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MX2017010801A - Proceso no destructivo para remover metales, iones metalicos y oxidos metalicos de materiales a base de alumina. - Google Patents

Proceso no destructivo para remover metales, iones metalicos y oxidos metalicos de materiales a base de alumina.

Info

Publication number
MX2017010801A
MX2017010801A MX2017010801A MX2017010801A MX2017010801A MX 2017010801 A MX2017010801 A MX 2017010801A MX 2017010801 A MX2017010801 A MX 2017010801A MX 2017010801 A MX2017010801 A MX 2017010801A MX 2017010801 A MX2017010801 A MX 2017010801A
Authority
MX
Mexico
Prior art keywords
alumina
metal
metals
metal ions
metal oxides
Prior art date
Application number
MX2017010801A
Other languages
English (en)
Inventor
Pérez Romo Patricia
Aguilar Barrera Cándido
Navarrete Bolaños Juan
Glorindo Reyes Robles Santos
Original Assignee
Mexicano Inst Petrol
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mexicano Inst Petrol filed Critical Mexicano Inst Petrol
Priority to MX2017010801A priority Critical patent/MX2017010801A/es
Priority to EP18849315.9A priority patent/EP3673999A4/en
Priority to PCT/MX2018/050017 priority patent/WO2019039930A1/es
Priority to CA3072438A priority patent/CA3072438C/en
Priority to US16/640,454 priority patent/US11498847B2/en
Publication of MX2017010801A publication Critical patent/MX2017010801A/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/20—Regeneration or reactivation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/656—Manganese, technetium or rhenium
    • B01J23/6567—Rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/882—Molybdenum and cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/883—Molybdenum and nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B01J23/94—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B01J23/96—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/02—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/50—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using organic liquids
    • B01J38/52—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using organic liquids oxygen-containing
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F7/00—Compounds of aluminium
    • C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
    • C01F7/46—Purification of aluminium oxide, aluminium hydroxide or aluminates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00—Reforming naphtha
    • C10G35/04—Catalytic reforming
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/70—Catalyst aspects
    • C10G2300/706—Catalytic metal recovery

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)

Abstract

La presente invención se refiere a un proceso no destructivo para remover metales, iones metálicos y óxidos metálicos contenidos en materiales a base de alúmina sin destruirla, por lo que su uso principal se encuentra en la regeneración de catalizadores a base de alúmina, en la recuperación y/o reciclamiento de metales y en la reutilización de la alúmina de catalizadores usados principalmente en procesos de la industria petrolera como catalizadores de hidrotratamiento, isomerización y reformación catalítica de naftas. Al respecto, es importante señalar que dichos catalizadores son usados principalmente para eliminar compuestos de azufre, nitrógeno y silicio, así como para incrementar el número de octano e isomerizar compuestos, contenidos en las corrientes de los procesos de hidrotratamiento, isomerización y reformación catalítica de naftas de la industria petrolera. Al respecto, es importante hacer notar que los procedimientos y/o métodos convencionales conocidos para eliminar o remover metales, iones metálicos y óxidos metálicos contenidos en materiales a base de alúmina, utilizan algún ácido inorgánico o sus mezclas haciendo una digestión, lo cual modifica las propiedades de la alúmina y de cualquier otro elemento contenido en el material, destruyendo la alúmina e impidiendo su reutilización. El proceso no destructivo de la presente invención se caracteriza porque emplea un agente de extracción que secuestra metales, iones metálicos y/u óxidos metálicos presentes en los materiales a base de alúmina, sin modificar las propiedades del material a base de alúmina. El agente de extracción empleado es un alcohol, preferentemente un poliol, el cual es un material accesible comercialmente y que no requiere un grado de pureza elevado para su aplicación. El proceso no destructivo de la presente invención presenta remociones de metales (M) de por lo menos el 42 % cuando se emplea un reactor tubular de flujo continuo, y de por lo menos el 27 % cuando se emplea un reactor batch.
MX2017010801A 2017-08-23 2017-08-23 Proceso no destructivo para remover metales, iones metalicos y oxidos metalicos de materiales a base de alumina. MX2017010801A (es)

Priority Applications (5)

Application Number Priority Date Filing Date Title
MX2017010801A MX2017010801A (es) 2017-08-23 2017-08-23 Proceso no destructivo para remover metales, iones metalicos y oxidos metalicos de materiales a base de alumina.
EP18849315.9A EP3673999A4 (en) 2017-08-23 2018-07-27 NON-DESTROYING PROCESS FOR REMOVING METALS, METAL IONS AND METAL OXIDES FROM ALUMINA-BASED MATERIALS
PCT/MX2018/050017 WO2019039930A1 (es) 2017-08-23 2018-07-27 Proceso no destructivo para remover metales, iones metálicos y oxidos metálicos de materiales a base de alúmina
CA3072438A CA3072438C (en) 2017-08-23 2018-07-27 Non-destructive process for removing metals, metal ions and metal oxides from alumina-based materials
US16/640,454 US11498847B2 (en) 2017-08-23 2018-07-27 Non-destructive process for removing metals, metal ions and metal oxides from alumina-based materials

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
MX2017010801A MX2017010801A (es) 2017-08-23 2017-08-23 Proceso no destructivo para remover metales, iones metalicos y oxidos metalicos de materiales a base de alumina.

Publications (1)

Publication Number Publication Date
MX2017010801A true MX2017010801A (es) 2019-03-07

Family

ID=65439162

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2017010801A MX2017010801A (es) 2017-08-23 2017-08-23 Proceso no destructivo para remover metales, iones metalicos y oxidos metalicos de materiales a base de alumina.

Country Status (5)

Country Link
US (1) US11498847B2 (es)
EP (1) EP3673999A4 (es)
CA (1) CA3072438C (es)
MX (1) MX2017010801A (es)
WO (1) WO2019039930A1 (es)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111151236B (zh) * 2020-01-17 2022-11-22 北京诺维新材科技有限公司 一种二氧化硅负载碱金属铯废催化剂的处理方法
WO2021260138A1 (en) 2020-06-26 2021-12-30 Basf Se Shaped catalyst body for the production of ethylene oxide
EP4171800A1 (en) 2020-06-26 2023-05-03 Basf Se Process for producing a porous alpha-alumina catalyst support
US20230256415A1 (en) 2020-06-26 2023-08-17 Basf Se Production of porous alpha-alumina supports from boehmitic derived aluminas
US20240293802A1 (en) 2021-06-25 2024-09-05 Basf Se High purity tableted alpha-alumina catalyst support

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US3461064A (en) * 1967-04-28 1969-08-12 Gulf Research Development Co Process for removing vanadium from catalysts
FR2453904A1 (fr) 1979-04-09 1980-11-07 Europ Derives Manganese Procede de recuperation de metaux a partir de catalyseurs d'hydrodesulfuration d'hydrocarbures
AU562406B2 (en) 1982-09-24 1987-06-11 Chevron Research Company Recovering metal values from spent catalysts
US4973462A (en) 1987-05-25 1990-11-27 Kawatetsu Mining Company, Ltd. Process for producing high purity silica
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KR100615773B1 (ko) 1998-05-08 2006-08-25 쉘 오일 캄파니 소모된 촉매로부터 알칼리 침출에 의한 몰리브덴 및바나듐 금속의 회수방법
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SG11201500226QA (en) * 2012-07-19 2015-03-30 Chiyoda Corp Method for reactivating used hydrogenation treatment titania catalyst, and regenerated hydrogenation treatment titania catalyst

Also Published As

Publication number Publication date
CA3072438C (en) 2022-03-15
US11498847B2 (en) 2022-11-15
WO2019039930A1 (es) 2019-02-28
EP3673999A4 (en) 2021-06-02
EP3673999A1 (en) 2020-07-01
CA3072438A1 (en) 2019-02-28
US20200207635A1 (en) 2020-07-02

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