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MX2018008207A - Sistema catalizador sin ftalato y su uso en la polimerizacion de olefinas. - Google Patents

Sistema catalizador sin ftalato y su uso en la polimerizacion de olefinas.

Info

Publication number
MX2018008207A
MX2018008207A MX2018008207A MX2018008207A MX2018008207A MX 2018008207 A MX2018008207 A MX 2018008207A MX 2018008207 A MX2018008207 A MX 2018008207A MX 2018008207 A MX2018008207 A MX 2018008207A MX 2018008207 A MX2018008207 A MX 2018008207A
Authority
MX
Mexico
Prior art keywords
catalyst system
polymerization
olefins
phthalate catalyst
phthalate
Prior art date
Application number
MX2018008207A
Other languages
English (en)
Inventor
Mitchell Brandi
Meverden Craig
Original Assignee
Braskem America Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Braskem America Inc filed Critical Braskem America Inc
Publication of MX2018008207A publication Critical patent/MX2018008207A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
    • C08F4/6494—Catalysts containing a specific non-metal or metal-free compound organic containing oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/38—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of titanium, zirconium or hafnium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/02—Carriers therefor
    • C08F4/022—Magnesium halide as support anhydrous or hydrated or complexed by means of a Lewis base for Ziegler-type catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/651—Pretreating with non-metals or metal-free compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/12—Olefin polymerisation or copolymerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/20—Constitutive chemical elements of heterogeneous catalysts of Group II (IIA or IIB) of the Periodic Table
    • B01J2523/22—Magnesium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/40—Constitutive chemical elements of heterogeneous catalysts of Group IV (IVA or IVB) of the Periodic Table
    • B01J2523/47—Titanium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/04—Broad molecular weight distribution, i.e. Mw/Mn > 6
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/12—Melt flow index or melt flow ratio
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/15—Isotactic

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Emergency Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

Esta invención se refiere a un sistema catalítico que sin ftalato para la polimerización de olefinas. El sistema catalizador que sin ftalato comprende (a) una composición catalizadora Ziegler-Natta sólida que comprende un metal de transición, un metal del Grupo 2 y uno o más halógenos; y uno o más compuestos donantes de electrones internos; y (b) uno o más compuestos donantes de electrones externos.
MX2018008207A 2015-12-31 2016-12-29 Sistema catalizador sin ftalato y su uso en la polimerizacion de olefinas. MX2018008207A (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201562273584P 2015-12-31 2015-12-31
US201662278256P 2016-01-13 2016-01-13
PCT/US2016/069299 WO2017117443A1 (en) 2015-12-31 2016-12-29 Non-phthalate catalyst system and its use in the polymerization of olefins

Publications (1)

Publication Number Publication Date
MX2018008207A true MX2018008207A (es) 2018-08-28

Family

ID=59225403

Family Applications (3)

Application Number Title Priority Date Filing Date
MX2018008209A MX2018008209A (es) 2015-12-31 2016-12-29 Sistema catalizador sin ftalato y su uso en la polimerizacion de olefinas.
MX2018008207A MX2018008207A (es) 2015-12-31 2016-12-29 Sistema catalizador sin ftalato y su uso en la polimerizacion de olefinas.
MX2018008208A MX2018008208A (es) 2015-12-31 2016-12-29 Sistema catalizador sin ftalato y su uso en la polimerizacion de olefinas.

Family Applications Before (1)

Application Number Title Priority Date Filing Date
MX2018008209A MX2018008209A (es) 2015-12-31 2016-12-29 Sistema catalizador sin ftalato y su uso en la polimerizacion de olefinas.

Family Applications After (1)

Application Number Title Priority Date Filing Date
MX2018008208A MX2018008208A (es) 2015-12-31 2016-12-29 Sistema catalizador sin ftalato y su uso en la polimerizacion de olefinas.

Country Status (5)

Country Link
US (4) US10633464B2 (es)
EP (3) EP3397659A4 (es)
BR (4) BR112018013487B1 (es)
MX (3) MX2018008209A (es)
WO (3) WO2017117433A1 (es)

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CN109912735B (zh) * 2017-12-12 2020-09-29 中国科学院化学研究所 烯烃聚合催化剂用外给电子体、催化剂体系以及聚烯烃的制备方法
KR20210145787A (ko) 2019-04-02 2021-12-02 알리고스 테라퓨틱스 인코포레이티드 Prmt5를 표적으로 하는 화합물
JP7797202B2 (ja) 2019-05-31 2026-01-13 ザ プロクター アンド ギャンブル カンパニー 腰部ガスケット要素を有する吸収性物品
CN110483666A (zh) * 2019-07-02 2019-11-22 浙江石油化工有限公司 一种丙烯聚合催化剂
JP7377969B2 (ja) 2019-11-04 2023-11-10 ザ プロクター アンド ギャンブル カンパニー 腰部ガスケット要素を有する吸収性物品
EP4146132A1 (en) 2020-05-05 2023-03-15 The Procter & Gamble Company Absorbent articles including improved elastic panels
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KR20240019289A (ko) * 2021-06-10 2024-02-14 더블유.알. 그레이스 앤드 캄파니-콘. 3차원 인쇄를 위한 폴리프로필렌 랜덤 공중합체 및 이로부터 제조된 필라멘트
CN119331140B (zh) * 2023-07-21 2025-09-05 中国石油天然气股份有限公司 一种用于烯烃聚合的催化剂组分、催化剂及其应用
JP2026500034A (ja) * 2023-07-21 2026-01-05 中国石油天然气股▲ふん▼有限公司 オレフィン重合用触媒成分、触媒及びその使用
CN119331145B (zh) * 2023-07-21 2025-08-19 中国石油天然气股份有限公司 一种用于烯烃聚合的催化剂组分、催化剂及其应用
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Also Published As

Publication number Publication date
WO2017117443A1 (en) 2017-07-06
EP3397657B1 (en) 2024-06-12
WO2017117439A1 (en) 2017-07-06
BR112018013506B1 (pt) 2022-10-11
BR112018013506A2 (pt) 2018-12-11
EP3397657A1 (en) 2018-11-07
WO2017117433A1 (en) 2017-07-06
US20190010258A1 (en) 2019-01-10
EP3397658B1 (en) 2022-07-27
US10633464B2 (en) 2020-04-28
BR112018013476A2 (pt) 2018-12-04
US11041028B2 (en) 2021-06-22
US20190016832A1 (en) 2019-01-17
BR122022010417B1 (pt) 2023-01-31
US10633463B2 (en) 2020-04-28
US11117982B2 (en) 2021-09-14
MX2018008209A (es) 2018-08-28
BR112018013487B1 (pt) 2022-08-30
EP3397659A1 (en) 2018-11-07
EP3397657A4 (en) 2019-09-11
BR112018013487A2 (pt) 2018-12-04
EP3397659A4 (en) 2019-09-04
BR112018013476B1 (pt) 2022-10-11
EP3397658A1 (en) 2018-11-07
US20200199262A1 (en) 2020-06-25
BR112018013476B8 (pt) 2022-11-08
US20190010264A1 (en) 2019-01-10
MX2018008208A (es) 2018-08-28
EP3397658A4 (en) 2019-09-11

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