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MX2019015134A - Proceso de síntesis de a-terpineol a partir de la hidratación de a-pineno utilizando un líquido iónico como solvente. - Google Patents

Proceso de síntesis de a-terpineol a partir de la hidratación de a-pineno utilizando un líquido iónico como solvente.

Info

Publication number
MX2019015134A
MX2019015134A MX2019015134A MX2019015134A MX2019015134A MX 2019015134 A MX2019015134 A MX 2019015134A MX 2019015134 A MX2019015134 A MX 2019015134A MX 2019015134 A MX2019015134 A MX 2019015134A MX 2019015134 A MX2019015134 A MX 2019015134A
Authority
MX
Mexico
Prior art keywords
terpineol
solvent
ionic liquid
pinene
reaction
Prior art date
Application number
MX2019015134A
Other languages
English (en)
Inventor
Elguezabal Alfredo Aguilar
AGUIRRE Manuel ROMÁN
La Torre Sáenz Luis De
Original Assignee
Centro De Investigacion En Mat Avanzados Sc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Centro De Investigacion En Mat Avanzados Sc filed Critical Centro De Investigacion En Mat Avanzados Sc
Priority to MX2019015134A priority Critical patent/MX2019015134A/es
Priority to US17/110,845 priority patent/US20210170379A1/en
Publication of MX2019015134A publication Critical patent/MX2019015134A/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0277—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature
    • B01J31/0278—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre
    • B01J31/0279—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre the cationic portion being acyclic or nitrogen being a substituent on a ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0277—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature
    • B01J31/0298—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature the ionic liquids being characterised by the counter-anions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

La presente invención provee un proceso para obtener a-terpineol mediante la hidratación de a-pineno, en el cual se utiliza como solvente un líquido iónico sintetizado a partir de una amina terciaria y un ácido inorgánico. El uso del líquido iónico como solvente favorece la selectividad hacia la formación de a-terpineol y al término de la reacción, una vez llevado a temperatura ambiente el producto de reacción, puede separarse físicamente de la fase orgánica de la inorgánica por decantación. La fase inorgánica contiene el líquido iónico, agua y catalizador de la reacción y puede directamente ser reutilizado para una nueva carga de reacción, reponiendo solamente el agua consumida en la reacción previa.
MX2019015134A 2019-12-06 2019-12-06 Proceso de síntesis de a-terpineol a partir de la hidratación de a-pineno utilizando un líquido iónico como solvente. MX2019015134A (es)

Priority Applications (2)

Application Number Priority Date Filing Date Title
MX2019015134A MX2019015134A (es) 2019-12-06 2019-12-06 Proceso de síntesis de a-terpineol a partir de la hidratación de a-pineno utilizando un líquido iónico como solvente.
US17/110,845 US20210170379A1 (en) 2019-12-06 2020-12-03 Hydration of alpha-Pinene to obtain alpha-terpineol, using an ionic liquid as solvent, which is synthesized from a tertiary amine and an inorganic acid

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
MX2019015134A MX2019015134A (es) 2019-12-06 2019-12-06 Proceso de síntesis de a-terpineol a partir de la hidratación de a-pineno utilizando un líquido iónico como solvente.

Publications (1)

Publication Number Publication Date
MX2019015134A true MX2019015134A (es) 2021-06-07

Family

ID=76209561

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2019015134A MX2019015134A (es) 2019-12-06 2019-12-06 Proceso de síntesis de a-terpineol a partir de la hidratación de a-pineno utilizando un líquido iónico como solvente.

Country Status (2)

Country Link
US (1) US20210170379A1 (es)
MX (1) MX2019015134A (es)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20240111772A (ko) 2021-11-19 2024-07-17 엔테그리스, 아이엔씨. 트리알킬암모늄 디히드로겐 포스페이트를 제조하는 방법

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4499594B2 (ja) * 2005-03-29 2010-07-07 第一工業製薬株式会社 超高純度イオン性液体
CN104529707B (zh) * 2015-01-05 2016-05-04 广西民族大学 利用碳基固体酸催化松节油一步水合合成松油醇的方法
CN105702990B (zh) * 2016-01-29 2018-03-30 青岛科技大学 一种三元复合质子交换膜及其制备方法
CN111014272B (zh) * 2019-11-19 2021-06-15 清华苏州环境创新研究院 一种利用硫酸氢三乙胺离子液体去除土壤或植物中重金属的方法

Also Published As

Publication number Publication date
US20210170379A1 (en) 2021-06-10

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