 2017-08-11 2018-08-07 Proceso de varias etapas para convertir alquilenoureas ciclicas en sus correspondientes alquilenaminas. MX2020001449A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP17185945 2017-08-11
PCT/EP2018/071319 WO2019030190A1 (en) 2017-08-11 2018-08-07 MULTI-STEP PROCESS FOR CONVERTING CYCLIC ALKYLENE UREA TO THEIR CORRESPONDING ALKYLENE AMINES

Publications (1)

Publication Number Publication Date
MX2020001449A true MX2020001449A (es) 2020-03-20

Family

ID=59592932

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2020001449A MX2020001449A (es) 2017-08-11 2018-08-07 Proceso de varias etapas para convertir alquilenoureas ciclicas en sus correspondientes alquilenaminas.

Country Status (10)

Country Link
US (1) US11236039B2 (es)
EP (1) EP3665153A1 (es)
JP (2) JP2020530455A (es)
KR (1) KR20200036011A (es)
CN (1) CN111032616B (es)
BR (1) BR112020002389B1 (es)
CA (1) CA3071903A1 (es)
MX (1) MX2020001449A (es)
TW (1) TWI761570B (es)
WO (1) WO2019030190A1 (es)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110072841B (zh) 2016-12-15 2022-04-19 阿克苏诺贝尔化学品国际有限公司 制备羟乙基亚乙基胺的方法
WO2018108890A1 (en) * 2016-12-15 2018-06-21 Akzo Nobel Chemicals International B.V. Process for manufacturing ethylene amines
WO2019011710A1 (en) * 2017-07-10 2019-01-17 Akzo Nobel Chemicals International B.V. PROCESS FOR THE PREPARATION OF ETHYLENEAMINES AND ETHYLENEAMINE DERIVATIVES
WO2019030193A1 (en) * 2017-08-11 2019-02-14 Akzo Nobel Chemicals International B.V. TWO-CYCLE ALKYLENE-UREA CONVERSION PROCESS INTO THEIR ALKYLENE AMINOUS CORRESPONDENTS
EP3665152A1 (en) * 2017-08-11 2020-06-17 Nouryon Chemicals International B.V. Process for converting cyclic alkylene ureas into their corresponding alkylene amines
EP3665159B1 (en) * 2017-08-11 2022-12-28 Nouryon Chemicals International B.V. Process to convert the cyclic monourea of an ethylene amine compound into the ethylene amine compound
CN114901383A (zh) * 2020-01-28 2022-08-12 东曹株式会社 二氧化碳分离用组合物、以及二氧化碳的分离方法

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2812333A (en) * 1954-09-27 1957-11-05 Union Carbide Corp Process for the preparation of 1-(2-hydroxyethyl) imidazolidine-2
US4503250A (en) 1981-09-30 1985-03-05 Union Carbide Corporation Preparation of polyalkylene polyamines
US4387249A (en) 1981-12-18 1983-06-07 The Dow Chemical Company Process for the manufacture of diethylenetriamine
SE513250C2 (sv) 1997-11-11 2000-08-07 Akzo Nobel Nv Amineringsförfarande för framställning av polyaminer
DE102004011320A1 (de) 2004-03-09 2005-09-22 Degussa Ag Verfahren zur Herstellung von Aminen aus Carbodiimidgruppen aufweisenden Verbindungen durch Hydrolyse mit Wasser
JP6150347B2 (ja) * 2012-03-02 2017-06-21 国立大学法人九州大学 アミノ基および／または水酸基を有する化合物の製造方法
JP6496088B2 (ja) * 2016-02-12 2019-04-03 アクゾ ノーベル ケミカルズ インターナショナル ベスローテン フエンノートシャップＡｋｚｏ Ｎｏｂｅｌ Ｃｈｅｍｉｃａｌｓ Ｉｎｔｅｒｎａｔｉｏｎａｌ Ｂ．Ｖ． 環状アルキレン尿素をそれらの対応するアルキレンアミンに変換するプロセス
EP3665159B1 (en) * 2017-08-11 2022-12-28 Nouryon Chemicals International B.V. Process to convert the cyclic monourea of an ethylene amine compound into the ethylene amine compound

Also Published As

Publication number Publication date
US20200165187A1 (en) 2020-05-28
CA3071903A1 (en) 2019-02-14
BR112020002389B1 (pt) 2023-03-21
TWI761570B (zh) 2022-04-21
CN111032616A (zh) 2020-04-17
EP3665153A1 (en) 2020-06-17
CN111032616B (zh) 2024-01-19
WO2019030190A1 (en) 2019-02-14
JP2023017864A (ja) 2023-02-07
RU2020109528A3 (es) 2021-09-14
US11236039B2 (en) 2022-02-01
KR20200036011A (ko) 2020-04-06
TW201920065A (zh) 2019-06-01
BR112020002389A2 (pt) 2020-09-01
JP2020530455A (ja) 2020-10-22
RU2020109528A (ru) 2021-09-14

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