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MX2018015764A - Proceso para la epoxidacion de un alqueno tetrasustituido. - Google Patents

Proceso para la epoxidacion de un alqueno tetrasustituido.

Info

Publication number
MX2018015764A
MX2018015764A MX2018015764A MX2018015764A MX2018015764A MX 2018015764 A MX2018015764 A MX 2018015764A MX 2018015764 A MX2018015764 A MX 2018015764A MX 2018015764 A MX2018015764 A MX 2018015764A MX 2018015764 A MX2018015764 A MX 2018015764A
Authority
MX
Mexico
Prior art keywords
epoxidation
tetrasubstituted alkene
tetrasubstituted
alkene
terpinolene
Prior art date
Application number
MX2018015764A
Other languages
English (en)
Inventor
Rack Michael
Kraus Helmut
Wolf Bernd
Gebhardt Joachim
Goetz Roland
BENSON Stefan
Original Assignee
Basf Agro Bv
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Agro Bv filed Critical Basf Agro Bv
Publication of MX2018015764A publication Critical patent/MX2018015764A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/14—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic peracids, or salts, anhydrides or esters thereof
    • C07D301/16—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic peracids, or salts, anhydrides or esters thereof formed in situ, e.g. from carboxylic acids and hydrogen peroxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0086—Processes carried out with a view to control or to change the pH-value; Applications of buffer salts; Neutralisation reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D493/00—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
    • C07D493/02—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains two hetero rings
    • C07D493/08—Bridged systems

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

La presente invención se refiere a un proceso para la epoxidación de un alqueno tetrasustituido, tal coma terpinoleno, en el epóxido correspondiente, tal coma epóxido de terpinoleno, hacienda reaccionar el alqueno tetrasustituido con ácido perfórmico preparado in situ a partir de ácido fórmica y peróxido de hidrogeno en presencia de al menos un agente amortiguador. Asimismo, la invención se refiere al uso de un agente oxidante que comprende peroxido de hidrogeno y acido fórmico para la epoxidación in situ de un alqueno tetrasustituido.
MX2018015764A 2016-06-15 2017-06-01 Proceso para la epoxidacion de un alqueno tetrasustituido. MX2018015764A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP16174601 2016-06-15
PCT/EP2017/063276 WO2017215928A1 (en) 2016-06-15 2017-06-01 Process for the epoxidation of a tetrasubstituted alkene

Publications (1)

Publication Number Publication Date
MX2018015764A true MX2018015764A (es) 2019-08-29

Family

ID=56132819

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2018015764A MX2018015764A (es) 2016-06-15 2017-06-01 Proceso para la epoxidacion de un alqueno tetrasustituido.

Country Status (12)

Country Link
US (1) US11072593B2 (es)
EP (1) EP3472138B1 (es)
KR (1) KR20190017924A (es)
CN (1) CN109311835A (es)
AR (1) AR108740A1 (es)
AU (1) AU2017286055B2 (es)
BR (1) BR112018076043B1 (es)
DK (1) DK3472138T3 (es)
ES (1) ES2833202T3 (es)
IL (1) IL263518B (es)
MX (1) MX2018015764A (es)
WO (1) WO2017215928A1 (es)

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BR112017028322A2 (pt) 2015-07-22 2018-09-11 Basf Se compostos, processo para a produção de compostos i, para a produção de compostos ii dos compostos iii e para a produção de compostos iii, compostos intermediários v e utilização dos compostos i
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EP3419955B1 (en) 2016-02-26 2020-03-04 BASF Agro B.V. Process for preparing a mixture of terpene alcohols
WO2017215928A1 (en) 2016-06-15 2017-12-21 BASF Agro B.V. Process for the epoxidation of a tetrasubstituted alkene
BR112018076030A2 (pt) 2016-06-15 2019-03-26 BASF Agro B.V. processo de epoxidação de alqueno tetrassubstituído e uso de agente oxidante

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BR112018076043B1 (pt) 2023-09-26
AR108740A1 (es) 2018-09-19
EP3472138B1 (en) 2020-08-26
IL263518B (en) 2021-03-25
ES2833202T3 (es) 2021-06-14
US11072593B2 (en) 2021-07-27
BR112018076043A2 (pt) 2019-03-26
WO2017215928A1 (en) 2017-12-21
KR20190017924A (ko) 2019-02-20
US20200308125A1 (en) 2020-10-01
EP3472138A1 (en) 2019-04-24
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