[go: up one dir, main page]

MX2018006241A - Produccion de derivados de olefina grasa via metatesis de olefina. - Google Patents

Produccion de derivados de olefina grasa via metatesis de olefina.

Info

Publication number
MX2018006241A
MX2018006241A MX2018006241A MX2018006241A MX2018006241A MX 2018006241 A MX2018006241 A MX 2018006241A MX 2018006241 A MX2018006241 A MX 2018006241A MX 2018006241 A MX2018006241 A MX 2018006241A MX 2018006241 A MX2018006241 A MX 2018006241A
Authority
MX
Mexico
Prior art keywords
olefin
fatty
metathesis
production
catalyst
Prior art date
Application number
MX2018006241A
Other languages
English (en)
Inventor
Ondi Levente
M Wampler Keith
Meinhold Peter
Coelho Pedro
Bui Vu
Mehdi Hasan
Original Assignee
Provivi Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Provivi Inc filed Critical Provivi Inc
Publication of MX2018006241A publication Critical patent/MX2018006241A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C07C67/343—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2265—Carbenes or carbynes, i.e.(image)
    • B01J31/2278—Complexes comprising two carbene ligands differing from each other, e.g. Grubbs second generation catalysts
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
    • A01P19/00—Pest attractants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2217—At least one oxygen and one nitrogen atom present as complexing atoms in an at least bidentate or bridging ligand
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/21—Alkatrienes; Alkatetraenes; Other alkapolyenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C201/00—Preparation of esters of nitric or nitrous acid or of compounds containing nitro or nitroso groups bound to a carbon skeleton
    • C07C201/02—Preparation of esters of nitric acid
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C203/00—Esters of nitric or nitrous acid
    • C07C203/02—Esters of nitric acid
    • C07C203/04—Esters of nitric acid having nitrate groups bound to acyclic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C33/00—Unsaturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C33/02—Acyclic alcohols with carbon-to-carbon double bonds
    • C07C33/025—Acyclic alcohols with carbon-to-carbon double bonds with only one double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/29—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/41—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by hydrogenolysis or reduction of carboxylic groups or functional derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/20—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms
    • C07C47/21—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
    • C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/28—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/293—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
    • C07C69/04—Formic acid esters
    • C07C69/06—Formic acid esters of monohydroxylic compounds
    • C07C69/07—Formic acid esters of monohydroxylic compounds of unsaturated alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
    • C07C69/12—Acetic acid esters
    • C07C69/14—Acetic acid esters of monohydroxylic compounds
    • C07C69/145—Acetic acid esters of monohydroxylic compounds of unsaturated alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/54—Metathesis reactions, e.g. olefin metathesis
    • B01J2231/543—Metathesis reactions, e.g. olefin metathesis alkene metathesis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/64—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/66—Tungsten
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/09—Geometrical isomers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • General Chemical & Material Sciences (AREA)
  • Plant Pathology (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

En un aspecto, la invención proporciona un método para la síntesis de un derivado de olefina grasa. El método incluye: a) el contacto de una olefina de acuerdo con la Fórmula I (ver Fórmula) con un compañero de reacción de metátesis de acuerdo con la Fórmula IIb (ver Fórmula) en presencia de un catalizador de metátesis en condiciones suficientes para formar un producto de metátesis de acuerdo con la Fórmula llIb: (ver Fórmula) b) la conversión del producto de metátesis al derivado de olefina grasa. Cada R1 se selecciona de manera independiente de H, C1-18 alquilo y C2-18 alquenilo; R2b es C1-8 alquilo; subíndice y es un número entero que varía de 0 a 17; y el subíndice z es un número entero que varía de 0 a 17. En ciertas formas de realización, el catalizador de metátesis es un catalizador de tungsteno o un catalizador de molibdeno. En diversas formas de realización, el derivado de olefina grasa es una feromona de insecto. Se describen además composiciones de feromonas y métodos para su uso.
MX2018006241A 2015-11-18 2016-11-17 Produccion de derivados de olefina grasa via metatesis de olefina. MX2018006241A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201562257148P 2015-11-18 2015-11-18
PCT/US2016/062595 WO2017087710A2 (en) 2015-11-18 2016-11-17 Production of fatty olefin derivatives via olefin metathesis

Publications (1)

Publication Number Publication Date
MX2018006241A true MX2018006241A (es) 2018-11-09

Family

ID=58689813

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2018006241A MX2018006241A (es) 2015-11-18 2016-11-17 Produccion de derivados de olefina grasa via metatesis de olefina.

Country Status (14)

Country Link
US (4) US9776179B2 (es)
EP (2) EP3377465B1 (es)
JP (2) JP6970088B2 (es)
CN (2) CN108473390B (es)
AR (2) AR108028A1 (es)
AU (1) AU2016357756B2 (es)
BR (1) BR112018009885B1 (es)
CA (1) CA3005562C (es)
CL (2) CL2018001337A1 (es)
HU (1) HUE063333T2 (es)
IL (1) IL259459B (es)
MX (1) MX2018006241A (es)
PL (1) PL3377465T3 (es)
WO (1) WO2017087710A2 (es)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR112015023269B8 (pt) 2013-03-14 2022-08-16 Ximo Ag Método de formação de um produto de olefinas em uma reação de metátese a partir de uma matéria-prima compreendendo uma primeira olefina e uma segunda olefina e método para aumentar a reatividade de um composto
EP3052229B1 (en) 2013-10-01 2021-02-24 Verbio Vereinigte BioEnergie AG Immobilized metathesis tungsten oxo alkylidene catalysts and use thereof in olefin metathesis
GB201406591D0 (en) * 2014-04-11 2014-05-28 Ximo Ag Compounds
DK3376859T3 (da) 2015-11-18 2021-03-29 Provivi Inc Mikroorganismer til fremstilling af insektferomoner og relaterede forbindelser
MX2018006241A (es) 2015-11-18 2018-11-09 Provivi Inc Produccion de derivados de olefina grasa via metatesis de olefina.
AR110606A1 (es) 2016-06-06 2019-04-17 Provivi Inc Producción semi-biosintética de alcoholes grasos y aldehídos grasos
EP3583088B1 (en) * 2017-02-17 2025-09-10 Provivi, Inc. Synthesis of pheromones and related materials via olefin metathesis
AR112543A1 (es) 2017-05-17 2019-11-13 Provivi Inc Microorganismos para la producción de feromonas de insectos y compuestos relacionados
US11702436B2 (en) 2018-03-22 2023-07-18 Verbio Vereinigte Bioenergie Ag Tetraphenylphenoxy tungsten oxo alkylidene complexes and methods of making same and use thereof
EP3823946A4 (en) 2018-07-16 2021-09-22 Provivi, Inc. SUMMARY OF STRAIGHT-CHAIN LEPIDOPTERA PHEROMONES BY APPROVAL OF ONE OR TWO CARBON ATOMS OF FAT ALKENES
US12049443B2 (en) 2018-12-10 2024-07-30 Provivi, Inc. Synthesis of conjugated diene pheromones and related compounds
CN113728082A (zh) * 2019-02-21 2021-11-30 丰益贸易私人有限公司 甘油酯低聚物的生产方法和由其形成的产品
CN114174310A (zh) 2019-05-27 2022-03-11 韦尔比奥联合生物能源股份公司 钨亚氨基亚烷基O-bitet和O-binol配合物及其在烯烃复分解反应中的用途
FI128954B (en) * 2019-09-26 2021-03-31 Neste Oyj Preparation of renewable base oil including metathesis
FI128953B (en) 2019-09-26 2021-03-31 Neste Oyj Production of renewable chemicals including metathesis and microbial oxidation
FI128952B (en) 2019-09-26 2021-03-31 Neste Oyj Preparation of renewable alkenes including metathesis
MY208435A (en) 2019-12-11 2025-05-08 Novoloop Inc Compositions and methods for the degradation of waste polypropylene
CA3183733A1 (en) * 2020-06-01 2021-12-09 Provivi, Inc. Synthesis of pheromone derivatives via z-selective olefin metathesis
JP7475264B2 (ja) * 2020-12-10 2024-04-26 信越化学工業株式会社 ３－イソプロペニル－６－ヘプテナール化合物及び６－イソプロペニル－３－メチル－３，９－デカジエニル＝カルボキシレート化合物の製造方法並びにその中間体
WO2025199154A1 (en) * 2024-03-18 2025-09-25 Provivi, Inc Synthesis of e pheromones
CN118852298B (zh) * 2024-09-24 2024-11-22 云南大学 一种制备线虫蛔糖苷和葡萄糖苷二聚信息素的方法

Family Cites Families (76)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4231947A (en) 1979-01-02 1980-11-04 Massachusetts Institute Of Technology Tantalum and niobium catalysts or catalyst precursors
US4245131A (en) 1979-07-02 1981-01-13 Massachusetts Institute Of Technology Dimerization of olefins using tantalum and niobium catalysts
HU180386B (en) * 1980-10-24 1983-02-28 Egyt Gyogyszervegyeszeti Gyar Process for producing 11-dodecen-1-ol and 11-dodecen-1-yl-acetate of insect-feromone activity
US4427595A (en) 1981-07-16 1984-01-24 Massachusetts Institute Of Technology Catalyst composition to effect metathesis of acetylenes
US4560792A (en) * 1982-07-20 1985-12-24 Phillips Petroleum Company Disproportionation of functional olefins
DE3460103D1 (en) 1983-06-15 1986-05-28 Elf Aquitaine Catalyst for olefin methathesis
US4792620A (en) * 1983-10-14 1988-12-20 Bp Chemicals Limited Carbonylation catalysts
US4681956A (en) 1985-09-25 1987-07-21 Massachusetts Institute Of Technology Catalyst composition for effecting metathesis of olefins
US4727215A (en) 1985-09-25 1988-02-23 Massachusetts Institute Of Technology Catalyst composition for effecting metathesis of olefins
US4837358A (en) 1986-02-26 1989-06-06 Phillips Petroleum Company Preparation of 9-alkenyl ester compounds
US5081287A (en) * 1989-06-30 1992-01-14 Fmc Corporation Pesticidal polyhalo alkenoic acid esters
US5146033A (en) 1990-01-04 1992-09-08 Massachusetts Institute Of Technology Homogeneous rhenium catalysts for metathesis of olefins
US5087710A (en) 1990-01-04 1992-02-11 Massachusetts Institute Of Technology Homogeneous rhenium catalysts for metathesis of olefins
US5142073A (en) 1991-04-30 1992-08-25 Massachusetts Institute Of Technology Synthesis of molybdenum and tungsten complexes
DE4434640C1 (de) * 1994-09-28 1996-02-01 Hoechst Ag Verfahren zur Herstellung verbrückter Metallocene
SG72861A1 (en) 1997-09-30 2000-05-23 Kuraray Co Process for producing 7-octen-1-al
US6121473A (en) 1998-02-19 2000-09-19 Massachusetts Institute Of Technology Asymmetric ring-closing metathesis reactions
JP4169801B2 (ja) 1998-04-01 2008-10-22 フイルメニツヒ ソシエテ アノニム 亜鉛触媒存在下でのシランによるカルボニル化合物の還元
DE19815275B4 (de) 1998-04-06 2009-06-25 Evonik Degussa Gmbh Alkylidenkomplexe des Rutheniums mit N-heterozyklischen Carbenliganden und deren Verwendung als hochaktive, selektive Katalysatoren für die Olefin-Metathese
US6346652B1 (en) 1998-07-13 2002-02-12 Massachusetts Institute Of Technology Asymmetric ring-closing metathesis reactions involving achiral and meso substrates
US6696597B2 (en) * 1998-09-01 2004-02-24 Tilliechem, Inc. Metathesis syntheses of pheromones or their components
US6215019B1 (en) * 1998-09-01 2001-04-10 Tilliechem, Inc. Synthesis of 5-decenyl acetate and other pheromone components
ATE438462T1 (de) 1998-09-10 2009-08-15 Univ New Orleans Foundation Katalysatorkomplex mit phenylindenyliden-ligand
US6478081B1 (en) * 1999-08-04 2002-11-12 Apv North America Inc. Plate heat exchanger
IL149720A0 (en) * 1999-11-18 2002-11-10 Metathesis syntheses of pheremones or their components
WO2002079126A1 (en) * 2001-03-30 2002-10-10 California Institute Of Technology Cross-metathesis reaction of functionalized and substituted olefins using group 8 transition metal carbene complexes as metathesis catalysts
JP2004035452A (ja) * 2002-07-03 2004-02-05 Honshu Chem Ind Co Ltd 脂環式モノオレフィンメタノールの製造方法
EP1735352B1 (en) 2004-03-29 2019-08-21 California Institute Of Technology Latent, high-activity olefin metathesis catalysts containing an n-heterocyclic carbene ligand
GB0514612D0 (en) 2005-07-15 2005-08-24 Sasol Technology Uk Ltd The use of a phosphorus containing ligand and a cyclic organic ligand in a metathesis catalyst
CN101460513B (zh) 2005-12-16 2014-08-27 马特里亚公司 有机金属钌配合物和制备四取代烯烃及其他受阻烯烃的相关方法
PL379879A1 (pl) 2006-06-07 2007-12-10 Umicore Ag & Co.Kg. Kompleksy rutenu i osmu, sposób ich wytwarzania oraz ich zastosowanie jako (pre)katalizatorów reakcji metatezy
DE102006043704A1 (de) 2006-09-18 2008-03-27 Umicore Ag & Co. Kg Neue Metathesekatalysatoren
WO2008140468A2 (en) * 2006-10-13 2008-11-20 Elevance Renewable Sciences, Inc. METHODS OF MAKING α, ω -DICARBOXYLIC ACID ALKENE DERIVATIVES BY METATHESIS
US7932397B2 (en) 2006-11-22 2011-04-26 Massachusetts Institute Of Technology Olefin metathesis catalysts and related methods
FR2909382B1 (fr) 2006-11-30 2009-01-23 Enscr Complexes catalytiques a base de ruthenium et utilisation de tels complexes pour la metathese d'olefines
DE102007020694A1 (de) 2007-05-03 2008-11-06 Evonik Degussa Gmbh Schwefelhaltige Metathesekatalysatoren
EP2242578B1 (en) 2008-01-25 2017-11-01 Trustees of Boston College Catalysts for metathesis reactons including enantioselective olefin metathesis
BRPI0911432B1 (pt) 2008-04-08 2018-01-02 Evonik Degussa Gmbh COMPLEXOS DE Ru-CARBENO, SEUS PROCESSOS DE PREPARAÇÃO E SEU USO
US8877936B2 (en) 2008-04-09 2014-11-04 California Institute Of Technology Ruthenium olefin metathesis catalysts bearing N-heterocyclic carbene ligands with substituted backbone
WO2010037550A1 (en) 2008-10-04 2010-04-08 Umicore Ag & Co. Kg Method for preparation of ruthenium-indenylidene carbene catalysts
US8222469B2 (en) 2009-07-15 2012-07-17 Massachusetts Institute Of Technology Catalysts and processes for the formation of terminal olefins by ethenolysis
US8362311B2 (en) 2009-09-30 2013-01-29 Massachusetts Institute Of Technology Highly Z-selective olefins metathesis
AP3604A (en) 2009-10-12 2016-02-25 Elevance Renewable Sciences Methods of refining and producing fuel from natural oil feedstocks
PL2506972T3 (pl) 2009-12-03 2019-09-30 Umicore Ag & Co. Kg Nośnikowe katalizatory metatezy olefin
EP2361683A1 (en) 2010-01-29 2011-08-31 Umicore AG & Co. KG Process for preparation of ruthenium-based carbene catalysts with chelating alkylidene ligands
EP2534140B1 (en) 2010-02-08 2018-04-11 Trustees of Boston College Efficient methods for z- or cis-selective cross-metathesis
US8546500B2 (en) 2011-05-27 2013-10-01 Massachusetts Institute Of Technology Complexes for use in metathesis reactions
JP6266509B2 (ja) 2011-06-03 2018-01-24 マサチューセッツ インスティテュート オブ テクノロジー Ｚ選択的閉環メタセシス反応
PL216649B1 (pl) 2011-06-06 2014-04-30 Univ Warszawski Nowe kompleksy rutenu, sposób ich wytwarzania oraz zastosowanie w reakcji metatezy olefin
EP2780349B1 (en) 2011-11-07 2019-02-27 Massachusetts Institute of Technology Tungsten oxo alkylidene complexes for z selective olefin metathesis
EP2838359A4 (en) 2012-03-05 2015-12-09 California Inst Of Techn SYNTHESIS OF Z-OLEFIN-CONTAINING PHEROMONES OF LEPIDOPTERA INSECTS
EP2639219B1 (en) 2012-03-14 2016-08-10 Umicore AG & Co. KG Ruthenium-based metathesis catalysts and precursors for their preparation
CN104271542A (zh) 2012-04-24 2015-01-07 艾勒旺斯可再生科学公司 来源于天然油脂复分解的不饱和脂肪醇组合物及其衍生物
GB201208589D0 (en) 2012-05-16 2012-06-27 Givaudan Sa Improvements in or relating to organic compounds
EP2679593B1 (en) 2012-06-26 2018-03-21 Umicore AG & Co. KG Method for preparation of a ruthenium indenylidene complex
WO2014018578A1 (en) * 2012-07-24 2014-01-30 Heliae Development, Llc Methods of converting mixtures of palmitoleic and oleic acid esters to high value products
US10697706B2 (en) 2012-09-25 2020-06-30 Modine Manufacturing Company Heat exchanger
EP2725030A1 (en) 2012-10-29 2014-04-30 Umicore AG & Co. KG Ruthenium-based metathesis catalysts, precursors for their preparation and their use
MX2015010583A (es) 2013-02-27 2016-04-07 Materia Inc Composiciones catalizadoras de metátesis de olefina que comprenden por lo menos dos catalizadores de metátesis de olefina metal carbeno..
US20160039737A1 (en) * 2013-03-14 2016-02-11 Materia, Inc. Use of soluble metal salts in metathesis reactions
AU2014243795B2 (en) 2013-03-14 2018-03-29 Wilmar Trading Pte Ltd Treated metathesis substrate materials and methods of making and using the same
BR112015023269B8 (pt) 2013-03-14 2022-08-16 Ximo Ag Método de formação de um produto de olefinas em uma reação de metátese a partir de uma matéria-prima compreendendo uma primeira olefina e uma segunda olefina e método para aumentar a reatividade de um composto
WO2014139030A1 (en) 2013-03-15 2014-09-18 Goussev Dmitri Complex catalysts based on amino-phosphine ligands for hydrogenation and dehydrogenation processes
GB201305858D0 (en) 2013-03-28 2013-05-15 Ximo Ag Catalyst composition
US9315604B2 (en) 2013-04-09 2016-04-19 Massachusetts Institute Of Technology Metathesis catalysts and methods thereof
WO2014172534A1 (en) 2013-04-17 2014-10-23 Massachusetts Institute Of Technology Metathesis catalysts and methods thereof
US20140330018A1 (en) 2013-05-01 2014-11-06 Massachusetts Institute Of Technology Metathesis catalysts and methods thereof
EP3008078B1 (en) 2013-06-12 2018-12-19 Trustees of Boston College Catalysts for efficient z-selective metathesis
US9441059B2 (en) 2013-06-20 2016-09-13 Massachusetts Institute Of Technology Metathesis catalysts and methods thereof
EP3019510B1 (en) 2013-07-12 2020-12-02 Verbio Vereinigte BioEnergie AG Use of immobilized molybden- und tungsten-containing catalysts in olefin cross metathesis
CN103319704B (zh) 2013-07-12 2015-06-17 南开大学 一种用10-十一碳烯酸和香草酸制备聚酯的方法
US20160122375A1 (en) 2013-07-12 2016-05-05 Ximo Ag Immobilized metathesis tungsten catalysts and use thereof in olefin metathesis
EP3107655B1 (en) 2014-02-21 2024-05-08 Massachusetts Institute of Technology Catalysts and methods for ring opening metathesis polymerization
GB201404468D0 (en) 2014-03-13 2014-04-30 Givaudan Sa Process
GB201406591D0 (en) * 2014-04-11 2014-05-28 Ximo Ag Compounds
MX2018006241A (es) 2015-11-18 2018-11-09 Provivi Inc Produccion de derivados de olefina grasa via metatesis de olefina.

Also Published As

Publication number Publication date
IL259459A (en) 2018-07-31
JP2022025109A (ja) 2022-02-09
CL2018001337A1 (es) 2018-10-26
EP3377465B1 (en) 2023-08-02
HUE063333T2 (hu) 2024-01-28
CN115215748A (zh) 2022-10-21
CA3005562A1 (en) 2017-05-26
WO2017087710A2 (en) 2017-05-26
WO2017087710A3 (en) 2017-08-17
EP4234522A3 (en) 2023-10-25
IL259459B (en) 2022-07-01
JP6970088B2 (ja) 2021-11-24
PL3377465T3 (pl) 2024-02-12
CN108473390B (zh) 2022-08-09
US9776179B2 (en) 2017-10-03
JP7348939B2 (ja) 2023-09-21
EP3377465A2 (en) 2018-09-26
BR112018009885B1 (pt) 2021-09-21
US11077433B2 (en) 2021-08-03
US20170137365A1 (en) 2017-05-18
AU2016357756A1 (en) 2018-06-14
AR108028A1 (es) 2018-07-11
US11779911B2 (en) 2023-10-10
US20180099268A1 (en) 2018-04-12
AR122037A2 (es) 2022-08-03
CL2019003183A1 (es) 2020-03-20
CA3005562C (en) 2024-05-28
EP3377465A4 (en) 2019-10-09
JP2018535983A (ja) 2018-12-06
US20200261898A1 (en) 2020-08-20
US20220032280A1 (en) 2022-02-03
CN108473390A (zh) 2018-08-31
AU2016357756B2 (en) 2021-09-30
BR112018009885A2 (pt) 2018-11-13
EP4234522A2 (en) 2023-08-30
US10596562B2 (en) 2020-03-24

Similar Documents

Publication Publication Date Title
MX2018006241A (es) Produccion de derivados de olefina grasa via metatesis de olefina.
CO2020001927A2 (es) Método de producción de composiciones farmacéuticas que comprende el virus chikungunya inmunogénico chikv-delta5nsp3
MX2023004157A (es) Composiciones de oligosacaridos para el uso como alimento para animales y sus metodos para producirlas.
MX2019002966A (es) Catalizador de oligomerizacion y procedimiento para su produccion.
MY194771A (en) Method for ketonisation of biological material
WO2018175258A8 (en) Methods and compositions for preparing nucleic acid libraries
MX387642B (es) Proceso para la preparación de etilenglicol a partir de azúcares.
HK1243322A1 (zh) 脂肪酸半胱胺缀合物和它们作为自噬的活化剂的用途
MX2016013950A (es) Metodo para producir l-aminoacidos utilizando una bacteria alcalifilica.
MX2016015132A (es) Cepas de labyrinthulomycete para producir acido docosahexanoico.
EA201691754A1 (ru) Рекомбинантный микроорганизм, экспрессирующий аналог авермектина, и его применение
MX2022015233A (es) Produccion de alcoholes grasos no saturados y acetatos de alcohol grasos no saturados en la levadura.
AR110460A1 (es) Proceso para preparar terpinen-4-ol
MX378313B (es) Produccion microbiana de dioles grasos.
EA202090501A1 (ru) Способ отделения липидов от лизированной липидосодержащей биомассы
MX2019001465A (es) Metodo de produccion de cetoenoles ciclicos sustituidos con espirocetales.
MX2020002287A (es) Metodo de produccion para polisulfato de pentosan.
MX2018004594A (es) Composiciones lubricantes y metodos para uso de las mismas.
EA201690083A1 (ru) Способ селективной гидрогенизации растительных масел
CO2017000010A2 (es) Proceso para la preparacion de ácidos 3-hidroxipicolínicos
FI20145305A7 (fi) Proteiinituotteet ja menetelmät niiden valmistamiseksi
EA201692246A1 (ru) Способ получения 2,6-диметилбензохинона
MX2018014918A (es) Esteres de tetrahidropiranilalquilo inferior y su produccion usando un compuesto de ceteno.
MX366822B (es) Composicion estabilizada liquida de baja concentracion de metsulfuron-metilo.
EA201691550A1 (ru) Промоторы, подходящие для экспрессии гетерологичных генов в дрожжах