MX2016017106A - Proceso para la preparacion de acidos 4-alcoxi-3-hidroxipicolinico s. - Google Patents
Proceso para la preparacion de acidos 4-alcoxi-3-hidroxipicolinico s.Info
- Publication number
- MX2016017106A MX2016017106A MX2016017106A MX2016017106A MX2016017106A MX 2016017106 A MX2016017106 A MX 2016017106A MX 2016017106 A MX2016017106 A MX 2016017106A MX 2016017106 A MX2016017106 A MX 2016017106A MX 2016017106 A MX2016017106 A MX 2016017106A
- Authority
- MX
- Mexico
- Prior art keywords
- alkoxy
- preparation
- hydroxypicolinic acids
- hydroxypicolinonitrile
- dibromo
- Prior art date
Links
- UREMOXFNMQZKHW-UHFFFAOYSA-N 4,6-dibromo-3-hydroxypyridine-2-carbonitrile Chemical compound BrC1=C(C(=NC(=C1)Br)C#N)O UREMOXFNMQZKHW-UHFFFAOYSA-N 0.000 abstract 2
- HYBBIBNJHNGZAN-UHFFFAOYSA-N furfural Chemical compound O=CC1=CC=CO1 HYBBIBNJHNGZAN-UHFFFAOYSA-N 0.000 abstract 2
- 239000000126 substance Substances 0.000 abstract 2
- 238000005576 amination reaction Methods 0.000 abstract 1
- -1 amine salt Chemical class 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 125000001246 bromo group Chemical group Br* 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 238000010641 nitrile hydrolysis reaction Methods 0.000 abstract 1
- 238000006467 substitution reaction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/84—Nitriles
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K31/00—Medicinal preparations containing organic active ingredients
- A61K31/33—Heterocyclic compounds
- A61K31/395—Heterocyclic compounds having nitrogen as a ring hetero atom, e.g. guanethidine or rifamycins
- A61K31/435—Heterocyclic compounds having nitrogen as a ring hetero atom, e.g. guanethidine or rifamycins having six-membered rings with one nitrogen as the only ring hetero atom
- A61K31/44—Non condensed pyridines; Hydrogenated derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D213/54—Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/79—Acids; Esters
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/79—Acids; Esters
- C07D213/803—Processes of preparation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D307/54—Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Veterinary Medicine (AREA)
- Epidemiology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Medicinal Chemistry (AREA)
- Public Health (AREA)
- Pharmacology & Pharmacy (AREA)
- Pyridine Compounds (AREA)
- Plural Heterocyclic Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Furan Compounds (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
Abstract
4,6-Dibromo-3-hidroxipicolinonitrilo se puede preparar de furfural en una serie de etapas químicas seleccionadas de ciano-aminación, formación de sal de amina y reordenación de bromación. Los ácidos de 4-alcoxi-3-hidroxipocolínicos se pueden preparar convenientemente de 4,6-dibromo-3-hidroxipicolinonitrilo en una serie de etapas químicas seleccionadas de la sustitución de bromo, hidrolisis de nitrilo y reducción de halógeno.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201462021876P | 2014-07-08 | 2014-07-08 | |
| US201462021881P | 2014-07-08 | 2014-07-08 | |
| US201462021877P | 2014-07-08 | 2014-07-08 | |
| PCT/US2015/039565 WO2016007634A1 (en) | 2014-07-08 | 2015-07-08 | Process for the preparation of 4-alkoxy-3-hydroxypicolinic acids |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MX2016017106A true MX2016017106A (es) | 2017-05-10 |
| MX369327B MX369327B (es) | 2019-11-05 |
Family
ID=55064837
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2016017106A MX369327B (es) | 2014-07-08 | 2015-07-08 | Proceso para la preparacion de acidos 4-alcoxi-3-hidroxipicolinico s. |
| MX2016017127A MX373312B (es) | 2014-07-08 | 2015-07-08 | Proceso para la preparación de ácidos 4-alcoxi-3-hidroxipicolínicos. |
| MX2016017120A MX387774B (es) | 2014-07-08 | 2015-07-08 | Proceso para la preparacion de acidos 4-alcoxi-3-hidroxipicolinicos. |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2016017127A MX373312B (es) | 2014-07-08 | 2015-07-08 | Proceso para la preparación de ácidos 4-alcoxi-3-hidroxipicolínicos. |
| MX2016017120A MX387774B (es) | 2014-07-08 | 2015-07-08 | Proceso para la preparacion de acidos 4-alcoxi-3-hidroxipicolinicos. |
Country Status (16)
| Country | Link |
|---|---|
| US (4) | US9475771B2 (es) |
| EP (3) | EP3166611B1 (es) |
| JP (4) | JP6513178B2 (es) |
| KR (3) | KR102441177B1 (es) |
| CN (3) | CN106660957B (es) |
| BR (3) | BR112017000061B8 (es) |
| CA (3) | CA2954284C (es) |
| CO (3) | CO2017000049A2 (es) |
| DK (3) | DK3166927T3 (es) |
| ES (3) | ES2738401T3 (es) |
| IL (3) | IL249893B (es) |
| MX (3) | MX369327B (es) |
| PL (3) | PL3166611T3 (es) |
| TW (5) | TWI720647B (es) |
| WO (3) | WO2016007634A1 (es) |
| ZA (1) | ZA201700254B (es) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI720647B (zh) * | 2014-07-08 | 2021-03-01 | 美商陶氏農業科學公司 | 用於製備4-烷氧基-3-羥基吡啶甲酸之方法（三） |
| US10476159B2 (en) * | 2015-11-30 | 2019-11-12 | Electronics And Telecommunications Research Institute | Coaxial resonance coil having toroidal shape for wireless power transmission |
| US10550083B2 (en) * | 2016-01-22 | 2020-02-04 | Dow Agrosciences Llc | Processes for the preparation of 4-alkoxy-3-hydroxypicolinic acids |
| US10259789B2 (en) * | 2016-01-22 | 2019-04-16 | Dow Agrosciences Llc | Process for the preparation of 4-alkoxy-3-acetoxypicolinic acids |
| TW201733985A (zh) * | 2016-02-29 | 2017-10-01 | 陶氏農業科學公司 | 用於製備4-烷氧基-3-羥基吡啶甲酸之方法 |
| TWI733749B (zh) * | 2017-01-25 | 2021-07-21 | 美商陶氏農業科學公司 | 用於製備4-烷氧基-3-羥基吡啶甲酸之方法 |
| US10382579B2 (en) * | 2017-02-28 | 2019-08-13 | International Business Machines Corporation | Personalized location-based services for users |
| DK4153599T3 (da) * | 2020-05-22 | 2024-06-17 | Boehringer Ingelheim Int | Fremgangsmåde til at fremstille alkyl 7-amino-5-methyl-[1,2,5]oxadiazolo[3,4-b]pyridin-carboxylat |
| AR123502A1 (es) | 2020-09-15 | 2022-12-07 | Pi Industries Ltd | Nuevos compuestos de picolinamida para combatir hongos fitopatógenos |
| UY39423A (es) | 2020-09-15 | 2022-03-31 | Pi Industries Ltd | Nuevos compuestos de picolinamida para combatir hongos fitopatógenos |
| UY40356A (es) | 2022-07-18 | 2024-01-31 | Pi Industries Ltd | Un proceso para la síntesis de ácidos 4-alcoxi-3-hidroxipicolínicos e intermedios de los mismos. |
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| CH617452A5 (es) * | 1974-10-25 | 1980-05-30 | Hoffmann La Roche | |
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| DE3170401D1 (en) * | 1980-07-28 | 1985-06-13 | Ciba Geigy Ag | Triazoline derivatives and processes for their preparation |
| DE3274859D1 (en) | 1981-03-19 | 1987-02-05 | Ici Plc | Amide derivatives, processes for preparing them, their use as fungicides and pesticidal compositions containing them |
| EP1054011B1 (en) | 1998-02-06 | 2006-09-13 | Meiji Seika Kaisha Ltd. | Novel antifungal compounds and process for producing the same |
| JP4689042B2 (ja) * | 1998-11-04 | 2011-05-25 | 明治製菓株式会社 | ピコリン酸アミド誘導体、それを有効成分として含有する有害生物防除剤 |
| EP1155011A1 (en) * | 1999-02-20 | 2001-11-21 | AstraZeneca AB | Di- and tripeptide nitrile derivatives as inhibitors of cathepsin l and cathepsin s |
| EP1516874B1 (en) | 1999-07-20 | 2015-08-19 | Dow AgroSciences LLC | Fungicidal heterocyclic aromatic amides and their compositions, methods of use and preparation |
| AU780698B2 (en) | 1999-07-20 | 2005-04-14 | Dow Agrosciences Llc | Fungicidal heterocyclic aromatic amides and their compositions, methods of use and preparation |
| US20030018052A1 (en) | 1999-07-20 | 2003-01-23 | Ricks Michael J. | Fungicidal heterocyclic aromatic amides and their compositions, methods of use and preparation |
| US6355660B1 (en) | 1999-07-20 | 2002-03-12 | Dow Agrosciences Llc | Fungicidal heterocyclic aromatic amides and their compositions, methods of use and preparation |
| US20050239873A1 (en) | 1999-08-20 | 2005-10-27 | Fred Hutchinson Cancer Research Center | 2 Methoxy antimycin a derivatives and methods of use |
| ES2307525T3 (es) * | 1999-08-20 | 2008-12-01 | Dow Agrosciences Llc | Amidas aromaticas heterociclicas fungicidas y sus composiciones, metodos de uso y preparacion. |
| WO2003011857A1 (en) | 2001-07-31 | 2003-02-13 | Dow Agrosciences Llc | Reductive cleavage of the exocyclic ester of uk-2a or its derivatives and products formed therefrom |
| US6903219B2 (en) | 2001-10-05 | 2005-06-07 | Dow Agrosciences Llc | Process to produce derivatives from UK-2A derivatives |
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| WO2004056774A2 (en) * | 2002-12-19 | 2004-07-08 | Neurogen Corporation | Substituted biphenyl-4-carboxylic acid arylamide analogues as capsaicin receptor modulators |
| EA008225B1 (ru) | 2003-05-28 | 2007-04-27 | Басф Акциенгезельшафт | Фунгицидные смеси, содержащие их фунгицидное средство и посевной материал, и способ применения фунгицидных смесей |
| DE10347090A1 (de) | 2003-10-10 | 2005-05-04 | Bayer Cropscience Ag | Synergistische fungizide Wirkstoffkombinationen |
| WO2005042524A1 (en) * | 2003-10-30 | 2005-05-12 | Virochem Pharma Inc. | Pyridine carboxamide and methods for inhibiting hiv integrase |
| WO2008051533A2 (en) * | 2006-10-25 | 2008-05-02 | Takeda Pharmaceutical Company Limited | Benzimidazole compounds |
| ATE551901T1 (de) | 2007-09-26 | 2012-04-15 | Basf Se | Ternäre fungizidzusammensetzungen mit boscalid und chlorthalonil |
| KR101698610B1 (ko) | 2008-05-30 | 2017-01-20 | 다우 아그로사이언시즈 엘엘씨 | Ｑｏｉ-내성 진균 병원체의 방제 방법 |
| MX2012002579A (es) | 2009-09-01 | 2012-07-23 | Dow Agrosciences Llc | Composiciones fungicidas sinergisticas que contienen un derivado de 5-fluoropirimidina para el control de hongos en cereales. |
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| US8883811B2 (en) | 2009-10-07 | 2014-11-11 | Dow Agrosciences, Llc. | Synergistic fungicidal mixtures for fungal control in cereals |
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| CA2818925A1 (en) | 2010-11-24 | 2012-05-31 | Stemergie Biotechnology Sa | Inhibitors of the activity of complex iii of the mitochondrial electron transport chain and use thereof for treating diseases |
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| BR112014027572A2 (pt) | 2012-05-07 | 2017-06-27 | Dow Agrosciences Llc | picolinamidas macrocíclicas como fungicidas |
| BR112014027673A2 (pt) | 2012-05-07 | 2017-06-27 | Dow Agrosciences Llc | picolinamidas macrocíclicas como fungicidas |
| KR20150013690A (ko) | 2012-05-07 | 2015-02-05 | 다우 아그로사이언시즈 엘엘씨 | 살진균제로서 매크로사이클 피콜린아미드 |
| EP2938191B1 (en) | 2012-12-28 | 2018-01-31 | Dow AgroSciences LLC | Synergistic fungicidal mixtures for fungal control in cereals |
| PL2938190T3 (pl) | 2012-12-31 | 2018-05-30 | Dow Agrosciences Llc | Makrocykliczne pikolinamidy jako fungicydy |
| TWI720647B (zh) * | 2014-07-08 | 2021-03-01 | 美商陶氏農業科學公司 | 用於製備4-烷氧基-3-羥基吡啶甲酸之方法（三） |
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2015
- 2015-07-08 TW TW108136698A patent/TWI720647B/zh active
- 2015-07-08 MX MX2016017106A patent/MX369327B/es active IP Right Grant
- 2015-07-08 EP EP15818752.6A patent/EP3166611B1/en active Active
- 2015-07-08 WO PCT/US2015/039565 patent/WO2016007634A1/en not_active Ceased
- 2015-07-08 WO PCT/US2015/039569 patent/WO2016007638A1/en not_active Ceased
- 2015-07-08 WO PCT/US2015/039568 patent/WO2016007637A1/en not_active Ceased
- 2015-07-08 ES ES15819075T patent/ES2738401T3/es active Active
- 2015-07-08 DK DK15818435.8T patent/DK3166927T3/da active
- 2015-07-08 BR BR112017000061A patent/BR112017000061B8/pt active IP Right Grant
- 2015-07-08 BR BR112016031007A patent/BR112016031007B8/pt active IP Right Grant
- 2015-07-08 DK DK15818752.6T patent/DK3166611T3/da active
- 2015-07-08 TW TW108129670A patent/TW201943703A/zh unknown
- 2015-07-08 EP EP15819075.1A patent/EP3166612B1/en active Active
- 2015-07-08 KR KR1020177000806A patent/KR102441177B1/ko active Active
- 2015-07-08 KR KR1020177000805A patent/KR102450085B1/ko active Active
- 2015-07-08 US US14/794,471 patent/US9475771B2/en active Active
- 2015-07-08 EP EP15818435.8A patent/EP3166927B1/en active Active
- 2015-07-08 CA CA2954284A patent/CA2954284C/en active Active
- 2015-07-08 BR BR112017000135A patent/BR112017000135B8/pt active IP Right Grant
- 2015-07-08 TW TW104122162A patent/TWI682923B/zh active
- 2015-07-08 CN CN201580036749.4A patent/CN106660957B/zh active Active
- 2015-07-08 CN CN201580036750.7A patent/CN106573005B/zh active Active
- 2015-07-08 DK DK15819075.1T patent/DK3166612T3/da active
- 2015-07-08 JP JP2017500360A patent/JP6513178B2/ja active Active
- 2015-07-08 ES ES15818752T patent/ES2836201T3/es active Active
- 2015-07-08 KR KR1020177000726A patent/KR102436286B1/ko active Active
- 2015-07-08 JP JP2017500905A patent/JP6625115B2/ja active Active
- 2015-07-08 PL PL15818752T patent/PL3166611T3/pl unknown
- 2015-07-08 MX MX2016017127A patent/MX373312B/es active IP Right Grant
- 2015-07-08 CA CA2954276A patent/CA2954276C/en active Active
- 2015-07-08 US US14/794,430 patent/US9522887B2/en active Active
- 2015-07-08 JP JP2017500029A patent/JP6688278B2/ja active Active
- 2015-07-08 TW TW104122167A patent/TWI689498B/zh active
- 2015-07-08 US US14/794,450 patent/US9481651B2/en active Active
- 2015-07-08 MX MX2016017120A patent/MX387774B/es unknown
- 2015-07-08 PL PL15818435T patent/PL3166927T3/pl unknown
- 2015-07-08 CN CN201580036748.XA patent/CN106659724B/zh active Active
- 2015-07-08 CA CA2954167A patent/CA2954167C/en active Active
- 2015-07-08 TW TW104122166A patent/TWI684587B/zh active
- 2015-07-08 ES ES15818435T patent/ES2807622T3/es active Active
- 2015-07-08 PL PL15819075T patent/PL3166612T3/pl unknown
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2016
- 2016-10-31 US US15/339,190 patent/US9718783B2/en active Active
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2017
- 2017-01-02 IL IL249893A patent/IL249893B/en active IP Right Grant
- 2017-01-02 IL IL249891A patent/IL249891B/en active IP Right Grant
- 2017-01-03 IL IL249911A patent/IL249911B/en active IP Right Grant
- 2017-01-04 CO CONC2017/0000049A patent/CO2017000049A2/es unknown
- 2017-01-11 ZA ZA2017/00254A patent/ZA201700254B/en unknown
- 2017-01-19 CO CONC2017/0000430A patent/CO2017000430A2/es unknown
- 2017-01-19 CO CONC2017/0000446A patent/CO2017000446A2/es unknown
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2020
- 2020-01-20 JP JP2020006857A patent/JP2020073575A/ja not_active Withdrawn
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