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MX2016011858A - Un procedimiento para la preparacion de un articulo de material compuesto con fibra reforzada, los articulos compuestos obtenidos y el uso de los mismos. - Google Patents

Un procedimiento para la preparacion de un articulo de material compuesto con fibra reforzada, los articulos compuestos obtenidos y el uso de los mismos.

Info

Publication number
MX2016011858A
MX2016011858A MX2016011858A MX2016011858A MX2016011858A MX 2016011858 A MX2016011858 A MX 2016011858A MX 2016011858 A MX2016011858 A MX 2016011858A MX 2016011858 A MX2016011858 A MX 2016011858A MX 2016011858 A MX2016011858 A MX 2016011858A
Authority
MX
Mexico
Prior art keywords
composite
fiber reinforced
resin
preform
composite articles
Prior art date
Application number
MX2016011858A
Other languages
English (en)
Inventor
Smolka Pavel
Grindling Josef
Scobbie Kenneth
Howland Duncan
Cherkaoui Zoubair
Original Assignee
Huntsman Advanced Mat Licensing (Switzerland) Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Huntsman Advanced Mat Licensing (Switzerland) Gmbh filed Critical Huntsman Advanced Mat Licensing (Switzerland) Gmbh
Publication of MX2016011858A publication Critical patent/MX2016011858A/es

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/0005Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor using fibre reinforcements
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/40Shaping or impregnating by compression not applied
    • B29C70/42Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles
    • B29C70/46Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using matched moulds, e.g. for deforming sheet moulding compounds [SMC] or prepregs
    • B29C70/48Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using matched moulds, e.g. for deforming sheet moulding compounds [SMC] or prepregs and impregnating the reinforcements in the closed mould, e.g. resin transfer moulding [RTM], e.g. by vacuum
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/22Di-epoxy compounds
    • C08G59/24Di-epoxy compounds carbocyclic
    • C08G59/245Di-epoxy compounds carbocyclic aromatic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50Amines
    • C08G59/5006Amines aliphatic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50Amines
    • C08G59/5026Amines cycloaliphatic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/68Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
    • C08G59/687Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used containing sulfur
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04Reinforcing macromolecular compounds with loose or coherent fibrous material
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/36Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/41Compounds containing sulfur bound to oxygen
    • C08K5/42Sulfonic acids; Derivatives thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2063/00Use of EP, i.e. epoxy resins or derivatives thereof, as moulding material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/0005Condition, form or state of moulded material or of the material to be shaped containing compounding ingredients
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2307/00Use of elements other than metals as reinforcement
    • B29K2307/04Carbon
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2363/00Characterised by the use of epoxy resins; Derivatives of epoxy resins
    • C08J2363/02Polyglycidyl ethers of bis-phenols

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Composite Materials (AREA)
  • Reinforced Plastic Materials (AREA)
  • Epoxy Resins (AREA)
  • Casting Or Compression Moulding Of Plastics Or The Like (AREA)

Abstract

Un proceso para la preparación de un artículo de material compuesto con fibra reforzada que comprende las etapas de: a) proporcionar una preforma de fibra en un molde, b) inyectar una composición de resina termoendurecible de múltiples componentes en el molde, en donde la resina composición comprende: (b1) una resina epoxi líquida, (b2) un agente de curado que comprende 1,3-bis (aminometilo) ciclohexano, y (b3) un acelerador comprende al menos un compuesto seleccionado del grupo de ácido sulfónico y sal de imidazolio de un ácido sulfónico, c) permitir que la resina impregne la preforma de fibra, d) curar la preforma impregnada de resina, e) desmoldear la pieza de material compuesto curado, facilitar la fabricación de artículos de material compuesto con tiempos de ciclo reducidos, dichos artículos de material compuesto exhiben excelentes propiedades mecánicas, especialmente el alargamiento y la resistencia a la fractura, y se pueden utilizar para la construcción de vehículos de transporte de masas, en particular en la industria automotriz y aeroespacial.
MX2016011858A 2014-03-28 2015-03-02 Un procedimiento para la preparacion de un articulo de material compuesto con fibra reforzada, los articulos compuestos obtenidos y el uso de los mismos. MX2016011858A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP14162453 2014-03-28
PCT/EP2015/054266 WO2015144391A1 (en) 2014-03-28 2015-03-02 A process for manufacturing a fiber reinforced epoxy composite article, the composite articles obtained and the use thereof

Publications (1)

Publication Number Publication Date
MX2016011858A true MX2016011858A (es) 2016-12-02

Family

ID=50478706

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2016011858A MX2016011858A (es) 2014-03-28 2015-03-02 Un procedimiento para la preparacion de un articulo de material compuesto con fibra reforzada, los articulos compuestos obtenidos y el uso de los mismos.

Country Status (8)

Country Link
US (1) US20170081487A1 (es)
EP (1) EP3122804A1 (es)
JP (1) JP2017509781A (es)
KR (1) KR20160140605A (es)
CN (1) CN106459450A (es)
CA (1) CA2940132A1 (es)
MX (1) MX2016011858A (es)
WO (1) WO2015144391A1 (es)

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WO2018000125A1 (en) * 2016-06-27 2018-01-04 Evonik Degussa Gmbh Room temperature ionic liquid curing agent
US10807277B2 (en) * 2016-11-07 2020-10-20 The Boeing Company Resin-infused short fiber composite materials
JP6878944B2 (ja) * 2017-02-21 2021-06-02 三菱瓦斯化学株式会社 エポキシ樹脂硬化剤、エポキシ樹脂組成物、繊維強化複合材
EP3450126A1 (en) * 2017-09-01 2019-03-06 Hexion Research Belgium SA Multi-component mixing and metering equipment with online stoichiometry control
US10507776B2 (en) * 2017-10-12 2019-12-17 GM Global Technology Operations LLC Fiber-reinforced composite bumper beam and crush members
KR102200972B1 (ko) * 2017-12-22 2021-01-08 (주)엘지하우시스 사출물의 표면 품질이 개선된 고압수지 이송성형 방법
JP7459861B2 (ja) 2019-03-06 2024-04-02 三菱瓦斯化学株式会社 エポキシ樹脂組成物及びその硬化物、並びに繊維強化複合材
KR102209369B1 (ko) * 2019-12-31 2021-01-28 한화큐셀앤드첨단소재 주식회사 T-rtm 공정을 활용한 천연섬유복합재 성형 방법
EP3882294A1 (de) * 2020-03-18 2021-09-22 Hilti Aktiengesellschaft Härterzusammensetzung auf basis von diaminomethylcyclohexan und 1,3-cyclo-hexan-bis(methylamin) für eine epoxidharzmasse, epoxidharzmasse und mehrkomponenten-epoxidharzsystem
EP4215559A4 (en) * 2020-09-15 2024-03-06 Mitsubishi Gas Chemical Company, Inc. EPOXY RESIN HARDENER, EPOXY RESIN COMPOSITION AND USE OF THE AMINE COMPOSITION
CN116075538B (zh) 2020-09-15 2024-03-08 三菱瓦斯化学株式会社 环氧树脂固化剂、环氧树脂组合物和胺组合物的用途
PL443393A1 (pl) * 2022-12-30 2024-07-01 Skarb Państwa Reprezentowany Przez Ministra Obrony Narodowej Wieloskładnikowa kompozycja utwardzająco-modyfikująca żywice epoksydowe

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Also Published As

Publication number Publication date
WO2015144391A1 (en) 2015-10-01
CN106459450A (zh) 2017-02-22
CA2940132A1 (en) 2015-10-01
EP3122804A1 (en) 2017-02-01
US20170081487A1 (en) 2017-03-23
JP2017509781A (ja) 2017-04-06
KR20160140605A (ko) 2016-12-07

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Owner name: HUNTSMAN ADVANCED MATERIALS LICENSING (SWITZERLAND