MX2016009095A - Proceso para preparar microcapsulas aminoplasticas. - Google Patents
Proceso para preparar microcapsulas aminoplasticas.Info
- Publication number
- MX2016009095A MX2016009095A MX2016009095A MX2016009095A MX2016009095A MX 2016009095 A MX2016009095 A MX 2016009095A MX 2016009095 A MX2016009095 A MX 2016009095A MX 2016009095 A MX2016009095 A MX 2016009095A MX 2016009095 A MX2016009095 A MX 2016009095A
- Authority
- MX
- Mexico
- Prior art keywords
- aminoplastic
- microcapsules
- prepare
- polyisocyanate
- encapsulating
- Prior art date
Links
- 239000003094 microcapsule Substances 0.000 title abstract 3
- 239000013543 active substance Substances 0.000 abstract 1
- 229920003180 amino resin Polymers 0.000 abstract 1
- 239000012792 core layer Substances 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 239000002304 perfume Substances 0.000 abstract 1
- 229920001228 polyisocyanate Polymers 0.000 abstract 1
- 239000005056 polyisocyanate Substances 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/06—Making microcapsules or microballoons by phase separation
- B01J13/14—Polymerisation; cross-linking
- B01J13/16—Interfacial polymerisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/06—Making microcapsules or microballoons by phase separation
- B01J13/14—Polymerisation; cross-linking
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/0007—Aliphatic compounds
- C11B9/0015—Aliphatic compounds containing oxygen as the only heteroatom
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/0007—Aliphatic compounds
- C11B9/0015—Aliphatic compounds containing oxygen as the only heteroatom
- C11B9/0019—Aliphatic compounds containing oxygen as the only heteroatom carbocylic acids; Salts or esters thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/0026—Essential oils; Perfumes compounds containing an alicyclic ring not condensed with another ring
- C11B9/0034—Essential oils; Perfumes compounds containing an alicyclic ring not condensed with another ring the ring containing six carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/0061—Essential oils; Perfumes compounds containing a six-membered aromatic ring not condensed with another ring
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/0069—Heterocyclic compounds
- C11B9/0073—Heterocyclic compounds containing only O or S as heteroatoms
- C11B9/0076—Heterocyclic compounds containing only O or S as heteroatoms the hetero rings containing less than six atoms
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3723—Polyamines or polyalkyleneimines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
- C11D3/502—Protected perfumes
- C11D3/505—Protected perfumes encapsulated or adsorbed on a carrier, e.g. zeolite or clay
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Dispersion Chemistry (AREA)
- Manufacturing Of Micro-Capsules (AREA)
- Fats And Perfumes (AREA)
- Cosmetics (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
La presente invención se refiere a una microcápsula de núcleo-capa externa aminoplástica reticulada con un poliisocianato y que encapsula un aceite de perfume, preparada con una cantidad muy baja de la resina aminoplástica. También se proporciona el uso de las microcápsulas aminoplásticas en productos para el consumidor ricos en el agente activo, en polvo y acuosos, líquidos.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP14152610 | 2014-01-27 | ||
| PCT/EP2015/051329 WO2015110568A1 (en) | 2014-01-27 | 2015-01-23 | Process for preparing aminoplast microcapsules |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MX2016009095A true MX2016009095A (es) | 2016-10-13 |
| MX374831B MX374831B (es) | 2025-03-06 |
Family
ID=49998164
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2016009095A MX374831B (es) | 2014-01-27 | 2015-01-23 | Proceso para preparar microcapsulas aminoplasticas. |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US10124309B2 (es) |
| EP (1) | EP3099404B1 (es) |
| JP (1) | JP6590815B2 (es) |
| CN (1) | CN105934272B (es) |
| BR (1) | BR112016017264B1 (es) |
| ES (1) | ES2671409T3 (es) |
| MX (1) | MX374831B (es) |
| TR (1) | TR201808534T4 (es) |
| WO (1) | WO2015110568A1 (es) |
Families Citing this family (49)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104011193B (zh) * | 2011-12-22 | 2017-04-12 | 弗门尼舍有限公司 | 制备聚脲微胶囊的方法 |
| EP3061500B1 (de) * | 2015-02-25 | 2019-07-10 | Symrise AG | Stabile Dispersion |
| EP3497191A1 (en) * | 2016-08-08 | 2019-06-19 | Givaudan SA | Improvements in or relating to organic compounds |
| GB201621887D0 (en) * | 2016-12-21 | 2017-02-01 | Givaudan Sa | Improvements in or relating to organic compounds |
| WO2018115330A1 (en) | 2016-12-22 | 2018-06-28 | Firmenich Sa | Microcapsules having a mineral layer |
| CN110099743B (zh) | 2016-12-22 | 2022-06-14 | 弗门尼舍有限公司 | 具有矿物层的微胶囊 |
| DE202017007590U1 (de) | 2016-12-22 | 2023-03-21 | Firmenich Sa | Hochwirksame Parfüm-Mikrokapseln mit Dichteausgleich |
| MX2019009936A (es) | 2017-03-24 | 2019-10-09 | Firmenich & Cie | Composicion solida reforzadora del aroma. |
| WO2018172514A1 (en) | 2017-03-24 | 2018-09-27 | Firmenich Sa | Solid scent booster composition |
| US11857659B2 (en) | 2017-06-15 | 2024-01-02 | Firmenich Sa | Rinse-off conditioner compositions comprising microcapsules |
| CN111163840B (zh) | 2017-11-15 | 2022-06-24 | 弗门尼舍有限公司 | 改善沉积的微胶囊 |
| JP7275116B2 (ja) | 2017-12-14 | 2023-05-17 | フイルメニツヒ ソシエテ アノニム | 活性成分を放出する方法 |
| EP3668479B8 (en) | 2017-12-14 | 2023-04-26 | Firmenich SA | Process for preparing a powdered composition |
| US11484480B2 (en) | 2018-01-26 | 2022-11-01 | Firmenich Sa | Hair coloring composition comprising microcapsules |
| CN111417709B (zh) | 2018-03-05 | 2022-06-14 | 弗门尼舍有限公司 | 包含防火剂的粉末状组合物 |
| JP7405770B2 (ja) * | 2018-09-26 | 2023-12-26 | フイルメニツヒ ソシエテ アノニム | 粉末洗剤組成物 |
| EP3823469B1 (en) | 2018-12-19 | 2023-09-06 | Firmenich SA | Sweetener formulations and uses |
| FR3092502A1 (fr) | 2019-02-12 | 2020-08-14 | Européenne D'application Des Cristaux Liquides | Formulation de microcapsules à membrane aminoplaste renforcée |
| WO2020200916A1 (en) | 2019-04-04 | 2020-10-08 | Firmenich Sa | Mogroside compounds and uses thereof |
| FR3099711B1 (fr) * | 2019-08-06 | 2021-07-16 | Microcapsules Tech | Procédé de fabrication de microcapsules renfermant un actif lipophile, microcapsules préparées par ce procédé et leur utilisation |
| US20220273011A1 (en) | 2019-11-11 | 2022-09-01 | Firmenich Sa | Gingerol compounds and their use as flavor modifiers |
| WO2021118864A1 (en) | 2019-12-13 | 2021-06-17 | Firmenich Incorporated | Taste modifying compositions and uses thereof |
| EP4040986B1 (en) | 2019-12-13 | 2025-12-24 | Firmenich Incorporated | Taste modifying compositions and uses thereof |
| WO2021126569A1 (en) | 2019-12-18 | 2021-06-24 | Firmenich Incorporated | Taste modifying compositions and uses thereof |
| CN114727636A (zh) | 2019-12-18 | 2022-07-08 | 弗门尼舍公司 | 味道改良组合物及其用途 |
| EP4048086A1 (en) | 2020-03-05 | 2022-08-31 | Firmenich SA | 11-oxo-cucurbitanes and their use as flavor modifiers |
| EP4055006A1 (en) | 2020-04-17 | 2022-09-14 | Firmenich SA | Amino acid derivatives and their use as flavor modifiers |
| GB202005756D0 (en) * | 2020-04-21 | 2020-06-03 | Givaudan Sa | Improvements in or relating to organic compounds |
| US20230276835A1 (en) | 2020-07-24 | 2023-09-07 | Firmenich Incorporated | Savory taste enhancement via transmembrane region binding |
| CN114901081B (zh) | 2020-10-13 | 2023-03-24 | 弗门尼舍有限公司 | 丙二酰基甜菊醇糖苷及其可食用用途 |
| CN114468199A (zh) | 2020-10-27 | 2022-05-13 | 弗门尼舍有限公司 | 共轭二炔及其作为风味改良剂的用途 |
| WO2022155667A1 (en) | 2021-01-15 | 2022-07-21 | Firmenich Incorporated | Sweetener compositions comprising mogrosides and uses thereof |
| US20240090547A1 (en) | 2021-01-15 | 2024-03-21 | Firmenich Incorporated | Sweetener compositions comprising mogrosides and uses thereof |
| US20240188613A1 (en) | 2021-01-15 | 2024-06-13 | Firmenich Incorporated | Sweetener compositions comprising mogrosides and uses thereof |
| JP2024517692A (ja) | 2021-04-26 | 2024-04-23 | フィルメニッヒ インコーポレイテッド | アミド化合物および風味修飾剤としてのその使用 |
| EP4304386A1 (en) | 2021-04-26 | 2024-01-17 | Firmenich Incorporated | Amide compounds and their use as flavor modifiers |
| WO2022238249A2 (en) | 2021-05-11 | 2022-11-17 | Firmenich Sa | Process of making gingerol compounds and their use as flavor modifiers |
| EP4301158A1 (en) | 2021-06-02 | 2024-01-10 | Firmenich SA | Deacetylation process, compositions, and uses thereof |
| EP4362704A1 (en) | 2021-06-29 | 2024-05-08 | Firmenich SA | Licorice compounds and their use as flavor modifiers |
| WO2023278226A1 (en) | 2021-06-29 | 2023-01-05 | Firmenich Incorporated | Mogroside compounds and their comestible use |
| US20250024871A1 (en) | 2021-11-16 | 2025-01-23 | Firmenich Incorporated | Amide compounds and their use as flavor modifiers |
| CN118829632A (zh) | 2022-03-11 | 2024-10-22 | 弗门尼舍公司 | 黄烷酮化合物及其作为风味修饰剂的用途 |
| WO2023172372A1 (en) | 2022-03-11 | 2023-09-14 | Firmenich Incorporated | Amide compounds and their use as flavor modifiers |
| US20250194649A1 (en) | 2022-03-25 | 2025-06-19 | Firmenich Sa | Fatty acid amides and their use as flavor modifiers |
| EP4611928A1 (en) | 2022-11-03 | 2025-09-10 | Symrise AG | Microcapsules, process for the preparation of microcapsules and use of microcapsules for perfuming a consumer product |
| WO2024177901A1 (en) | 2023-02-25 | 2024-08-29 | Firmenich Incorporated | Flavanone compounds and their use as flavor modifiers |
| WO2025073683A1 (en) | 2023-10-04 | 2025-04-10 | Firmenich Sa | Flavanone compounds and their use as flavor modifiers |
| WO2025132803A1 (en) | 2023-12-20 | 2025-06-26 | Firmenich Sa | 3-hydroxybenzoic acid and its use as a flavor modifier |
| WO2025252858A1 (en) | 2024-06-04 | 2025-12-11 | Eurofragance Sl | Delivery systems with low polymer content |
Family Cites Families (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA729145A (en) | 1962-03-20 | 1966-03-01 | The Procter & Gamble Company | Built liquid detergent |
| DE1543970B2 (de) | 1965-11-29 | 1977-04-21 | Witco Chemical Corp., New York, N. Y. (V.StA.) | Verfahren zur herstellung stabiler, fluessiger, polyfunktioneller detergentien- mischungen |
| DE3008658A1 (de) | 1979-03-09 | 1980-09-11 | Fuji Photo Film Co Ltd | Verfahren zur herstellung von mikrokapseln |
| JPS6064627A (ja) * | 1983-09-19 | 1985-04-13 | Kureha Chem Ind Co Ltd | 疎水性の揮発性物質を芯物質とするマイクロカプセル |
| DE3621536A1 (de) | 1986-06-27 | 1988-01-07 | Henkel Kgaa | Fluessiges waschmittel und verfahren zu seiner herstellung |
| DE69432297T2 (de) * | 1993-12-28 | 2004-02-05 | Otsuka Kagaku K.K. | Verfahren zur herstellung einer mikrokapsel eines hydrophoben heilmittels |
| MX276989B (es) | 2002-08-14 | 2010-06-30 | Quest Int Serv Bv | Composiciones que comprenden material encapsulado. |
| BRPI0410210A (pt) * | 2003-05-11 | 2006-05-09 | Univ Ben Gurion | processos para preparar microcápsulas de óleo essencial e para formar microcápsulas de óleos essencias |
| US20050112152A1 (en) | 2003-11-20 | 2005-05-26 | Popplewell Lewis M. | Encapsulated materials |
| US20070161534A1 (en) | 2003-11-28 | 2007-07-12 | Renee Boerefijn | Detergent compositions with improved malodour properties and process to make them |
| US20060248665A1 (en) | 2005-05-06 | 2006-11-09 | Pluyter Johan G L | Encapsulated fragrance materials and methods for making same |
| GB0513803D0 (en) | 2005-07-06 | 2005-08-10 | Unilever Plc | Fabric care composition |
| EP1767185B2 (en) | 2005-09-23 | 2018-11-28 | Takasago International Corporation | Core shell capsules containing an oil or waxy solid |
| GB2432843A (en) | 2005-12-02 | 2007-06-06 | Unilever Plc | Perfume carrying polymeric particle |
| GB2432851A (en) | 2005-12-02 | 2007-06-06 | Unilever Plc | Laundry composition including polymer particles containing perfume and a non-ionic deposition aid |
| GB2432852A (en) | 2005-12-02 | 2007-06-06 | Unilever Plc | Laundry composition including polymer particles containing perfume and a cationic deposition aid |
| GB0524659D0 (en) | 2005-12-02 | 2006-01-11 | Unilever Plc | Improvements relating to fabric treatment compositions |
| GB0524665D0 (en) | 2005-12-02 | 2006-01-11 | Unilever Plc | Laundry composition |
| GB2432850A (en) | 2005-12-02 | 2007-06-06 | Unilever Plc | Polymeric particle comprising perfume and benefit agent, in particular a laundry composition |
| WO2007100501A2 (en) | 2006-02-28 | 2007-09-07 | Appleton Papers Inc. | Benefit agent containing delivery particle |
| ES2358178T3 (es) | 2006-08-01 | 2011-05-06 | The Procter And Gamble Company | Partícula liberadora que contiene un agente beneficioso. |
| DE602008006169D1 (de) | 2007-02-13 | 2011-05-26 | Givaudan Sa | Mikrokapseln |
| EP2204155A1 (en) * | 2008-12-30 | 2010-07-07 | Takasago International Corporation | Fragrance composition for core shell microcapsules |
| BR112012032491A2 (pt) | 2010-06-25 | 2016-12-13 | Firmenich & Cie | microcápsulas estáveis isentas de formaldeído |
| GB201010701D0 (en) * | 2010-06-25 | 2010-08-11 | Givaudan Sa | Process for producing microcapsules |
| ES2683315T3 (es) * | 2011-11-10 | 2018-09-26 | Firmenich Sa | Microcápsulas estables libres de formaldehído |
| CN104011193B (zh) | 2011-12-22 | 2017-04-12 | 弗门尼舍有限公司 | 制备聚脲微胶囊的方法 |
-
2015
- 2015-01-23 TR TR2018/08534T patent/TR201808534T4/tr unknown
- 2015-01-23 JP JP2016548681A patent/JP6590815B2/ja active Active
- 2015-01-23 WO PCT/EP2015/051329 patent/WO2015110568A1/en not_active Ceased
- 2015-01-23 MX MX2016009095A patent/MX374831B/es active IP Right Grant
- 2015-01-23 EP EP15702194.0A patent/EP3099404B1/en active Active
- 2015-01-23 ES ES15702194.0T patent/ES2671409T3/es active Active
- 2015-01-23 US US15/114,511 patent/US10124309B2/en active Active
- 2015-01-23 BR BR112016017264-7A patent/BR112016017264B1/pt active IP Right Grant
- 2015-01-23 CN CN201580005859.4A patent/CN105934272B/zh active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN105934272B (zh) | 2020-03-20 |
| ES2671409T3 (es) | 2018-06-06 |
| EP3099404A1 (en) | 2016-12-07 |
| JP6590815B2 (ja) | 2019-10-16 |
| EP3099404B1 (en) | 2018-03-21 |
| CN105934272A (zh) | 2016-09-07 |
| TR201808534T4 (tr) | 2018-07-23 |
| US20160346752A1 (en) | 2016-12-01 |
| BR112016017264B1 (pt) | 2021-09-08 |
| MX374831B (es) | 2025-03-06 |
| BR112016017264A2 (es) | 2017-08-08 |
| JP2017504629A (ja) | 2017-02-09 |
| WO2015110568A1 (en) | 2015-07-30 |
| US10124309B2 (en) | 2018-11-13 |
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