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MX2017009054A - Procedimiento de preparacion de agentes de transferencia de hidrogeno solidos mejorados para el procesamieno de crudos pesados, extrapesados y residuos, y producto resultante. - Google Patents

Procedimiento de preparacion de agentes de transferencia de hidrogeno solidos mejorados para el procesamieno de crudos pesados, extrapesados y residuos, y producto resultante.

Info

Publication number
MX2017009054A
MX2017009054A MX2017009054A MX2017009054A MX2017009054A MX 2017009054 A MX2017009054 A MX 2017009054A MX 2017009054 A MX2017009054 A MX 2017009054A MX 2017009054 A MX2017009054 A MX 2017009054A MX 2017009054 A MX2017009054 A MX 2017009054A
Authority
MX
Mexico
Prior art keywords
transfer agents
hydrogen transfer
heavy
improved solid
solid hydrogen
Prior art date
Application number
MX2017009054A
Other languages
English (en)
Inventor
Ancheyta Juárez Jorge
Olivia Alemán Vázquez Laura
Pablo Torres Mancera León
Original Assignee
Mexicano Inst Petrol
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mexicano Inst Petrol filed Critical Mexicano Inst Petrol
Priority to MX2017009054A priority Critical patent/MX2017009054A/es
Priority to US16/031,725 priority patent/US10793784B2/en
Publication of MX2017009054A publication Critical patent/MX2017009054A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J33/00—Protection of catalysts, e.g. by coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/643—Pore diameter less than 2 nm
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/31—Monomer units or repeat units incorporating structural elements in the main chain incorporating aromatic structural elements in the main chain
    • C08G2261/312—Non-condensed aromatic systems, e.g. benzene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C08G61/10—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aromatic carbon atoms, e.g. polyphenylenes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/107—Atmospheric residues having a boiling point of at least about 538 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1077—Vacuum residues
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/30—Physical properties of feedstocks or products
    • C10G2300/302—Viscosity
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/30—Physical properties of feedstocks or products
    • C10G2300/308—Gravity, density, e.g. API

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Nanotechnology (AREA)

Abstract

La presente invención se relaciona con el procedimiento de preparación de agentes de transferencia de hidrógeno sólidos mejorados obtenido a partir de un polímero con unidades que contienen la estructura de naftaleno, fenantreno o antraceno, que presentan actividad como agentes de transferencia de hidrógeno en cualquier reacción química de reducción que involucre la ruptura de dobles enlaces y en reacciones de tratamiento, hidrotratamiento y de hidrodesintegración de crudos pesados y extra-pesados y de cortes y corrientes derivadas del mismo. Estos agentes de transferencia de hidrógeno solidos mejorados, pueden estar soportados y no soportados en óxidos metálicos tales como boehmita, alúmina, sílice, titania, caolín y/o mezcla de ellos, en presencia de agentes reductores como hidrógeno, metano, o gas natural. Además, la aplicación de estos agentes de transferencia de hidrógeno sólidos mejorados obtenido a partir de un polímero con unidades que contienen la estructura de naftaleno, fenantreno o antraceno, permite mejorar propiedades de los crudos tales como viscosidad, disminución en la formación de coque, incremento en el rendimiento de destilados y de gravedad °API. Estos agentes de transferencia de hidrógeno por ser sólidos pueden ser reutilizados y recuperados del medio de reacción; además presentan una estabilidad térmica tal que permite llevar a cabo reacciones a temperaturas superiores a los 450 °C.
MX2017009054A 2017-07-10 2017-07-10 Procedimiento de preparacion de agentes de transferencia de hidrogeno solidos mejorados para el procesamieno de crudos pesados, extrapesados y residuos, y producto resultante. MX2017009054A (es)

Priority Applications (2)

Application Number Priority Date Filing Date Title
MX2017009054A MX2017009054A (es) 2017-07-10 2017-07-10 Procedimiento de preparacion de agentes de transferencia de hidrogeno solidos mejorados para el procesamieno de crudos pesados, extrapesados y residuos, y producto resultante.
US16/031,725 US10793784B2 (en) 2017-07-10 2018-07-10 Procedure for preparation of improved solid hydrogen transfer agents for processing heavy and extra-heavy crude oils and residues, and resulting product

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
MX2017009054A MX2017009054A (es) 2017-07-10 2017-07-10 Procedimiento de preparacion de agentes de transferencia de hidrogeno solidos mejorados para el procesamieno de crudos pesados, extrapesados y residuos, y producto resultante.

Publications (1)

Publication Number Publication Date
MX2017009054A true MX2017009054A (es) 2019-02-08

Family

ID=64904476

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2017009054A MX2017009054A (es) 2017-07-10 2017-07-10 Procedimiento de preparacion de agentes de transferencia de hidrogeno solidos mejorados para el procesamieno de crudos pesados, extrapesados y residuos, y producto resultante.

Country Status (2)

Country Link
US (1) US10793784B2 (es)
MX (1) MX2017009054A (es)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MX2022013720A (es) * 2022-10-31 2024-05-01 Mexicano Inst Petrol Polimeros de tipo naftaleno como agentes de transferencia de hidrogeno solidos (aths), combinados con catalizadores de hidrotratamiento para obtener diesel de ultra bajo azufre (duba).

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US272038A (en) 1883-02-13 James lobenzo gage
US2740747A (en) 1952-11-20 1956-04-03 Exxon Research Engineering Co Catalytically sweetening of naphtha
BE529891A (es) 1953-07-01
US3413212A (en) 1965-12-08 1968-11-26 Mobil Oil Corp Cracking of hydrocarbons with a crystalline aluminosilicate in the presence of a hydrogen donor
US4016106A (en) * 1976-01-05 1977-04-05 Exxon Research And Engineering Company Preparation of catalysts of predetermined pore size distribution and pore volume
DE2949935C2 (de) 1979-12-12 1985-06-05 Metallgesellschaft Ag, 6000 Frankfurt Verfahren zur Umwandlung von hochsiedenden Rohölen in erdölähnliche Produkte
US4284139A (en) 1980-02-28 1981-08-18 Conoco, Inc. Process for stimulating and upgrading the oil production from a heavy oil reservoir
CA1122914A (en) 1980-03-04 1982-05-04 Ian P. Fisher Process for upgrading heavy hydrocarbonaceous oils
US4294686A (en) 1980-03-11 1981-10-13 Gulf Canada Limited Process for upgrading heavy hydrocarbonaceous oils
US4363716A (en) 1981-02-26 1982-12-14 Greene Marvin I Cracking of heavy carbonaceous liquid feedstocks utilizing hydrogen donor solvent
US4395324A (en) 1981-11-02 1983-07-26 Mobil Oil Corporation Thermal cracking with hydrogen donor diluent
US4485004A (en) 1982-09-07 1984-11-27 Gulf Canada Limited Catalytic hydrocracking in the presence of hydrogen donor
ZA845721B (en) 1983-08-01 1986-03-26 Mobil Oil Corp Process for visbreaking resids in the presence of hydrogen-donor materials
US4642175A (en) 1984-05-03 1987-02-10 Mobil Oil Corporation Process for upgrading heavy petroleum feedstock
US4604186A (en) 1984-06-05 1986-08-05 Dm International Inc. Process for upgrading residuums by combined donor visbreaking and coking
US4640765A (en) 1984-09-04 1987-02-03 Nippon Oil Co., Ltd. Method for cracking heavy hydrocarbon oils
US4696733A (en) 1984-09-17 1987-09-29 Mobil Oil Corporation Process for selectively hydrogenating polycondensed aromatics
US4592830A (en) 1985-03-22 1986-06-03 Phillips Petroleum Company Hydrovisbreaking process for hydrocarbon containing feed streams
CA1291057C (en) 1986-12-19 1991-10-22 Junichi Kubo Method for hydrocracking heavy fraction oils
JPS63243196A (ja) 1987-03-30 1988-10-11 Nippon Oil Co Ltd 重質油の軽質化法
US7351395B1 (en) * 2003-05-06 2008-04-01 Air Products And Chemicals, Inc. Hydrogen storage by reversible hydrogenation of pi-conjugated substrates
US7594990B2 (en) 2005-11-14 2009-09-29 The Boc Group, Inc. Hydrogen donor solvent production and use in resid hydrocracking processes
MX380336B (es) 2014-11-06 2025-03-11 Mexicano Inst Petrol Uso de polimeros como donadores de hidrogeno heterogeneos para reacciones hidrogenacion.
MX375006B (es) 2015-08-06 2025-03-06 Mexicano Inst Petrol Uso de polímeros como donadores de hidrógeno heterogéneos en el mejoramiento de crudos pesados y extrapesados.

Also Published As

Publication number Publication date
US20190010409A1 (en) 2019-01-10
US10793784B2 (en) 2020-10-06

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