MX2017004083A - A method to improve halogenation reactions. - Google Patents
A method to improve halogenation reactions.Info
- Publication number
- MX2017004083A MX2017004083A MX2017004083A MX2017004083A MX2017004083A MX 2017004083 A MX2017004083 A MX 2017004083A MX 2017004083 A MX2017004083 A MX 2017004083A MX 2017004083 A MX2017004083 A MX 2017004083A MX 2017004083 A MX2017004083 A MX 2017004083A
- Authority
- MX
- Mexico
- Prior art keywords
- excess
- halogen gas
- improve
- olefin
- organic
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 4
- 238000005658 halogenation reaction Methods 0.000 title abstract 2
- 229910052736 halogen Inorganic materials 0.000 abstract 4
- 150000002367 halogens Chemical class 0.000 abstract 4
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052794 bromium Inorganic materials 0.000 abstract 1
- 239000003518 caustics Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 229910052731 fluorine Inorganic materials 0.000 abstract 1
- 239000011737 fluorine Substances 0.000 abstract 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 abstract 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
- 239000002699 waste material Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/013—Preparation of halogenated hydrocarbons by addition of halogens
- C07C17/04—Preparation of halogenated hydrocarbons by addition of halogens to unsaturated halogenated hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/245—Stationary reactors without moving elements inside placed in series
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/30—Loose or shaped packing elements, e.g. Raschig rings or Berl saddles, for pouring into the apparatus for mass or heat transfer
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/013—Preparation of halogenated hydrocarbons by addition of halogens
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/24—Stationary reactors without moving elements inside
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/30—Details relating to random packing elements
- B01J2219/304—Composition or microstructure of the elements
- B01J2219/30408—Metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/30—Details relating to random packing elements
- B01J2219/304—Composition or microstructure of the elements
- B01J2219/30466—Plastics
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/013—Preparation of halogenated hydrocarbons by addition of halogens
- C07C17/02—Preparation of halogenated hydrocarbons by addition of halogens to unsaturated hydrocarbons
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Treating Waste Gases (AREA)
Abstract
In the halogenation reaction of olefin/halo-olefin (i.e., organic), an excess amount of halogen gas (fluorine, chlorine, vaporized bromine and iodine, or their combination) is normally used in order to achieve as complete as possible conversion of the organic. In a conventional process, the excess halogen gas in the off-gas stream is scrubbed by caustic solution which increases the consumption of halogen and generates waste for disposal. The present invention provides a novel process to recover and reuse the excess halogen gas and thus reduce the operating cost of the process.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201462060272P | 2014-10-06 | 2014-10-06 | |
| US14/873,346 US9416073B2 (en) | 2014-10-06 | 2015-10-02 | Method to improve halogenation reactions |
| PCT/US2015/053950 WO2016057373A1 (en) | 2014-10-06 | 2015-10-05 | A method to improve halogenation reactions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX2017004083A true MX2017004083A (en) | 2017-07-20 |
Family
ID=55632321
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2017004083A MX2017004083A (en) | 2014-10-06 | 2015-10-05 | A method to improve halogenation reactions. |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US9416073B2 (en) |
| EP (1) | EP3204345A4 (en) |
| JP (1) | JP2017530200A (en) |
| KR (1) | KR20170063682A (en) |
| CN (1) | CN106795069A (en) |
| CA (1) | CA2961961A1 (en) |
| MX (1) | MX2017004083A (en) |
| WO (1) | WO2016057373A1 (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CZ309360B6 (en) * | 2014-10-16 | 2022-10-05 | Spolek Pro Chemickou A Hutní Výrobu, Akciová Společnost | Method of producing highly pure chlorinated alkane |
| CN106349005B (en) * | 2016-08-25 | 2018-08-28 | 浙江衢州巨新氟化工有限公司 | A kind of method of coproduction trifluoropropyl alkenes product and tetrafluoropropene class product |
| WO2020041669A1 (en) | 2018-08-24 | 2020-02-27 | Blue Cube Ip Llc | Improved process for liquid phase chlorination of chlorinated alkenes |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3475504A (en) * | 1967-05-25 | 1969-10-28 | Detrex Chem Ind | Process for the chlorination of olefinic hydrocarbons and ethylenically unsaturated chlorohydrocarbons |
| US4072728A (en) * | 1972-12-27 | 1978-02-07 | Rhone-Progil | Process for the preparation of 1,2-dichloroethane in two reaction zones by reacting chlorine with not more than 102 mole percent of ethylene |
| JPS573653B2 (en) * | 1974-05-24 | 1982-01-22 | ||
| DE2803124C2 (en) * | 1978-01-25 | 1985-05-30 | Bayer Ag, 5090 Leverkusen | Process for the preparation of perchlor -2,5-diaza-1,5-hexadiene |
| FR2478074A1 (en) * | 1980-03-17 | 1981-09-18 | Rhone Poulenc Ind | PROCESS FOR THE PREPARATION OF TRIFLUOROMETHYLBENZENES FROM THE CORRESPONDING TRICHLORO- OR TRIBROMO-METHYLBENZENES |
| US4548995A (en) | 1983-04-01 | 1985-10-22 | Exxon Research & Engineering Co. | Process for the manufacture of halogenated polymers |
| JPH03294236A (en) * | 1990-04-10 | 1991-12-25 | Nippon Mektron Ltd | Production of branched perfluorononane |
| US5504266A (en) * | 1995-05-24 | 1996-04-02 | The Dow Chemical Company | Process to make allyl chloride and reactor useful in that process |
| TW442449B (en) * | 1996-07-04 | 2001-06-23 | Hoechst Ag | Process for preparing 1,2-dichloroethane by direct chlorination |
| JP2000103747A (en) * | 1998-09-30 | 2000-04-11 | Tokuyama Corp | Method for producing liquid organic fluorinated compound and reactor |
| EP1396505A4 (en) | 2001-04-02 | 2005-04-20 | Otkrytoe Aktsionernoe Obschest | Method for continuously producing halogenated elastomers and device for carrying out said method |
| US7838708B2 (en) | 2001-06-20 | 2010-11-23 | Grt, Inc. | Hydrocarbon conversion process improvements |
| US20030049485A1 (en) * | 2001-09-06 | 2003-03-13 | Brupbacher John M. | Corrosion control coatings |
| CN102026945B (en) * | 2008-05-16 | 2013-09-18 | 昭和电工株式会社 | Manufacturing method and refining method for 1,2,3,4-tetrachlorohexafluorobutane |
| CN102341156B (en) * | 2009-03-05 | 2014-11-26 | 陶氏环球技术有限责任公司 | Method and apparatus for liquid phase reactions |
| US8779219B2 (en) * | 2009-05-13 | 2014-07-15 | Daikin Industries, Ltd. | Process for preparing chlorine-containing fluorocarbon compound |
| JP5599271B2 (en) * | 2010-09-13 | 2014-10-01 | 株式会社トクヤマ | Method for producing chloropropane |
| KR101595196B1 (en) * | 2011-07-26 | 2016-02-17 | 다이킨 고교 가부시키가이샤 | Process for preparing 2,3,3,3-tetrafluoropropene |
| US8889929B2 (en) * | 2013-02-19 | 2014-11-18 | Honeywell International Inc. | Process to make 1,1,2,3-tetrachloropropene from 1,1,3-trichloropropene and/or 3,3,3-trichloropropene |
| ES2986004T3 (en) * | 2013-03-15 | 2024-11-08 | Honeywell Int Inc | Process for manufacturing 2-chloro-1,1,1,2-tetrafluoropropane (HCFC-244bb) |
| CN104058928B (en) * | 2014-06-19 | 2017-11-21 | 巨化集团技术中心 | A kind of method that plant capacity is improved in brominated fluoric ether synthesis |
-
2015
- 2015-10-02 US US14/873,346 patent/US9416073B2/en not_active Expired - Fee Related
- 2015-10-05 CN CN201580054102.4A patent/CN106795069A/en active Pending
- 2015-10-05 CA CA2961961A patent/CA2961961A1/en not_active Abandoned
- 2015-10-05 EP EP15849151.4A patent/EP3204345A4/en not_active Withdrawn
- 2015-10-05 WO PCT/US2015/053950 patent/WO2016057373A1/en not_active Ceased
- 2015-10-05 MX MX2017004083A patent/MX2017004083A/en unknown
- 2015-10-05 KR KR1020177009263A patent/KR20170063682A/en not_active Withdrawn
- 2015-10-05 JP JP2017538173A patent/JP2017530200A/en active Pending
-
2016
- 2016-07-20 US US15/214,615 patent/US10011543B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US20160326072A1 (en) | 2016-11-10 |
| CN106795069A (en) | 2017-05-31 |
| CA2961961A1 (en) | 2016-04-14 |
| US10011543B2 (en) | 2018-07-03 |
| JP2017530200A (en) | 2017-10-12 |
| EP3204345A1 (en) | 2017-08-16 |
| EP3204345A4 (en) | 2018-05-30 |
| US9416073B2 (en) | 2016-08-16 |
| WO2016057373A1 (en) | 2016-04-14 |
| KR20170063682A (en) | 2017-06-08 |
| US20160096786A1 (en) | 2016-04-07 |
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