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MX2018003375A - Composicion prepolimerica activada, estable al almacenamiento. - Google Patents

Composicion prepolimerica activada, estable al almacenamiento.

Info

Publication number
MX2018003375A
MX2018003375A MX2018003375A MX2018003375A MX2018003375A MX 2018003375 A MX2018003375 A MX 2018003375A MX 2018003375 A MX2018003375 A MX 2018003375A MX 2018003375 A MX2018003375 A MX 2018003375A MX 2018003375 A MX2018003375 A MX 2018003375A
Authority
MX
Mexico
Prior art keywords
prepolymer
storage stable
alkyl sulfoxide
prepolymer composition
curing agents
Prior art date
Application number
MX2018003375A
Other languages
English (en)
Inventor
R Doyle Thomas
Original Assignee
Lanxess Solutions Us Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lanxess Solutions Us Inc filed Critical Lanxess Solutions Us Inc
Publication of MX2018003375A publication Critical patent/MX2018003375A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
    • C08G18/0809—Manufacture of polymers containing ionic or ionogenic groups containing cationic or cationogenic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/166—Catalysts not provided for in the groups C08G18/18 - C08G18/26
    • C08G18/168—Organic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3203—Polyhydroxy compounds
    • C08G18/3206—Polyhydroxy compounds aliphatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3225—Polyamines
    • C08G18/3237—Polyamines aromatic
    • C08G18/3243—Polyamines aromatic containing two or more aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3225—Polyamines
    • C08G18/3253—Polyamines being in latent form
    • C08G18/3268—Salt complexes of polyamines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/34—Carboxylic acids; Esters thereof with monohydroxyl compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3819—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen
    • C08G18/3823—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing -N-C=O groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/44—Polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
    • C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

La adición de una pequeña cantidad de un alquilsulfóxido, p. ej., DMSO, a un prepolímero rematado con isocianato proporciona una composición prepolimérica estable al almacenamiento, en la que el prepolímero está también altamente activado hacia el curado con determinados agentes de curado bloqueados tales como complejos de coordinación de metilendianilina y sal de metal. Las composiciones de prepolímero/alquilsulfóxido son curadas por dichos agentes de curado bloqueados a bajas temperaturas y/o a una velocidad acelerada en comparación con composiciones similares que carecen del alquilsulfóxido, proporcionando elastómeros de poliuretano de alto rendimiento.
MX2018003375A 2015-09-25 2016-09-19 Composicion prepolimerica activada, estable al almacenamiento. MX2018003375A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201562232496P 2015-09-25 2015-09-25
PCT/US2016/052456 WO2017053224A1 (en) 2015-09-25 2016-09-19 Storage stable activated prepolymer composition

Publications (1)

Publication Number Publication Date
MX2018003375A true MX2018003375A (es) 2018-05-30

Family

ID=57018198

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2018003375A MX2018003375A (es) 2015-09-25 2016-09-19 Composicion prepolimerica activada, estable al almacenamiento.

Country Status (6)

Country Link
US (1) US10577450B2 (es)
JP (1) JP6855461B2 (es)
BR (1) BR112018005209B1 (es)
CA (1) CA2994186A1 (es)
MX (1) MX2018003375A (es)
WO (1) WO2017053224A1 (es)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112892190B (zh) * 2021-01-27 2023-03-10 成都中科绿生环境科技有限公司 一种化学除臭剂及其制备方法
US20240239948A1 (en) 2021-06-03 2024-07-18 Carbon, Inc. Methods for the rapid production of blocked prepolymers
CN115093540B (zh) * 2022-05-24 2023-03-17 烟台瑞特橡塑有限公司 一种高硬度聚氨酯轮胎及其制备方法
CN116082603B (zh) * 2022-12-28 2025-05-16 上海信斯帝克新材料有限公司 一种封闭异氰酸酯预聚物、预热处理双重固化3d打印树脂及成型方法

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3936409A (en) * 1969-03-10 1976-02-03 Textron, Inc. Urea-urethane compositions and films prepared therefrom
US3755261A (en) 1972-05-01 1973-08-28 Du Pont Curing of amine curable polymers diamines with complexes of selected and alkali metal salts
US3876604A (en) 1973-02-14 1975-04-08 Du Pont Curing with dispersed complexes of selected diamines and alkali salts
US3888831A (en) 1973-10-01 1975-06-10 Du Pont Curing with complexes of selected diamines and alkali metal salts
GB1499215A (en) * 1974-06-05 1978-01-25 Firestone Tire & Rubber Co Catalysis of amine curable polymers by high dielectric constant compounds
US4046743A (en) 1974-08-12 1977-09-06 The Firestone Tire & Rubber Company Catalysis of amine curable polymers by high dielectric constant compounds
US4282344A (en) 1978-11-02 1981-08-04 E. I. Du Pont De Nemours And Company Polyurethane curing agent dispersion, process and product
US4517331A (en) 1984-03-05 1985-05-14 The Goodyear Tire & Rubber Company Activating plasticizer for urethane prepolymers and complex of alkali metal salt with 4,4'-methylenedianiline
US4525568A (en) * 1984-03-09 1985-06-25 American Cyanamid Company Storage stable, one-package heat curable polyurethane adhesive compositions
US4772676A (en) 1987-11-18 1988-09-20 The Firestone Tire & Rubber Company Ambient temperature quasi-polar catalysts of amine curable polymers
EP0358406A3 (en) * 1988-09-05 1991-01-30 Sanyo Chemical Industries, Ltd. Use of a polyol as a structural component of a polyurethane resin and method of forming an article
US8217133B2 (en) * 2006-03-08 2012-07-10 Chemtura Corporation Storage stable one component polyurethane system
US20080064844A1 (en) * 2006-09-13 2008-03-13 Nagaraj Phaniraj T Isocyanate terminated polycaprolactone polyurethane prepolymers
US8754184B2 (en) 2009-11-16 2014-06-17 Chemtura Corporation Accelerated cure of isocyanate terminated prepolymers

Also Published As

Publication number Publication date
BR112018005209A2 (es) 2018-10-02
US20170088660A1 (en) 2017-03-30
BR112018005209B1 (pt) 2022-03-22
WO2017053224A1 (en) 2017-03-30
JP2018528314A (ja) 2018-09-27
CA2994186A1 (en) 2017-03-30
JP6855461B2 (ja) 2021-04-07
US10577450B2 (en) 2020-03-03

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