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MX2018013275A - Agente de soplado de z-hfo-1336mzz para espumacion de polimero termoplastico que comprende poliestireno. - Google Patents

Agente de soplado de z-hfo-1336mzz para espumacion de polimero termoplastico que comprende poliestireno.

Info

Publication number
MX2018013275A
MX2018013275A MX2018013275A MX2018013275A MX2018013275A MX 2018013275 A MX2018013275 A MX 2018013275A MX 2018013275 A MX2018013275 A MX 2018013275A MX 2018013275 A MX2018013275 A MX 2018013275A MX 2018013275 A MX2018013275 A MX 2018013275A
Authority
MX
Mexico
Prior art keywords
thermoplastic polymer
hfo
blowing agent
carried out
polystyrene
Prior art date
Application number
MX2018013275A
Other languages
English (en)
Inventor
Anthony Creazzo Joseph
L Robin Mark
Original Assignee
Chemours Co Fc Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chemours Co Fc Llc filed Critical Chemours Co Fc Llc
Publication of MX2018013275A publication Critical patent/MX2018013275A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/143—Halogen containing compounds
    • C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
    • C08J9/146—Halogen containing compounds containing carbon, halogen and hydrogen only only fluorine as halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/149—Mixtures of blowing agents covered by more than one of the groups C08J9/141 - C08J9/143
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C08L25/04—Homopolymers or copolymers of styrene
    • C08L25/08—Copolymers of styrene
    • C08L25/12—Copolymers of styrene with unsaturated nitriles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2201/00—Foams characterised by the foaming process
    • C08J2201/02—Foams characterised by the foaming process characterised by mechanical pre- or post-treatments
    • C08J2201/03—Extrusion of the foamable blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
    • C08J2203/142—Halogenated saturated hydrocarbons, e.g. H3C-CF3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/16—Unsaturated hydrocarbons
    • C08J2203/162—Halogenated unsaturated hydrocarbons, e.g. H2C=CF2
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/18—Binary blends of expanding agents
    • C08J2203/182—Binary blends of expanding agents of physical blowing agents, e.g. acetone and butane
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2205/00—Foams characterised by their properties
    • C08J2205/04—Foams characterised by their properties characterised by the foam pores
    • C08J2205/042—Nanopores, i.e. the average diameter being smaller than 0,1 micrometer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2205/00—Foams characterised by their properties
    • C08J2205/04—Foams characterised by their properties characterised by the foam pores
    • C08J2205/044—Micropores, i.e. average diameter being between 0,1 micrometer and 0,1 millimeter
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2205/00—Foams characterised by their properties
    • C08J2205/04—Foams characterised by their properties characterised by the foam pores
    • C08J2205/052—Closed cells, i.e. more than 50% of the pores are closed
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C08J2325/02—Homopolymers or copolymers of hydrocarbons
    • C08J2325/04—Homopolymers or copolymers of styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C08J2325/02—Homopolymers or copolymers of hydrocarbons
    • C08J2325/04—Homopolymers or copolymers of styrene
    • C08J2325/06—Polystyrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C08J2325/02—Homopolymers or copolymers of hydrocarbons
    • C08J2325/04—Homopolymers or copolymers of styrene
    • C08J2325/08—Copolymers of styrene
    • C08J2325/12—Copolymers of styrene with unsaturated nitriles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/14—Applications used for foams

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)

Abstract

Se proporciona un proceso que comprende extrudir una composición fundida que comprende polímero termoplástico que comprende poliestireno y agente de soplado que comprende Z-1,1,1,4,4,4-hexafluoro-2-buteno (Z-HFO-1336mzz) bajo las condiciones (a) la composición fundida se forma al mezclar por fusión a una temperatura de al menos 180 °C, (b) el mezclado por fusión se lleva a cabo y bajo una presión de al menos 10.3 MPa (1500 psi (103 Bar)), (c) la extrusión se lleva a cabo a una temperatura de al menos 120 °C, y (d) la extrusión se lleva a cabo bajo una presión de al menos 6.9 MPa (1000 psi (69 Bar)), las condiciones son efectivas para producir polímero termoplástico espumado de baja densidad, celda cerrada y superficie lisa que comprende poliestireno en ausencia de cualquier agente de cosoplado.
MX2018013275A 2016-05-06 2017-05-02 Agente de soplado de z-hfo-1336mzz para espumacion de polimero termoplastico que comprende poliestireno. MX2018013275A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201662332616P 2016-05-06 2016-05-06
PCT/US2017/030587 WO2017192550A1 (en) 2016-05-06 2017-05-02 Z-HFO-1336mzz BLOWING AGENT FOR FOAMING THERMOPLASTIC POLYMER COMPRISING POLYSTYRENE

Publications (1)

Publication Number Publication Date
MX2018013275A true MX2018013275A (es) 2019-03-28

Family

ID=58709573

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2018013275A MX2018013275A (es) 2016-05-06 2017-05-02 Agente de soplado de z-hfo-1336mzz para espumacion de polimero termoplastico que comprende poliestireno.

Country Status (8)

Country Link
US (1) US20190218358A1 (es)
EP (1) EP3452538B1 (es)
JP (1) JP2019515112A (es)
CN (2) CN120554701A (es)
ES (1) ES3004011T3 (es)
MX (1) MX2018013275A (es)
PL (1) PL3452538T3 (es)
WO (1) WO2017192550A1 (es)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20200325297A1 (en) * 2017-10-10 2020-10-15 The Chemours Company Fc, Llc Process for the manufacture of thermoplastic foam containing hfo-1336mzz(z) and hfo-1336mzz(e)
PL3824021T3 (pl) * 2018-07-16 2024-03-04 The Chemours Company Fc, Llc Mieszanki środków porotwórczych
JP7568650B2 (ja) * 2019-05-29 2024-10-16 ザ ケマーズ カンパニー エフシー リミテッド ライアビリティ カンパニー 熱可塑性ポリマーのための発泡剤ブレンド
EP3986961A1 (en) * 2019-06-24 2022-04-27 The Chemours Company FC, LLC Blowing agent blends for thermoplastic polymers
JP7141983B2 (ja) * 2019-07-01 2022-09-26 旭有機材株式会社 フェノールフォーム製造用樹脂組成物並びにフェノールフォーム及びその製造方法
AU2021208850B2 (en) * 2020-01-16 2023-10-05 Asahi Kasei Construction Materials Corporation Phenolic resin foam laminate board and composite board
JP7674081B2 (ja) * 2020-08-13 2025-05-09 ディーディーピー スペシャルティ エレクトロニック マテリアルズ ユーエス リミテッド ライアビリティ カンパニー 押出発泡法によるスチレン系樹脂発泡体の製造方法、及び製造される発泡体、並びに、製造方法に使用する発泡性樹脂組成物
US12054596B2 (en) 2020-11-30 2024-08-06 Honeywell International Inc. Azeotrope or azeotrope-like compositions of Z-1-chloro-2,3,3,3-tetrafluoropropene (HCFO-1224yd(Z))
KR20240046756A (ko) * 2021-08-16 2024-04-09 허니웰 인터내셔날 인코포레이티드 발포성 열가소성 조성물, 열가소성 폼 및 이의 제조 방법
JP7674229B2 (ja) * 2021-12-09 2025-05-09 株式会社ジェイエスピー ポリスチレン系樹脂押出発泡板の製造方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS597728B2 (ja) * 1976-03-23 1984-02-20 旭ダウ株式会社 スチレン系樹脂発泡体の製造方法
CN102690434B (zh) * 2005-11-01 2015-08-19 纳幕尔杜邦公司 利用包含不饱和碳氟化合物的发泡剂制备泡沫的方法
US8198340B2 (en) * 2007-03-27 2012-06-12 Dow Global Technologies Llc Quality polymer foam from fluorinated alkene blowing agents
PL2129710T3 (pl) * 2007-03-29 2012-06-29 Arkema Inc Zawierające fluoropropen środki porotwórcze dla polistyrenu
CN101688013B (zh) * 2007-07-03 2011-12-28 陶氏环球技术公司 具有大的泡孔尺寸和高填料含量的闭孔泡沫体
ES2644518T3 (es) * 2009-06-02 2017-11-29 The Chemours Company Fc, Llc Composiciones azeotrópicas y similares a azeótropos de Z-1,1,1,4,4,4-hexafluoro-2-buteno
EP2706086A1 (de) * 2012-09-05 2014-03-12 Basf Se Verfahren zur Herstellung von Schaumstoffplatten niedriger Dichte durch Extrusion von Styrolpolymeren unter Verwendung von Hydrofluorolefinen als Treibmittel
CN103172489B (zh) * 2013-03-14 2015-07-15 巨化集团技术中心 一种1,1,1,4,4,4-六氟-2-丁烯的合成方法
CN106795310A (zh) * 2014-07-10 2017-05-31 欧文斯科宁知识产权资产有限公司 使用二氧化碳作为主发泡剂制造挤出聚苯乙烯泡沫体的方法

Also Published As

Publication number Publication date
US20190218358A1 (en) 2019-07-18
WO2017192550A1 (en) 2017-11-09
CN109071862A (zh) 2018-12-21
JP2019515112A (ja) 2019-06-06
EP3452538B1 (en) 2024-12-18
CN120554701A (zh) 2025-08-29
CA3021687A1 (en) 2017-11-09
ES3004011T3 (en) 2025-03-11
PL3452538T3 (pl) 2025-04-14
EP3452538A1 (en) 2019-03-13

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