[go: up one dir, main page]

MX2016010843A - Composiciones de copolimero de etapa multiple para usarse en recubrimiento final de cuero. - Google Patents

Composiciones de copolimero de etapa multiple para usarse en recubrimiento final de cuero.

Info

Publication number
MX2016010843A
MX2016010843A MX2016010843A MX2016010843A MX2016010843A MX 2016010843 A MX2016010843 A MX 2016010843A MX 2016010843 A MX2016010843 A MX 2016010843A MX 2016010843 A MX2016010843 A MX 2016010843A MX 2016010843 A MX2016010843 A MX 2016010843A
Authority
MX
Mexico
Prior art keywords
stage
polymer
copolymer compositions
aqueous multi
stage copolymer
Prior art date
Application number
MX2016010843A
Other languages
English (en)
Other versions
MX380717B (es
Inventor
M Hoefler Joseph
K Hageman Bradley
Nungesser Edwin
Eryazici Ibrahim
Original Assignee
Rohm & Haas
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rohm & Haas filed Critical Rohm & Haas
Publication of MX2016010843A publication Critical patent/MX2016010843A/es
Publication of MX380717B publication Critical patent/MX380717B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C14—SKINS; HIDES; PELTS; LEATHER
    • C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
    • C14C11/00—Surface finishing of leather
    • C14C11/003—Surface finishing of leather using macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1808—C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
    • C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
    • C08G18/0823—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing carboxylate salt groups or groups forming them
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/44—Polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
    • C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
    • C08G18/625—Polymers of alpha-beta ethylenically unsaturated carboxylic acids; hydrolyzed polymers of esters of these acids
    • C08G18/6254—Polymers of alpha-beta ethylenically unsaturated carboxylic acids and of esters of these acids containing hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/005—Processes for mixing polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/54—Silicon-containing compounds
    • C08K5/541—Silicon-containing compounds containing oxygen
    • C08K5/5415—Silicon-containing compounds containing oxygen containing at least one Si—O bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C09D151/06—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C14—SKINS; HIDES; PELTS; LEATHER
    • C14B—MECHANICAL TREATMENT OR PROCESSING OF SKINS, HIDES OR LEATHER IN GENERAL; PELT-SHEARING MACHINES; INTESTINE-SPLITTING MACHINES
    • C14B7/00—Special leathers and their manufacture
    • C—CHEMISTRY; METALLURGY
    • C14—SKINS; HIDES; PELTS; LEATHER
    • C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
    • C14C11/00—Surface finishing of leather
    • C14C11/003—Surface finishing of leather using macromolecular compounds
    • C14C11/006—Surface finishing of leather using macromolecular compounds using polymeric products of isocyanates (or isothiocyanates) with compounds having active hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/04—Polymerisation in solution
    • C08F2/10—Aqueous solvent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/09—Processes comprising oligomerisation of isocyanates or isothiocyanates involving reaction of a part of the isocyanate or isothiocyanate groups with each other in the reaction mixture
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/002—Physical properties
    • C08K2201/005—Additives being defined by their particle size in general
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/54—Aqueous solutions or dispersions
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Paints Or Removers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Treatment And Processing Of Natural Fur Or Leather (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

La presente invención se refiere a una composición acuosa que comprende un polímero de emulsión acrílica de etapa múltiple que tiene un polímero de primera etapa de 0.5 hasta 4 % en peso, con base en el peso total de monómeros usados para hacer el polímero de primera etapa, de un ácido carboxílico copolímerizado o grupo de sal que contiene monómero, y que tiene 10 hasta 30 % en peso, en sólidos totales del polímero de emulsión acrílica de etapa múltiple, de un polímero de segunda etapa de 3 hasta 15 % en peso de un grupo hidroxilo copolimerizado que contiene monómero, el polímero de primera etapa que tiene una temperatura de transición vítrea (Tg) por análisis mecánico dinámico (DMA) de menos de -10°C y el polímero de segunda etapa que tiene una Tg (DMA) mayor de 80°C; y (ii) desde 25 hasta 75 % en peso, con base en el peso total de sólidos del polímero acrílico de etapa múltiple, de un poliuretano.
MX2016010843A 2015-08-31 2016-08-19 Composiciones de copolimero de etapa multiple para usarse en recubrimiento final de cuero. MX380717B (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US201562212048P 2015-08-31 2015-08-31

Publications (2)

Publication Number Publication Date
MX2016010843A true MX2016010843A (es) 2017-02-27
MX380717B MX380717B (es) 2025-03-11

Family

ID=56888920

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2016010843A MX380717B (es) 2015-08-31 2016-08-19 Composiciones de copolimero de etapa multiple para usarse en recubrimiento final de cuero.

Country Status (8)

Country Link
US (1) US10100377B2 (es)
EP (1) EP3135701B1 (es)
JP (1) JP6838892B2 (es)
KR (1) KR102556669B1 (es)
CN (1) CN106479298B (es)
BR (1) BR102016019328B1 (es)
MX (1) MX380717B (es)
TW (1) TWI705114B (es)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3594305A4 (en) * 2017-03-07 2021-01-06 Showa Denko K.K. COMPOSITION OF OIL-REPELLENT AGENT
AU2018217319B2 (en) 2017-09-05 2023-04-06 Rohm And Haas Company Process for preparing an aqueous dispersion of polymeric microspheres
DE102017127490A1 (de) * 2017-11-21 2019-05-23 Brillux Gmbh & Co. Kg Wässrige Zusammensetzung und wässriges Beschichtungsmittel
AU2018274905B2 (en) * 2017-12-13 2024-03-21 Dow Global Technologies Llc Aqueous dispersion of microspheres p-acid functionalized polymer particles
AU2018274908B2 (en) 2017-12-19 2024-02-08 Rohm And Haas Company Aqueous dispersion of polymer particles, microspheres, and polyethylene wax
KR102388191B1 (ko) * 2018-04-20 2022-04-19 디아이씨 가부시끼가이샤 수지 조성물, 및 합성 피혁
US11912871B2 (en) 2018-07-12 2024-02-27 Dow Global Technologies Llc Aqueous polymer dispersion and process of making the same
KR102845244B1 (ko) * 2018-10-24 2025-08-11 다우 실리콘즈 코포레이션 중합체 입자, 마이크로구형체 및 폴리실록산 입자의 수성 분산액
CN114555667B (zh) 2019-10-29 2024-07-30 陶氏环球技术有限责任公司 双组分聚氨酯组合物
WO2021101651A1 (en) 2019-11-19 2021-05-27 Dow Silicones Corporation Aqueous leather coating composition
CN114829491B (zh) * 2019-12-23 2023-07-28 美国陶氏有机硅公司 包含硅橡胶和交联有机聚合物的互穿网络的水性乳液
WO2021247342A1 (en) * 2020-06-04 2021-12-09 Rohm And Haas Company Coated leather article
CN111718646A (zh) * 2020-07-07 2020-09-29 上海金狮化工有限公司 一种水性聚氨酯皮革光亮剂及其制备方法
JP7627567B2 (ja) * 2020-12-24 2025-02-06 株式会社イーテック 皮革用コーティング組成物
KR102684769B1 (ko) * 2021-08-24 2024-07-11 현대트랜시스 주식회사 인조가죽 시트 커버링 제조 방법
CA3231625A1 (en) 2021-09-20 2023-03-23 Rohm And Haas Company Leather covered game ball
CN114262563A (zh) * 2022-01-13 2022-04-01 重庆韩拓科技有限公司 一种环保型汽车内饰涂料及其制备方法
CN115368792B (zh) * 2022-09-28 2023-03-28 广州海豚新材料有限公司 水性皮革边油及其制备方法和应用
CN120981626A (zh) 2023-10-27 2025-11-18 美国陶氏有机硅公司 硅酮-(甲基)丙烯酸酯共聚物乳液及其制备以及乳液赋予纺织品拒油性的用途
WO2025106269A1 (en) 2023-11-16 2025-05-22 Dow Global Technologies Llc Aqueous coating composition containing an aminosiloxane ester copolymer and a polyurethane binder, and methods for preparation and use thereof
WO2025106268A1 (en) 2023-11-16 2025-05-22 Dow Global Technologies Llc Aqueous coating composition containing an aminosiloxane ester copolymer, method for preparation of the aqueous coating composition, and use for treating leather
WO2025216964A1 (en) 2024-04-11 2025-10-16 Dow Silicones Corporation Aqueous coating composition containing a hydroxyl – functional aminosiloxane ester copolymer, method for preparation thereof, and use for leather treatment

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4325856A (en) 1980-01-02 1982-04-20 The Dow Chemical Company Sequential emulsion polymerization process
DE3443964A1 (de) * 1984-12-01 1986-06-12 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von polymer-dispersionen, die blockfeste filme bilden
US4814373A (en) 1984-12-20 1989-03-21 Rohm And Haas Company Modified latex polymer composition
US5185387A (en) 1989-03-16 1993-02-09 Rohm Gmbh Aqueous synthetic resin dispersion
US5328952A (en) * 1992-02-14 1994-07-12 Rohm And Haas Company Multi-stage polymer latex cement modifier and process of making
WO1994004581A1 (en) 1992-08-13 1994-03-03 Ppg Industries, Inc. Waterborne latices adapted for spray application
JP3358437B2 (ja) * 1996-04-15 2002-12-16 東洋インキ製造株式会社 水性感圧接着剤
US6153690A (en) 1996-05-29 2000-11-28 Rohm And Haas Company Method of producing isocyanate-modified latex polymer
ATE230422T1 (de) * 1997-03-03 2003-01-15 Roehm Gmbh Verfahren zur herstellung von wässrigen dispersionen als grundierung für heisssiegelkleber
DE69914333T2 (de) 1998-06-23 2004-11-18 Akzo Nobel N.V. Wässrige beschichtungszusammensetzung mit eimem additionspolymer und einem rheologiemodifiziermittel
CZ20023184A3 (cs) 2000-03-24 2003-03-12 Atofina Kompozice pro úpravu usní obsahující vodné disperze polymerů, jež jsou filmotvorné za nepřítomnosti organického rozpouštědla
CA2343423A1 (en) * 2000-05-31 2001-11-30 Rohm And Haas Company Leather coating composition
TWI256416B (en) * 2003-06-02 2006-06-11 Rohm & Haas Aqueous leather treatment composition and method of use
EP1837362A1 (de) * 2006-03-24 2007-09-26 Solvay Infra Bad Hönningen GmbH Durch Coploymerisate olefinisch ungesättigter Monomere modifizierte Partikel
KR20100137490A (ko) 2008-03-12 2010-12-30 다우 코닝 코포레이션 실리콘 중합체 분산제와 이를 형성하는 방법
CN104487509B (zh) * 2012-05-24 2016-05-04 巴斯夫欧洲公司 水性粘合剂组合物
JP6247492B2 (ja) 2012-11-06 2017-12-13 ダウ グローバル テクノロジーズ エルエルシー 水性皮革コーティング組成物および皮革をコーティングするための方法
GB201402179D0 (en) * 2014-02-07 2014-03-26 Dow Corning Surface treatment

Also Published As

Publication number Publication date
BR102016019328A2 (pt) 2017-03-07
CN106479298A (zh) 2017-03-08
US10100377B2 (en) 2018-10-16
CN106479298B (zh) 2020-06-23
US20170058371A1 (en) 2017-03-02
MX380717B (es) 2025-03-11
KR20170026147A (ko) 2017-03-08
TWI705114B (zh) 2020-09-21
BR102016019328B1 (pt) 2022-04-12
EP3135701B1 (en) 2019-01-09
EP3135701A1 (en) 2017-03-01
JP6838892B2 (ja) 2021-03-03
JP2017048381A (ja) 2017-03-09
TW201708428A (zh) 2017-03-01
KR102556669B1 (ko) 2023-07-17

Similar Documents

Publication Publication Date Title
MX2016010843A (es) Composiciones de copolimero de etapa multiple para usarse en recubrimiento final de cuero.
MX388406B (es) Composiciones polimericas en emulsion de multi-etapas acuosas para usarse en aplicaciones de ebanisteria.
MY188161A (en) Pressure sensitive adhesive compositions and methods for preparing same
MX2018000740A (es) Aditivo de recubrimiento.
IN2014DN05910A (es)
EA201692184A1 (ru) Асфальтовая композиция
EA201691318A1 (ru) Блок-сополимер и клеевая композиция
TW201614029A (en) Adhesive compositions comprising a silsesquioxane polymer crosslinker, articles and methods
WO2016057270A3 (en) Titanium phosphinimide and titanium iminoimidazolidide catalyst systems with activator-supports
MX2016010790A (es) Resinas acrilicas y composiciones en polvo para recubrimiento y substratos recubiertos con polvo que incluyen las mismas.
EA201290640A1 (ru) Двухкомпонентные полиуретановые композиции и покрытия на водной основе
IN2012DE01025A (es)
MY181589A (en) Copolymer for antifouling coating composition, antifouling coating composition, antifouling coating film
MX2018006918A (es) Composiciones polimericas liquidas.
PH12017502077A1 (en) Copolymers of bicyclic (meth)acrylates and alkyl (meth)acrylates and their use as rheology modifiers in fuels
EP4241797A3 (en) (meth)acrylamide polymers for contact lens and intraocular lens
JP2016536436A5 (es)
TW201129648A (en) Aqueous coating composition
MX2018006530A (es) Polimeros de emulsion y composiciones y composiciones de recubrimiento resistentes a manchas fabricadas de los mismos.
MY176754A (en) Method for processing cooling water system
BR112017024047A2 (pt) copolímero, pacote aditivo para combustíveis, método de preparação de copolímero, e uso de polímero ou pacote de aditivo
BR112015019616A2 (pt) formulação de filtro solar
MX2020002379A (es) Composiciones adhesivas sensibles a la presion a base de agua y metodos para elaborarlas.
MX2017007091A (es) Composiciones sensibles a la presion basadas en una dispersion acuosa de polimero de caucho modificado.
BR112015027832A2 (pt) copolímeros estatísticos livres de açucar feitos pelo menos três monômeros