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MX2016013879A - Procedimiento para preparar bifenilaminas a partir de anilidas por catalisis con rutenio. - Google Patents

Procedimiento para preparar bifenilaminas a partir de anilidas por catalisis con rutenio.

Info

Publication number
MX2016013879A
MX2016013879A MX2016013879A MX2016013879A MX2016013879A MX 2016013879 A MX2016013879 A MX 2016013879A MX 2016013879 A MX2016013879 A MX 2016013879A MX 2016013879 A MX2016013879 A MX 2016013879A MX 2016013879 A MX2016013879 A MX 2016013879A
Authority
MX
Mexico
Prior art keywords
anilides
producing
biphenylamines
formula
ruthenium catalysis
Prior art date
Application number
MX2016013879A
Other languages
English (en)
Inventor
Himmler Thomas
Rodefeld Lars
HUBRICH Jonathan
Ackermann Lutz
Original Assignee
Bayer Cropscience Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from EP14189192.9A external-priority patent/EP3009420A1/de
Application filed by Bayer Cropscience Ag filed Critical Bayer Cropscience Ag
Publication of MX2016013879A publication Critical patent/MX2016013879A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C231/00—Preparation of carboxylic acid amides
    • C07C231/12—Preparation of carboxylic acid amides by reactions not involving the formation of carboxamide groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C231/00—Preparation of carboxylic acid amides
    • C07C231/22—Separation; Purification; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C231/00—Preparation of carboxylic acid amides
    • C07C231/22—Separation; Purification; Stabilisation; Use of additives
    • C07C231/24—Separation; Purification
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00—Carboxylic acid amides
    • C07C233/01—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C233/02—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having nitrogen atoms of carboxamide groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals
    • C07C233/04—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having nitrogen atoms of carboxamide groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals with carbon atoms of carboxamide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
    • C07C233/07—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having nitrogen atoms of carboxamide groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals with carbon atoms of carboxamide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a six-membered aromatic ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

La presente invención se refiere a procedimiento novedoso para preparar bifenilamidas sustituidas de la fórmula general (V) (ver Fórmula) caracterizado porque se hacen reaccionar anilidas de la fórmula (II) (ver Fórmula) en un solvente distinto de tetrahidrofurano, con un compuesto orgánico de boro de la fórmula (III) (ver Fórmula) en presencia de un sistema catalizador que consiste en un catalizador de rutenio, un activador, un agente oxidante y un triflato de metal.
MX2016013879A 2014-04-25 2015-04-22 Procedimiento para preparar bifenilaminas a partir de anilidas por catalisis con rutenio. MX2016013879A (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP14166058 2014-04-25
EP14189192.9A EP3009420A1 (de) 2014-10-16 2014-10-16 Verfahren zum Herstellen von Biphenylaminen aus Aniliden durch Rutheniumkatalyse
PCT/EP2015/058636 WO2015162144A1 (de) 2014-04-25 2015-04-22 Verfahren zum herstellen von biphenylaminen aus aniliden durch rutheniumkatalyse

Publications (1)

Publication Number Publication Date
MX2016013879A true MX2016013879A (es) 2017-03-09

Family

ID=52875720

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2016013879A MX2016013879A (es) 2014-04-25 2015-04-22 Procedimiento para preparar bifenilaminas a partir de anilidas por catalisis con rutenio.

Country Status (12)

Country Link
US (2) US10246407B2 (es)
EP (1) EP3134383B1 (es)
JP (1) JP6588924B2 (es)
KR (1) KR20160148589A (es)
CN (1) CN106232573B (es)
BR (1) BR112016024801B1 (es)
DK (1) DK3134383T3 (es)
ES (1) ES2799722T3 (es)
IL (1) IL248336B (es)
MX (1) MX2016013879A (es)
TW (1) TWI669286B (es)
WO (1) WO2015162144A1 (es)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3015452A1 (de) 2014-11-03 2016-05-04 Bayer CropScience AG Verfahren zum Herstellen von Biphenylaminen aus Azobenzolen durch Rutheniumkatalyse
CN117285427B (zh) * 2023-09-28 2025-12-16 山东京博农化科技股份有限公司 一种氟唑菌酰胺中间体3',4',5'-三氟联苯基-2-胺的制备方法

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20020058089A (ko) 1999-12-09 2002-07-12 릴리 엠 씨즐러 스피허, 아네뜨 워너 살진균제로서의 피라졸카복스아미드 및 피라졸티오아미드
DE10215292A1 (de) 2002-02-19 2003-08-28 Bayer Cropscience Ag Disubstitutierte Pyrazolylcarbocanilide
DE102004041531A1 (de) * 2004-08-27 2006-03-02 Bayer Cropscience Ag Verfahren zum Herstellen von Biphenylaminen
US7709684B2 (en) 2006-06-01 2010-05-04 Basf Se Process for preparing substituted biphenyls
AR064416A1 (es) * 2006-12-21 2009-04-01 Cancer Rec Tech Ltd Derivados de purina, piridina y pirimidina condensadas con heterociclos, moduladores de pka y/o pkb, composiciones farmaceuticas que los contienen, y usos para el tratamiento de enfermedades hiperproliferativas.
EP2008991A1 (de) 2007-06-29 2008-12-31 Bayer CropScience AG Verfahren zur Herstellung von Biarylen
EP2119697A1 (en) * 2008-05-09 2009-11-18 Bayer CropScience AG Process for preparing substituted biphenylanilides
CA2760630A1 (en) * 2009-04-30 2010-11-04 Teijin Pharma Limited Quaternary ammonium salt compounds
JP2012107008A (ja) * 2010-10-29 2012-06-07 Teijin Pharma Ltd 四級アンモニウム塩化合物
IN2015DN00665A (es) 2012-08-02 2015-06-26 Bayer Cropscience Ag

Also Published As

Publication number Publication date
US10246408B2 (en) 2019-04-02
EP3134383B1 (de) 2020-04-01
IL248336B (en) 2020-05-31
KR20160148589A (ko) 2016-12-26
JP2017515808A (ja) 2017-06-15
EP3134383A1 (de) 2017-03-01
US20170044094A1 (en) 2017-02-16
CN106232573B (zh) 2020-04-21
BR112016024801A2 (pt) 2018-06-19
BR112016024801B1 (pt) 2021-01-12
TWI669286B (zh) 2019-08-21
CN106232573A (zh) 2016-12-14
US20180362446A1 (en) 2018-12-20
WO2015162144A1 (de) 2015-10-29
ES2799722T3 (es) 2020-12-21
US10246407B2 (en) 2019-04-02
DK3134383T3 (da) 2020-06-29
JP6588924B2 (ja) 2019-10-09
IL248336A0 (en) 2016-11-30
TW201604175A (zh) 2016-02-01

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